Thermal Transport Model Research Articles

Investigation of thermal transport mechanism of silicone-modified phenolic matrix nanocomposites with different pyrolysis degrees

Polymeric nanocomposites with low thermal conductivity show promising applications for next-generation thermal protection materials used in re-entry vehicles due to their lightweight, high char yield, and excellent ablation-oxidation resistance. However, the thermal conductivity of polymeric nanocomposites varies with the pyrolysis degree of the polymer matrix in aerodynamic environments, which significantly affects thermal protection and structural applications but is challenging to identify experimentally. Herein, non-equilibrium molecular dynamics simulations combined with experiments were implemented to determine the dependence of thermal conductivities on pyrolysis degree and microstructures for polymeric nanocomposites. We further explore the thermal transport mechanism through various contributions to the morphology. The results show that the thermal conductivity of the polymer matrix can be increased by a factor of 4.44 (from 0.27 W/m/K to 1.47 W/m/K) as the pyrolysis degree increases from 0 to 100%, and the thermal conductivity depends nonlinearly on the pyrolysis degree and temperature. Molecular dynamics simulations found that the side chains of the polymer matrix are rapidly scissored with the increasing pyrolysis degrees, and the structural ordering of the residual solids containing sp2 hybridization is enhanced, exhibiting graphene-like microtopological features, which reduces phonon scattering and makes thermal transport more efficient. This work provides insight into the linkage between the thermal transport properties and the pyrolysis degree of polymeric nanocomposites, which is valuable for improving the thermal transport performance and modeling ablation response for polymeric nanocomposites.

Measuring thermal diffusivity and gap conductance in uranium nitride and Zircaloy relevant for microreactor applications

Heat transfer across nuclear fuels and structural interfaces is an important factor for evaluating the performance of nuclear power systems. Specifically, heat generated as nuclear fuel fissions must be transported through the cladding material and through the reactor to reach the steam turbine for power generation. As new microreactor designs emerge, maximizing the efficiency of this heat transfer process becomes crucial to make them commercially viable. This article examines thermal diffusivity and gap conductance in uranium nitride (UN) fuel and Zircaloy-4 (Zry4) cladding using light flash analysis (LFA). Thermal diffusivity measurements were made on monolithic UN pellets and Zry4 exposed to carbon at peak operating temperatures of microreactors and show that carbon ingress has a minimal effect on thermal diffusivity when compared with identical materials not exposed to carbon. Evaluation of gap conductance at the UN-Zry4 interface was done using one-dimensional two-layer thermal transport models as a function of applied pressure. The results show that increasing pressure on the UN-Zry4 interface leads to gains in gap conductance per unit area in fuel-cladding assemblies at microreactor operating temperatures. While many other variables are expected to influence UN-Zry4 interfacial gap conductance (e.g. contact surface roughness, porosity, localized heating, environmental gas pressure), the work offers a demonstration of using a conventional LFA apparatus to determine this parameter at elevated temperatures.

Nanoscale Heat Transport of Vertically Aligned Carbon Nanotube Bundles for Thermal Management Applications.

Electronic devices continue to shrink in size while increasing in performance, making excess heat dissipation challenging. Traditional thermal interface materials (TIMs) such as thermal grease and pads face limitations in thermal conductivity and stability, particularly as devices scale down. Carbon nanotubes (CNTs) have emerged as promising candidates for TIMs because of their exceptional thermal conductivity and mechanical properties. However, the thermal conductivity of CNT films decreases when integrated into devices due to defects and bundling effects. This study employs a novel cross-sectional approach combining high-vacuum scanning thermal microscopy (SThM) with beam-exit cross-sectional polishing (BEXP) to investigate the nanoscale morphology and thermal properties of vertically aligned CNT bundles at low and room temperatures. Using appropriate thermal transport models, we extracted effective thermal conductivities of the vertically aligned nanotubes and obtained 4 W m-1 K-1 at 200 K and 37 W m-1 K-1 at 300 K. Additionally, non-negligible lateral thermal conductance between CNT bundles suggests more complex heat transfer mechanisms in these structures. These findings provide unique insights into nanoscale thermal transport in CNT bundles, which is crucial for optimizing novel thermal management strategies.

