Molecular Emission Research Articles

Utilization of D2 molecular band emission for electron density measurement

D2 molecular band emission observed at a wavelength range of λ∼557−643nm is utilized to measure electron density, ne, in D plasmas of the PISCES-A and PISCES-RF linear plasma devices. The D2 band is divided at λ=593nm to make an intensity ratio, D2L (∼557–593nm)/D2R (∼593–643nm), where D2L consists predominantly of the g3Σg+3dσ, h3Σg+3sσ, i3Πg3dπ, j3Δg3dδ→c3Πu2pπ transitions, while D2R mainly includes the d3Πu3pπ→a3Σg+2sσ Fulcher band emission. It is experimentally found that D2L/D2R depends strongly on ne with little Te dependence in ranges of ne∼(0.031−6.1)×1018 m−3 and Te∼2.3−13.9eV. This observed trend is consistent with collisional-radiative model calculations using Yacora on the Web.

Investigation of linear and microscopic nonlinear optical responses of 1-indanone compounds in different environments based on polarity models

Molecular spectroscopic and nonlinear features can indicate positive changes by solvent molecules. In this work, DFT and spectroscopic techniques were used to study the polarity effects of different solvent environments. Polarity-based models were used for studying solvent induced interactions on the optical features of new groups of biomolecules. Despite the significant contribution of general effects on the molecular absorption spectra, there is considerable competition between general and specific environmental effects on the molecular emission properties. Under this condition, strong hydrogen bonds tend to increase molecular nonlinear responses. The same results were observed for the low order (first and second order) nonlinearity of biomolecules. Therefore, the studies on the environment effects on the biomolecules’ first order nonlinearity can give valuable information about higher-order optical responses. Moreover, 1-Indanone compounds with high nonlinearity can be considered as an effective element in designing optical devices.

First Detection of Molecular Gas in the Giant Low Surface Brightness Galaxy Malin 1

After over three decades of unsuccessful attempts, we report the first detection of molecular gas emission in Malin 1, the largest spiral galaxy observed to date, and one of the most iconic giant low surface brightness galaxies. Using Atacama Large Millimeter/submillimeter Array, we detect significant 12CO (J = 1–0) emission in the galaxy’s central region and tentatively identify CO emission across three regions on the disk. These observations allow for a better estimate of the H2 mass and molecular gas mass surface density, both of which are remarkably low given the galaxy’s scale. By integrating data on its H i mass, we derive a very low molecular-to-atomic gas mass ratio. Overall, our results highlight the minimal presence of molecular gas in Malin 1, contrasting sharply with its extensive, homogeneous atomic gas reservoir. For the first time, we position Malin 1 on the Kennicutt–Schmidt diagram, where it falls below the main sequence for normal spirals, consistent with previous upper limits but now with more accurate figures. These findings are crucial for constraining our understanding of star formation processes in environments characterized by extremely low molecular gas densities and for refining models of galaxy formation, thereby improving predictions concerning the formation, evolution, and distribution of these giant, elusive galaxies.

CHEMOUT: CHEMical complexity in star-forming regions of the OUTer Galaxy

Context. Single-dish observations suggest that the abundances of organic species in star-forming regions of the outer Galaxy, which are characterised by sub-solar metallicities, are comparable to those found in the local Galaxy. Aims. To understand this counter-intuitive result and avoid a misleading interpretation due to beam dilution effects at these large distances, spatially resolved molecular emission maps are needed to correctly link the measured abundances and local physical properties. Methods. We observed several organic molecules with the Atacama Large Millimeter Array towards WB89-671, the source with the largest galactocentric distance (23.4 kpc) of the project CHEMical complexity in star-forming regions of the OUTer Galaxy (CHEMOUT) at a resolution of ~15 000 au. We compared the observed molecular abundances with chemical model predictions. Results. We detected emission of c-C3H2, C4H, CH3OH, H2CO, HCO, H13CO+, HCS+, CS, HN13C, and SO. The emission morphology is complex, extended, and different in each tracer. In particular, the most intense emission in H13CO+, H2CO and c-C3H2 arises from two millimeter-continuum infrared-bright cores. The most intense CH3OH and SO emission predominantly arises from the part of the filament that lacks continuum sources. The narrow line widths across the filament indicate quiescent gas in spite of the two embedded protostars. The derived molecular column densities are comparable with those in local star-forming regions, and they suggest an anti-correlation between hydrocarbons, ions, HCO, and H2CO on the one hand, and CH3OH and SO on the other. Conclusions. The static chemical models that match the observed column densities best favour low-energy conditions that are expected at large galactocentric radii, but they also favour carbon elemental abundances that exceed those derived by extrapolating the [C/H] galactocentric gradient at 23 kpc by three times. This would indicate a flatter [C/H] trend at large galactocentric radii, which is in line with a flat abundance of organics. However, to properly reproduce the chemical composition of each region, models should include dynamical evolution.

