Modified Carbon Fiber Research Articles

ZnO modified carbon fiber-matrix interfacial evaluation via nanoscale digital image correlation and nanoindentation

Improving the adherence of the fiber-matrix interface is an important step for enhancing the capabilities of polymer composites. In this study, carbon fibers were modified by growing zinc oxide (ZnO) nanorods on the fiber surface using a hydrothermal approach, with the aim of increasing the interfacial area and enhancing the friction between the fiber and the matrix. To fully understand the deformation mechanisms at the interface, a microscale evaluation combining nanoindentation with digital image correlation (DIC) for mapping the deformations by using nanoscale speckles is developed in this work. The main objective of this research was to develop a protocol for speckling the modified single fiber composite and show that DIC can be used in microscopic level and to evaluate the fiber-matrix interface by means of nano indentation. The speckle pattern was created using Ti nano powder and used to generate the strain maps in the fiber-matrix interface region. A comparative analysis of DIC results from ZnO modified carbon fibers has shown that shear strains around the interfacial boundary are 60 % reduced on average, as compared to neat carbon fibers, across all nano indentations from 8mN to 65mN of peak load. Results used direct strain measurements to confirm that modification by ZnO growth on the surface of individual fibers has a significant benefit to the interfacial mechanical properties of fiber-matrix composites.

Surface matching design of carbon fiber composite honeycomb

Applying carbon fiber composite honeycomb in curved sandwich shells faces challenges due to the saddle-shaped bending surface in hexagon configurations and potential damage during the shape-forming process. This study analyzes the bending deformation of honeycombs by developing large deformation theoretical model for their bending surfaces. The study introduces two novel honeycomb configurations—Boomerang-shaped with a positive Poisson's ratio and Jellyfish-shaped with a negative Poisson's ratio—achieved through curved-wall design and fabrication using a modified carbon fiber composite tape winding molding process. Experimental tests, including bending deformation and shape-forming tests, measure the three-dimensional bending surfaces and mechanical responses of carbon fiber composite honeycombs. Additionally, a developed finite element model analyzes the damage states of various carbon fiber composite honeycombs during shape-forming processes. The results reveal the bending deformation of carbon fiber composite honeycombs and present damage state cloud maps to facilitate the optimal matching of objective sandwich shells with minimal scathe.

Polydopamine modified carbon fiber to improve the comprehensive properties of carbon paper for proton exchange membrane fuel cell

In this study, polydopamine (PDA) was used to modify functional groups on the surface of carbon fiber (CF), and the effects of different dopamine hydrochloride (DPH) concentrations on the surface morphology, functional groups, contact angle and dispersion stability of CF were studied. Subsequently, the raw carbon paper (RCP), hot-pressed carbon paper (HPCP) and carbon paper (CP) were prepared successively using the modified CF through wet forming, impregnation/hot-pressing, and carbonization methods. The surface morphology, tensile strength, flexural strength, electrical resistivity, air permeability and pore size distribution were analyzed for these materials. It was observed that the introduction of −OH and − NH2 groups improved the hydrophilicity and dispersion of PDA modified CFs, resulting in an increase in formation index (FI) from 39.2 to 48.1 for RCP samples. With increasing DPH concentration, the tensile strength of CP initially increased but then decreased while its electrical resistivity showed an opposite trend. Finally, PDA modified CP was assembled into proton exchange membrane fuel cells (PEMFC). The PEMFC assembled from DPH-CP-2.5 achieved a maximum limiting current density of 1440.0 mA/cm2 and power density of 458.25 mW/cm2. Meanwhile, the lower material transmission impedance for DPH-CP-2.5 as well as excellent water management ability and gas transmission performance.

Multiple Tin Compounds Modified Carbon Fibers to Construct Heterogeneous Interfaces for Corrosion Prevention and Electromagnetic Wave Absorption

HighlightsExcellent impedance matching through component modulation engineering.Rich heterogeneous interfaces are constructed to realize excellent electromagnetic wave (EMW) absorption performance.Long-term corrosion protection and excellent EMW absorption properties.