Image-based finite element modeling of air flow and thermal transport in Al-fiber-sintered porous materials

In this study, the pressure drop and heat transfer in a heat-transfer tube filled with a sintered porous medium comprising Al fibers were investigated using computational fluid dynamics (CFD) simulations. We reconstructed the sintered fibrous porous structure and generated a computational mesh using X-ray computed tomography data, and the simulated pressure drop and heat transfer agreed well with those reported by Enoki et al. [2021]. The differences in both the form coefficient and the permeability between two different samples can be explained from the differences in both the specific solid surface area and the porosity. Further, the CFD simulations indicated that thermal conduction of the Al solid phase enhanced the heat exchange between the air and Al fibers. To examine the effect of solid-phase thermal conduction, we generated a model of a heat-transfer tube having an ideal wire mesh structure, in which we introduced the interfacial thermal conductivity between Al fibers and the inner tube wall as additional factors. We also performed CFD simulations with four different shell-region thicknesses and found that even a very narrow gap of 5 to 10 μm heavily affected the heat-exchange performance because of the low thermal conductivity of the shell region.

Abstract PO1-07-12: Inverse modeling with surface temperature accurately detects the presence of breast cancer

Abstract Breast cancer affects over 250,000 women in the United States every year. Patient outcomes including overall survival significantly decline with large sized tumors and nodal involvement on initial presentation. The introduction of mammogram screening has been instrumental in the early detection of cancer. However, it has lower sensitivity in dense breast tissue and limited specificity which leads to unnecessary additional invasive testing. Several methods such as magnetic resonance imaging (MRI), computed tomography (CT) and ultrasound imaging are used as adjunctive methods. However, there is still a need for cost-effective techniques without additional radiation exposure for breast cancer screening for use with mammography. We propose an adjunctive screening method using surface temperature measurements and inverse breast modeling for early detection of breath cancer. Methods: We enrolled patients who presented with mammogram detected breast tumors that were confirmed to be cancerous lesions by biopsy. We used prone position steady state infrared imaging of bilateral breasts to measure surface temperatures and multi-view MRI images to create patient specific 3D breast models. The inverse technique applies Levenberg-Marquard algorithms (LMA) and utilizes commercial software for thermal transport modeling. The inverse technique predicts a heat generation map normalized for baseline surface temperatures to localize the presence of an underlying tumor. Results: A total of 25 breast tumors (diameter range from 5 to 27 mm) from 24 patients were included in the analysis with a median patient age of 67 years. One patient had bilateral breast tumors. Mammogram data showed inclusion of mixed breast tissue composition including dense and extremely dense breast tissue. LMA accurately detected the tumor in all 25 patients with maximum absolute errors of 7 mm in location of the tumor in the breast and 1.78 mm in diameter. The accuracy of detection was not affected by tumor histology which included invasive ductal and lobular carcinomas, ductal and lobular carcinoma in-situ and atypical ductal hyperplasia. No heat sensitive tumors were detected in the 23 contralateral breasts which acted as internal negative controls. Conclusion: Infrared temperature profiles and inverse modeling successfully detected malignant breast tumors with no missed tumors or false positive results and could be used as adjunctive screening along with mammography, especially in patients with dense breast tissue. Citation Format: Nithya Sritharan, Carlos Gutierrez, Isaac Perez-Raya, Jose-Luis Gonzalez-Hernandez, Alyssa Owens, Donnette Dabydeen, Lori Medeiros, Satish Kandlikar, Pradyumna Phatak. Inverse modeling with surface temperature accurately detects the presence of breast cancer [abstract]. In: Proceedings of the 2023 San Antonio Breast Cancer Symposium; 2023 Dec 5-9; San Antonio, TX. Philadelphia (PA): AACR; Cancer Res 2024;84(9 Suppl):Abstract nr PO1-07-12.

