Mixing Volume Ratio Research Articles

Facile Fabrication of Graded-Refractive-Index SiO2 Antireflective Films with Enhanced Laser Damage Resistance

The graded-refractive-index SiO2 antireflective (AR) films were prepared using the sol–gel method. A monolayer with a porous nanonetwork structure was designed as the mixed volume ratio of 70:30 between the alkali- and acid-catalyzed SiO2 sols. As the top layer, the hexamethylisilazane (HMDS) modified alkali catalyzed SiO2 sols induced SiO2 nanoparticles transforming from hydrophilic to hydrophobic nature. In comparison with the structures of monolayer and bilayer films, the AR properties and laser damage resistance were investigated in detail. By designing the nanostructures of the bottom and top layers, the graded- refractive-index SiO2 film was obtained, consequently enhancing the AR performance. In the bilayer film, the transmittance reached [Formula: see text]98%@532 nm and 97%@1064 nm, respectively, corresponding to the obvious reduction of reflectivity. The assembly of the bilayer SiO2 film increased the laser-induced damage threshold by [Formula: see text]30% from 25.3 J/cm2 (monolayer) to 33.1 J/cm2 (bilayer). The inducement of laser damage was further revealed by the analysis of morphological changes induced by laser damage, attributing to the initiator absorption of environmental contaminations. Therefore, the SiO2 film not only provided a graded-refractive-index structure with good AR performance, but also had high laser damage resistance. The unique graded-refractive-index structure of SiO2 AR films offers a new strategy for improving the performance of optical components in high-power laser systems.

Machine learning instructed microfluidic synthesis of curcumin-loaded liposomes

The association of machine learning (ML) tools with the synthesis of nanoparticles has the potential to streamline the development of more efficient and effective nanomedicines. The continuous-flow synthesis of nanoparticles via microfluidics represents an ideal playground for ML tools, where multiple engineering parameters – flow rates and mixing configurations, type and concentrations of the reagents – contribute in a non-trivial fashion to determine the resultant morphological and pharmacological attributes of nanomedicines. Here we present the application of ML models towards the microfluidic-based synthesis of liposomes loaded with a model hydrophobic therapeutic agent, curcumin. After generating over 200 different liposome configurations by systematically modulating flow rates, lipid concentrations, organic:water mixing volume ratios, support-vector machine models and feed-forward artificial neural networks were trained to predict, respectively, the liposome dispersity/stability and size. This work presents an initial step towards the application and cultivation of ML models to instruct the microfluidic formulation of nanoparticles.

Removal of arsenic from contaminated soils by combining tartaric acid with dithionite: An efficient composite washing agent

In the context of the increasing global problem of arsenic (As) contamination in soils, an efficient remediation method is urgently needed to alleviate it. In this study, a composite washing agent consisting of 0.2 mol L−1 dithionite and 0.05 mol L−1 tartaric acid (TA) in a 1:1 mixing volume ratio was prepared and used in the remediation of arsenic-contaminated soils. The results showed that the removal efficiency of arsenic was 62.47% in soil 1 at a concentration of 134 mg kg−1 and 70.08% in soil 2 at a concentration of 70 mg kg−1. Dithionite achieved greater release of the arsenic associated with amorphous hydrous oxides of iron and aluminium (F3) and arsenic associated with crystalline hydrous oxides of iron and aluminium (F4) forms of arsenic by the reductive dissolution of iron oxides, while also reducing Fe3+. TA released some arsenic in the specifically adsorbed (F2) and F3 forms through acidic effects. The mechanism of arsenic removal from the composite washing agent was found to be a synergistic effect between dithionite and TA. The TA complexation formed Fe-TA complexes with Fe2+ in solution, preventing the formation of new iron mineral phases and reducing the readsorption or precipitation of arsenic to the soil surface. Meanwhile, the formation of Fe-TA complexes kept the iron oxides dissolved, allowing more iron oxide-bound arsenic (F3 +F4) to be released. This study showed that combining TA with dithionite is a promising technology for remediating arsenic-contaminated soils because of its high efficiency.

