Moisture Sources For Precipitation Research Articles

The Contribution of Moisture Sources of Precipitation to Water Resources Recharge in Semi-Arid Regions

This study investigates the isotopic composition of precipitation in Iran and its moisture sources, offering insights crucial for addressing water recharge and management in semi-arid regions. This study analyzes 150 precipitation events collected from 11 stations across Iran over multiple years. The HYSPLIT model was used to trace air mass trajectories contributing to these events. The isotopic composition of precipitation from each moisture source was examined to identify their distinct characteristics. Furthermore, the contribution of each air mass to groundwater and surface water recharge was quantified using the Simmr mixing model in R programming language, combining stable isotope data from precipitation and surface/groundwater samples. Precipitation in northern Iran is associated with low d-excess values, indicating moisture from high-latitude sources, particularly the Caspian Sea, while higher d-excess values in the west and south point to moisture mainly from the Persian Gulf and the Mediterranean Sea. Air mass trajectory analysis via the HYSPLIT model identified the dominant pathways of Continental Tropical (CT), Continental Polar (CP), and Mediterranean (MedT) air masses across Iran. Quantitative analysis using the Simmr mixing model revealed that the CT air mass contributes up to 33.6% to groundwater recharge in southern Iran’s karstic regions, while the CP air mass dominates in the north, with up to 46.8% contribution. The MedT air mass, although significant in the west, decreases in influence towards the east. Isotope data from groundwater and surface water sites showed more depleted values than local precipitation, likely due to larger catchment areas. These findings contribute to water management strategies by identifying the variations in moisture sources that influence groundwater and surface water recharge in Iran. Understanding these variations enables the development of targeted strategies for managing water resources in semi-arid regions facing increasing water scarcity. The methodologies applied in this study can be adapted to other regions, providing a valuable framework for sustainable water management in areas where identifying moisture sources is critical.

Impact of Arctic Stratospheric Polar Vortex on Mediterranean Precipitation

Abstract The Mediterranean precipitation has significant implications for the local ecology and human livelihoods. This study explores the impact of the Arctic stratospheric polar vortex on the Mediterranean precipitation during the wet season (winter) using reanalysis data and large-scale ensemble experiments that are forced by anomalous stratospheric polar vortex states. Our findings reveal that total and extreme precipitation over the Mediterranean region are increased under weak polar vortex (WPV) conditions and decreased under strong polar vortex (SPV) conditions. Moisture budget suggests that the changes in vertical motion over the Mediterranean play the dominant role in precipitation changes. It is further found that the tropospheric quasi-stationary wave train propagating from Greenland to the European continent is enhanced under WPV conditions, accompanied by warming advection over the eastern Mediterranean and vorticity advection in the upper troposphere over the whole region of the Mediterranean. Consequently, the vertical motion and precipitation there are enhanced. The southward shift of the Atlantic jet stream under WPV conditions leads to enhanced moisture transport toward the Mediterranean, providing a favorable moisture source for precipitation. In addition, the background baroclinicity in the lower troposphere around the northern Mediterranean is enhanced under WPV conditions, intensifying frontogenesis and cyclonic activities, which are commonly accompanied by intensified precipitation. These results are consistent with earlier literature and suggest that the changes in the stratospheric polar vortex may be used as a potential predicting factor for Mediterranean precipitation.

Anomalous Water Vapor Circulation in an Extreme Drought Event of the Mid‐Reaches of the Lancang‐Mekong River Basin

AbstractThe middle reaches of the Lancang‐Mekong River Basin (M‐LMRB) experienced a record‐breaking drought event in 2019, resulting in significant economic losses of approximately 650 million dollars and affecting a population of 17 million. However, the anomalous circulation and transportation processes of water vapor, which may have played a crucial role in inducing the extreme drought, have not been fully studied. In this study, we analyze the water vapor circulation during the 2019 drought event using the land‐atmosphere water balance and a backward trajectory model for moisture tracking. Our results indicate that the precipitation in the M‐LMRB from May to October 2019 was only 71.9% of the long‐term climatological mean (1959–2021). The low precipitation during this drought event can be attributed to less‐than‐normal external water vapor supply. Specifically, the backward trajectory model reveals a decrease in the amount of water vapor transported from the Indian Ocean, the Bay of Bengal, and the Pacific Ocean, which are the main moisture sources for precipitation in the region. Comparing the atmospheric circulation patterns in 2019 with the climatology, we identify anomalous anticyclone conditions in the Bay of Bengal, anomalous westerlies in the Northeast Indian Ocean, and an anomalous cyclone in the Western Pacific Ocean, collectively facilitating a stronger export of water vapor from the region. Therefore, the dynamic processes played a more significant role than thermodynamic processes in contributing to the 2019 extreme drought event.