Coupled responses of thermomechanical waves in functionally graded viscoelastic nanobeams via thermoelastic heat conduction model including Atangana–Baleanu fractional derivative

Accurately characterizing the thermomechanical parameters of nanoscale systems is essential for understanding their performance and building innovative nanoscale technologies due to their distinct behaviours. Fractional thermal transport models are commonly utilized to correctly depict the heat transfer that occurs in these nanoscale systems. The current study presents a novel mathematical thermoelastic model that incorporates a new fractional differential constitutive equation for heat conduction. This heat equation is useful for understanding the effects of thermal memory. An application of a fractional-time Atangana–Baleanu (AB) derivative with a local and non-singular kernel was utilized in the process of developing the mathematical model that was suggested. To deal with effects that depend on size, nonlocal constitutive relations are introduced. Furthermore, in order to take into consideration, the viscoelastic behaviour of the material at the nanoscale, the fractional Kelvin–Voigt model is utilized. The proposed model is highly effective in properly depicting the unusual thermal conductivity phenomena often found in nanoscale devices. The study also considered the mechanical deformation, temperature variations, and viscoelastic characteristics of the functionally graded (FG) nanostructured beams. The consideration was made that the material characteristics exhibit heterogeneity and continuous variation across the thickness of the beam as the nanobeam transitions from a ceramic composition in the lower region to a metallic composition in the upper region. The complicated thermomechanical features of simply supported viscoelastic nanobeams that were exposed to harmonic heat flow were determined by the application of the model that was constructed. Heterogeneity, nonlocality, and fractional operators are some of the important variables that contribute to its success, and this article provides a full study and illustration of the significance of these characteristics. The results that were obtained have the potential to play a significant role in pushing forward the design and development of tools, materials, and nanostructures that have viscoelastic mechanical characteristics and graded functions.

A re-activation model for 169Yb intensity modulated brachytherapy sources accounting for spatiotemporal isotopic composition.

Intensity modulated brachytherapy based on partially shielded intracavitary and interstitial applicators is possible with a cost-effective 169Yb production method. 169Yb is a traditionally expensive isotope suitable for this purpose, with an average γ-ray energy of 93keV. Re-activating a single 169Yb source multiple times in a nuclear reactor between clinical uses was shown to theoretically reduce cost by approximately 75% relative to conventional single-activation sources. With re-activation, substantial spatiotemporal variation in isotopic source composition is expected between activations via 168Yb burnup and 169Yb decay, resulting in time dependent neutron transmission, precursor usage, and reactor time needed per re-activation. To introduce a generalized model of radioactive source production that accounts for spatiotemporal variation in isotopic source composition to improve the efficiency estimate of the 169Yb production process, with and without re-activation. A time-dependent thermal neutron transport, isotope transmutation, and decay model was developed. Thermal neutron flux within partitioned sub-volumes of a cylindrical active source was calculated by raytracing through the spatiotemporal dependent isotopic composition throughout the source, accounting for thermal neutron attenuation along each ray. The model was benchmarked, generalized, and applied to a variety of active source dimensions with radii ranging from 0.4 to 1.0mm, lengths from 2.5 to 10.5mm, and volumes from 0.31 to 7.85 mm3, at thermal neutron fluxes from 1×1014to1×1015 n cm-2 s-1. The 168Yb-Yb2O3 density was 8.5g cm-3 with 82% 168Yb-enrichment. As an example, a reference re-activatable 169Yb active source (RRS) constructed of 82%-enriched 168Yb-Yb2O3 precursor was modeled, with 0.6mm diameter, 10.5mm length, 3 mm3 volume, 8.5g cm-3 density, and a thermal neutron activation flux of 4 × 1014 neutronscm-2s-1. The average clinical 169Yb activity for a 0.99 versus 0.31 mm3 source dropped from 20.1 to 7.5Ci for a 4×1014ncm-2s-1 activation flux and from 20.9 to 8.7Ci for a 1×1015ncm-2s-1 activation flux. For thermal neutron fluxes ≥2×1014ncm-2s-1, total precursor and reactor time per clinic-year were maximized at a source volume of 0.99 mm3 and reached a near minimum at 3mm3. When the spatiotemporal isotopic composition effect was accounted for, average thermal neutron transmission increased over RRS lifetime from 23.6% to 55.9%. A 28% reduction (42.5 days to 30.6 days) in the reactor time needed per clinic-year for the RRS is predicted relative to a model that does not account for spatiotemporal isotopic composition effects. Accounting for spatiotemporal isotopic composition effects within the RRS results in a 28% reduction in the reactor time per clinic-year relative to the case in which such changes are not accounted for. Smaller volume sources had a disadvantage in that average clinical 169Yb activity decreased substantially below 20Ci for source volumes under 1mm3. Increasing source volume above 3 mm3 adds little value in precursor and reactor time savings and has a geometric disadvantage.