In situ growth of graphene on carbon fibers to enhance the mechanical and thermal conductivity of epoxy composites

High-strength and high-thermal-conductivity composite materials have become crucial requirements for thermal control systems in various field. Carbon fiber-reinforced polymer (CFRP) has demonstrated potential superior performance. However, the application of CFRP is limited by the chemical inertness of the carbon fiber surface and the shortness of low surface energy. Therefore, surface modification of carbon fibers is necessary. This research employs a pulse plasma discharge method, to in-situ grow graphene on the surface of carbon fibers by disrupting some polymer structures on the carbon fiber surface in a “bottom-up” approach. This method offers advantages such as rapid, simple, convenient, economical, and environmentally friendly preparation process., the modified carbon fibers used in CFRP exhibit superior mechanical and thermal conductivity properties. The flexural strength increased by 218 % to reach 109.5 MPa, and the thermal conductivity increased by 251 % to achieve 1.153 W/(m*K).

Highly Sensitive Potentiometric pH Sensor Based on Polyaniline Modified Carbon Fiber Cloth for Food and Pharmaceutical Applications.

This study introduces a potentiometric pH sensor that is extremely sensitive and specifically designed for food and pharmaceutical applications. The sensor utilizes a pH-sensitive interface fabricated by electropolymerizing polyaniline (PANI) on carbon fiber cloth (CFC). Structural and morphological analyses of PANI-CFC and CFC have been conducted by using X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), and X-ray photoelectron spectroscopy (XPS). The investigation of the functional groups was conducted by using Fourier transform infrared spectroscopy (FTIR) and Raman spectroscopy. The electrochemical characteristics were assessed by utilization of cyclic voltammetry (CV) and open-circuit potential (OCP) measurements in a three-electrode configuration. The sensor exhibited a sensitivity of 60.9 mV/pH, while retaining consistent performance within the pH range of 4 to 12. The repeatability and robustness of the sensors were verified. The accuracy of the PANI-CFC sensor was confirmed by validation using real samples, demonstrating its compatibility with commercially available pH sensors. The application of density functional theory (DFT) calculations revealed an interaction energy of -173.2886 kcal/mol, indicating a strong affinity of H+ ions towards PANI-CFC electrode. Further investigation was conducted to examine the chemical reactivity of PANI, revealing a HOMO-LUMO energy gap of -0.98 eV. This study highlights the PANI-CFC sensor as a reliable and efficient pH-sensing platform for food and pharmaceuticals applications, performing robustly in both laboratory and real-world settings.

Competence of Carbonaceous Fibers/Nanofillers (Graphene, Carbon Nanotube) Reinforced Shape Memory Composites/Nanocomposites Towards Aerospace—Existent Status and Expansions

Abstract Shape memory or stimuli responsive polymers have established a unique grouping of smart materials. The technical merit of these polymers has been evaluated in aerospace sector, since last few decades. Particularly, the stimuli responsive polymers render inherent competences to recuperate the structural damages in exterior/interior space architectures. In this context, both the thermoplastics as well as thermosetting polymers depicted essential stimuli responsive behaviour. As interpreted in this state-of the-art review, the carbonaceous reinforcement like carbon fibers and nano-reinforcements including nanocarbons (graphene, carbon nanotube) have been employed in the shape recovering matrices. The performance of ensuing shape retrieving aerospace materials was seemed to be reliant on the polymer chain crosslinking effects, filler/nanofiller dispersal/alignment, microstructural specs, interfacial contour and interactions, and processing techniques used. Consequently, the shape actuations of polymer/carbon fiber composites were found to be instigated and upgraded through the inclusion of nanocarbon nano-additives. The ensuing high-tech shape memory composites/nanocomposites have anomalous significance for various aero-structural units (fuselage, wings, antennas, engines, etc.) due to prevention of possible thermal/shock/impact damages. Future implications of carbonaceous shape memory composites/nanocomposites in aerospace demands minimizing the structure-property-performance challenges and large scale fabrication for industrial scale utilizations. In this way, deployment of carbonaceous nanofiller/filler based composites revealed enormous worth due to low density, anti-fatigue/wear, anti-corrosion, non-flammability, self-healing, and extended durability and long life operations. However, there are certain challenges associated with the use of nanocarbons and ensuing nanocomposites in this field markedly the adoption of appropriate carbon fiber coating technique, aggregation aptitude of nanocarbons, additional processing steps/cost, nanoparticle initiated invisible defects/voids, difficulty in machinability operations due to presence of nanoparticles, and corrosion risk of composite structures in contact with metal surfaces. By overcoming these hinderances, nanoparticles modified carbon fiber based composites can be promising towards a new look of upcoming modernized aerospace industry.