Understanding Precipitation Moisture Sources and Their Dominant Factors During Droughts in the Vietnamese Mekong Delta

AbstractThe Vietnamese Mekong Delta (VMD) is the most productive region in Vietnam in terms of agriculture and aquaculture. Unsurprisingly, droughts have been a prevalent concern for stakeholders across the VMD over the past decades. However, the VMD precipitation moisture sources and their dominant factors during drought conditions were not well understood. Using the ERA5 reanalysis data as inputs, the Water Accounting Model‐2layers (WAM‐2layers), a moisture tracking tool, was applied to identify the VMD precipitation moisture sources from 1980 to 2020. The modeling simulation indicates that the moisture sources transported from the upwind regions dominate the VMD precipitation by 60.4%–93.3%, and the moisture source areas vary seasonally with different monsoon types. Results of the causal inference algorithms indicate that the humidity and wind speed in the upwind area are the dominant factors for driving moisture transport and determining the amount of VMD precipitation in dry and wet seasons, respectively. The local atmospheric conditions may also have a causal effect on moisture recycling. During the drought events in 2015–2016 and 2019–2020, the reduced moisture transport in the 2016 dry season was mainly caused by the anomalies in both humidity and wind speed, while the below average moisture sources in the 2020 dry season were dominated by humidity. In the 2019 wet season, an anomaly in wind speed led to a decrease in the tracked moisture. These findings are of great significance for understanding the moisture sources of precipitation and further improving drought prediction in the VMD.

Moisture sources of precipitation over the Pearl River Basin in South China

AbstractMoisture sources and transport processes play a critical part in hydrological cycle and determine regional precipitation. This paper utilizes the Water Accounting Model‐2layers (WAM‐2layers) and the ERA5 reanalysis data to track the sources of precipitation over the Pearl River Basin (PRB). The contribution of external moisture and the role of local recycling are investigated. The results show that during the period from 1980 to 2020, oceanic sources including the western North Pacific and Indian Oceans serve as the primary moisture sources of precipitation over the PRB. The contributions to total seasonal precipitation are respectively 62.57% in MAM, 54.79% in JJA, 43.70% in SON and 60.88% in DJF. By contrast, the contribution of local recycling is generally below 5.50%. In the dry years of 1994, 1997 and 2001, the contribution of terrestrial sources is about 19.22%; in the wet years of 1989, 2009 and 2011, the contribution is about 16.31%. The summer precipitation anomalies are mainly attributable to moisture anomalies from the Equatorial Indian Ocean in the wet years and from Southeast Asia in the dry years. Furthermore, vertically integrated moisture flux anomalies over the boundaries of the PRB are generally the result of anomalous wind rather than anomalous moisture. In the wet years, low‐pressure systems induce strong cyclonic moisture transports, increasing the PRB precipitation. In the dry years, high‐pressure anomalies over the PRB block the moisture transports from the Indian Ocean and western North Pacific.

Effect of oasis and irrigation on mountain precipitation in the northern slope of Tianshan Mountains based on stable isotopes

