ABSTRACT Fire accidents caused by fuel leakage to hot surfaces are of significant concern in the aerospace domain due to their potential for severe consequences. This paper investigates the evaporation and ignition characteristics of fuel leakage to a hot surface through a series of experiments with different volumes of RP-3 droplets. The evolution patterns of evaporation lifetime, ignition position, and ignition delay time are examined. The results show that within the surface temperature range of 500–700°C, the fuel droplets of all volumes almost immediately reach the film boiling state upon contact with the hot surface. The droplets move erratically across the surface, changing shape from irregular to elliptical and finally to spherical. The evaporation lifetime decreases with increasing hot surface temperature. The occurrence of ignition is stochastic, and the ignition probability rises with the hot surface temperature, while the minimum ignition temperature decreases with the increase of fuel volume. The movement of the fuel droplets in the film boiling state leads to the irregularity of the ignition position. Additionally, the ignition delay time decreases with an increase in the temperature of the hot surface. The relationship between ignition delay time and surface temperature in the film boiling state is discussed in the context of the vapor plume model and boiling heat transfer analysis.