Interfacial chemistry and structural engineering modified carbon fibers for stable sodium metal anodes

Interfacial chemistry and structural engineering modified carbon fibers for stable sodium metal anodes

Modification of carbon fiber with barium hexaferrite nanostructures

Modification of carbon fiber with barium hexaferrite nanostructures

Design, Manufacturing, and Evaluation of Race and Automotive Prototypal Components Fabricated with Modified Carbon Fibres and Resin.

This study explores the enhancement of Carbon Fibre Reinforced Polymers (CFRPs) for automotive applications through the integration of modified carbon fibres (CF) and epoxy matrices. The research emphasizes the use of block copolymers (BCPs) and electropolymerisation techniques to improve mechanical properties and interfacial adhesion. Incorporating 2.5 wt.% D51N BCPs in the epoxy matrix led to a 64% increase in tensile strength and a 51.4% improvement in interlaminar fracture toughness. The electropolymerisation of CFs further enhanced interlaminar shear strength by 23.2%, reflecting a substantial enhancement in fibre-matrix interaction. A novel out-of-autoclave manufacturing process for an energy absorber prototype was developed, achieving significant reductions in production time and cost while maintaining performance. Compression tests demonstrated that the modified materials attained an energy absorption rate of 93.3 J/mm, comparable to traditional materials. These results suggest that the advanced materials and manufacturing processes presented in this study are promising for the development of lightweight, high-strength automotive components, meeting rigorous performance and safety standards. This research highlights the potential of these innovations to contribute significantly to the advancement of materials used in the automotive industry.

Enhancing mechanical properties of cementitious composites by boron nitride nanosheets modified carbon fiber

Carbon fiber (CF) is commonly employed to enhance the mechanical properties, electrical conductivity, and electromagnetic absorption properties of cementitious composites. However, its weak interfacial bonding with the matrix limits its application in such composites. In this study, boron nitride (BN) nanosheets were synthesized via the solid-state reaction and used to modify CF surface. The flexural and compressive strengths of cementitious composites incorporating BN nanosheets coated CF (BN@CF) increased by 18.45 % and 29.38 %, respectively, with CF doping at only 0.2 wt%. Isothermal calorimetry and TGA results revealed that BN nanosheets on CF surface would provide nucleation sites for the formation of C–S–H and CH. The microstructure and bonding properties of BN@CF were characterized using SEM/EDS, FTIR, XPS, finite element analysis, and single fiber pullout test. The results showed that the significant improvement of interfacial properties between the fiber and the matrix contributed to the increase of mechanical properties of cementitious composites. These findings provide an effective strategy for the strength development of CF-reinforced cementitious composites.

Convenient and Accurate Detection of Dopamine and Glucose by Modifying Carbon Fiber Electrodes

Fast, sensitive, and low-cost high-performance detectors have gradually become an indispensable tool for people to keep healthy, and sensors are the key devices of detection equipment. In this work, a ZnO nanocrystal modified carbon fiber electrode was prepared using a hydrothermal method, and on this basis, a galvanostatic point deposition method was used to load copper nanoparticles to prepare a sensor electrode. Scanning electron microscopy and X-ray diffraction were used to comprehensively analyze composition, morphology, and environmental adaptability of the prepared electrodes. The DPV test was used to verify the enhanced effect of ZnO nanorods on neurotransmitter detection. The ZnO/CF showed an obvious electrical signal (0.22 V, 4 × 10−5A) in the detection of dopamine (DA) solution, and the Cu-NPs/ZnO/CF also showed excellent detection results in the glucose detection experiment., providing two excellent examples for the development of low-cost electrochemical sensors. The electrodes can specifically detect DA in the presence of ascorbic acid and uric acid, and the detection limit of the electrode for detecting DA is about 0.4 μM. In addition, the Cu-NPs/ZnO/CF electrode successfully realized the enzyme-free detection of glucose, and the detection limit could reach 0.5 μM.