Kinematical signatures: Distinguishing between warps and radial flows

Increasing evidence shows that warped disks are common, challenging the methods used to model their velocity fields. Molecular line emission of these disks is characterized by a twisted pattern, similar to the signal from radial flows, complicating the study of warped disk kinematics. Previous attempts to model these features have encountered difficulties in distinguishing between the underlying kinematics of different disks. This study aims to advance gas kinematics modeling capabilities by extending the Extracting Disk Dynamics ( eddy ) package to include warped geometries and radial flows. We assess the performance of eddy in recovering input parameters for scenarios involving warps, radial flows, and combinations of the two. Additionally, we provide a basis to break the visual degeneracy between warped disks and radial flow, establishing a criterion to distinguish them. We extended the eddy package to handle warped geometries by including a parametric prescription of a warped disk and a ray-casting algorithm to account for the surface self-obscuration arising from the 3D to 2D projection. The effectiveness of the tool was tested using the radiative transfer code RADMC3D generating synthetic models for disks with radial flows, warped disks, and warped disks with radial flows. We demonstrate the efficacy of our tool in accurately recovering the geometrical parameters of systems, particularly in data with sufficient angular resolution. Importantly, we observe minimal impact from thermal noise levels typical in Atacama Large Millimeter/submillimeter Array (ALMA) observations. Furthermore, our findings reveal that fitting an incorrect model type produces characteristic residual signatures, which serve as kinematic criteria for disk classification. Characterizing gas kinematics requires careful consideration of twisted motions. While our model provides insights into disk geometries, caution is needed when interpreting parameters in regions with complex kinematics or low-resolution data. Future ALMA baseline observations should help clarify warped disk kinematics.

ISMGCC: Finding Gas Structures in Molecular Interstellar Medium Using Gaussian Decomposition and Graph Theory

Molecular line emissions are commonly used to trace the distribution and properties of molecular Interstellar Medium. However, the emissions are heavily blended on the Galactic disk toward the inner Galaxy because of the relatively large line widths and the velocity overlaps of spiral arms. Structure identification methods based on voxel connectivity in Position-Position-Velocity (PPV) data cubes often produce unrealistically large structures, which is the “over-linking” problem. Therefore, identifying molecular cloud structures in these directions is not trivial. We propose a new method based on Gaussian decomposition and graph theory to solve the over-linking problem, named InterStellar Medium Gaussian Component Clustering (ISMGCC). Using the Milky Way Imaging Scroll Painting (MWISP) 13CO(1–0) data in the range of 13.°5 ≤ l ≤ 14.°5, ∣b∣ ≤ 0.°5, and −100 ≤ V lsr ≤ +200 km s−1, our method identified three hundred molecular gas structures with at least 16 pixels. These structures contain 92% of the total flux in the raw data cube and show single-peaked line profiles on more than 93% of their pixels. The ISMGCC method could distinguish gas structures in crowded regions and retain most of the flux without global data clipping or assumptions on the structure geometry, meanwhile, allowing multiple Gaussian components for complicated line profiles.

Characterization of Line Ratio Variations in Orion A

Here we use a new method to study the correlation between different molecular emission lines in star-forming molecular dust clouds. This method is applied to maps from the Line Emission as a Tool for Galaxy Observations project (12CO, 13CO, C18O, N2H+, CCH, HCN, and CN) in Orion A. Our data shows the correlation properties change within dust clouds in Orion A, suggesting that the physical properties change as well. We are preparing our code and data to be publicly accessible in an online repository.