Dissolution of aluminum hydroxide to provide Al and to neutralize acidity for the removal and recovery of fluoride through cryolite crystallization

Dissolution of aluminum hydroxide (Al(OH)3(s)) was investigated for providing Al and at the same time neutralizing the acidity generated in the recovery of fluoride through the crystallization of cryolite. The alkalinity provided by the dissolution of Al(OH)3(s) combined with Na2CO3 reduces the total treatment cost for fluoride recovery by 45%, compared to when other aluminum salts were used. In this study, two types of aluminum hydroxide having different degrees of crystallinity of 61.53% and 25.57%, denoted as crystalline Al(OH)3(s) (CAH) and amorphous Al(OH)3(s) (AAH), respectively, were investigated. The results showed that the dissolution of AAH was very efficient but an excess amount of AAH adsorbed the freshly formed AlFx3−x complexes, impairing the purity of cryolite. On the other hand, the dissolution of the CAH was mostly dependent on the time, the Al dosage, and the initial pH of the solution. Upon reaching equilibrium, the dissolved Al to the initial F molar ratio reached 2/6. With the mixed volume ratio of 1:1 between the raw HF solution and the HF solution being equilibrated with CAH initially, the removal of F reached 96% and the cryolite formation was positively confirmed based on the XRD analysis of the resulting solid.

The Effects of Nanoparticles- Zerovalent Iron on Sustainable Biomethane Production through Co-Digestion of Olive Mill Wastewater and Chicken Manure

The impacts of nanoparticles-zerovalent iron (NP-ZVI) on anaerobic co-digestion (AcoD) were assessed. The production of biogas and methane (CH4), as well as the removal efficiency of volatile solids (VS) and contaminants were investigated in the AcoD of chicken manure (CM) and olive mill wastewater (OMWW) with the addition of NP-ZVI at different concentrations (10–50 mg/g VS) and different sizes resulting from various mixing volume ratios (MVR) of NaBH4:FeSO4.7H2O. The results show that NP-ZVI ≤ 30 mg/g VS at MVR-2:1, MVR-4:1, and MVR-6:1 improves the AcoD. In contrast to 40–50 mg/g VS of NP-ZVI, which caused an inhibitory impact in all of the AcoD stages, as well as a decrease in the contaminant’s removal efficiency, the concentration of 10–30 mg NP-ZVI/g VS at MVR-4:1 achieved a maximum improvement of CH4 by 21.09%, 20.32%, and 22.87%, respectively, and improved the biogas by 48.14%, 55.0%, and 80.09%, respectively, vs. the 0 additives. Supplementing AcoD with NP-ZVI at a concentration of 30 mg/g VS at MVR-4:1 resulted in maximum enhancement of the contaminant removal efficiency, with a total oxygen demand (TCOD) of up to 73.99%, turbidity up to 79.07%, color up to 53.41%, total solid (TS) up to 59.57%, and volatile solid (VS) up to 74.42%. It also improved the hydrolysis and acidification percentages by up to 86.67% and 51.3%, respectively.

The role of fluid mixing in the formation of vein-type Zn-Pb deposits in eastern Guizhou Province, SW China: Insights from elemental compositions and chlorine isotopes of fluid inclusions