Microstructure evolution and failure mechanism of 2D Cf/SiBCN–ZrB2 composite at elevated temperatures

SiBCN ceramic has already been widely used in the thermal insulation field. To further enhance their mechanical properties in high-temperature environments, the preparation of SiBCN and ZrB2 based pyrolytic carbon (PyC) modified carbon fiber reinforced composite, i.e., 2D Cf/SiBCN–ZrB2, was proposed in this study. By using five cycles of polymer impregnation and pyrolysis (PIP), the composite could be synthesized with a high flexural strength at room temperature, i.e., 275 ± 15 MPa. To understand the evolution of the microstructure caused by high temperatures and their influences on the mechanical properties, the composite samples were heat treated at 1200, 1400, 1600, and 1800 °C for 2 h, respectively. Comparing the flexural strengths of the samples before and after the heat treatments, and meanwhile combining the advanced microstructural characterizations, it was found that the composite was stable when the treating temperature was below 1400 °C, i.e., the flexural strength was 250 ± 15 MPa with a strength retention rate of over 90 %. However, once the temperature was above 1600 °C, due to the crystallization of SiBCN–ZrB2 matrix, the pyrolysis of PyC interfaces, the carbothermal reduction reaction and the erosion of carbon fibers, the mechanical properties of the composite would reduce to 74 ± 9 MPa. This study provides a new method for preparing 2D Cf/SiBCN–ZrB2, which reduces the number of PIP cycles of composite materials and enables rapid prototyping of composite materials. Additionally, this research can help materials scientists understand the mechanical properties of 2D Cf/SiBCN–ZrB2 composite materials in high-temperature environments and the evolution of their microstructure, identifying the range of application temperatures for 2D Cf/SiBCN–ZrB2.

Recyclable multiscale composite structural supercapacitor

AbstractThis study presents a proof‐of‐concept for a fully recyclable and sustainable composite structural supercapacitor. The fabricated device shows promising energy storage capabilities and mechanical strength. Generally, structural supercapacitors capacitance is considerably lower than non‐load‐bearing mono‐functional supercapacitors and are made via thermoset polymer electrolyte. Here, the device is fabricated using an optimized solid electrolyte composition of carbon aerogel modified carbon fibers, fumed silica, lithium salt, and a thermoplastic polymer matrix. The supercapacitor exhibits a high capacitance of 5225 mFg−1 (193 mFcm−2) at 1 mVs−1 scan rate and a large voltage window of 4 V. A simple dissolution/reprecipitation method is used to demonstrate the recycling feasibility, with minimal mechanical degradation (<10%) in the polymer matrix and no chemical structure changes in the electrolyte. This work establishes a promising ecologically‐sound structural energy storage technology with favorable performance compared to prior studies.Highlights A proof‐of‐concept fully recyclable composite structural supercapacitor is made. Thermoplastic‐based robust polymer electrolytes are fabricated. Recycling via dissolution and re‐precipitation of components is demonstrated. Comparison to prior structural supercapacitors shows favorable performance.