Water is one of the scarcest resources in arid regions, and irrigation is an important means to improve crop yield and ensure food security. The Xinjiang features an integrated irrigation agriculture and oasis economy paradigm. However, the understanding of the impact mechanism and quantitative analysis of irrigation on precipitation is inadequate now. With the aim of clarifying the response relationship between mountain precipitation and irrigation in oasis, we clarify and quantify the moisture sources of precipitation using the Hybrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model and multisource data (including field-collected isotopes data, C-Isoscape, ERA5, and GDAS). The results obtained show: (1) Isotope analysis provides valuable insights into the climate background and precipitation recycling. The Local Meteoric Water Line's lower slope and intercept than Global Meteoric Water Line suggest a severe arid climate and strong sub-cloud evaporation. The intercept (13.44) of Local Meteoric Water Line in Mountain Areas exceeds the global average, indicating significant moisture recycling in mountain areas (MA). The d-excess in MA is prominent year-round, highlighting the influence of recycled moisture. (2) The oasis and irrigation influence the local precipitation through offset, remote, combination, and delayed effects. The offset effect hinders precipitation formation in irrigation areas (IA) due to the counteracting irrigation-induced humidification and cooling effect. Through the interaction of westerly circulation and local mountain-oasis hydrological cycle, irrigation-induced moisture is transported to MA and uplifted, which is remote effect. The combination effect synergistically enhances precipitation intensity, especially in intricate MA, through the combined influence of terrain's forced uplift and convective cells. Furthermore, the mountainous precipitation influenced by the mountain-oasis hydrological cycle often exhibits a delayed effect. (3) Based on HYSPLIT model tracking results, the contribution ratio of oasis and irrigation induced evapotranspiration to summer precipitation in MA is approximately 19.60%, ranging from 13.68% to 28.49%. The findings provide insights into the mechanisms of irrigation and water resource management in the northern slope of Tianshan Mountains.

Attribution of Moisture Sources for Summer Precipitation in the Upstream Catchment of the Three Gorges Dam

Abstract Currently, there is a lack of investigating moisture sources for precipitation over the upstream catchment of the Three Gorges Dam (UCTGD), the world’s largest dam. Using the dynamical recycling model (DRM), trajectory frequency method (TFM), and the Climate Forecast System Reanalysis (CFSR), this study quantifies moisture sources and transport paths for UCTGD summer precipitation from 1980 to 2009 based on two categories of sources: region-specific and source-direction. Overall, the land and oceanic sources contribute roughly 63% and 37%, respectively, of the moisture to UCTGD summer precipitation. UCTGD and the Indian Ocean are the most important land and oceanic sources, respectively, in which the southern Indian Ocean with over 10% of moisture contribution was overlooked previously. Under the influence of the Asian monsoon and prevailing westerlies, the land contribution decreases to 57.3% in June, then gradually increases to 68.8%. It is found that for drought years with enhanced southwest monsoon, there is a weakening of the moisture contribution from the C-shaped belt along the Arabian Sea, South Asia, and UCTGD, and vice versa. TFM results show three main moisture transport paths and highlight the importance of moisture from the southwest. Comparison analysis indicates that, generally, sink regions are more affected by land evaporation with their locations more interior to the center of the mainland. Furthermore, correlations between moisture contributions and indices of general circulation and sea surface temperature are investigated, suggesting that these indices affect precipitation by influencing moisture contributions of the subregions. All of these are useful for comprehending the causes of summer UCTGD precipitation. Significance Statement Quantitative research on the moisture sources of summer precipitation has been implemented for the upstream catchment of the Three Gorges Dam (UCTGD), which is of particular hydrological significance but has not been investigated previously. The dynamical recycling model (DRM)–trajectory frequency method (TFM) approach is used to quantify and interpret the results of the moisture sources both in different specific subregions and directions, which produce more meaningful results than a single method for the areal division of moisture sources. Furthermore, antecedent indices that significantly influence the following moisture contributions of the subregions and then summer UCTGD precipitation are studied in terms of large-scale general circulation indices, which would help our understanding of precipitation forecast for UCTGD.

Moisture sources for precipitation over the Pamirs Plateau in winter and spring

AbstractThe abundant precipitation over Pamirs Plateau (PP) in spring and winter plays a vital role in the water resources over the arid areas of Central Asia. Understanding the moisture sources and water vapour transportation associated with precipitation are very important, but there were few studies investigating the moisture sources of PP. We used a Lagrangian model driven with the Weather Research and Forecasting output to analyse the moisture sources at Northern Pamirs Plateau (NPP) and Southern Pamirs Plateau (SPP) in spring 2016, 2009 and 2001, and in winter 2016, 2010 and 2017, as the seasonal precipitation in PP was the largest, median and lowest during 2001 to 2018, and the precipitation in spring and winter was much higher than that in summer and autumn. The moisture sources from four regions were quantified: Atlantic‐Europe‐Africa, Arctic‐Northern Asia, Indian Ocean, and moisture recycling from the PP. Atlantic‐Europe‐Africa and Indian Ocean are the dominant moisture source regions in spring and winter, which contribute more than 70% to the total moisture affecting the precipitation at PP. The contributions of Indian Ocean are higher at SPP than those at NPP in spring and winter. The contributions from Arctic‐Northern Asia and PP are generally low, except that the moisture from PP region contributed 19% to the spring precipitation at NPP, indicating the importance of a local moisture source in enhancing the spring precipitation at NPP. The moisture contributions originating from the different source regions show great differences between winter and spring. The moisture transportation is affected by westerlies, and the zonal winds in spring affect the moisture transportation, while the meridional winds over the Arabian Peninsula mainly affect the moisture transportation in winter.

