Styles Of Mineralization Research Articles

Tracing fluid signature and metal mobility in complex orogens: insights from Pb-Zn mineralization in the Pyrenean Axial Zone

AbstractOrogenic processes encompass a complex interplay of deformation and metamorphic events, which can impact the formation of ore deposits to various degrees. However, distinguishing fluid signatures from orogenic versus post-orogenic events presents a significant challenge due to the scarcity of robust geochemical indicators that remain unaffected during multiple post-mineral reworking events. This study carefully examines the properties and chemistry of primary and secondary fluid inclusions (FIs), identifying distinct signatures of two fluid populations linked to different styles of Pb-Zn mineralization in the Pyrenean Axial Zone (PAZ) of Southern-France/Northern-Iberia: These included late-Carboniferous stratabound epigenetic Pb-Zn deposits and Mesozoic crosscutting Pb-Zn(-Ge) vein systems. Population (I) is identified in primary and secondary FIs in a few crosscutting Pb-Zn veins and constitutes a minor component in stratabound epigenetic bodies. It exhibits Na-dominated low to intermediate salinity (< 20 wt% NaCl eq.), intermediate temperatures (200–350 °C), abundant CO2-rich FIs and shows low homogeneous Cl/Br molar ratios. These characteristics are consistent with a metamorphic origin of the fluids, associated with Late-Variscan metamorphism. Population (II) is commonly observed in the crosscutting vein systems where it occurs as primary and pseudosecondary FIs, as well as in stratabound epigenetic bodies where it represents the main fluid component of secondary FIs. Population (II) is Ca-dominated with intermediate to high salinity (15–35 wt% NaCl eq.), relatively low temperature (< 200 °C), and shows high Cl/Br molar ratios with significant variations. This last characteristic is typical of mixing of at least two fluids, one with a probable low Cl/Br molar ratio at shallow crustal levels and another with high Cl/Br molar ratio at deeper levels. Characteristics of population (II) are consistent with a fluid of basinal origin that interacted with the basement while circulating in the Pyrenees during the Mesozoic, although a Pyrenean-Alpine age cannot be excluded. Locally, in sphalerite-hosted secondary FIs that form trails in the crosscutting veins, we find evidence of high Ge concentrations (up to few 1000s ppm), which correlate with anomalous Pb and Tl concentrations. Very high metal concentrations (up to 1–2 wt% Pb, Zn), which are inversely proportional to Cl/Br molar ratios, are found in FIs mainly within veins hosted in deep-seated high-grade metamorphic rocks. Based on a compilation of fluid data from the literature, a first-order correlation can be deduced between the metamorphic grade of the rocks hosting the mineralization and the Pb and Zn content in the FIs. Early stratabound orebodies are considered likely sources of metal for the development of the late crosscutting vein mineralization. This study demonstrates the significance and complexity of orogen-scale fluid circulation and supports the importance of pre-existing metal enrichment in the crust, especially in high-grade metamorphic rocks as a prerequisite for the formation of Pb-Zn veins in complex multi-stage orogens.

Revealing Yukon’s hidden treasure: an atomic-scale investigation of Carlin-type gold mineralization in the Nadaleen Trend, Canada

AbstractThe invisible-gold deposits known as Carlin-type are becoming more important as easier to find deposits are progressively depleted. The combination of the invisible nature of the Au in these deposits, as well as the limited surface indicators of these deposits, makes exploration to find new Carlin-type deposits extremely difficult. Comprehensive mineralization models are essential to find new Carlin-type deposits in similar geologic settings. The Nadaleen Trend of Yukon, Canada, is one such district where an improved understanding of this deposit type has led to new discoveries. Previous studies compared and contrasted the tectonic setting, host rock depositional setting, structural preparation, and mineralization style of the Nadaleen Trend with those in Carlin-type localities, Nevada. However, the comparisons at an atomic scale, between Carlin-type Au deposits in the Nadaleen Trend and those in Nevada, has yet to be investigated. This study fills this knowledge gap by combining high resolution microanalytical techniques with atom probe tomography to examine the distribution of Au and other trace elements in the Nadaleen Trend, compare them to a representative Carlin-type deposit in Nevada (Turquoise Ridge), and determine how widespread the mineralization model is. Our findings show that in the Nadaleen Trend, as in Nevada, Au is generally directly linked with As at the macro to atomic scale, and is incorporated into As/Au rich overgrowths on sedimentary/diagenetic pyrite. Gold-rich pyrite rims in the Nadaleen Trend are generally smaller than those found in Nevada (0.5–2 µm vs > 10 µm), although the ore grades appear comparable. We find that the Au in the pyrite of the Nadaleen Trend is homogenously distributed (i.e. lattice bound) at the atomic scale, but that there is a notable enrichment of As surrounding individual Au atoms. These findings are in agreement with those from previous work on a representative deposit in Nevada, and support the assertation that As is the key ingredient in facilitating the incorporation of Au into the pyrite lattice. Arsenic as an essential component in the trapping mechanisms of Au in CTG deposits, is something that has been as to yet underappreciated in the current models of CTG deposit formation.