Polyamide 6/carbon fibre composite: An investigation of carbon fibre modifying pathways for improving mechanical properties

Carbon fibre-reinforced polyamide 6 (PA6) composites exhibit exceptional mechanical properties, making them a highly attractive material option for various industries. Their ability to combine the advantages of carbon fibres with the versatility of PA6 provides opportunities for lightweight, high-performance applications. This work presented the fabrication of a PA6/carbon fibre composition with carbon fibre was modified by two different chemicals: nitric acid and diglycidil ether bisphenol A (DGEBA). The tensile strength at break, flexural strength, Rockwell hardness and Izod impact were measured to compare the mechanical properties of composites based on the PA6 matrix with two different modified carbon fibres. The morphology of PA6-based composite with different modified carbon fibres was observed by scanning electron microscopy. The results showed that PA6 is more compatible with acid-modified carbon fibre than DGEBA-modified carbon fibre and unmodified carbon fibre. In comparison to composite materials containing unmodified carbon fibre and DGEBA-modified carbon fibre, composite containing acid-modified carbon fibre increase tensile strength (16–38% and 7–15%, respectively), flexural strength (18–66% and 51–70%, respectively), Izod impact (23–65% and 32–78%, respectively) and Rockwell hardness (50–400% and equivalence, respectively).

Real-time monitoring abscisic acid release from single rice protoplast by amperometry at microelectrodes modified with abscisic acid receptor PYL2

It was previously reported that stress induces a cellular production of abscisic acid in plants, but no direct method shows the evidence. Here, an electrochemical microsensor involving an abscisic acid receptor PYL2 modified carbon fiber microelectrode was fabricated by self-assembly method, where the Cu2+ combined with the histidine tag of PYL2 on the surface of microelectrode was used as the detection probe, the mediated reaction between Cu+ and ferricyanide realized the amplification responses and provided the microsensor with a high sensitivity for detection of abscisic acid with a detection limit of 0.8 nM. With use of this microsensor, an increase of extracellular abscisic acid from single rice protoplast induced by sulfate, osmotic and salinity stress was real-time monitored. Direct measurement of free extracellular abscisic acid in single plant cells might offer important new insights into its role in plants challenged by abiotic stresses.

Mechanical improvement of carbon fiber/epoxy composites by sizing functionalized carbon nanotubes on fibers

AbstractA sizing agent mainly consisting of polyethersulfone and acidified multi‐walled carbon nanotubes (MWCNT) was developed for surface modification of carbon fibers (CF) to enhance the interfacial bond and to form carbon fiber‐carbon nanotube (CF‐MWCNT) multiscale reinforcements. To prepare the modified carbon fiber/epoxy resin composites (CFRP), a vacuum molding technique was used in this study. The effects of the MWCNT‐containing sizing agent on the morphology and chemical structure of the CF surface were observed by scanning electron microscopy and Fourier transform infrared spectroscopy. The influence of MWCNT length and content on the mechanical properties of CFRP were also studied. The experimental results showed that the strength of the CFRP decreased with the increase of MWCNT length, and the MWCNT with a content of 0.05 wt% had a good reinforced effect on the CFRP. After the sizing treatment, the interlaminar shear strength (ILSS) of the CFRP is increased. These enhancements are attributed to the improved mechanical bonding and chemical bonding between CF and resin matrix. The MWCNT provides nanosized rough surface to CF and these acidified MWCNTs attached to the surface of CF with polar oxygen‐containing functional groups improve the compatibility with reinforcement and resin matrix.Highlights Carbon fiber was modified by a sizing agent mainly consisting of polyethersulfone and acidified carbon nanotube (CNT). CNTs enhance the interfacial chemical bonding and mechanical bonding. The CNT length affects the mechanical properties of the carbon fiber/epoxy resin composites (CFRP). The modified carbon fiber has enhanced the mechanical properties of the CFRP.