Tracking Moisture Sources of Precipitation Over China

AbstractMoisture of precipitation originates from terrestrial and oceanic evaporation through atmospheric transport. Understanding the contributions from different moisture sources to precipitation is essential for the hydrologic study. China is the world's third largest country in terms of land area and has contributed 25% of the global net increase in vegetation leaf area since 2000. Thus, it provides a good platform to understand the contributions from different moisture sources to precipitation and how increasing vegetation greenness affects precipitation trends. In this study, we investigated the moisture sources of precipitation and their changes in China during 1980–2018 based on the UTrack moisture recycling data set. We found that 47.3% of the moisture was from oceanic evaporation, and 52.7% was from terrestrial evapotranspiration (ET). For the moisture from terrestrial ET, 33.0% was from vegetation transpiration. The observed annual precipitation showed a significant increasing trend with 2.07 mm/year in China from 1980 to 2018. Increasing moisture from oceanic evaporation contributed the most to the increasing precipitation trend (0.98 mm/year), followed by the increasing moisture from vegetation transpiration (0.72 mm/year) and other terrestrial evaporation (0.37 mm/year). The increasing contribution of vegetation transpiration from China was comparable with that from neighboring countries (0.37 vs. 0.35 mm/year). The increasing moisture from vegetation transpiration could be due to the nationwide afforestation projects in China since 1999. The results provide a reference for understanding changes in precipitation and hydrologic processes.

Extreme precipitation stable isotopic compositions reveal unexpected summer monsoon incursions in the Qilian Mountains

Isotope composition and moisture sources of precipitation are important for understanding water cycles and reconstructing paleoclimate. Based on 15-years' precipitation stable Isotope composition (δ18O and δ2H) from four stations of the Qilian Mountains, we found unique δ18O and δ2H features associated with the incursion of the summer monsoon over the Qilian Mountains, northwestern China. In 12 of the 15 years, similar seasonal variations of δ18O and δ2H confirmed a dominant source of moisture from Westerly circulation, and higher intercepts of the local meteoric water line (LMWL) indicated strong recycling of continental moisture. However, in August 2016 and 2018, extremely low slopes and intercepts of the LMWL, and more negative δ18O and δ2H revealed substantial contributions of the Asian summer monsoon to precipitation of the Qilian Mountains, with extremely heavy precipitation in August 2016. The column moisture flux, land-sea thermal contrast, correlations of precipitation δ18O with East Asian Summer Monsoon Index and Westerlies Index, HYSPLIT modeling results and precipitation δ18O along backward trajectories confirmed incursions of the summer monsoon in August 2016 and 2018. Our redefining of the boundary of the summer monsoon region confirmed the summer monsoon incursion zone can extend to the west of longitude 96°E and north of latitude 40°N in strong monsoon years, corresponding to boundaries of monsoon incursions in the mid-Holocene. Temperature correlated with precipitation δ18O at monthly and shorter time scales, but not for whole seasons or at yearly scale, revealing that summer monsoon incursions are therefore more likely than changing temperature to explain the multi-year cycles in the Qilian Mountains ice archives. Continent-scale shifts in atmospheric circulation strongly influence water resources in the Qilian mountains, and may change in frequency as climate warms. This study therefore has important implications for understanding water resources in the Qilian mountains in the past and into the future.

