Changes In Surface Morphology Research Articles

Effect of Chloride Ions on the Electrochemical Performance of Magnesium Metal‐Organic‐Frameworks‐Based Semi‐Solid Electrolytes

AbstractThe majority of research on magnesium (Mg) electrolytes has focused on enhancing reversible Mg deposition, often employing chloride‐containing electrolytes. However, there is a notable gap in the literature regarding the influence of chloride ions in semi‐solid Mg electrolytes. In this study, we systematically explore the impact of chloride ions on Mg deposition/dissolution on a copper (Cu) anode using a semi‐solid electrolyte composed of Mg‐based mixed metal‐organic frameworks, MgCl2 and Mg[TFSI]2. We separate the Mg deposition/dissolution process from changes in the anode's surface morphology In this respect, the morphological and compositional transformations in the electrolyte and electrode following galvanostatic cycling are meticulously investigated. Initial potential cycling reveals the feasibility of Mg deposition/dissolution on Cu electrodes, albeit with reduced reversibility in subsequent cycles. Extending the upper potential limit to 4.0 V vs. Mg/Mg2+ enhances Mg dissolution, attributed to chloride ions facilitating Cu surface dissolution. Our findings provide insights into optimizing semi‐solid electrolytes for advanced Magnesium battery technologies.

Surface Self-Diffusion Induced Sintering of Nanoparticles.

Despite the critical role of sintering phenomena in constraining the long-term durability of nanosized particles, a clear understanding of nanoparticle sintering has remained elusive due to the challenges in atomically tracking the neck initiation and discerning different mechanisms. Through the integration of in situ transmission electron microscopy and atomistic modeling, this study uncovers the atomic dynamics governing the neck initiation of Pt-Fe nanoparticles via a surface self-diffusion process, allowing for coalescence without significant particle movement. Real-time imaging reveals that thermally activated surface morphology changes in individual nanoparticles induce significant surface self-diffusion. The kinetic entrapment of self-diffusing atoms in the gaps between closely spaced nanoparticles leads to the nucleation and growth of atomic layers for neck formation. This surface self-diffusion-driven sintering process is activated at a relatively lower temperature compared to the classic Ostwald ripening and particle migration and coalescence processes. The fundamental insights have practical implications for manipulating the morphology, size distribution, and stability of nanostructures by leveraging surface self-diffusion processes.

Comprehensive Screening of Plasma-Facing Materials for Nuclear Fusion

Plasma-facing materials (PFMs) represent one of the most significant challenges for the design of future nuclear fusion reactors. Inside the reactor, the divertor will experience the harshest material environment: intense bombardment of neutrons and plasma particles coupled with extremely large and intermittent heat fluxes. The material designated to cover this role in ITER is tungsten. While no other materials have shown the potential to match the properties of tungsten, many drawbacks associated with its application remain, including cracking and erosion induced by a low recrystallization temperature combined with a high ductile-brittle transition temperature and neutron-initiated embrittlement; surface morphology changes (helium bubbles and fuzz layer) due to plasma-tungsten interaction with subsequent risk of spontaneous material melting and delamination; and low oxidation resistance in the case of air contamination. Exploring alternatives to tungsten requires the design of a multivariable optimization problem. This work aims to produce a structured and comprehensive material screening of PFM candidates based on known inorganic materials. The method applied in this study to identify the most promising PFM candidates combines peer-reviewed data present in the PAULING FILE database and first-principles density-function theory calculations focusing on two key PFM defects—namely, the sputtering of surface atoms and the incorporation of interstitial hydrogen, respectively characterized by the surface binding energy and the interstitial formation energy. The crystal structures and their related properties, extracted from the PAULING FILE, are ranked according to the heat-balance equation of a PFM subjected to the heat loads in the divertor region of an ITER-like tokamak. The materials satisfying the requirements are critically compared with the state-of-the-art in plasma-facing materials research and in studies of refractory materials exposed to high temperatures, plasma, and neutron bombardment. This comparison assesses their thermo-mechanical properties under such conditions, identifying a subset of promising materials for first-principles electronic structure calculations. Most previously known and extensively studied PFMs, such as tungsten, molybdenum, and carbon-based materials, are captured by this screening process, confirming its reliability. Additionally, less familiar refractory materials suggest performance that calls for further investigations. Published by the American Physical Society 2024

