The molecular structure of BeBr2 has been investigated by gas-phase electron diffraction at the temperature 800(10) K. The conventional analysis yielded the following values: rg(Be–Br) = 1.944(6)A, l(Be–Br) = 0.068(4)A, rg(Br–Br) = 3.848(8)A, l(Br–Br) = 0.109(3)A, k(Be–Br) = 1.1(1.1) × 10−5 A3, κ(Br–Br) = 2.1(1.0) × 10−5 A3. Three models of nuclear dynamics were used to simulate the conventional analysis values—infinitesimal vibrations and two models, which take into account the kinematic and dynamic anharmonicity of the bending vibration. All models give similar values of bond angle, amplitudes, and shrinkage, excluding the harmonic model, which yields too low value l(Br–Br). The equilibrium bond distance re(Be–Br) = 1.932(11) A was estimated, taking into account the anharmonicity corrections for stretching and bending vibrations and centrifugal distortion.