Warm Season Extreme Flood Events in the Midwestern US—Sources of Moisture and Physical Mechanisms

AbstractA comprehensive picture of the development of warm season extreme floods in the Midwestern US is presented. We first identify the climatological moisture sources for precipitation in the Midwest using the two‐layer dynamic recycling model (2L‐DRM) with ECMWF Reanalysis v5 (ERA5) data. Terrestrial sources supply most of the moisture for Midwestern US precipitation during the warm season, while oceanic sources dominate during the cold season. The Empirical Orthogonal Function (EOF) analysis is used to select extreme flood events characterized by both positive soil moisture and precipitation anomalies. During the warm season flood events, moisture coming from oceanic sources increases by more than 45% compared to the climatology. In addition, our results show that moisture can come from remote regions due to sustained anomalous circulation. Low‐level circulation anomalies associated with wave trains that traverse the continent enhance moisture contributions from terrestrial sources along narrow paths. However, moisture budget analysis reveals that the primary flood‐producing mechanism is the convergence of moisture due to intense circulation anomalies. Moisture advection and thermodynamic terms are responsible for flood termination. Our results suggest that knowledge of antecedent wet soil moisture conditions is unlikely to improve the predictability of flood‐producing storms.

Moisture sources for precipitation variability over the Arabian Peninsula

We apply the Lagrangian-based moisture back trajectory method to two reanalysis datasets to determine the moisture sources for wet season precipitation over the Arabian Peninsula, defined as land on the Asian continent to the south of the Turkish border and west of Iran. To accomplish this, we make use of the evaporative source region between 65°W–120°E and 30°S–60°N, which is divided into twelve sub-regions. Our comparison of reanalyses and multiple observations allows us to validate datasets and highlight broad-scale similarities in characteristics, notwithstanding some inconsistencies in the southwest AP. The results indicate north-to-south spatiotemporal heterogeneity in the characteristics of dominant moisture sources. In the north, moisture for precipitation is mainly sourced from midlatitude land and water bodies, such as the Mediterranean and Caspian Seas. Areas further south are dependent on moisture transport from the Western Indian Ocean and parts of the African continent. The El Niño-Southern Oscillation (ENSO) exhibits an overall positive but sub-seasonally varying influence on the precipitation variability over the region, with noticeable moisture anomalies from all major source regions. A significant drying trend exists over parts of the Peninsula, which both reanalyses partially attribute to anomalies in the moisture advection from the Congo Basin and South Atlantic Ocean. However, considerable uncertainty in evaporation trends over the terrestrial evaporative sources in observations warrants additional modeling studies to further our understanding of key processes contributing to the negative trends.

Climatological variations of moisture sources for precipitation of North Atlantic tropical cyclones linked to their tracks

The tropical cyclones (TCs) trajectories are mainly controlled by the large-scale parameters related with the steering flow. We used the HURDAT2 database from 1980 to 2018 for grouping the tracks of TCs formed in the North Atlantic (NATL) main development region into straight moving (SM), recurving landfall (RCL) and recurving ocean (RCO). Based on this classification, we investigated the changes in the moisture sources' contributions to the precipitation along the TCs trajectories for each track category by applying a Lagrangian moisture source diagnostic method to the air parcels pathways from the FLEXPART model. The highest moisture contribution occurred within 3-5° from the average TCs trajectories. The moisture supplied from the Gulf of Mexico represented 19.1% of humidity gained by SM but was negligible for recurving TCs. Likewise, the Caribbean Sea contributed 31.8% for SM, and its humidity support notably decreased for recurving storms to 0.9–8.3%. In addition, the moisture uptake from the tropical NATL was similar for all track types. The western NATL increased the moisture supply from 15.3% for SM to 31.1% for RCO and 42.6% for RCL, while the eastern subtropical NATL provided 3.1% of moisture to SM, 12.5% to RCL and 45.4% to RCO. It was also notable the moisture support from the terrestrial source southeastern United States (5.3%) for RCL tracks. Furthermore, we found that El Niño–Southern Oscillation, the North Atlantic Oscillation, the Atlantic Multidecadal Oscillation and the Atlantic Meridional Mode influence the moisture contributions variability from sources for each track type.

Influences of variability of stable isotopes and composition of moisture sources on precipitation at multiple timescales in the Alpine regions of Central Asia

The accurate representation of variability of isotopic composition of modern precipitation based on long-term continuous monitoring is vital for interpreting hydrological and climatic processes. Based on measurements of δ2H and δ18O of 353 precipitation samples from five stations in the Alpine Mountains of Central Asia (ACA) during 2013–2015, the spatiotemporal variability of isotopic composition of precipitation and its controlling factors under multiple timescales were explored. Results showed that (1) the stable isotopes in precipitation at multiple timescales displayed an obviously inconsistent trend, especially in winter. (2) δ18O composition of precipitation (δ18Op) under multiple timescales had a significant correlation with the variability of air temperature, except for in the case of the synoptic scale, while the correlation was weak between precipitation amount and variability in altitude. (3) The westerly wind had a stronger influence on the ACA, the southwest monsoon had an important influence on the transport of water vapor in the Kunlun Mountains region, and Arctic water vapor had a higher contribution to the region of the Tianshan Mountains. (5) The contribution rate of recycled vapor to precipitation ranged from 15.44 to 24.11 %, and the composition of moisture source of precipitation in arid inland areas of Northwestern China exhibited spatial heterogeneity. The results of this study improve our understanding of the regional water cycle and will enable the optimization of the allocation of regional water resources.