Evolution of tool wear and machining quality during dry milling of AlCoCrFeNi2.1 eutectic high entropy alloy

AlCoCrFeNi2.1, a new class of eutectic high entropy alloy (EHEA) has drawn significant interest owing to the lamellar structure of alternating face-centered cubic (FCC) and B2 phases. Properties such as high strength and high plasticity render the machining of this alloy challenging. Addressing this issue, the milling experiments were conducted under dry conditions to investigate the machining quality of AlCoCrFeNi2.1 EHEA as well as the tool wear. The cutting temperature and cutting force were measured to explain the changes in tool wear and machining quality. The tool wear mechanisms and evolution modes were clarified. Finally, the change of surface roughness and surface morphology under different parameters were analyzed and the characterization method of plastic flow marked by B2 phase was proposed. Results showed that both the cutting temperature and cutting force increase as the milling parameters become larger. The width of flank wear increases with the increase of the cutting speed and the feed rate when the volume of material removal volume is constant. The tool wear modes evolved differently with different cutting parameters, for instance, abrasive wear dominated while the cutting speed was less than 80 m/min, but for higher speeds up to 110 m/min, adhesive wear and coating peeling occurred. As the cutting speed increases further, crater wear on the rake face starts to arise in addition to the flank wear. Abrasive wear and adhesive wear with increasing feed rate were dominant until a certain threshold (0.10 mm/tooth) beyond which the coating peels off the tool. Furthermore, chipping occurred for a higher feed rate of 0.14 mm/tooth. In particular, the formation of tool adhesive wear is mainly caused by the FCC phase adheres. In terms of machining quality, larger cutting parameters will worsen the surface roughness and morphology as well as lead to deeper subsurface plastic flow. The research will be conducive to promoting the applications of AlCoCrFeNi2.1 HEA.

Exploring Platinum Thin Films as Electrodes for High‐Temperature and ‐Pressure Electrochemical Studies in Aqueous Systems

ABSTRACTThis work reports a methodology for the fabrication of Pt thin‐film electrodes for electrochemical studies in hydrothermal systems. The research process was meticulous, with particular attention paid to the multilayer Ti/Pt/Ti/Al2O3 film structure and annealing conditions that are expected to impact the morphology of the films, surface composition and electrochemical response. The findings of this study are significant, as they provide valuable insights into the behaviour of Pt thin‐film electrodes in various media and conditions. Two different approaches were adopted for the preparation of the electrodes: in one case, the Ti/Pt/Ti/Al2O3 films deposited on sapphire wafers were exposed to rapid thermal annealing at 900°C under argon for 5 min, followed by argon ion milling to etch the final electrode pattern (Pt‐RA(900)), while in the other case, uncapped Pt films were annealed, after etching, in a tubular oven under argon at specific temperatures between 200°C and 900°C (Pt‐TO). Rapid annealing at 900°C on capped films resulted in the formation of a Pt3Ti intermetallic alloy with remarkable mechanical and chemical stability even after 10 h of immersion in deionised water, acid (0.1 M H2SO4) and alkaline media (0.1 M KOH) conditions at temperatures up to 150°C, despite the dissolution of the Al2O3 top layer at 150°C and long immersion times (> 10 h). In the case of uncapped Pt films, diffusion and oxidation of Ti through the Pt film at high temperature resulted in the formation of TiO2 on the surface of Pt. The results were confirmed by using a comprehensive suite of ex‐situ characterisation techniques to follow changes in the Pt electrode surface morphology and composition before and after immersion in H2O, 0.1 M H2SO4 and 0.1 M KOH solutions under argon. Ex‐situ electrochemical characterisation studies were also conducted to correlate the changes in the electrode surface properties, including the electrochemical surface area, with different annealing conditions and after various hydrothermal treatments in neutral, alkaline and acidic media.

Efficacy of Sodium Fluoride and Fluoridated Calcium Phosphate in Mitigating Dental Erosion on Human Enamel: An In Vitro Analysis.