• Multiple fluid sources are identified by variation range of Cl isotopes and Cl/Br ratios from. • Vein-type Zn-Pb mineralization is triggered by mixing of evaporated seawater and magmatic hydrothermal fluids . • Quantitative model shows that the mixing volume ratios of both sources are between 1:9 and 4:6. Numerous hydrothermal vein-type Zn–Pb deposits worldwide are characterized by low-temperature metallogeny, no spatial relationship with plutons, and strong water-rock interaction, which result in the difficulty of constraining the fluid origin and the process of ore formation by traditional geochemistry. In this study, we employ chemical and chlorine isotopic composition of bulk fluid inclusions from ore-bearing and ore-barren quartz veins to constrain the possible sources of ore-forming fluids and the process of metal precipitation in the hydrothermal systems of the economic vein-type mineralization in eastern Guizhou Province, SW China. Our new geochemical data are indicative of two end-members in the systems, one identified in the ore-bearing veins with high K/Na, Li/Na, Cl/Br ratios, and δ 37 Cl values representing magmatic hydrothermal fluids, another distinguished in the ore-barren veins with low Cl/Br ratios and δ 37 Cl values representing evaporated seawater. We conclude there is a systematic variation of these geochemical data as the results of the mixing between the former and the latter end-member. In the meantime, the mixing is quantitively assessed to study the mixing volume ratios of both end-members. Based on our data and our own previous study, a genetic fluid mixing model involving the magmatic hydrothermal fluids related to deep magma activity and the evaporated seawater is established for the formation of the vein-type Zn–Pb deposits. This study provides a novel geochemical approach for recognizing hydrothermal mineralizing systems.

Investigation of biochemical properties of flash sintered ZrO2–SnO2 nanofibers

ZrO2–SnO2 nanocomposition were produced in nanofibers (NFs) form with three various mixing volume ratio by electrospinning technique. The microstructure and morphological characterization of NFs reveals the ternary system of ZrO2–SnO2–ZrSnO4. Furthermore, Band gap structure of NFs was varied with the composition ratio which consequently affect the Flash sintering (FS) event. The FS experiments were utilized under thermal (844–878 °C) and electric field (420 V/mm) with 3.77 mA/mm2 current cutoff. Highly dense nanocomposition were obtained in less than 80secs with a max power absorption of 1.58 W/mm3. Thanks to low sintering temperature and time, nanostructured surface morphology were acquired which is crucial for biochemical properties of nanocompositions. Drosophila melanogaster food was covered with sintered nanocompositions and the control food. The toxicity of the nanomaterial in the insect, survival rate(%), development time(days) were investigated. In order to support the results, biochemical analyzes (total oxidative level-TOS, total antioxidant level-TAS and oxidative stress index-OSI) were performed in adults. In addition, antimicrobial activity was evaluated with Escherichia coli and Staphylococcus aureus. It was determined that the nanomaterials had an antimicrobial effect along with non-toxic effect on the insect. Besides, it did not change the survival rate of the insect in all groups. Although there was a one-day difference in development times, it did not cause a statistical change in the OSIs of female and male individuals. We believe that the synthesized nanocompositions can be used as a valid candidate in the healthcare system, such as dental implants, due to its antimicrobial effect and non-toxicity in the model organism.

Sol-Gel Synthesis and Characterization of Highly Selective Poly(N-methyl pyrrole) Stannous(II)Tungstate Nano Composite for Mercury (Hg(II)) Detection

The sol-gel process was used to create a new type of polypyrrole-Stannous(II)tungstate nanocomposite by poly(N-methyl pyrrole (PNMPy) sol in Stannous(II)tungstate gel, produced separately using sodium silicotungstic acid and Tn(II)chloride. Tin(II)tungstate (SnWO3) was made by changing the mixing volume ratios of SnWO3 and with a constant amount of an organic polymer. The composite was characterized by TGA, XRD, FTIR, and SEM measurements. A commercially available glassy carbon electrode (GCE) was modified with PNMPy/nano-Stannous(II)WO3 nanocomposites to create a chemical sensor for selective detection of Hg2+ ions using an effective electrochemical methodology. In the I-V technique, selectively toxic Hg2+ ion was targeted selectively, which shows a rapid reaction toward PNMPy/nano-Stannous(II)WO3/Nafion/GCE sensor. It also demonstrates long-term stability, an ultra-low detection limit, exceptional sensitivity, and excellent reproducibility and repeatability. For 0.1 mM to 1.0 nM aqueous Hg2+ ion solution, a linear calibration plot (r2: 0.9993) was achieved, with a suitable sensitivity value of 2.8241 AM−1 cm−2 and an extraordinarily low detection limit (LOD) of 3.40.1 pM (S/N = 3). As a result, the cationic sensor modified by PNMPy/nano-Stannous(II)WO3/GCE could be a promising electrode.