Study on high-temperature emission behaviors of crumb rubber modified asphalt: Experimental analysis and molecular simulation approach

The harmful emissions produced during the manufacturing and construction processes of crumb rubber modified asphalt (CRMA) significantly hinder its widespread application. Addressing this issue hinges on a thorough investigation into the mechanism governing its high-temperature emissions. This study employed microscale testing methods to analyze the microstructure and chemical property disparities between CRMA and base asphalt (BA). Subsequently, the impacts of varying crumb rubber (CR) content, experimental temperature, and sulfur stabilizer dosage on the high-temperature emissions of CRMA were investigated. Furthermore, comparative analyses of the molecular weight distribution, emission species, and CR crosslink density in asphalt after the fume experiment were conducted to further elucidate the high-temperature emission mechanisms. Finally, molecular simulation techniques were employed to analyze the interactions between CR and the four fraction molecules of asphalt at the microscale. The results indicated that the fume release volume of CRMA initially decreased and then increased with the addition of CR, while both the experimental temperature and sulfur stabilizer content exhibited a positive correlation with emission volume. CR reduced the volatilization of some small molecular hydrocarbons in the BA by absorbing light fractions. Meanwhile, excessive swelling caused the crosslinking density of CR to decrease by 77 %, which led to the release of toxic substances. At 20% CR content, the overall emissions of CRMA achieve their lowest level; however, the emission of toxic gases does not diminish. Molecular simulations have also confirmed the above results, showing that there is a strong interaction between CR and the light fractions. Compared with asphaltene molecules, rubber molecules had higher molecular polarity and stronger adsorption behavior for light fraction molecules.

Gating Single-Molecule Fluorescence with Electrons.

Tip-enhanced photoluminescence (TEPL) measurements are performed with subnanometer spatial resolution on individual molecules decoupled from a metallic substrate by a thin NaCl layer. TEPL spectra reveal progressive fluorescence quenching with decreasing tip-molecule distance when electrons tunneling from the tip of a scanning tunneling microscope are injected at resonance with the molecular states. Rate equations based on a many-body model reveal that the luminescence quenching is due to a progressive population inversion between the ground neutral (S_{0}) and the ground charge (D_{0}^{-}) states of the molecule occurring when the current is raised. We demonstrate that the bias voltage and the lateral tip position can be used to gate the molecular emission. Our approach can be applied to any molecular system, providing unprecedented control over the fluorescence of a single molecule.

FAST Observations of Four Comets to Search for the Molecular Line Emissions between 1.0 and 1.5 GHz Frequencies

We used the Five-hundred-meter Aperture Spherical radio Telescope (FAST) to search for the molecular emissions in the L-band between 1.0 and 1.5 GHz toward four comets, C/2020 F3 (NEOWISE), C/2020 R4 (ATLAS), C/2021 A1 (Leonard), and 67P/Churyumov-Gerasimenko during or after their perihelion passages. Thousands of molecular transition lines fall in this low-frequency range, many attributed to complex organic or prebiotic molecules. We conducted a blind search for the possible molecular lines in this frequency range in those comets and could not identify clear signals of molecular emissions in the data. Although several molecules have been detected at high frequencies of greater than 100 GHz in comets, our results confirm that it is challenging to detect molecular transitions in the L-band frequency ranges. The non-detection of L-band molecular lines in the cometary environment could rule out the possibility of unusually strong lines, which could be caused by the masers or non-LTE effects. Although the line strengths are predicted to be weak, for FAST, using the ultra-wide bandwidth receiver and improving the radio frequency interference environments would enhance the detectability of those molecular transitions at low frequencies in the future.

MICONIC: JWST/MIRI MRS observations of the nuclear and circumnuclear regions of Mrk 231