Moisture Sources of Precipitation in the Great Lakes Region: Climatology and Recent Changes

AbstractGiven the critical role of precipitation on hydroclimate, we quantified the contributions of moisture source regions to precipitation in the Great Lakes Region (GLR) using multiple reanalysis data sets. Results show that the Great Plains (GPs) and the GLR itself are the primary sources of moisture. The moisture sources for the double peaks in the GLR precipitation that occur in June and September are identified, which is caused by a shift in the peak timing of moisture contribution from the GLR and GPs. In particular, moisture from the GPs contributes more to the heavy precipitation, while moisture from the GLR contributes more to the light precipitation. We also found a statistically significant (p < 0.05) increasing trend in the moisture contribution from the mid‐Pacific, caused by an intensified zonal moisture transport from the mid‐Pacific through changes in atmospheric circulation.

Isotopic compositions (δD, δ18O) and end-member mixing for the control interface in a complex tidal region

Identifying the mixing processes of waters and currents in tidal reach is an important aspect of environmental management to protect freshwater resources and prevent water pollution. In this study, three field investigations conducted in a typical tidal reach in August, November and the following April focused on two isotopes (δD and δ18O) and salinity. A salinity-isotope conservative mixing model was established to differentiate water flows of the important control interface (CI) from freshwater, transition zone and saltwater end-members. Results suggested that the average δD and δ18O values during the ebb and flood tides depleted from August to November, then enriched significantly in the following April and were even higher than those in August. The δD and δ18O values in the saltwater zone enriched markedly compared with those in freshwater zone and transition zone due to the stronger evaporation occurring in the saltwater zone. Based on the revised model, the average contributions of freshwater end-member, transition zone end-member and saltwater end-member in three months were, respectively, 51.50 %, 36.93 % and 11.57 %. However, the contributions of freshwater and transition zones in April end-member were equivalent (47.45 % vs 44.31 %). Meanwhile the largest contribution of saltwater end-member was 20.56 % and occurred in August. The proportions of three end-members that contributed to CI changed with different evaporation scenarios and moisture sources of precipitation. Our research provides important information that furthers our understanding of the isotopes and their applications to environmental management in estuarine regions.

Last millennium hydroclimate and atmospheric circulation change in Northeast China: A dual δ13C and δ18O approach from a mountaintop Sphagnum bog

