Directional fracturing blasting is effective for rock engineering, but it is inevitably disturbed by multiple reflected waves from different directions in natural rock mass due to discontinuous boundaries. Reflected waves affect both crack-tip stress and crack propagation, hence affect the results of directional fracturing blasting. In this paper, with the aid of high-speed photography, an optical caustics method is used to study effects of multiple reflected P waves on a directional blast-induced crack in a polymethyl methacrylate (PMMA) plate, specifically on crack path, crack fracturing mode, crack-tip stress and crack velocity. Crack-tip stress field is indicated by the shape of caustics pattern. Before the loading of reflected P waves, the mode I directional crack driven by blast-induced gases propagates in a straight path; crack-tip stress field is K-dominated, and crack-tip caustics pattern is consistent with classical caustics theory. On the contrary, under the loading of reflected P waves, the directional crack changes to be mixed-mode I + II and propagates in a curved path; Crack-tip stress field is non-K-dominated due to transient stress superposition of reflected P waves, and crack-tip caustics pattern is consistent with modified caustics theory. Transient stress superposition is not obvious for reflected P waves with a longer reflection distance. The tension loading of reflected P waves plays a more important role than the compression loading, which increases crack-tip stress intensity factors and crack velocity. This study provides a comprehensive understanding of effects of multiple reflected P waves from different directions on directional fracturing blasting.