We present JWST/MIRI MRS spatially resolved ∼5 − 28 μm observations of the central ∼4 − 8 kpc of the ultraluminous infrared galaxy and broad absorption line quasar Mrk 231. These are part of the Mid-Infrared Characterization of Nearby Iconic galaxy Centers (MICONIC) program of the MIRI European Consortium guaranteed time observations. No high excitation lines (i.e., [Mg V] at 5.61 μm or [Ne V] at 14.32 μm) typically associated with the presence of an active galactic nucleus (AGN) are detected in the nuclear region of Mrk 231. This is likely due to the intrinsically X-ray weak nature of its quasar. Some intermediate ionization potential lines, for instance, [Ar III] at 8.99 μm and [S IV] at 10.51 μm, are not detected either, even though they are clearly observed in a star-forming region ∼920 pc south-east of the AGN. Thus, the strong nuclear mid-infrared (mid-IR) continuum is also in part hampering the detection of faint lines in the nuclear region. The nuclear [Ne III]/[Ne II] line ratio is consistent with values observed in star-forming galaxies. Moreover, we resolve for the first time the nuclear starburst in the mid-IR low-excitation line emission (size of ∼400 pc, FWHM). Several pieces of evidence also indicate that it is partly obscured even at these wavelengths. At the AGN position, the ionized and warm molecular gas emission lines have modest widths (W80 ∼ 300 km s−1). There are, however, weak blueshifted wings reaching velocities v02 ≃ − 400 km s−1 in [Ne II]. The nuclear starburst is at the center of a large (∼8 kpc), massive rotating disk with widely-spread, low velocity outflows. Given the high star formation rate of Mrk 231, we speculate that part of the nuclear outflows and the large-scale non-circular motions observed in the mid-IR are driven by its powerful nuclear starburst.

Neutral atomic and molecular gas dynamics in the nearby spiral galaxies NGC 1512, NGC 4535, and NGC 7496

Neutral atomic gas (H I) effectively traces galactic dynamics across mid to large galactocentric radii. However, its limitations in observing small-scale changes within the central few kiloparsecs, coupled with the often observed H I deficit in galactic centers, necessitates the use of molecular gas emission as a preferred tracer in these regions. Understanding the dynamics of both neutral atomic and molecular gas is crucial for a more complete understanding of how galaxies evolve, funnel gas from the outer disk into their central parts, and eventually form stars. In this work we aim to quantify the dynamics of both, the neutral atomic and molecular gas, in the nearby spiral galaxies NGC 1512, NGC 4535, and NGC 7496 using new MeerKAT H I observations together with ALMA CO (2-1) observations from the PHANGS collaboration. We use the analysis tool 3DBarolo to fit tilted ring models to the H I and CO observations. A combined approach of using the H I to constrain the true disk orientation parameters before applying these to the CO datasets is tested. This paper sets expectations for the results of the upcoming high-resolution H I coverage of many galaxies in the PHANGS-ALMA sample using MeerKAT or VLA, to establish a robust methodology for characterizing galaxy orientations and deriving dynamics from combing new H I with existing CO data.

Magnetic Fields in Massive Star-forming Regions (MagMaR). IV. Tracing the Magnetic Fields in the O-type Protostellar System IRAS 16547–4247

The formation of the massive stars, and in particular, the role that the magnetic fields play in their early evolutionary phase is still far from being completely understood. Here, we present the Atacama Large Millimeter/submillimeter Array 1.2 mm full polarized continuum and H13CO+(3−2), CS(5−4), and HN13C(3−2) line observations with a high angular resolution (∼0.″4 or 1100 au). In the 1.2 mm continuum emission, we reveal a dusty envelope surrounding the massive protostars, IRAS16547-E and IRAS16547-W, with dimensions of ∼10,000 au. This envelope has a biconical structure likely carved by the powerful thermal radio jet present in region. The magnetic field vectors follow very well the biconical envelope. The polarization fraction is ∼2.0% in this region. Some of these vectors seem to converge to IRAS 16547-E and IRAS 16547-W, the most massive protostars. Moreover, the velocity fields revealed from the spectral lines H13CO+(3−2) and HN13C(3−2) show velocity gradients with a good correspondence with the magnetic fields, which maybe are tracing the cavities of molecular outflows or maybe infalling in some parts. We derived a magnetic field strength in some filamentary regions that goes from 2 to 6.1 mG. We also find that the CS(5−4) molecular line emission reveals multiple outflow cavities or bow shocks with different orientations, some of which seem to follow the NW–SE radio thermal jet.