SOL impurity transport analysis with SONIC code with a kinetic effect on a thermal force transport model in JT‐60U

AbstractThe latest version of the SONIC code with the extended thermal force model that is capable to treat collisionality dependence of the force has been applied to the interpretative simulation of L‐mode discharge of JT‐60 U to investigate the impact of kinetic correction of the thermal force on the scrape‐off layer (SOL) plasma properties. As a first attempt, we have selected an L‐mode attached discharge #39090 (Ip = 1.6 MA, Bt = 3.1 T, and PNBI = 4.5 MW), where = 2.08 × 1019 m−3, = 0.392 with deuterium plasmas. It has been found that the peak values of SOL impurity density are reduced by a factor of 2, with the kinetic correction, because the thermal force is reduced by the low collisionality of SOL plasma between the X‐point and the (inner and outer) midplane. On the other hand, the profiles near the divertor plates are unaffected by the kinetic correction due to the highly collisional condition. The kinetic correction is found more pronounced for the higher charge states impurity due to the charge dependence of the parallel impurity force balance. Overall effects due to the kinetic correction on the total impurity radiation and the divertor heat load are confirmed to be a few % in the present discharge condition of JT‐60U.

Modeling of thermal and solute transport within a Maxwell fluid in contact with a porous rotating disc

Modeling of thermal and solute transport within a Maxwell fluid in contact with a porous rotating disc

Space-time dependent non-local thermal transport effects on laser ablation dynamics in inertial confinement fusion

In inertial confinement fusion (ICF), electron thermal transport plays a key role in laser ablation and the subsequent implosion processes, which always exhibits intractable non-local effects. Simple modifications of the local Spitzer–Härm model with either an artificially-assumed constant flux limiter or a purely time-dependent one are applied to explain some experimental data, but fail to simultaneously reproduce the space-time evolution of the whole laser ablation process. Here, by carrying out a series of one-dimensional and two-dimensional radiation hydrodynamic simulations where the space-time-dependent non-local thermal transport model proposed by Schurt, Nicolaï and Busquet (the SNB model) are self-consistently included, we systematically study the non-local effects on the whole laser ablation dynamics including those occurring at the critical surface, the conduction zone and the ablation front. Different from those obtained previously, our results show that due to the non-local heat flow redistribution and redirection, at the critical surface the thermal flux is more inhibited, in the conduction zone the lateral thermal transport is suppressed, and ahead of the ablation front the plasma is preheated. When combined together they eventually result in significant improvement of the laser absorption efficiency, extension of the conduction zone, increase of both the mass ablation rate and shock velocity. Furthermore, the dependence of these laser ablation dynamics on different drive laser intensities is investigated, which provides beneficial enlightenments on potential laser pulse shaping and/or ignition scheme optimization in ICF.

Radiation and heat transport in divergent shock–bubble interactions

Shock–bubble interactions (SBIs) are important across a wide range of physical systems. In inertial confinement fusion, interactions between laser-driven shocks and micro-voids in both ablators and foam targets generate instabilities that are a major obstacle in achieving ignition. Experiments imaging the collapse of such voids at high energy densities (HED) are constrained by spatial and temporal resolution, making simulations a vital tool in understanding these systems. In this study, we benchmark several radiation and thermal transport models in the xRAGE hydrodynamic code against experimental images of a collapsing mesoscale void during the passage of a 300 GPa shock. We also quantitatively examine the role of transport physics in the evolution of the SBI. This allows us to understand the dynamics of the interaction at timescales shorter than experimental imaging framerates. We find that all radiation models examined reproduce empirical shock velocities within experimental error. Radiation transport is found to reduce shock pressures by providing an additional energy pathway in the ablation region, but this effect is small (∼1% of total shock pressure). Employing a flux-limited Spitzer model for heat conduction, we find that flux limiters between 0.03 and 0.10 produce agreement with experimental velocities, suggesting that the system is well-within the Spitzer regime. Higher heat conduction is found to lower temperatures in the ablated plasma and to prevent secondary shocks at the ablation front, resulting in weaker primary shocks. Finally, we confirm that the SBI-driven instabilities observed in the HED regime are baroclinically driven, as in the low energy case.