Self-powered biosensing sutures for real-time wound monitoring

Effective wound management has the potential to reduce both the duration and cost of wound healing. However, traditional methods often rely on direct observation or complex and expensive biological testing to monitor and evaluate the invasive damage caused by wound healing, which can be time-consuming. Biosensors offer the advantage of precise and real-time monitoring, but existing devices are not suitable for integration with sensitive wound tissue due to their external dimensions. Here, we have designed a self-powered biosensing suture (SPBS) based on biofuel cells to accurately monitor glucose concentration at the wound site and promote wound healing. The anode of the SPBS consists of carbon nanotubes-modified carbon fibers, tetrathiafulvalene (TTF), and glucose oxidase (GOx), while the cathode is composed of Ag2O and carbon nanotubes modified nanotubes modified carbon fibers. It was observed that SPBS exhibited excellent physical and chemical stability in vitro. Regardless of different bending degrees or pH values, the maximum power density of SPBS remained above 92%, which is conducive to long-term dynamic evaluation. Furthermore, the voltage generated by SPBS reflects blood glucose concentration, and measurements at wound sites are consistent with those obtained using a commercially available blood glucose meter. SPBS achieves the healing effect of traditional medical sutures after complete healing within 14 days. It offers valuable insights for intelligent devices dedicated to real-time wound monitoring.

Fabrication of GNPs sprayed carbon fiber and its effects on the interfacial and mechanical behavior of reinforced epoxy multiscale laminated composite

AbstractThe current research compares the effects of modifying carbon fiber [via spraying graphene nanoplates (GNPs)] and/or GNPs reinforcement on the mechanical and interfacial behavior of carbon fiber epoxy composites. Using a spraying method, the epoxy matrix was reinforced, and carbon fiber was modified with 0.2 and 1 wt% of GNPs, respectively. Tensile, interlaminar, and dynamic mechanical analyses (DMA) tests were conducted on the composite to assess the role of GNPs in enhancing mechanical, interfacial, and thermomechanical properties. The obtained results indicate that the spraying technique effectively enhanced the ultimate tensile strength (UTS) and interlaminar fracture toughness (ILFT) of the composite. The UTS improved by 31%, while the ILFT significantly improved by 38%. Additionally, assessing the modulus gradient through the interface shows improved interfacial interaction between modified carbon fiber and reinforced epoxy. Scanning electron microscopy examination of the fractured surfaces indicated that the existence of nanofillers with high surface area contributed to significant improvements in adhesion between the modified fiber and reinforced epoxy matrix, leading to enhanced interfacial, mechanical, and thermomechanical properties of CFRPs for structural applications.Highlights Incorporation of surface modified carbon fibers and GNPs reinforcement in the epoxy matrix to enhance the interfacial interaction. Evaluation of the effects of GNP nanofiller on interfacial and mechanical performance of the composite. Fracture surfaces in ILSS, tensile, and mode I test were analyzed using FESEM. Utilization of nanoscale modulus mapping for the fiber‐matrix interface assessment.

Preparation of biomimetic reinforced modified carbon fiber composites and study of their friction properties

Because aluminum-based parts cannot be used for long-term applications in large load-wear environments, nickel–tungsten (molybdenum disulfide)/carbon fiber/aluminum composites were successfully prepared in this study for that purpose. By adjusting the plating solution ratio, nickel–tungsten was used as a carrier to introduce molybdenum disulfide nanoparticles, forming a nickel–tungsten/molybdenum disulfide composite coating on the surface of carbon fibers. To enhance the interfacial bonding strength between the carbon fiber and aluminum matrix, a laser was employed to induce the formation of a honeycomb-like structure on the surface of the aluminum base. This increased the contact area between the carbon fiber, aluminum matrix, and epoxy resin adhesives, forming a nickel–tungsten (molybdenum disulfide)/carbon fiber/aluminum composite material. The performance of this composite material was tested and analyzed. The results demonstrated that compared with the carbon fiber/aluminum composite material, the shear strength of the nickel–tungsten (molybdenum disulfide)/carbon fiber/aluminum composite material was increased by 129.7 %, and the friction coefficient and wear rate were reduced by 54.8 % and 83 %, respectively. Next, investigation of the mechanism underlying the honeycomb structure's contribution to the adhesive strength of the composites and their resistance to shear load revealed that the wear-resistant mechanism of molybdenum disulfide nanoparticles reinforced the nickel–tungsten composite coatings. The preparation and study of nickel–tungsten (molybdenum disulfide)/carbon fiber/aluminum composites provide a reference for expanding the applications of aluminum-based composite materials to meet the service requirements of complex environments.