With increasing prevalence of dental erosion, this study explores the protective role of traditional fluoride-based products and newer formulations on eroded enamel. To assess the protective effectiveness of casein phosphopeptide-amorphous calcium phosphate fluoride (CPP-ACPF) and sodium fluoride (NaF) on human enamel against erosion using surface microhardness (SMH) and Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM) analyses. Ten extracted human third molars were sectioned to obtain 40 enamel sections and randomly assigned into four groups (n = 10) and treated as follows: G1 (Sound Enamel), G2 (Erosive Challenge), G3 (CPP-ACPF + Erosive Challenge), and G4 (NaF + Erosive Challenge). All samples were subjected to Vicker's SMH analysis, while changes in surface morphology and elemental composition were validated in few representative samples using FTIR and SEM, respectively. Paired samples test, Kruskal-Wallis test, and Tukey HSD test were performed using SPSS software version 23 setting P value < 0.05 as statistically significant. The mean SMH1 values for the experimental groups G3 and G4 were significantly higher (426.58VHN and 455.83VHN) when compared to G1 (P = 0.000) and G2 (P = 0.000). In SEM analysis, G2 showed eroded honeycomb appearance compared to the smooth homogenous surface of G1, while both G3 and G4 showed deposition of some precipitates. FTIR analysis revealed that in G3 and G4, a characteristic peak of phosphate vibrations between 528 and 823 cm-1 and carbonate bands at 845-932 cm-1 was observed. Both CPP-ACPF and NaF demonstrated a protective effect on enamel against erosive challenge by an orange juice-based beverage.

UV Exposure Time Optimization for Enhanced Conversion, Hardness, and Flexural Strength in UDMA/TEG-DMA Composite Resins

This study examines the effects of varying ultraviolet (UV) exposure times on the properties of UDMA/TEG-DMA composite resins, focusing on degree of conversion, surface morphology, water absorption, shrinkage, hardness, and flexural strength. Composite resin samples were exposed to UV light for 30, 60, 90, and 120 min. The degree of conversion was assessed using Fourier Transform Infrared Spectroscopy (FTIR). Surface morphology was analyzed via Scanning Electron Microscopy (SEM). Water absorption and shrinkage were measured following standard procedures, while mechanical properties, including hardness and flexural strength, were evaluated using a Vickers hardness tester and a 3-point bending test, respectively. The results indicate that a UV exposure time of 90 min optimizes the composite resin properties, achieving the highest degree of conversion at 77 %, optimal surface morphology, minimal water absorption and shrinkage, and superior mechanical properties, including maximum flexural strength and hardness. In contrast, both shorter and longer UV exposure times detrimentally affected these properties, with prolonged exposure causing thermal degradation and reduced performance. This research underscores the importance of precise UV curing time control to enhance the performance and durability of UDMA/TEG-DMA composite resins, providing valuable insights and practical guidelines for their application in dental and industrial fields. HIGHLIGHTS The incorporation of UDMA/TEG-DMA in composite resin formulations significantly enhanced mechanical properties such as flexural strength and modulus. Exposure to UV light affected the degree of conversion of the resin, impacting its polymerization kinetics and potentially influencing long-term durability. The study revealed notable changes in surface morphology, indicating potential implications for bonding characteristics and aesthetic outcomes. Investigating water absorption and shrinkage behavior provided insights into material stability and dimensional changes over time, critical for clinical longevity and patient satisfaction. GRAPHICAL ABSTRACT

Synthesis and assessment of the Mo/MoO3/CZTS/Ag diode fabricated by one-pot hydrothermal route: impact of temperature

A facile one-step hydrothermal method was utilized to prepare Cu2ZnSnS4 film employing EDTA as a complexing agent. An effective Molybdenum oxide layer was also formed in the same approach for forming the Cu2ZnSnS4 film. The influence of preparation temperature on structural, morphology, and optical characteristics was studied. The formation of crystalline kesterite phase Cu2ZnSnS4 films with preferred orientation along the (112) plane was confirmed by X-ray diffraction and Raman spectroscopy, and it was also demonstrated that structure property changes with preparation temperatures: kesterite phase Cu2ZnSnS4 is formed at lower preparation temperatures and kesterite phase Cu2ZnSnS4 and Cu2S are formed with increasing preparation temperature. Also, Raman analysis confirmed the formation of a Molybdenum oxide layer on the Mo substrate. Field emission scanning electron microscopy revealed that surface morphology changes from leaves of trees to flake-flowers. According to UV-visible analysis, Cu2ZnSnS4 films exhibited high and wide absorbance spectra in the visible and infrared regions and a band gap between (1.67-1.9) eV. Photoluminescence analysis revealed emission peaks at (1.569, 1.55, and 1.56) eV for samples prepared at (160, 200, and 230)0C, respectively, which is very close to the band's gap of Cu2ZnSnS4. Finally, the electrical study of Mo/MoO3/CZTS/Ag junctions was performed by using current-voltage (I-V) measurement.