Fissure Grouting Mechanism Accounting for the Time-Dependent Viscosity of Silica Sol.

Subject to the complex hydrogeological environment where underground engineering is located, the grouting prevention and control of microfissure water ingress are increasingly strict. Silica sol grout has been increasingly used in field tests because of its fine particles and good injectability. Therefore, it is necessary to examine the time-dependent viscosity of silica sol grout and clarify its diffusion law in a rock fissure. In this study, the time dependence of the viscosity of silica sol grout was studied, and then the grout viscosity was subdivided into a slow growth period, accelerated growth period, and rapid curing period according to the growth rate. The effects of the concentration of colloidal silica suspension, the concentration of accelerant, and the mixing volume ratio of the two on the growth of the slurry viscosity were studied. A parameter λ was introduced to comprehensively characterize the influence of the three factors on the rheological properties of the slurry. The relationship between the gel induction time and λ and the accelerating growth stage of the slurry gel was obtained by data fitting. The time-dependent equation of the silica sol solution was established. The difference in the grouting diffusion law between silica sol grout and cement–sodium silicate grout (C-S grout) is compared and analyzed by a stepwise calculation method under two grouting modes (constant-pressure grouting and constant-rate grouting). The results show that under the condition of constant-pressure grouting, the silica sol grout migrates and diffuses continuously for a long time, while the C-S grout is close to the final diffusion form at 15–20 s, and the maximum diffusion distance is much smaller than that of silica sol grout. Under the condition of constant-rate grouting, the grouting pressure driving C-S grout increases sharply with time. Compared with C-S grout, silica sol grout has the obvious advantages of a longer effective diffusion time and lower energy consumption. The research results have certain theoretical significance and reference value for the engineering design of silica sol grouting.

Controlled restructuring of bidisperse silica nanospheres for size-selective nanowire growth

We investigate neck mediated restructuring of silica nanospheres (SNs) of different radii assembled in a single-layer via sintering, resulting in the fabrication of size-tunable templates. We explore the influence of physical dimensions and mixing ratios of the participating SNs, over the neck formation and the assembly. We elucidate variation in the neck parameters pertinent to the template dimensions at every stage of sintering by a generalized geometrical model. The resultant geometry, morphological properties, and sintering parameters of SNs thin films, parametrized by particle radii, sintering duration, and mixing volume ratios, are quantified. The sintering mechanism between SNs, which are chemically and geometrically identical but of different radii, scales in accordance with Herring's law and provides valuable insights into the dominant mass transport mechanism contributing to neck formation. Control over sintering parameters facilitates the fabrication of tunable templates to grow size-selective nanowires with water-splitting, optoelectronics, and anti-reflective coating applications.

Effect of Methanol/Water Mixed Fuel Compound Injection on Engine Combustion and Emissions

Due to the recent global increase in fuel prices, to reduce emissions from ground transportation and improve urban air quality, it is necessary to improve fuel efficiency and reduce emissions. Water, methanol, and a mixture of the two were added at the pre-intercooler position to keep the same charge and cooling of the original rich mixture, reduce BSFC and increase ITE, and promote combustion. The methanol/water mixing volume ratios of different fuel injection strategies were compared to find the best balance between fuel consumption, performance, and emission trends. By simulating the combustion mechanism of methanol, water, and diesel mixed through the Chemkin system, the ignition delay, temperature change, and the generation rate of the hydroxyl group (−OH) in the reaction process were analyzed. Furthermore, the performance and emission of the engine were analyzed in combination with the actual experiment process. This paper studied the application of different concentration ratios of the water–methanol–diesel mixture in engines. Five concentration ratios of water–methanol blending were injected into the engine at different injection ratios at the pre-intercooler position, such as 100% methanol, 90% methanol/10% water, 60% methanol/40% water, 30% methanol/70% water, 100% water was used. With different volume ratios of premixes, the combustion rate and combustion efficiency were affected by droplet extinguishment, flashing, or explosion, resulting in changes in combustion temperature and affecting engine performance and emissions. In this article, the injection carryout at the pre-intercooler position of the intake port indicated thermal efficiency increase and a brake specific fuel consumption rate decrease with the increase of water–methanol concentration, and reduce CO, UHC, and nitrogen oxide emissions. In particular, when 60% methanol and 40% water were added, it was found that the ignition delay was the shortest and the cylinder pressure was the largest, but the heat release rate was indeed the lowest.

