The objective of this research is to investigate the effect of slice thickness on the profile accuracy of the model maker (MM) rapid prototyping (RP) system, layer by layer, through non-contact laser probe measurement. A circular triangulation laser probe, model OTM-3A20, made by Wolf & Beck Co., was mounted on a coordinate measuring machine (CMM), as the non-contact sensor. An adjustment device for the laser probe was designed to minimise the cosine error caused by assembly inaccuracy. The alignment test of the measuring laser beam was carried out using a calibrated specimen. The systematic accuracy of the circular triangulation laser probe with respect to the surface roughness and the surface slope of the RP workpiece was investigated using a HP5529A laser interferometer system. The maximum error of 21/2D RP part profile accuracy can be improved from 220 μm to 131 μm, and the average error can be improved from 78 μm to 46 μm as the slice thickness changed from 0.127 mm (0.005 in.) to 0.0127 μm (0.0005 in). However, the machining time increases by about seven fold based on the experimental results. An overall error of 197 μm as measured by the laser probe is attainable using the finest slice thickness 0.0127 mm (0.0005 in.) for the 3D profile accuracy. To verify the accuracy of non-contact laser probe measurement, the 3D profile of the RP part was also measured by a CNC CMM, with good consistency.