Comprehensive study of epitaxial (Nd,Eu,Gd)Ba2Cu3O7−δ films grown on textured templates

We report the successful epitaxial growth and comprehensive study of structural and superconducting properties of (Nd,Eu,Gd)Ba2Cu3O7−δ films with a thickness of up to 1.2 μm prepared by on-axis pulsed laser deposition on SrTiO3 (STO) single crystals as well as on ion-beam-assisted deposition (IBAD) and rolling-assisted biaxially textured substrate (RABiTS)-based metal templates. X-ray diffraction demonstrates the epitaxial quality of the grown films on both single crystalline substrates and metal-based templates. In addition, no significant changes in surface morphology were found with increasing thickness for films on all types of substrates. On all substrates, a T c value of about 89 K was observed, however, significant inhomogeneities indicating small superconducting volume were found for all films on STO. In general, the best transport characteristics over a wide range of magnetic fields and temperatures were observed for thicker films on IBAD-MgO and RABiTS templates, respectively. The J c values at 77 K for the films on IBAD-MgO templates are comparable to YBCO films, but inferior in the low temperature region and high magnetic fields, whereas the films on RABiTS and especially on STO showed much lower J c over the entire temperature and magnetic field range. A maximum pinning force of about 7 GN·m−3 at 65 K was found for the 900 nm thick films on IBAD-MgO template. In addition, the pinning mechanism seems to depend on both temperature and type of substrate. In general, no correlation between local microstructure and transport characteristics was revealed for NEG films on both metal templates.

Beneficiation of High Sulfur Tertiary Coal of Assam with Burkholderia sp. GR 8-02. An Eco-Friendly Approach Toward Clean Coal Production

The high sulfur content in North-East Indian coal is one of the primary challenges with using it as an energy source. Therefore, the present study uses Burkholderia sp. GR 8-02 to explore coal beneficiation from the Tipong mine (T20 and T60) in Assam (North-East India). Various particle size fractions (−125 to +210 µm, −210 to +250 µm, −250 to +297 µm, −297 to +400 µm and −400 to +500 µm) were treated and subjected to petrographic and chemical analysis, X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), Scanning Electron Microscope-Energy Dispersive Spectroscopy (SEM-EDS), Thermogravimetric analysis (TGA), and Raman spectral analysis. The results revealed a 39.04% and 32.43% reduction in total sulfur for T20 and T60 samples, respectively. The ash content decreased by 19.79% in the T20 coal sample and by 24.52% in the T60 coal samples, with a relative decrease in the mineral matter content of approximately 17.43%. Following beneficiation with Burkholderia sp. GR 8-02, the −125 to +250 µm coal fraction exhibited maximum ash removal. The T20 sample useful heating value increased from 8116 to 8203 kcal/kg and the T60 sample from 8060 to 8210 kcal/kg. X-ray diffraction and FTIR patterns showed mineral phases like quartz, kaolinite, and pyrite. The FTIR spectra indicated altered C-S, SO2, and C=O bonds. The thermal profile showed a 12.54% mass loss difference between untreated and treated coal samples, suggesting lower thermal stability post-treatment without affecting the useful heating value (UHV). The treated coal’s surface leaching and morphological structure changes were investigated using Scanning Electron Microscope-Energy Dispersive Spectroscopy (SEM-EDS) images. Raman analysis revealed increased carbon crystallinity and molecular structure in treated coal. This study offers an environmentally friendly and efficient approach to clean coal production.