Study of hydrogen bonding interactions in ethylene glycol-water binary solutions by Raman spectroscopy

EG (ethylene glycol) is a good model system for the study of the fundamental hydrogen bonds in aqueous solutions. Using Raman spectroscopy, we have investigated the EG volume fraction induced variation in the hydrogen bonding interactions and conformations of EG-H2O (water) binary solutions. New hydrogen bonding networks is evidenced by the appearance of remarkable changes in Raman spectra and the full width at half maximum (FWHM) when the mixing volume ratio is 0.5. The H-bond in water molecules firstly strengthened and then weakened with the increasing concentration of EG. Meanwhile, the dominant association structure also changed from H2O-H2O to EG-H2O in binary solutions in this process. We provide a simple but effective method for studying EG-H2O binary solutions. It also has exciting potential prospects and can be easily extended to other mixing situations.

Computational fluid dynamics simulation of an Inert Particles Spouted Bed Reactor (IPSBR) system

AbstractA novel system for contacting gases and liquids, suitable for many applications involving gas–liquid contact such as CO2 capture and brine desalination, has been simulated and experimentally validated. The system comprises a vertical vessel with gas and liquid ports and inert particles that enhance mixing and provide a high gas–liquid interfacial area. A low gas flow rate was statistically demonstrated and experimentally verified to be the optimum condition for CO2 capture and brine desalination; however, the gas velocity can have a considerable effect on the motion of inert particles inside the reactor. Uniform particles motion ensures good mixing within the reactor and hence efficient absorption and stripping process. A computational fluid dynamics (CFD) model, namely Eulerian model, presented in this paper, will help demonstrate the effect of mixing particles at specific conditions on the gas and liquid velocities inside the reactor, gas and liquid volume distribution through reactor, and eddy viscosities stresses of the mixing particles. A mesh-independent study was conducted to demonstrate the independency of mesh structure and size on the output responses. A quasi-steady state was attained to ensure the stability and feasibility of the selected model. The assembled model exhibits remarkable applicability in determining the optimum mixing particles densities, volume ratios, and sizes to ensure best velocity distribution and gas spreading inside the reactor and accordingly enhance the associated chemical reactions.

Experimental study on fluidization, mixing and separation characteristics of binary mixtures of particles in a cold fluidized bed for biomass fast pyrolysis

To guarantee the uniform mixing of biomass and inert particles in the fluidized bed reactor for the full and complete reaction during the biomass fast pyrolysis process, a visualized cold fluidized bed experimental apparatus was set up to investigate the effects of static bed height, moisture content and particle diameter on the fluidization quality of single component particles, and the mixed volume ratio on the fluidization characteristics of binary mixtures. The results showed that the appropriate static bed height was significant for the stability of the fluidized bed. As the moisture content increased, the minimum fluidization velocity increased rapidly while the fluidization index continued to decrease. In addition, the fluidization performed on binary mixtures of larch/quartz sand-2 indicated that the same minimum fluidization velocity was the key parameter for the two kinds of particles to be fully fluidized simultaneously, avoiding the semi-fluidization phenomenon. The mixed volume ratio of larch (M = 10.3%)/quartz sand-2 and superficial gas velocity range were also the important factors affecting fluidization and mixing quality, and the optimal value were 1: 3 and 3–5 umf, respectively.