CORINOS. II. JWST-MIRI Detection of Warm Molecular Gas from an Embedded, Disk-bearing Protostar

We present James Webb Space Telescope (JWST) Mid-InfraRed Instrument (MIRI) observations of warm CO and H2O gas in emission toward the low-mass protostar IRAS 15398-3359, observed as part of the CORINOS program. The CO is detected via the rovibrational fundamental band and hot band near 5 μm, whereas the H2O is detected in the rovibrational bending mode at 6–8 μm. Rotational analysis indicates that the CO originates in a hot reservoir with an excitation temperature of 1598 ± 118 K, while the water is much cooler at 204 ± 7 K. Neither the CO nor the H2O line images are significantly spatially extended, constraining the emission to within ∼40 au of the protostar. The compactness and high temperature of the CO are consistent with an origin in the embedded protostellar disk, or in a compact disk wind. In contrast, the water must arise from a cooler region and requires a larger emitting area (compared to the CO) to produce the observed fluxes. The water may arise from a more extended part of the disk, or from the inner portion of the outflow cavity. Thus, the origin of the molecular emission observed with JWST remains ambiguous. Better constraints on the overall extinction, comparison with realistic disk models, and future kinematically resolved observations may all help to pinpoint the true emitting reservoirs.

No evidence of active galactic nucleus features in the nuclei of Arp 220 from JWST/NIRSpec IFS

Context. Arp 220 is the nearest ultra-luminous infrared galaxy. It shows evidence of 100 pc scale molecular outflows that are likely connected with galaxy-scale outflows traced by ionised and neutral gas. The two highly obscured nuclei of Arp 220 are sites of intense star formation, with extreme (far-infrared based) star formation rate surface densities, ΣSFR ≳ 103 M⊙ yr−1 kpc−2. Despite extensive investigations that searched for active galactic nucleus (AGN) activity in the Arp 220 nuclei, direct evidence remains elusive. Aims. We present JWST/NIRSpec integral field spectroscopy (IFS) observations covering the 0.9 − 5.1 μm wavelength range of the innermost (5″ × 4″, i.e. 1.8 × 1.5 kpc) regions of Arp 220. The primary goal is to investigate the potential presence of AGN signatures in the nuclear regions by analysing the spectra extracted from circular apertures with a radius of 55 pc (0.15″) around each of the two nuclei. Methods. The analysis aims to identify highly ionised gas emission lines (with ionisation potential > 54 eV) and other spectral features indicative of AGN activity. Atomic and molecular gas kinematics were also taken into account to study the outflow signatures at < 60 pc scales. Results. We identify ∼70 atomic and ∼50 molecular emission lines in the nuclear spectra of Arp 220. We used recombination line ratios to measure optical extinctions in the range AV ∼ 11 − 14 mag. High-ionisation lines are not detected, except for the [Mg IV] line at 4.49 μm, which we interpret as due to shocks rather than to AGN ionisation. We identify broadening and multiple kinematic components in the H I and H2 lines caused by outflows and shocks, with velocities up to ∼550 km s−1. Significantly higher velocities (up to ∼900 km s−1) are detected in the off-nuclear regions, but they do not conclusively represent direct evidence for AGN activity. Broad-line region components are not detected in any permitted emission line within the NIRSpec wavelength range. Conclusions. Even with the unprecedented sensitivity of JWST/NIRSpec IFS, achieving an unambiguous identification or exclusion of the presence of an AGN in the Arp 220 system remains challenging because of its extreme dust obscuration.

High-resolution observations of 12CO and 13CO J = 3 2 towards the NGC 6334 extended filament. I. Emission morphology and velocity structure

NGC 6334 is a giant molecular cloud (GMC) complex that exhibits elongated filamentary structure and harbours numerous OB-stars, H II regions, and star-forming clumps. To study the emission morphology and velocity structure of the gas in the extended NGC 6334 region using high-resolution molecular line data, we made observations of the 12CO and 13CO $J=3 2$ lines with the LAsMA instrument at the APEX telescope . The LAsMA data provided a spatial resolution of 20" (sim 0.16 pc) and sensitivity of 0.4 K at a spectral resolution of 0.25 km $. Our observations revealed that gas in the extended NGC 6334 region exhibits connected velocity coherent structure over sim 80 pc parallel to the Galactic plane. The NGC 6334 complex has its main velocity component at $ -3.9$ km $ with two connected velocity structures at velocities $ -9.2$ km $ (the `bridge' features) and $ km $ (the northern filament, NGC 6334-NF). We observed local velocity fluctuations at smaller spatial scales along the filament that are likely tracing local density enhancement and infall, while the broader V-shaped velocity fluctuations observed towards the NGC 6334 central ridge and G352.1 region located in the eastern filament EF1 indicate globally collapsing gas onto the filament. We investigated the 13CO emission and velocity structure around 42 WISE H II regions located in the extended NGC 6334 region and found that most H II regions show signs of molecular gas dispersal from the centre (36 of 42) and intensity enhancement at their outer radii (34 of 42). Furthermore most H II regions (26 of 42) are associated with least one ATLASGAL clump within or just outside of their radii, the formation of which may have been triggered by H II bubble expansion. Typically towards larger H II regions we found visually clear signatures of bubble shells emanating from the filamentary structure. Overall the NGC 6334 filamentary complex exhibits sequential star formation from west to east. Located in the west, the GM-24 region exhibits bubbles within bubbles and is at a relatively evolved stage of star formation. The NGC 6334 central ridge is undergoing global gas infall and exhibits two gas bridge features possibly connected to the cloud-cloud collision scenario of the NGC 6334-NF and the NGC 6334 main gas component. The relatively quiescent eastern filament (EF1 - G352.1) is a hub-filament in formation, which shows the kinematic signature of global gas infall onto the filament. Our observations highlight the important role of H II regions in shaping the molecular gas emission and velocity structure as well as the overall evolution of the molecular filaments in the NGC 6334 complex.