Inversion of downhole resistivity properties through infrared spectroscopy and whole‐rock geochemistry using machine‐learning

AbstractThe electrical properties of rocks are widely used in the geophysical exploration of natural resources, such as minerals, hydrocarbons and groundwater. In mining exploration, the primary goal is to map electrically anomalous geological features associated with different mineralization styles, such as clay alteration haloes, metal oxides and sulphides, weathered crystalline rocks or fractured zones. As such, the reconciliation of geophysical data with geological information (geochemistry, mineralogy, texture and lithology) is a critical step and can be performed based on petrophysical properties collected either on core samples or as downhole measurements. Based on data from 189 diamond drill cores collected for uranium exploration in the Athabasca Basin (Saskatchewan, Canada), this paper presents a case study of reconciliation of downhole resistivity probing with core sample geochemistry and short‐wave infrared spectroscopy (350–2500 nm) through three successive steps: (i) multivariate analysis of resistivity and other petrophysical properties (porosity, density) against geochemical and infrared spectroscopy information to characterize electrical properties of rocks with respect to other physical parameters, (ii) a machine‐learning workflow integrating geochemistry and spectral signatures in order to infer synthetic resistivity logs along with uncertainties. The best model in the basin was Light Gradient‐Boosting Machine with pairwise log‐ratio, which yielded a coefficient of determination R2 = 0.80 (root mean square error = 0.16), and in the basement, support vector regression with data fusion of infrared spectroscopy and pairwise log‐ratios on geochemistry yielded R2 = 0.82 (root mean square error = 0.35); (iii) the best model was then fitted on an area that was excluded from the original dataset (Getty Russell property) in order to infer synthetic resistivity logs for that zone. Software code is publicly available. This workflow can be re‐used for the valorization of legacy datasets.

Constraints of in-situ elemental compositions and U–Pb ages of cassiterite on the origin of the Cretaceous Gejiu and Dulong tin deposits, SW China: Implications for the linkage of tin belts in SE Asia

The western Yunnan tin belts in SW China and the southern Myanmar tin belt in SE Asia are traditionally thought to be part of the SE Asian tin metallogenic province. However, the tectonic setting of the Youjiang tin belt in SW China and its genetic relationship to the other tin belts are poorly documented. In this belt, the giant Gejiu and Dulong tin deposits are typical of skarn-type deposits and both contain contact and distal skarn orebodies. Tin ores of distal orebodies in these two deposits are composed of cassiterite, sulfide and calcite. In both deposits, most cassiterite grains from these ores are rich in Fe and W and depleted in Nb and Ta. They have 238U/206Pb ages between 81.4 and 84.1 Ma, similar to hosting granitic plutons. Two generations of cassiterite with distinctly different microtextures and trace elemental compositions can be recognized. The first generation (Cst-I) is compositionally and texturally homogeneous, but the second generation (Cst-II) displays distinctly oscillatory zoning. Cst-II contains Nb, W, and U lower, and Fe, Ta, Zr and chalcophile elements (Ga, Ge, In, and Sb) higher than Cst-I. These textural and compositional variations reflect the potential involvement of meteoric water in the magmatic-hydrothermal system. In this system, ore-forming fluids were evolved to more alkaline and oxidized to facilitate the precipitation of cassiterite. Our study indicates that these two deposits in the Youjiang tin belt have mineralization styles similar to those in the adjacent western Yunnan and southern Myanmar tin belts and all these tin belts belong to the SE Asian metallogenic provinces. A westward-younging trend of tin mineralization in these three belts can be explained by the rollback of the subducted Neo-Tethyan oceanic slab. This setting is different from the one related to the subduction of the Paleo-Pacific plate.

From birth to death: The role of upper-crustal thermal maturation and volcanism in porphyry ore formation revealed in the Yerington district