Interface-driven microwave absorption enhancement in Mn-optimized Co2FeAl1-xMnx Heusler alloys

To address the urgent need for efficient and stable electromagnetic wave absorbing materials for electromagnetic interference (EMI) protection, we synthesized Co2FeAl1−xMnx Heusler soft magnetic alloys using a high-energy planetary ball milling method. We comprehensively analyzed their structural characteristics, surface morphology, magnetic properties, and electromagnetic parameters to explore their potential in electromagnetic wave absorption. The results show that incorporating manganese (Mn) significantly changes the alloys' crystal structure, surface morphology, and magnetic properties, greatly enhancing their wave absorption performance. The Mn doping specifically alters the surface morphology, which plays a crucial role in influencing the wave absorption characteristics of the Heusler alloys. When the Mn content increased to 25 %, the sample exhibits superior wave absorption, achieving the maximum reflection loss of −44.83 dB at 13.68 GHz with a thickness of 1.5 mm and an effective absorption bandwidth of 5.52 GHz. With a significant increase in the aspect ratio and noticeable changes in surface morphology, the sample with 75 % Mn content shows exceptional performance with an effective absorption bandwidth of 5.68 GHz, representing the highest effective absorption bandwidth in single-phase Heusler alloys. The Mn doping strategy effectively improves the material's impedance matching by adjusting its permittivity and permeability, facilitating multiple polarization relaxation mechanisms and significantly enhancing the alloys' electromagnetic wave absorption efficiency. Our study provides detailed experimental data for optimizing the electromagnetic wave absorption characteristics of Heusler alloys, verifies their practical application potential, and paves the way for developing new high-performance electromagnetic wave absorbing materials.

Effects of chemical etching on surface structure and tribological behavior of silicate substrates

Abstract This study investigated the effect of chemical etching on the surface structure and tribological behavior of silicate substrates. Silicate surfaces were etched using a mixture of nitric acid (HNO3) and ammonium bifluoride (NH4HF2) for durations ranging from 1 to 60 min. The etched surfaces were characterized using optical microscopy, scanning electron microscopy, surface profilometry, water contact angle measurements, and UV–vis spectroscopy to evaluate the changes in surface morphology, roughness, wettability, and optical properties. Tribological performance was assessed using reciprocating ball-on-plate friction tests. The results showed that increasing the etching time resulted in the formation of microscale surface features, increased surface roughness, enhanced hydrophilicity, and reduced optical transmittance. The average friction coefficient decreased with an increase in the etching time up to 30 min, beyond which a slight increase was observed. The 1-minute etched specimen exhibited the best wear resistance with the narrowest wear track and the least material removal. The improved tribological performance was attributed to the formation of a stable transfer film, reduced real contact area, and entrapment of wear debris. This study highlights the potential of chemical etching as a technique to tailor the surface structure and tribological properties of silicate materials for various applications.

Surface Morphology and Chemical Changes of Maple and Beech Cut Through by CO2 Laser Under Different Angles Relative to the Wood Grain

This paper examined the surface morphology of maple and beech cut through by CO2 laser under different angles relative to the wood grain: 0°, 15°, 30°, 45°, 60°, 75°, and 90°. In the analysis, stylus measurements, stereo-microscopic images, and chemical changes were considered. Laser uncovers more wood anatomical details, with enhanced clarity, when the cutting transitions from along the grain to across the grain. This is particularly noticeable in the earlywood and is more pronounced in maple compared to beech. The first tissue of earlywood was deeply ablated by the laser, leading to a wavy anatomical pattern, which is more visible for higher angles of laser cutting in relation to the wood grain. The anatomical structure of beech was more affected by carbonization in comparison to maple and had a significantly higher core roughness, Rk. For both species, the worst surface roughness occurred when cutting at 15°. In maple, the laser caused more degradation of the polysaccharides compared to beech, and this impact was particularly noticeable parallel to the grain rather than at a 90° angle. The degradation of hemicelluloses occurred in parallel with more advanced cellulose degradation for beech compared to maple and for cutting along the grain compared to across the grain. Structural changes in lignin, such as condensation processes, were observed for both species.