Cyclic Thermal and Structural Testing of a Hot Particle Storage Bin

Thermal energy storage is a key element in concentrating solar energy systems. In 2017 a Roadmap toward a third-generation system that could meet the SunSHOT goals of 0.06 $/kWe recommended increasing temperatures to > 700° C for heat transfer media to in-crease thermal efficiencies and lower levelized costs of heat. In 2021, the U.S. Department of Energy selected the particle pathway, G3P3, to build a 1 MWt prototype solar tower with 6 MWh thermal energy storage at the NSTTF in Albuquerque, NM. Of the primary components, the falling particle receiver, and particle-to-sCO2 heat exchanger have been demonstrated at the 250 kWt capacity. The storage component is now being demonstrated as part of the G3P3-USA and G3P3-KSA pilot plants. Storage bin liner materials have been demonstrated by KSU in 2016 and 2019. A flowing particle storage container was demonstrated in 2020 by KSU. The testing presented in this work will be the first to test the particle to wall interactions with mono-lithic refractory insulation, and to validate a transient thermal transport model with the unique kinetics of bulk solids in funnel-flow where cooler particles near the walls flow inward toward a hot central flow channel. This work will also de-risk and characterize the specific design of the G3P3-USA storage bin.

Magnetoinduced spin Nernst effect in topological nodal-line semimetals

The spin Nernst effect (SNE) of a topological nodal-line semimetals (TNLSMs) nanowire in a four-terminal cross-bar device is studied. Based on the nonequilibrium Green’s function method combining with the tight-binding Hamiltonian, the spin Nernst coefficients Ns3z, Ns3x and Ns3y of the two thermal transport models (kz-y case and kx-y case) under a perpendicular magnetic field are obtained. The traditional SNE describes the transverse voltage and spin current caused by the longitudinal thermal gradient. The transverse spin current is generated by the spin–orbit interaction rather than the perpendicular magnetic field. Here we find that the spin Nernst coefficients are equal to zero at the zero-magnetic field, but have finite values for non-zero magnetic fields in TNLSMs. The spin Nernst coefficient is closely related to the strength of the magnetic field and temperature. With the increase of the magnetic field strength, the peak height of the spin Nernst coefficient increases. These results indicate that the SNE is induced by the perpendicular magnetic field in the present TNLSMs system, which can be considered as an anomalous spin Nernst phenomenon. In addition, we find that Ns3z displays a series of peaks when the transmission coefficient TLR jumps from one integer plateau to another, and the spin Nernst coefficient Ns3i (i=x,y,z) is an odd function of the Fermi energy EF with Ns3z/x/y(−EF)=−Ns3z/x/y(EF) in connection mode kz-y. For the kx-y connection mode, due to the presence of the mass term m opening the energy gap, a sudden jump of the transmission coefficient TLR in the vicinity of the energy gap edge causes a very larger peak for the spin Nernst coefficient Ns3z/x/y, and the symmetrical properties of the spin Nernst coefficient Ns3z/x/y are completely broken in the strong magnetic field. These results indicate that the spin Nernst coefficient in TNLSMs strongly depends on the thermal gradient direction and the transverse lead connection direction. The spin Nernst coefficient in TNLSMs has strongly spatial anisotropy, which can be used as the characterization of the experimental detection of TNLSMs.