Effect of pH, Rotation Speed and Imidazoline - Paracetamol Based Inhibitor Volume Ratio on Corrosion Protection of St 41 Steel in CO<sub>2</sub> Environment Using Rotating Cylinder Electrode (RCE)

Inhibitor is a chemical compound which commonly used to control corrosion in a tank or a pipelines. Organic inhibitor recently developed because of the availability and the ability to act like commercial inhibitor. The performance of mixed inhibitor was studied on St 41 carbon steel immersed in NaCl solution containing CO2 gas. Research parameter used were pH 4 and 6, rotation speed of 150 and 250 rpm, with mixed inhibitor volume ratio of 1 (imidazoline) : 2 (paracetamol), 1:1, also 2:1. The Weight loss measurement, isotherm adsorption calculation, FTIR, and XRD measurement have also been done. Based on weight loss test, the highest inhibitor efficiency was 61.412 % at pH 6, 150 rpm, with inhibitor volume ratio of 2:1, adsorption isotherm calculation indicate the adsorption mechanism of the mixed inhibitor is physical adsorption. Tafel test result showed the tendency of inhibitor worked anodically. The FTIR spectrum result found functional group of N-H from the inhibitor precipitated on the metal surface after ten days of immersion Based on the EIS result, there was an increase value of polarization resistance value and decrease on CPE (constant phase element) value. While X – ray diffraction (XRD) result from the volume ratio of 1:2 confirm the CO2 corrosion product FeCO3 and Fe2O3 formed on metal surface. With volume ratio of 2:1 mixed inhibitor, it was confirmed that iron nitride (Fe24N10) compound was formed on steel surface because of the chemisorption reaction between Fe and nitrogen atom from pyridine at the imidazoline inhibitor. The inhibition mechanism was physisorption for entire parameters, based on calculation of Langmuir adsorption theorem.

Evaluation of the effect of sodium hydroxide solution on biogas yield of anaerobic digestion of poultry waste and the digestate

The effect of adding an alkaline solution, sodium hydroxide (NaOH), in optimizing biogas and methane yield from poultry waste anaerobically was investigated in this work. Two digesters of 50 l capacity each were set up and labeled A and B. Digester A was batched with a mixture of 19 kg of PW and 19 l of water, while digester B has the same mixed volume ratio of poultry waste and water as in digester A but with the addition of 380 ml of 1 M NaOH. Daily gas yield was obtained from the two digesters for a retention period of 30 days; the temperature and pH were also recorded. The peak yield from digester A was recorded on day 23 to be 0.0392 m3, while digester B peak yield of 0.0522 m3 was recorded on day 18. The cumulative biogas yields at the end of the retention period were 0.5511 m3 and 0.6070 m3, respectively, for both digesters. The coefficient of correlation R2 between the gas yields of the two samples is 0.9657. The biogas obtained from the two setups was analyzed with digester B (poultry waste + water + 380 ml of 1 M NaOH) having an appreciable methane yield of 3.03% than digester A.

Hemoglobin–albumin cluster: physiological responses after exchange transfusion into rats and blood circulation persistence in dogs

A core–shell protein cluster comprising hemoglobin and human serum albumins, hemoglobin–albumin cluster (Hb–HSA3), was designed and synthesized for use as an artificial O2 carrier and red blood cell (RBC) substitute. For initial preclinical safety evaluation of the Hb–HSA3 solution, we observed blood compatibility in vitro, physiological responses after exchange transfusion into rats and blood circulation lifetime in dogs. Dilution of human whole blood with Hb–HSA3 showed an appropriate decrease in blood cell number, proportional to the mixing volume ratio. Time courses in the circulation parameters and blood gas parameters after 20% exchange transfusion with Hb–HSA3 in anesthetized rats were almost identical to those observed in a sham group (without infusion) and an HSA group (with HSA administration) for 6 h. Serum biochemical tests of the withdrawn blood indicated safety of the protein cluster. Furthermore, fluorescent Hb–HSA3 was infused into beagle dogs to assess blood retention. Fluorescence measurements of the blood samples enabled us to ascertain the cluster half-life within the intravascular space. Histopathologic inspections of the vital organs imply no abnormality in tissues. All these results indicate sufficient initial preclinical safety of Hb–HSA3 as an alternative material for use in RBC transfusion.