An In Situ Automated System for Real-Time Monitoring of Failures in Large-Scale Field Emitter Arrays

Nano-scale vacuum transistors (NVCTs) based on field emission have the potential to operate at high frequencies and withstand harsh environments, such as radiation, high temperatures, and high power. However, they have demonstrated instability and failures over time. To achieve high currents from NVCTs, these devices are typically fabricated in large-scale arrays known as field emitter arrays (FEAs), which share a common gate, cathode, and anode. Consequently, the measured currents come from the entire array, providing limited information about the emission characteristics of individual tips. Arrays can exhibit nonuniform emission behavior across the emitting area. A phosphor screen can be used to monitor the emission pattern of the array. Additionally, visible damage can occur on the surface of the FEAs, potentially leading to the destruction of the gate and emitters, causing catastrophic failure of the FEAs. To monitor damage while operating the device, an ITO-coated glass anode, which is electrically conductive and visible-light-transparent, can be used. In this work, a method was developed to automatically monitor the emission pattern of the emitters and the changes in surface morphology while operating the devices and collecting electrical data, providing real-time information on the failure sequence of the FEAs.

Analyzing Surface Morphology Changes Induced by Cyclic Fatigue in Three Different Nickel–Titanium Rotary Files Using Scanning Electron Microscopy Analysis

Analyzing Surface Morphology Changes Induced by Cyclic Fatigue in Three Different Nickel–Titanium Rotary Files Using Scanning Electron Microscopy Analysis

In vitro dynamic digestion properties and fecal fermentation of Dictyophora indusiata polysaccharide: Structural characterization and gut microbiota

The in vitro dynamic digestive model more realistically simulates the human digestive system compared to static digestive model. In this study, the dynamic in vitro stomach-intestine digestive system and fecal fermentation was used to investigate the dynamic digestion properties and fermentation properties of Dictyophora indusiata polysaccharide. The results showed that there were no significant changes in molecular weight, functional groups and surface morphology after the in vitro dynamic simulated digestion, indicating that D. indusiata polysaccharide maintained a relatively stable structure during the dynamic in vitro salivary-gastrointestinal digestion. In addition, D. indusiata polysaccharide improved the abundance of beneficial bacteria, including Blautia, Coprobacter and Fusicatenibacter. It is remarkable that D. indusiata polysaccharide significantly increased the level of acetic acid and propionic acid. In conclusion, these results suggested that D. indusiata polysaccharide was a potential source of prebiotics, which provides a basis for the development of D. indusiata polysaccharide in the food or medical field.

Effect of patients in-use and accelerated stability conditions on quality attributes and pharmacokinetic profile of four FDA approved extended-release anti-epileptic-drug products

Divalproex (DVS) is a popular drug widely used in various neurological and psychiatric disorders. Commercially, it is a multisource-drug available in different generic equivalents. Incidents of (class II)-recalls have been repeated over the last years due to failure to consistently meet dissolution specifications. Class II recalls are known to be associated with temporary or medically reversible adverse health consequences. This study aimed to evaluate the dissolution profiles, among other quality attributes, of select FDA-approved extended-release DVS products before and after exposure to conditions usually seen as short-lived and insignificant on product stability, such as pharmacy dispensing and patients’ in-use conditions to assess their possible role in the failures observed. Products were stored for 6 weeks in pharmacy vials at 30 °C/75 % RH to simulate patient in-use conditions, for 12 weeks in unsealed HPDE bottles at 25 °C/65 % RH to simulate the pharmacy storage conditions, and for 3 days in open containers at 40 °C/75 % RH for accelerated stability studies. Physicochemical changes were detected by near infrared imaging, Fourier transformed infrared, X-ray powder diffraction and differential scanning calorimetry. All samples were analyzed for in vitro dissolution. Two products were further selected for in vivo study on Beagle dogs before and after storage. The physicochemical characterization tests revealed changes in tablets’ composition and drug crystallinity over time. An improved discriminatory dissolution test was developed and used in this study. The in vitro release testing revealed that short-lived environmental changes at 30 or 25 °C could fail some unit doses and significantly lower the drug release (average reduction among all products was 12.97 ± 11.3 % and 27.48 ± 10.26 %, respectively). Some extended-release products showed a significant increase in the amount of drug dissolved in the first 6 h (early burst) owing to changes in tablet surface morphology and enhanced drug dissolution. In vivo studies showed a decrease in the AUC0-t by overall average of 21.1 % using the non-transformed data, a decrease that mirrored the dissolution results. The study shows that significant changes can occur during routine drug dispensing and patients’ use that might variably impact the stability and quality of commercial bioequivalent unit doses. It is possible that these changes may also contribute to the adverse effects reported on DVS or upon drug switches that were previously attributed to the intersubject variability. The study findings are encouraging to further investigate the effect of such minor excursions on the drug effectiveness during products’ shelf lives especially for narrow therapeutic index drugs.