The current race towards greener energy and its intertwined increase in Cu demand imposes the need to find mineralized centers that are economic despite greater depths. To this end, a better understanding of the processes controlling the metal tonnage of porphyry Cu deposits, the main source of Cu, is needed and the focus of current research and debate. This study provides a comprehensive view of the duration of upper-crustal magmatism and its significance in the degree of metal endowment in porphyry Cu deposits using the Yerington batholith, Nevada, USA, as a case study. The Yerington district constitutes an exceptional example of an exposed porphyry Cu system where the plutonic environment that fed the porphyritic dikes is accessible. Combining trace element geochemistry and high-precision geochronology of zircon from all exposed units, we propose that the thermal maturation of the upper crust by a continuum in magmatic activity without significant hiatuses is a key factor in enabling the formation of large porphyry Cu style mineralization. The Yerington magmatic system transitioned from a volcanically active environment with coeval plutonism to a growing upper-crustal magmatic reservoir that fed the porphyritic dikes and associated mineralized centers to then resume its volcanic activity terminating the ore-forming episode. A relatively high volcanic/plutonic ratio characterized the first expressions of Jurassic magmatism in the district from ∼170 Ma with the coeval eruption of the Artesia Lake volcanics and the protracted emplacement of the McLeod Hill pluton. Geochemically, this period recorded distinctive negative Eu anomalies and a gentle increase in Yb/Dy ratios in zircon with decreasing Ti contents over a large range of zircon crystallization temperatures. This persistent magmatism over ∼2 Myr thermally matured the upper crust, enabling the growth of magmatic reservoirs that formed the Bear and Luhr Hill plutons without known volcanic activity for ∼1.3 Myr. Zircon trace element compositions indicate that this transition occurred as a continuum in decreasing negative Eu anomalies and increasing Yb/Dy with decreasing Ti contents and age across the plutonic units, reaching the more evolved signatures and lowest crystallization temperatures in the zircon from porphyry dikes. An increase in the volcanic/plutonic ratio with the eruption of the Fulstone Spring sequence likely terminated the ore-forming potential of the district. Although many other studies have provided important views on the timing and duration of porphyry Cu deposit formation, the link to their plutonic roots has been limited due to their inaccessibility. Therefore, this study offers the first complete picture into the temporal and chemical evolution of an upper-crustal magmatic system and the roles that factors like prolonged magmatism and volcanism play before and after ore formation. We argue that without the thermal maturation of the upper crust, the construction of a long-lived magmatic reservoir would not have been possible, precluding the formation of porphyry Cu deposits. Under this premise, not only the duration of ore-related magmatic activity, but the occurrence of long-lived precursor magmatism might exercise crucial control on the final tonnage of the deposit and should be considered during exploration for new porphyry deposits.

A synthesis of the REE-Fe-polymetallic mineral system of the REE-line, Bergslagen, Sweden: New mineralogical and textural-paragenetic constraints

Rare earth elements (REE) have gained increasing significance for numerous technologies, particularly in today’s rapidly expanding “green transition” applications such as wind generators and electric vehicle traction engines. Among the more well-known REE mineralisation types in Sweden, together with alkaline intrusions and apatite-iron oxide ores, is the classic yet enigmatic REE-Fe-polymetallic mineral system of Bastnäs-type. The mineralisation type is regional in context and occurs in a discontinuous SW-NE-striking belt (the REE-line) in the west-central part of the Palaeoproterozoic Bergslagen ore province, Sweden. This contribution is aimed at integrating and synthesising existing geological mineralogical, and textural features with new observations from both well-known and several lesser-known, underexplored or previously unrecognised REE-enriched occurrences within this belt, and to discuss key features within the context of mineral systems modelling. A considerable diversity in both the style and abundance of REE mineralisation as well as in discrete REE mineralogy is evident both regionally across the entire REE-line and locally within different ore districts or mine fields. These variations also extend laterally within or across different stratigraphic levels, and within different host rocks, primarily skarn-altered metacarbonates but also variably altered felsic metavolcanic rocks. Many of the mineralisations share similar textural features, which record a protracted evolution with multiple stages of formation or replacement of REE-minerals. The earliest recognised REE assemblages feature fine-grained cerite-(CeCa) with minor bastnäsite-(Ce) – bastnäsite-(La) or fluorbritholite-(Ce) – fluorbritholite-(Y) or locally britholite-(Ce) – britholite-(Y) minerals. Such assemblages typically display anhedral-granoblastic textures appearing in folded assemblages, all suggesting recrystallisation and ductile deformation during regional metamorphism of REE-minerals that had formed during an early stage of the Svecokarelian orogeny. Overprinting overgrowths and cross-cutting vein-like features of allanite-group minerals likely represent different stage(s) of REE mineralisation and (re)-mobilisation during this orogenic evolution. Several of the REE-enriched occurrences contain variably abundant and diverse polymetallic Cu-Mo-Bi-(Co) sulphide mineralisation that typically occur in late paragenetic positions and show a prevalence to REE-rich assemblages, often dominated by different allanite-group minerals. Sulphide and REE mineralisation are locally strongly associated with metamorphic minerals formed during metamorphism of variably Mg-(Fe)-altered metavolcanic rocks. The diversity in style and intensity of the REE mineralisations, along with variations in textures and specific mineralogy, suggest slight differences in the ore-forming conditions or environment at the time of mineralisation. