Modification Of Layer Research Articles

Effect of pinless friction stir processing on microstructure and properties of surface modification layer of 2024 aluminum alloy

Friction stir processing (FSP) is an advanced material surface modification technology that is both green and energy-efficient. This technology plays a crucial role in regulating the surface microstructure of alloys and improving alloys’ surface properties. It reaches this through the synergistic effect of non-equilibrium thermodynamic and surface mechanical deformation. In this work, the surface modification of an aluminum alloy was performed using pin-less FSP. Then, the modified surface was analyzed using stress–strain curves, optical microscopy (OM), x-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and electrochemical tests to investigate the impact of spindle velocity on the properties of the modified layer. Results of the study show that after undergoing pinless FSP modification treatment, the surface of the alloy appears bright and flat. The modified layer displays refined grains and numerous dispersed second-phase particles. Furthermore, the grains in the modified layer exhibit a gradient distribution from the surface to the matrix. Regarding the properties, compared to the base material (BM), the yield strength (σ 0.2) and tensile strength (σ b ) of the alloy-modified layer were increased by 34.8% and 29.4%, respectively. The maximum elongation (δ) of the modified coating reached 22.3%. The modified layer exhibits a tough-brittle mixed fracture pattern. Additionally, the modified layer’s corrosion resistance significantly improves. The performance of the modified coating shows the most significant improvement when the spindle speed reaches 1000 rpm.

Al modification layer method for enhancing InAlZnO transistors

In this work, a surface engineering method is proposed to boost electrical performance and stability of the InAlZnO (IAZO) transistors, of which an Al modification layer is deposited on surface of the IAZO channel layer. Through analysed by transmission electron microscope and X-ray photoelectron spectroscopy, the IAZO thin film with Al modification layer undergoes a reduction reaction to generate more oxygen vacancies. Hall effects measurement further demonstrates that IAZO thin films with Al modification layer exhibit higher carrier concentrations than the ones without Al modification layer. The IAZO transistors with Al modification layer exhibit better performance and stability, including a field-effect mobility of 4.36 cm2 V−1s−1 (an improvement of about three-fold), a small subthreshold swing of 105.23 mV/decade, a high on-to-off current ratio greater than 107, and a threshold voltage shift of less than 0.50 V under positive and negative gate bias stress. Moreover, the IAZO transistors with Al modification layer demonstrate high thermal stability under 400 °C for 120 min in air atmosphere. Based on this method, the IAZO inverters have been implemented with high voltage gain of 87.55 V/V. This surface engineering technology paves the way for application of high-performance oxide transistors for advanced monolithic three-dimensional integration.

Research on PbTiO3 nanoparticles optimized mesoporous layer for perovskite solar cells

Organic-inorganic hybrid perovskite solar cells have garnered significant attention due to their facile fabrication process and high photovoltaic conversion efficiency. The electron transport layer plays a crucial role in the carrier separation mechanism of perovskite solar cells, making it a focal point for enhancing cell performance. In this study, PbTiO3 was introduced into TiO2 mesoporous layers by modification and doping in order to optimize cell performance. Initially, the use of PbTiO3-modified mesoporous layers revealed issues such as non-uniform modification layers, low film coverage rates, and reduced light transmittance. These issues hindered the ability of PbTiO3 to facilitate carrier separation and resulting in suboptimal optimization effects. However, by utilizing PbTiO3-doped mesoporous layers for optimizing cell performance, we observed improved quality and higher light transmittance in the perovskite films. As a consequence of the improved carrier separation achieved by PbTiO3, the efficiency of the solar cell has been enhanced to 5.51%.

Enhancing electrochemical performance of high-entropy Co/Ni-free P2/O3 hybrid-phase layered metal oxide cathode for sodium-ion batteries

Sodium-ion batteries (SIBs) have currently garnered increasing attention due to their promising applications and potential advantages. Despite the cost and performance advantages, the Co/Ni-free Fe-Mn-based cathode materials tends to undergo a large phase transition in the sodium (de)intercalation layer, which will result in the material structure damage. In this work, high entropy P2/O3-Na0.75Cu0.1Fe0.2Mg0.2Mn0.4Ti0.1O2 (NCFMMT) materials were successfully prepared by employing NaTi2(PO4)3 (NTP) as the modification layer. It can be distinctly seen that the cyclic stability of NCFMMT@NTP has been significantly improved, and the first capacity at 0.2C reaches 165.32 mAh/g and the capacity can maintain 86.73 % after 100 cycles. Moreover, the voltage hysteresis after triggering anionic redox can be clearly ameliorated. Apparently, the high-entropy strategy not only can satisfactorily optimize the lattice structure and stability of the cathode material during sodium intercalation/de-intercalation process, but also can increase the ion mobilization rate and promote further electrochemical properties. Therefore, this study provides valuable exploration for the design and preparation of cobalt/nickel-free cathodes with excellent electrochemical performance.

Enhanced Interfacial Modification by Ordered Discotic Liquid Crystals for Thermotolerance Perovskite Solar Cells.

Traditionally used phenylethylamine iodide (PEAI) and its derivatives, such as ortho-fluorine o-F-PEAI, in interfacial modification, are beneficial for perovskite solar cell (PSC) efficiency but vulnerable to heat stability above 85 °C due to ion migration. To address this issue, we propose a composite interface modification layer incorporating the discotic liquid crystal 2,3,6,7,10,11-hexa(pentoxy)triphenylene (HAT5) into o-F-PEAI. The triphenyl core in HAT5 promotes π-π stacking self-assembly and enhances its interaction with o-F-PEAI, forming an oriented columnar phase that improves hole extraction along the one-dimensional direction. HAT5 repairs structural defects in the interfacial layer and retains the layered structure to inhibit ion migration under heating. Ultimately, our approach increases the efficiency of solar cells from 23.36 % to 25.02 %. The thermal stability of the devices retains 80.1 % of their initial efficiency after aging at 85 °C for 1008 hours without encapsulation. Moreover, the optimized PSCs maintained 82.4 % of the initial efficiency after aging under one sunlight exposure for 1008 hours. This work provides a simple yet effective strategy using composite materials for interface modification to enhance the thermal and light stability of semiconductor devices.

High-Performance, High-Resolution Quantum Dot Light-Emitting Diodes with Self-Assembly Single-Molecular Interface Modification.

With the development of near-eye displays, the demands for display resolution and performance are increasing. Quantum dot performance is virtually independent of pixel size, making it an efficient way to display ultrahigh resolution. However, the low efficiency of high-resolution quantum dot devices has been an urgent technical bottleneck to be solved. Here, we constructed a dense single-molecule modification layer and a leakage current blocking layer for high-resolution devices using self-assembly, thereby realizing ultrahigh-resolution, high-efficiency, and stable high-resolution quantum dot light-emitting diodes (QLEDs). The peak external quantum efficiencies of the red devices are 24.68% (8759 PPI) and 19.54% (26075 PPI), respectively, with an exceptional long lifetime (T95@1000 nit) up to 4871 h. In addition, we explored the feasibility of this modification strategy on non-Cd-based quantum dots. In conclusion, our strategy effectively improves the performance of high-resolution devices and provides a superior approach for realizing near-eye display applications.

Enhanced Interfacial Modification by Ordered Discotic Liquid Crystals for Thermotolerance Perovskite Solar Cells

AbstractTraditionally used phenylethylamine iodide (PEAI) and its derivatives, such as ortho‐fluorine o‐F‐PEAI, in interfacial modification, are beneficial for perovskite solar cell (PSC) efficiency but vulnerable to heat stability above 85 °C due to ion migration. To address this issue, we propose a composite interface modification layer incorporating the discotic liquid crystal 2,3,6,7,10,11‐hexa(pentoxy)triphenylene (HAT5) into o‐F‐PEAI. The triphenyl core in HAT5 promotes π–π stacking self‐assembly and enhances its interaction with o‐F‐PEAI, forming an oriented columnar phase that improves hole extraction along the one‐dimensional direction. HAT5 repairs structural defects in the interfacial layer and retains the layered structure to inhibit ion migration under heating. Ultimately, our approach increases the efficiency of solar cells from 23.36 % to 25.02 %. The thermal stability of the devices retains 80.1 % of their initial efficiency after aging at 85 °C for 1008 hours without encapsulation. Moreover, the optimized PSCs maintained 82.4 % of the initial efficiency after aging under one sunlight exposure for 1008 hours. This work provides a simple yet effective strategy using composite materials for interface modification to enhance the thermal and light stability of semiconductor devices.

In situ airborne measurements of atmospheric parameters and airborne sea surface properties related to offshore wind parks in the German Bight during the project X-Wakes

Abstract. Between 14 March 2020 and 11 September 2021, meteorological measurement flights were conducted above the German Bight in the framework of the project X-Wakes. The scope of the measurements was to study the transition of the wind field and atmospheric stability from the coast to the sea, to study the interaction of wind park wakes, and to study the large-scale modification of the marine atmospheric boundary layer by the presence of wind parks. In total, 49 measurement flights were performed with the research aircraft Dornier 128 of the Technische Universität (TU) Braunschweig during different seasons and different stability conditions. Seven of the flights in the time period from 24 to 30 July 2021 were organised using a second research aircraft, the Cessna F406 of TU Braunschweig. The instrumentation of both aircraft consisted of a nose boom with sensors for measuring the wind vector, temperature and humidity and, additionally, a surface temperature sensor. The Dornier 128 was further equipped with a laser scanner for deriving sea state properties and two downward-looking cameras in the visible and infrared wavelength range. The Cessna F406 was additionally equipped with shortwave and longwave broadband radiation sensors for measuring upward and downward solar and terrestrial radiation. A detailed overview of the aircraft, sensors, data post-processing and flight patterns is provided here. Further, averaged profiles of atmospheric parameters illustrate the range of conditions. The potential use of the dataset has been already shown by the first few publications. The data of both aircraft are publicly available on the world data centre PANGAEA at https://doi.org/10.1594/PANGAEA.955382 (Rausch et al., 2023a).

Advancements in Eco‐Friendly Colloidal Quantum Dots and their Application in Light Emitting Diodes: Achieving Bright and Color‐Pure Emission for Displays

AbstractSolution‐processable colloidal quantum dots (QDs) are regarded as promising light emitters for next‐generation displays owing to their high photoluminescence quantum yield (PLQY) and broad color tunability. Even though cadmium (Cd)‐based QDs and relevant electroluminescent light‐emitting diodes (LEDs) progressed rapidly, their commercial deployment remains prohibited due to potential environmental concerns. In this review, recent advances in synthesizing eco‐friendly, bright, and color‐pure emitting QDs including InP, ZnSeTe, and AgInGaS2 (AIGS) QDs toward high‐performing LEDs are presented. In particular, the synthetic strategies such as regulating the composition, core/shell structure, and surface ligands of QDs for enhancing the PLQY and reducing the spectral bandwidth are comprehensively discussed. Moreover, various techniques to obtain high‐performance QDs‐based LEDs (QLEDs) involving device architecture and interface engineering as well as modification in electron and hole transport layers are overviewed. Finally, the existing challenges and outlook regarding the optimization of QD's synthesis and optical properties for boosted QLEDs device performance are put forward to enable prospective advanced displays.

A strategy for achieving high-performance single layer polymer photodetectors through dark current reduction using PMMA additives

Suppressing dark current density is crucial for optimizing the performance of organic photodetectors (PDs), particularly in terms of detectivity (D∗) and linear dynamic range (LDR). Organic PDs often utilize the bulk heterojunction structure of organic solar cells to significantly increase photocurrent. However, unlike solar cells, which are unaffected by dark current, photodetectors' performance is substantially limited by it. The interconnected network of bulk heterojunctions leads to a noticeable increase in dark current, thus degrading device performance. Typically, reducing dark current involves adding a modification layer or using multilayer planar heterojunctions, which effectively reduce dark current but often delay response speed and complicate manufacturing. This study presents an alternative approach by incorporating a small concentration of PMMA into single-layer polymer photodetectors, significantly reducing dark current without affecting photocurrent. For this single-layer polymer PD, an ultra-low dark current density of 1.25 × 10−8 A/cm2, a high Dsh∗ of 2.74 × 1012 Jones, an LDR of 120.5 dB, and a fast response time with 1.6 μs were achieved. The capacitance-voltage (C-V), electrochemical impedance spectroscopy (EIS), scanning electron microscopy (SEM), and atomic force microscopy (AFM) measurements revealed that the PMMA additive reduces internal defects, increases bulk resistance, optimizes phase separation, and enhances carrier transport efficiency. The improved device performances are attributed to a more efficient vertical arrangement of the donor-acceptor interface and carrier channels, thus reducing carrier recombination loss. These findings offer a new direction for fabricating high-performance single-layer photodetectors.

Sensitive photoelectrochemical aptasensing of Salmonella enteritidis based on AgBiS2 and Ag/g-C3N4 with gold nanoparticles

In this paper, an ultrasensitive photoelectric chemical sensor based on AgBiS2 and Ag/g-C3N4 was prepared for the detection of Salmonella enteritidis (SE). The AgBiS2 and Ag/g-C3N4 were modified on FTO by layer modification to increase the photoelectric activity of the electrode, the gold nanoparticles continued to be modified, and the aptamer of SE was fixed by AuS bond to realize the specific detection of SE. Compared with the AgBiS2-modified electrode, the electrode prepared by the composite material produced a significantly enhanced and stable photocurrent signal under Xe lamp irradiation. The detection limit of sensor was 2.18 CFU/mL, and ideally, the concentration of SE detection would show a good linear relationship between 6.72 × 103 CFU/mL and 6.72 × 108 CFU/mL. The constructed photoelectrochemical sensor has strong sensitivity, wide linear range, and good selectivity for potential pathogenic bacteria. Therefore, this study provides a very promising photoelectric chemical platform for the detection of SE.

Sputter-deposited TiOx thin film as a buried interface modification layer for efficient and stable perovskite solar cells

Despite perovskite solar cells (PSCs) based on a SnO2 hole-blocking layer (HBL) are achieving excellent performance, the non-perfect buried interface between the SnO2 HBL and the perovskite layer is still an obstacle in achieving further improvement in power conversion efficiency (PCE) and stability. The poor morphology with numerous defects and the energy level mismatch at the buried interface constrain the open circuit voltage and cause instability. Herein, a sputter-deposited TiOx thin film is used as a buried interface modification layer to address the aforementioned issues. Utilizing in situ grazing-incidence small-angle X-ray scattering (GISAXS) during the sputter deposition, we monitor and unveil the growth process of the TiOx thin film, identifying a 10 nm thickness optimum. The defects at the buried interface are passivated through tuning the growth, leading to a suppressed non-radiative recombination and improved PCE (from 22.19 % to 23.93 %). The evolution of the device performance and the degradation process of PSCs using operando grazing-incidence wide-angle X-ray scattering (GIWAXS) under the protocol ISOS-L-1I explains the enhanced stability introduced by the buried interface modification via a sputter-deposited TiOx thin layer. The perovskite decomposition process and the detrimental formation of PbI2 are both slowed down by the TiOx thin layer.

Bifunctional fluorine doped Ru/RuO2 clusters with dynamic electron modification and strong metal-support interaction boost proton exchange membrane water electrolyzer

The sluggish kinetics and inherent instability over the Ru/RuO2 clusters are still enormous challenges in proton exchange membrane (PEM) water electrolyzer. Herein, we innovatively report synergistic modulation of dynamic electron modification and strong metal-support interaction (SMSI) to activate and stabilize bifunctional fluorine doped Ru/RuO2 clusters anchored on carbon nanotube (CNT), thus achieving efficient and stable acidic overall water splitting. Theoretical and experimental studies found that surface metal-fluorine modification layer could dynamically regulate the interfacial electronic environment to stabilize and activate multiple active Ru species; and the SMSI between Ru/RuO2 cluster and CNT maintains stable electronic environment for dynamic electron modification and avoids migrating or shedding of active species in acidic environment. Therefore, the PEM electrolyzer assembled with optimal F5.5-Ru/RuO2@CNT can operate stably for 100 h at a high current density of 100 mA cm−2, which is the first time that bifunctional Ru-based nanocatalysts applied to PEM device at a high current density.

Improving the Performance of LiFePO4 Cathodes with a Sulfur-Modified Carbon Layer

LiFePO₄ (LFP) cathodes are popular due to their safety and cyclic performance, despite limitations in lithium-ion diffusion and conductivity. These can be improved with carbon coating, but further advancements are possible despite commercial success. In this study, we modified the carbon coating layer using sulfur to enhance the electronic conductivity and stabilize the carbon surface layer via two methods: 1-step and 2-step processes. In the 1-step process, sulfur powder was mixed with cellulose followed by heat treatment to form a coating layer; in the 2-step process, an additional coating layer was applied on top of the carbon coating layer. Electrochemical measurements demonstrated that the 1-step sulfur-modified LFP significantly improved the discharge capacity (~152 mAh·g−1 at 0.5 C rate) and rate capability compared to pristine LFP. Raman analyses indicated that sulfur mixed with a carbon source increases the graphitization of the carbon layer. Although the 2-step sulfur modification did not exceed the 1-step process in enhancing rate capability, it improved the storage characteristics of LFP at high temperatures. The residual sulfur elements apparently protected the surface. These findings confirm that sulfur modification of the carbon layer is effective for improving LFP cathode properties, offering a promising approach to enhance the performance and stability of LFP-based lithium-ion batteries.

Fabrication of Self-Assembled Graphene Oxide Film and Its Application in Aqueous Zinc Metal Batteries.

Fabrication of well-dispersed thin graphene oxide (GO) films (GOFs) has always been a challenge. Herein, a quick preparation method for GOFs was developed using our homemade GO with a large lateral size. The film can be prepared in less than 2 h via a metal framework-induced self-assembly process. The thickness of the films can be as thin as ∼15.5 μm, which will be thinner with compression. When it is used as a flexible modification layer on the Zn metal for aqueous Zn-ion batteries, Zn can grow along the [010] direction in plane and stack orderly along the [002] direction even on the Cu substrate with GOF through epitaxial plating owing to negligible lattice mismatch between the (002) plane of Zn and the hexagonal ring [also (002) plane for graphite] of GO. Meanwhile, the rich O groups on the GO film can provide abundant zincophilic points and promote uniform distribution of Zn2+ around the anode. Finally, dendrite-free and dense Zn stripping/plating can be achieved and well remained. The GOF@Zn symmetric cell reveals long cyclic stability of 1300 h at 1 mA cm-2 and 1 mA h cm-2. It still can remain at 350 h even at a very high current density of 10 mA cm-2 accompanied by a high areal capacity of 10 mA h cm-2. With the same plating amount of 5 mA h cm-2, the thickness of the plated Zn is only ∼10 μm with GOF modification, very close to the theoretical value of 8.54 μm, much thinner than that without GOF (∼18 μm), indicating very dense deposition. Full cells assembled with the GOF@Zn anode and the MnO2 cathode exhibit a capacity retention rate of 71% over 1000 cycles at 0.7 A g-1, showing much better cycling performance than that using bare Zn.

Multi-Component Lithiophilic Alloy Film Modified Cu Current Collector for Long-Life Lithium Metal Batteries by a Novel FCVA Co-Deposition System.

Surface modification of Cu current collectors (CCs) is proven to be an effective method for protecting lithium metal anodes. However, few studies have focused on the quality and efficiency of modification layers. Herein, a novel home-made filtered cathode vacuum arc (FCVA) co-deposition system with high modification efficiency, good repeatability and environmental friendliness is proposed to realize the wide range regulation of film composition, structure and performance. Through this system, ZnMgTiAl quaternary alloy films, which have good affinity with Li are successfully constructed on Cu CCs, and the fully enhanced electrochemical performances are achieved. Symmetrical cells constructed with modified CCs maintained a fairly low voltage hysteresis of only 13mV after 2100h at a current density of 1mA cm-2. In addition, the capacity retention rate is as high as 75.0% after 100 cycles in the full cells. The influence of alloy films on the dynamic evolution process of constructing stable artificial solid electrolyte interphase (SEI) layer is revealed by in situ infrared (IR) spectroscopy. This work provides a promising route for designing various feasible modification films for LMBs, and it displays better industrial application prospects than the traditional chemical methods owing to the remarkable controllability and scale-up capacity.

English

English

Magnetic Nanocomposite Modified Hybrid Hole-Transport Layer for Constructing Organic Solar Cells with High Efficiencies.

An interface modification layer holds paramount significance in reducing interface carrier recombination and improving the ohmic contact between the active layer and the electrode in organic solar cells (OSCs). Modifying or doping the widely used hole-transport layer (HTL) PEDOT:PSS to adjust the work function, conductivity, and acidity has become a common strategy for achieving high-performance OSCs. Metal oxides and two-dimensional materials as secondary dopants into PEDOT:PSS, respectively, as well as a replacement of PEDOT:PSS both exhibit immense potential for achieving high-performance OSCs due to their excellent electrical properties. Herein, we report a method utilizing a Fe3O4/GO magnetic nanocomposite as a secondary dopant for PEDOT:PSS to modulate its inherent properties for constructing high-efficiency OSCs. The magnetic nanocomposite hybrid HTL exhibits a suitable optical transmittance and higher work function. Meanwhile, it is found that the addition of Fe3O4/GO magnetic nanoparticles expands the domain of PEDOT and enhances the phase separation between PEDOT and PSS segments, thereby improving the conductivity of PEDOT:PSS. By fine-tuning the doping ratio of a Fe3O4/GO magnetic nanocomposite in PEDOT:PSS, the best power conversion efficiency of OSCs based on PM6:L8-BO was up to 18.91%. The notable enhancement of the device's performance was due to the enhanced hole mobility and the improved charge extraction, further complemented by the decreased likelihood of interface recombination brought about by the hybrid HTL. Compared with PEDOT:PSS-based OSCs, an enhanced stability of the hybrid HTL-based device was also obtained. In addition, the diverse adaptability of the hybrid HTL was demonstrated in enhancing the performance of OSCs that are based on PM6:Y6 and PBDB-T:ITIC. The effectiveness and versatility of a magnetic nanocomposite hybrid HTL present opportunities for achieving high-performance OSCs.

XPS investigations of thin epitaxial and magnetron tin layers surface physico-chemical state

Thin layers of the tin-oxygen system with nanometer thicknesses and structures based on them are relevant objects of development for use in modern devices, for example in microelectronics. The general miniaturization of electronic devices, the achievement of energy efficiency in the operation of such devices, and the optimal modes of their operation determine the strategies for using the tin-oxygen system structures. First of all, the justification of the tin-oxygen system nanolayers formation technique. The dependence of the formed nanolayers properties on the state of their surface is significant. The article contains the results of direct experimental studies of the composition and physico-chemical state of the tinoxygen system thin nanolayers surface. To form the studied structures, the popular and in-demand methods of magnetron sputtering and molecular beam epitaxy were used. The X-ray photoelectron spectroscopy was applied with the use of the synchrotron radiation which has a high intensity and the possibility of spectrum excitation energy optimal selection, which is important for a small amount of the studied material. After formation, the research objects were stored in laboratory conditions for several weeks before synchrotron studies. Differences in the surface composition and physico-chemical state of the thin tin layers formed by magnetron sputtering or epitaxially, and then oxidized naturally, are shown. Five monolayers of tin formed by the molecular beam epitaxy make it possible to diffuse atmospheric oxygen, which oxidizes the Si buffer layer located under the Sn nanolayer on a silicon substrate. At the same time, the surface of the tin film obtained by magnetron sputtering is close to the natural oxide SnO2-x in its physico-chemical state. The results of the work can be useful for determining the optimal approaches to the formation and subsequent modification of thin and ultrathin layers of tin oxides for the tasks of creating active layers of modern electronic devices

Interfacial Dipole Engineering for Energy Level Alignment in NiOx-Based Quantum Dot Light-Emitting Diodes.

The solution-derived non-stoichiometric nickel oxide (NiOx) is a promising hole-injecting material for stable quantum dot light-emitting diodes (QLEDs). However, the carrier imbalance due to the misalignment of energy levels between the NiOx and polymeric hole-transporting layers (HTLs) curtails the device efficiency. In this study, the modification of the NiOx surface is investigated using either 3-cyanobenzoic acid (3-CN-BA) or 4-cyanobenzoic acid (4-CN-BA) in the QLED fabrication. Morphological and electrical analyses revealed that both 4-CN-BA and 3-CN-BA can enhance the work function of NiOx, reduce the oxygen vacancies on the NiOx surface, and facilitate a uniform morphology for subsequent HTL layers. Moreover, it is found that the binding configurations of dipole molecules as a function of the substitution position of the tail group significantly impact the work function of underlying layers. When integrated in QLEDs, the modification layers resulted in a significant improvement in the electroluminescent efficiency due to the enhancement of energy level alignment and charge balance within the devices. Specifically, QLEDs incorporating 4-CN-BA achieved a champion external quantum efficiency (EQE) of 20.34%, which is a 1.8X improvement in comparison with that of the devices utilizing unmodified NiOx (7.28%). Moreover, QLEDs with 4-CN-BA and 3-CN-BA modifications exhibited prolonged operational lifetimes, indicating potential for practical applications.