Microplastics interactions and transformations during in vitro digestion with milk

Despite increasing awareness of microplastic contamination in food, the specific interactions and transformations of microplastics during digestion remain poorly understood. The study investigates the behavior of microplastics during in vitro digestion processes and their interaction with components of milk. The in vitro digestion studies are conducted to study the changes in microplastics in simulated digestive fluids, with and without milk. The study revealed that microplastics undergo significant changes in size, surface morphology, and chemical properties when subjected to digestion with and without milk. Notably, microplastics digested with milk exhibited a 15–25 % increase in aggregation due to protein corona formation, enhancing their potential for interactions within biological systems. FTIR analysis revealed the formation of OH and CO groups in digested microplastics, indicating hydrolysis and structural changes. The stronger peaks in the 1630–1650 cm−1 range suggest significant adsorption of milk proteins, highlighting the complex interactions during digestion. Additionally, the chemicals and additives leached from microplastics into digesta raising the concerns about their potential health effects. The study emphasizes the necessity for additional research and regulatory measures to address the risks associated with microplastic contamination in food.

Analysis of solar absorption, degradation mechanism and thermal stability in air environments for SS/TiB2/Al2O3 spectrally selective absorber coating

The quest for high solar-thermal conversion efficiency and thermal stability is a significant challenge in the development of high-efficiency spectrally selectivity absorber coatings. A key aspect of this challenge is the creation of air-stabilized coatings, particularly crucial for scenarios involving unexpected vacuum loss or applications of concentrating solar power systems in air environments. In our study, TiB2 films own excellent spectral selectivity and thermal stability at air environment. In pursuit of revealing the absorption mechanism of the coating, the optical constants, absoption and transmission of the single TiB2 layer were measured. The result of analysis display that the TiB2 layer contribute the bulk of the sunlight absorption. Reflectance spectra of the SS/TiB2/Al2O3 coating was succeeding simulated by CODE software with the optical constant to fit the experimental spectra, which confirms the results obtained by spectroscopic ellipsometry. The solar-thermal conversion efficiency of the as-deposited coating could reach 88.9 % of 100 suns at 500 °C. After annealing at 300–500 °C, the absorbance and emittance of the coating change slightly. But after annealing at 600 °C, the changing surface morphology, increasing surface roughness, and oxidation reaction of TiB2 resulted in a decrease in the optical performance of the coating.

Spatial pattern and landscape change prediction of blowouts in sandy grassland

Blowouts are a common type of wind-eroded landform found in sandy and desertified areas. They also represent a major degradative surface process affecting grassland ecosystems. Blowouts exacerbate changes in surface morphology through their effects on other surface phenomena including vegetation. In this paper, Xilingol League sandy grassland blowouts are taken as the research object, and the U.S. Keyhole satellite data and China’s Gaofen-1 satellite data are used as the data source, and the blowouts are extracted based on the 3 S technology for a total of six periods of high-resolution remote sensing image data in the study area from 1962 to 2023. The Landscape Pattern Index method and Fuzzy Land Use Simulation (FLUS) modelling applied to changes over the last six decades provided spatial evolution parameters for predicting future blowout distributions. Results showed that blowouts affecting the Xilingol grassland area increased by 16.81% over the past 60 years. The patch density (PD) increased by 0.9 per hectare. The mean proximity index (PROX_MN) and mean Euclidean nearest neighbour distance (ENN_MN) showed a tendency to decrease and then increase indicating initial expansion and then merging of adjacent blowouts to create the present landscape. The FLUS model used ten factors to predict changes in blowout distributions from 2023 to 2033. Factors included digital elevation model (DEM), slope, aspect, normalized difference vegetation index (NDVI), mean annual temperature, mean annual precipitation, population density, real GDP, distance to water, and distance to impervious surfaces. It was found that grassland area decreased by 6217.12 hm2 and blowout area decreased by 102.91 hm2. Results of this study can expand understanding of blowout morphodynamics in ecologically sensitive areas.