Northeast China receives most moisture through warm air masses from the western Pacific Ocean and some moisture from the Eurasian Continent predominantly through the westerlies. Changes in the contribution of these different moisture sources affect the amount and isotopic composition of precipitation, which would in turn influence peatland surface moisture and peat moss (Sphagnum) growth. Recently a dual δ13C and δ18O approach from peat-core archive has been used not only as a proxy for peatland moisture/wetness but also as a constraint for interpreting isotope in precipitation and moisture trajectories. Here we used the coupled δ13C and δ18O measurements of peat moss cellulose, along with macrofossil and other proxy data, from a well-dated peat core retrieved from a Sphagnum-dominated ombrotrophic (meteoric water-fed) bog in Northeast China to reconstruct regional climate and moisture sources of precipitation over the last millennium.Our results show no sign of extremely negative δ13C signals that would have been caused by the uptake of respired CO2 by peat moss for photosynthesis, thus we argue that the cellulose δ13C signatures document the peatland moisture conditions, owing to water-film effect. We found a positive correlation between δ13C and δ18O, suggesting that δ18O primarily reflects the δ18O signal in precipitation rather than evaporative 18O-enrichment, because the evaporative enrichment would result in a negative correlation between these isotopes as documented in modern process studies along the hummock-hollow moisture gradients. We propose that the positive δ13C-δ18O correlation is a general feature in regions that are influenced by both summer monsoon and the westerlies, as warm Pacific moisture that has high δ18O values also brings abundant precipitation, resulting in wet conditions that induce high δ13C values, and vice versa. The δ13C results show a decrease of ca. 6‰ from −23 to −29‰, with large-magnitude fluctuations, over the last 1000 years, suggesting a long-term drying trend. An abrupt decrease at 1370 CE of 4‰ in δ18O from >21‰ to ca. 17‰ represents the transition from the warm and wet Medieval Climate Anomaly (MCA) at 815–1370 CE to the cold and dry Little Ice Age (LIA) at 1370–1940 CE, reaching the lowest δ18O value of ca. 15‰ at around 1850 CE. The increase in δ18O to 19‰ after 1900 CE reflects post-LIA climate warming. Enhanced moisture transport from the western Pacific might have contributed to the warm and wet MCA. Three short intervals with pronounced low δ13C and δ18O values occurred at 1370–1450 CE, the 19th Century, and the 1990s, suggesting extreme dry periods with reduced Pacific moisture inputs. The driest period with consistently low δ13C value of < -25‰ (Suess effect-corrected value of −23‰) occurred after 1990 CE, with a corresponding increase in dry-adapted moss Polytrichum.Variability in the regional atmospheric circulation—the western Pacific subtropical high (WPSH)—might have explained the change in moisture sources. The westward extension of the WPSH—often corresponding with the El Niño-like conditions—would block the Pacific moisture from transporting to Northeast China. Our record, together with other paleo-records over monsoon-influenced regions in East Asia, shows synchronous but opposite shifts of summer rainfall anomalies in North or Northeast China and South China on decadal to centennial scales, substantiating a coherent atmospheric circulation pattern associated with WPSH and ENSO variability. We argue that there were major shifts in synoptic-scale atmospheric circulation and associated hydroclimate change during the MCA, LIA, and Current Warming Period in Northeast China.

Is the deuterium excess in precipitation a reliable tracer of moisture sources and water resources fate in the western Mediterranean? New insights from Apuan Alps (Italy)

The deuterium excess is a function of the isotopic composition of oxygen and hydrogen in water. Traditionally, the d-excess is used worldwide to constrain the moisture sources of precipitation, as it mainly depends on the relative humidity and surface sea temperature at the evaporative sources, that control diffusion of the water molecules across the density gradient. A case in point is represented by precipitation deriving from vapor originating over the eastern Mediterranean Sea, characterized by the higher d-excess values (∼22‰) compared to the global average d-excess in precipitation of 10‰. Accordingly, d-excess values of ∼14‰ found in precipitation across the western Mediterranean are generally interpreted as the result of mixing of Atlantic and Mediterranean air masses. Nevertheless, several studies proved the d-excess values of precipitation evolves during transport of vapor and changes depending on local processes (e.g. sub-cloud evaporation of raindrops, continental moisture recycling, seeder-feeder mechanism), thus compromising the reliability of d-excess as a proxy of vapor source regions. With the aim to investigate the pattern of d-excess in precipitation at higher spatial and temporal resolution, and to evaluate its reliability for tracing the moisture source in the western Mediterranean, in this work we present the results of a study performed in the Apuan Alps (Tuscany, Italy), one of the rainiest areas in Italy. 19 single rain events were collected from 2020 to 2021 at two sites placed at different altitudes. Furthermore, monthly precipitations were collected at five sites at different elevations over different time intervals from 2019 to 2021. Event-based and monthly Local Meteoric Water Lines were computed at each site, indicating droplets evaporation beneath the clouds, especially at lower altitude sites. d-excess seasonally and spatially varied, with higher values registered at higher altitudes in winter and autumn, and lower values at lower altitudes in spring and summer. Large differences in d-excess were found among sites placed at different altitudes, and these differences ranged both at monthly and event scales. Mean and weighted mean d-excess vertical gradients of +0.73‰/100 m (r2 = 0.92) and +0.51‰/100 m (r2 = 0.95), respectively, were computed using 9 months in which monthly samples were collected at all five sites. This positive relationship between altitude and d-excess in precipitation is consistent with a process like sub-cloud evaporation that appears to be the most important process controlling the d-excess spatial variability in the mountainous areas. These findings evidence the importance of local processes acting on the d-excess and downsize the reliability of this parameter in tracing moisture sources in this area. Conversely, the d-excess vertical gradient, combined with the δ18O vertical gradient (i.e. altitude effect), could be used to identify the recharge areas of groundwater.

