Based on the Lombardini et al. model that can predict the hydrodynamic damping of rough sea surfaces in the presence of monomolecular slicks and the “choppy wave” model (CWM) that can describe the nonlinear interactions between ocean waves, the modeling of time-varying nonlinear sea surfaces damped by natural or organic sea slicks is presented in this paper. The polarimetric scattering model of second-order small-slope approximation (SSA-II) with tapered wave incidence is utilized for evaluating co- and cross-polarized backscattered echoes from clean and contaminated CWM nonlinear sea surfaces. The influence of natural sea slicks on Doppler shift and spectral bandwidth of radar sea echoes is investigated in detail by comparing the polarimetric Doppler spectra of contaminated sea surfaces with those of clean sea surfaces. A narrowing of Doppler spectra in the presence of oil slicks is observed for both co- and cross-polarization, which is qualitatively consistent with wave-tank measurements. Simulation results also show that the Doppler shifts in slicks can increase or decrease, depending on incidence angles and polarizations.
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