Modeling 4.3 billion years of water history on Phobos

Phobos, one of the Martian moonlets, has been the focus of long-standing scientific investigation, particularly regarding its origin: whether it was formed by a giant impact or a captured asteroid. In this study, we investigate the long-term internal evolution of Phobos over 4.3 billion years using a 3-dimensional thermal diffusion and water transport model, named ASTRA. The model newly implements reflected visible light and infrared radiation from Mars, orbital evolution of Phobos, water vapor adsorption on rock grain surfaces, and suppressed permeability due to the surface dust layer in addition to the previous study, allowing us to simulate different grain sizes of 1, 10, 100, and 1000 μm, adsorption coefficients of 1 and 10 kg m−3, and initial water contents of 0.1, 1 or 10 wt%.Our simulation results revealed that without the water vapor adsorption effect, the water inside Phobos would be lost over several billion years for an initial water content of 0.1 wt%. However, when water vapor adsorption was considered, scenarios emerge in which Phobos could retain water to the present day. In the case of a grain size of around 100 μm, Phobos could still continuously release water flux of 10−4–10−3 g s−1 for an initial water content of 0.1 wt%, and 10−2–1 g s−1 for an initial water content of >1 wt%. Furthermore, our research shows the possibility of subsurface condensed water ice in deep high latitude regions and the formation of a gas torus by escaping water-related molecules. If the future MMX mission can measure the water-related ions near the gas torus of Phobos with much >104 cm−2 s−1, the origin of Phobos is most likely the captured asteroid with an initial water content of >1%. For further detailed analysis, our results emphasize the importance of exploring surface soil parameters through soil sample return by the MMX mission.

Mesoscale multi-component energy density transport for natural convective microchip cooling with solid–liquid–gas phase changes

A design of microchip cooling with natural convection driven multi-phase coolant flows is proposed by using thermoelectric modules as heat sinks. A new multi-component multi-phase (MCMP) thermal energy transport model is built for convective heat transfer with solid–liquid–gas phase changes. Different from previous lattice Boltzmann models based on temperature distributions, the present model is based on MCMP energy density distributions, which track sensible and latent heat transport for each phase. The local MCMP heat fluxes are related to mesoscale relaxation times and phase volume fractions. Transient solid–liquid–gas interfaces and local temperatures are obtained through the dynamical balance of mesoscale forces and fluxes among all phases together with MCMP enthalpy–temperature distributions. Comparisons of the on and off states of the heat sink modules show that the chip temperature can drop from about 300 to 110 °C, with the coolant liquid–gas phase change temperature of 80 °C at equivalent heat source and sink intensities of 100 W/cm2. Results also show that increasing heat sink intensity to 300 W/cm2 or decreasing gas–liquid phase change temperature to 60 °C can further decrease the chip temperature to 90 °C. The effects of sizes of chips, modules, and cooling units are also illustrated. It is observed that gas bubbles attached on chips impede heat transfer due to the low gas phase thermal conductivity, which means future improvements should also focus on removing or degrading attached gas bubbles. This model provides a quantitative tool for immersion chip cooling performances.

Significance of Koo-Kleinstreuer-Li model for thermal enhancement in nanofluid under magnetic field and thermal radiation factors using LSM

Investigation of thermal transport in nanofluid flow squeezed inside a channel formed by two sheets with zero slope is common in industrial and engineering applications. The heat transmission could be affected by various physical constraints which reduce the machine efficiency for desired products. Therefore, this attempt clearly focus on the development of new nanofluid thermal transport model using the significance effects of Koo-Kleinstreuer-Li correlation which used for the estimation of nanofluid thermal conductivity, impacts of magnetic field, internal heating species, and thermal radiations. Then, the LSM (Least Square Method) is magnificently implemented and obtained the physical results for multiple ranges of parameters. It is noticed that when the squeezed parameter varied in the ranges of [Formula: see text] to [Formula: see text] and [Formula: see text] to [Formula: see text], the fluid loss their velocity and more reduction is occurred about [Formula: see text]. However, outward movement of the plate lead to quick declines in the velocity. Further, when the Hartmann number increased for [Formula: see text]–[Formula: see text] then the fluid moves slowly and stronger magnetic field resists its motion. Moreover, the Eckert and Radiation numbers boosted the fluid temperature by keeping the feasible nanoparticles concentration in the range of [Formula: see text]–[Formula: see text].

A numerical study of electro-osmosis Williamson nanofluid flow in a permeable tapered channel

This paper aims to analyze the mathematical and theoretical scrutiny of non-Newtonian Williamson liquid on an asymmetry tapered channel with thermal and mass transportation. No slip boundary conditions for velocity, heat and concentration are kept on channel walls. Buongiorno model for thermal transport of nano-fluid is also incorporated. Flow in permeable surface is categorized via modified Darcy law. Current problem is formulated by incorporating distinct effects such as modified Darcy law, electro osmosis, heat generation and chemical reaction. RK-4 based shooting method has been utilized to evaluate the nonlinear equations. Graphical results are formulated to visualize the prominence of distinct parameters.