ALMA high-resolution observations unveil planet formation shaping molecular emission in the PDS 70 disk

With two directly detected protoplanets, the PDS 70 system is a unique source in which to study the complex interplay between forming planets and their natal environment. The large dust cavity carved by the two giant planets can affect the disk chemistry, and therefore the molecular emission morphology. On the other hand, chemical properties of the gas component of the disk are expected to leave an imprint on the planetary atmospheres. In this work, we reconstruct the emission morphology of a rich inventory of molecular tracers in the PDS 70 disk, and we look for possible chemical signatures of the two actively accreting protoplanets, PDS 70b and c. We leverage Atacama Large Millimeter/submillimeter Array (ALMA) band 6 high-angular-resolution and deep-sensitivity line emission observations, together with image and uv-plane techniques, to boost the detection of faint lines. We robustly detect ring-shaped emission from 12CO, 13CO, C18O, H13CN, HC15N, DCN, H2CO, CS, C2H, and H13CO+ lines in unprecedented detail. Most of the molecular tracers show a peak of the emission inside the millimeter dust peak. We interpret this as the direct impact of the effective irradiation of the cavity wall, as a result of the planet formation process. Moreover, we have found evidence of an O-poor gas reservoir in the outer disk, which is supported by the observations of bright C-rich molecules, the non-detection of SO, and a lower limit on the CS/SO ratio of ~1. Eventually, we provide the first detection of the c-C3H2 transitions at 218.73 GHz, and the marginal detection of an azimuthal asymmetry in the higher-energy H2CO (32,1−22,0) line, which could be due to accretion heating near PDS 70b.

MINDS

Context. The majority of young stars form in multiple systems, the properties of which can significantly impact the evolution of any circumstellar disks. Aims. We investigate the physical and chemical properties of the equal-mass, small-separation (~66 milliarcsecond, ~9 au) binary system DF Tau. Previous spatially resolved observations indicate that only DF Tau A has a circumstellar disk, while DF Tau B does not, as concluded by a lack of accretion signatures and a near-infrared excess. Methods. We present JWST-MIRI MRS observations of DF Tau. The MIRI spectrum shows emission from a forest of H2O lines and emission from CO, C2H2, HCN, CO2, and OH. Local thermodynamic equilibrium slab models were used to determine the properties of the gas. The binary system is not spatially or spectrally resolved in the MIRI observations; therefore, we analyzed high spatial and spectral resolution observations from ALMA, VLTI-GRAVITY, and IRTF-iSHELL to aid in the interpretation of the molecular emission observed with JWST. Results. The 1.3 mm ALMA observations show two equal-brightness sources of compact (R ≲ 3 au) continuum emission that are detected at high significance, with separations consistent with astrometry from VLTI-GRAVITY and movement consistent with the known orbital parameters of the system. We interpret this as a robust detection of the disk around DF Tau B, which we suggest may host a small (~1 au) cavity; such a cavity would reconcile all of the observations of this source. In contrast, the disk around DF Tau A is expected to be a full disk, and spatially and spectrally resolved dust and gas emission traced by ground-based infrared observations point to hot, close-in (≲0.2 au) material around this star. High-temperature emission (~500–1000 K) from H2O, HCN, and potentially C2H2 in the MIRI data likely originates in the disk around DF Tau A, while a cold H2O component (≲200 K) with an extended emitting area is consistent with an origin from both disks. Conclusions. Given the unique characteristics of this binary pair, complementary observations are critical for constraining the properties of these disks. Despite the very compact outer disk properties, the inner disk composition and the conditions of the DF Tau disks are remarkably similar to those of isolated systems, suggesting that neither the outer disk evolution nor the close binary nature are driving factors in setting the inner disk chemistry in this system. However, constraining the geometry of the disk around DF Tau B, via higher angular resolution ALMA observations for instance, would provide additional insight into the properties of the mid-infrared gas emission observed with MIRI. JWST observations of spatially resolved binaries, at a range of separations, will be important for understanding the impact of binarity on inner disk chemistry more generally.