Process optimisation for green synthesis of zero-valent iron nanoparticles using Mentha piperita.

The potential of Mentha piperita in the iron nanoparticles (FeNPs) production was evaluated for the first time. The influences of the variables such as incubation time, temperature, and volume ratio of the extract to metal ions on the nanoparticle size were investigated using central composite design. The appearance of SPR bands at 284 nm in UV-Vis spectra of the mixtures verified the nanoparticle formation. Incubating the aqueous extract and metal precursor with 1.5 volume ratio at 50°C for 30 min leads to the formation of the smallest nanoparticles with the narrowest size distribution. At the optimal condition, the nanoparticles were found to be within the range of 35-50 nm. Experimental measurements of the average nanoparticle size were fitted well to the polynomial model satisfactory with R2 of 0.9078. Among all model terms, the linear term of temperature, the quadratic terms of temperature, and mixing volume ratio have the significant effects on the nanoparticle average size. FeNPs produced at the optimal condition were characterised by transmission electron microscopy, thermogravimetry analysis (TGA), and Fourier-transform infrared spectroscopy. The observed weight loss in the TGA curve confirms the encapsulation of FeNPs by the biomolecules of the extract which were dissociated by heat.

High‐sensitivity structure for the measurement of complex permittivity based on SIW

In this study, a substrate integrated waveguide (SIW) combined with complementary split-ring resonator (CSRR) structure is proposed for high-sensitivity measurement of complex permittivity of low loss material at 2.45 GHz. The simulated results demonstrated that the small changes can be sensed through loading the CSRR structure on both sides of SIW. Then, the experiments are performed on various dielectric samples to validate the proposed structure by measuring the particulate samples with different moisture contents and solution samples in different mixed volume ratio. The measured results show that the sensitivity of the proposed SIW with CSRR structure is always higher than the structure without CSRR. Furthermore, neural network based on actual experimental scattering parameters is used for obtaining the permittivity of samples under test. The experimental values agree well with the theoretical values, and the relative errors of and are <5 and 10%.

Effects of surface plasmon resonance of the Ag nanoparticles on the efficiency and color stability of the blue light phosphorescent organic light emitting diodes

The electroluminescence (EL) performance of the blue light phosphorescent organic light emitting diode (OLED) incorporating Ag nanoparticles (Ag NPs) beneath or within the PEDOT:PSS hole injection layer (HIL) has been investigated, and the surface plasmon-enhanced EL efficiency has been demonstrated. The OLED with the structures of Ag NPs beneath and within the HIL exhibit the respective optimal power efficiency of 43 lm/w (EQE of 31%) and 35 lm/w (EQE of 25%) at the brightness of 1000 cd/m2 compared to that of 15 lm/w (EQE of 13%) for the control device without Ag NPs incorporated. The mixing volume ratio of Ag NPs to PEDOT:PSS reveals remarkable influence on the OLEDs EL efficiency, and ratio of 1:3 is proved to be optimal due to the sufficient coupling between the surface plasmon of Ag NPs and excitons in the emission layer without significant exciton quenching from the Ag NPs. The blue OLEDs with Ag NPs beneath HIL also reveal considerable color shifting with the increasing luminance while the OLEDs with the mixture of Ag NPs and PEDOT:PSS at various ratios demonstrate stable EL spectrum. The influence of localized surface plasmon resonance (LSPR) from Ag NPs in the different structures on the EL efficiency and spectrum is discussed in details.