Ultrafast Switching of Interfacial Thermal Conductance.

Dynamical control of thermal transport at the nanoscale provides a time-domain strategy for optimizing thermal management in nanoelectronics, magnetic devices, and thermoelectric devices. However, the rate of change available for thermal switches and regulators is limited to millisecond time scales, calling for a faster modulation speed. Here, time-resolved X-ray diffraction measurements and thermal transport modeling reveal an ultrafast modulation of the interfacial thermal conductance of an FeRh/MgO heterostructure as a result of a structural phase transition driven by optical excitation. Within 90 ps after optical excitation, the interfacial thermal conductance is reduced by a factor of 5 and lasts for a few nanoseconds, in comparison to the value at the equilibrium FeRh/MgO interface. The experimental results combined with thermal transport calculations suggest that the reduced interfacial thermal conductance results from enhanced phonon scattering at the interface where the lattice experiences transient in-plane biaxial stress due to the structural phase transition of FeRh. Our results suggest that optically driven phase transitions can be utilized for ultrafast nanoscale thermal switches for device application.

Solar Photo-Voltaic and thermal (PVT) system facilitated with novel coaxial condensing heat pipe (CCHP): Thermo hydrodynamic modelling and parametric optimization for overall operation performance

Heat pipes offer tremendous potential for utilization in the energy and construction industries due to their excellent heat transmission efficiency. The current study involved the development of a theoretical model for thermal transport in a coaxial condensing heat pipe (CCHP) connected with solar photovoltaic and thermal (PVT) systems. Subsequently, parameter studies were conducted to analyze their impact on system performance, including irradiation intensity, surrounding temperature, inlet temperature, mass flow rate and PV coverage factor. In addition, temperature variation, thermal and electrical conversion capabilities of the CCHP/PVT system on typical days were discussed utilizing meteorological conditions in Wuhan city as inputs for the analysis. Our findings showed that the morning is when thermal efficiency is at its highest across the seasons, and it remained between 50% and 55%. Compared to natural cooling and conventional heat pipe cooling, the CCHP/PVT system reduced the temperature of the PV panels by approximately 30.3% and 16.3%, respectively. The proposed CCHP/PVT system has a respectively 14.4% and 5.2% enhancement in thermal and electrical efficiencies in comparison with those conventional heat pipes. Here, theoretical results agree well with former published ones, with average errors of no more than 10%. Our parametric investigations were then put into practice to assess the overall performance and to serve as a theoretical foundation for later development. It was really beneficial to boost the efficiency of solar energy utilization in the Yangtze River, China, where solar potentials were relatively poor than north western China.

Unusual thermal transport in molecular crystals

Phonon transport plays a vital role in various applications of molecular crystals, such as vibrational energy transfer in energetic materials during thermally- or shock-induced processes and in radiative cooling through infrared emissions in delignified and densified wood. Unlike inorganic crystals, molecular crystals are generally composed of large numbers of atoms in the repeating cell, a wide variety of force interactions ranging from long range electrostatic and London dispersion to short-range bonds of covalent or ionic character, and an accompanying broad-based vibrational spectrum with optic branches near 100 THz. Here, we examine the behavior of thermal carriers in four materials – silicon, Cs2PbI2Cl2, α-RDX, and cellulose I β– using multiple thermal transport models including the phonon gas, Cahill-Watson-Pohl, Allen-Feldman, and Wigner models. We show that three unusual mechanisms are remarkably present in molecular crystals: 1) wave-like carriers due to coupling of disparate modes are the dominant contributors to thermal transport in some complex crystals, 2) the thermal transport can occur through two, and as many as four, distinct phonon channels with each channel representing coupled modes through which varying degrees of Zener-like tunneling occur, and 3) anisotropy of thermal conductivity in some materials can only occur through direction-dependent tunneling. The mechanisms are responsible for ∼40, 75, and 80% of the total thermal conductivity in Cs2PbI2Cl2, α-RDX, and cellulose I β, respectively. The findings open new directions for controlling thermal transport in materials through chemical functionalization and molecular design principles.