Comparison of NH3 and 12CO, 13CO, C18O Molecular Lines in the Aquila Rift Cloud Complex

The observations of the Aquila Rift cloud complex at 23.708 and 115.271 GHz made using the Nanshan 26 m radio telescope and the 13.7 m millimeter-wavelength telescope are presented. We find that the CO(1 − 0) gas distribution is similar to the NH3 gas distribution in the Aquila Rift cloud complex. In some diffusion regions characterized by CO, we identified several dense clumps based on the distribution of detected ammonia molecular emission. Through the comparison of spectral line parameters for NH3, 13CO, and C18O, our study reveals that the line center velocities of the NH3, 13CO, and C18O lines are comparable and positively correlated, indicating that they originate from the same emission region. No significant correlation was identified for other parameters, including integrated intensity, line widths, main beam brightness temperature, as well as the column densities of NH3, 13CO, and C18O. The absolute difference in line-center velocities between the 13CO and NH3 lines is less than both the average line width of NH3 and that of 13CO. This suggests that there are no significant movements of NH3 clumps in relation to their envelopes. The velocity deviation is likely due to turbulent activity within the clumps.

The properties and kinematics of HCN emission across the closest starburst galaxy NGC 253 observed with ALMA

Context. Investigating molecular gas tracers, such as hydrogen cyanide (HCN), to probe higher densities than CO emission across nearby galaxies remains challenging. This is due to the large observing times required to detect HCN at a high sensitivity and spatial resolution. Although approximate kiloparsec scales of HCN maps are available for tens of galaxies, higher-resolution maps still need to be available. Aims. We aim to study the properties of molecular gas, the contrast in intensity between two tracers that probe different density regimes (the HCN(1–0)/CO(2–1) ratio), and their kinematics across NGC 253, one of the closest starburst galaxies. With its advanced capabilities, the Atacama Large Millimeter/submillimeter Array (ALMA) can map these features at a high resolution across a large field of view and uncover the nature of such dense gas in extragalactic systems. Methods. We present new ALMA Atacama Compact Array and Total Power (ACA+TP) observations of the HCN emission across NGC 253. The observations cover the inner 8.6′ of the galaxy disk at a spatial resolution of 300 pc. Our study examines the distribution and kinematics of the HCN-traced gas and its relationship with the bulk molecular gas traced by CO(2–1). We analyze the integrated intensity and mean velocity of HCN and CO along each line of sight. We also used the SCOUSE software to perform spectral decomposition, which considers each velocity component separately. Results. We find that the denser molecular gas traced by HCN piles up in a ring-like structure at a radius of 2 kpc. The HCN emission is enhanced by two orders of magnitude in the central 2 kpc regions, beyond which its intensity decreases with increasing galactocentric distance. The number of components in the HCN spectra shows a robust environmental dependence, with multiple velocity features across the center and bar. The HCN spectra exhibit multiple velocity features across the center and bar, which shows a robust environmental dependence. We have identified an increase in the HCN/CO ratio in these regions, corresponding to a velocity component likely associated with a molecular outflow. We have also discovered that the ratio between the total infrared luminosity and dense gas mass, which is an indicator of the star formation efficiency of dense gas, is anticorrelated with the molecular gas surface density up to approximately 200 M⊙ pc−2. However, beyond this point, the ratio starts to increase. Conclusions. We argue that using information about spectroscopic features of molecular emission is an important aspect of understanding molecular properties in galaxies.