Based on prior precision photometry and cluster age analysis, the bright star GSC 00154−01819 is a possible young pre-main sequence member of the Rosette cluster, NGC 2244. As part of a comprehensive study of the large-scale structure of the Rosette and its excitation by the cluster stars, we noted this star as a potential backlight for a probe of the interstellar medium and extinction along the sight line towards a distinctive nebular feature projected on to the cluster centre. New high-resolution spectra of the star were taken with the University College London Echelle Spectrograph of the AAT. They reveal that rather than being a reddened spectral type B or A star within the Mon OB2 association, it is a nearby, largely unreddened, solar twin of spectral type G2V less than 180 Myr old. It is about 219 pc from the Sun with a barycentric radial velocity of +14.35 ± 1.99 km s−1. The spectrum of the Rosette behind it and along this line of sight shows a barycentric radial velocity of +26.0 ± 2.4 km s−1 in H α, and a full width at half-maximum velocity dispersion of 61.94 ± 1.38 km s−1.