Isotopic composition and moisture sources of precipitation in midlatitude regions characterized by extratropical cyclones’ route

• The stable isotopes and water origins were investigated in the vicinity of Japan. • The effect of cyclone route on the stable isotopes and water origins was clarified. • The Sea of Japan cyclone induced higher δ 2 H and d-excess in the Pacific Ocean. • The Pacific cyclone caused lower δ 2 H and d-excess in the Pacific Ocean. • Results have implications for hydrological and paleoclimate studies using δ values. Isotopic composition and their corresponding moisture sources of precipitation are important for understanding water cycles and reconstructing paleoclimate. To clarify the isotopic composition and water origins, we sampled precipitation diurnally at Sapporo, Northern Japan, and simulated the isotopic composition and moisture sources by using an isotopic regional spectral model for the 2014/2015 winter period. During the period, ten intensified extratropical cyclones, approached Northern Japan, were classified as Sea of Japan cyclone and Pacific cyclone according to the cyclone route. For precipitation at Sapporo, the Sea of Japan cyclone induced higher δ 2 H with more moisture from the Kuroshio region, whereas the Pacific cyclone triggered precipitation to Sapporo with lower δ 2 H and more moisture from the North Pacific Ocean. Regarding moisture transport within the extratropical cyclone frontal system for both cyclone types, moisture transported by the warm conveyor belt from the Kuroshio region mainly condensed in the cold and eastern warm fronts with high δ 2 H and d-excess, resulting from a high sea surface temperature and low humidity during evaporation; in contrast, vapors transported by the cold conveyor belt from the North Pacific Ocean precipitated in the western warm front and cyclone center with low δ 2 H and d-excess, arising from a low sea surface temperature and high humidity. With respect to the cyclone route effect on the geographical distribution of isotopic characteristics around Japan, when the Sea of Japan cyclone occurred, condensation in the Pacific Ocean showed higher δ 2 H and d-excess with more moisture from the Kuroshio via the warm conveyor belt. In contrast, during passage of the Pacific cyclone, condensation in the Pacific Ocean exhibited lower δ 2 H and d-excess with more vapors from the North Pacific Ocean via the cold conveyor belt. These phenomena observed around Japan could be applied in other midlatitude regions and for hydrological, biogeochemical, and paleoclimate studies.

Influence of Sub-Cloud Secondary Evaporation and Moisture Sources on Stable Isotopes of Precipitation in Shiyang River Basin, Northwest China

Fractionation of stable isotopes in precipitation runs through the water cycle, and deuterium excess is a second-order parameter linking water-stable oxygen and hydrogen isotopes. It is strongly influenced by under-cloud evaporation in unsaturated air, especially in arid climates. Based on the improved Stewart model, this study used 670 precipitation stable isotope data and measured meteorological element data from 11 sampling points from January 2018 to September 2019 to verify the existence of sub-cloud secondary evaporation in the Shiyang river basin and quantitatively calculate the intensity of sub-cloud secondary evaporation and its influence on precipitation stable isotopes. The study used the vapor flux and the improved Lagrangian model to track the moisture source of precipitation and analyze the influence of the moisture source of different paths on the stable isotopes of precipitation. Therefore, this study is helpful to understand the evapotranspiration loss mechanism and recharge mechanism of moisture in the watershed. The results showed that there is sub-cloud secondary evaporation in the Shiyang River Basin, and from the seasonal scale, the sub-cloud secondary evaporation is stronger in spring and summer, but weaker in autumn and winter, which makes heavy isotopes enriched in spring and summer and depleted in autumn and winter. From the perspective of spatial distribution, the sub-cloud secondary evaporation is stronger in the midstream and downstream of the Shiyang river, resulting in more enrichment of heavy isotopes. In the vertical direction, the sub-cloud secondary evaporation at 850–700 hPa is the strongest, which enriches the heavy isotope in this layer and reduces the deuterium excess. In addition, the main moisture source of precipitation in the Shiyang River Basin is the westerly air mass, and the mid and high-latitude land sources contribute more moisture to the precipitation. However, the supply of the sea source is very limited, which makes the deuterium excess of precipitation higher and does not show regional consistency and seasonality well.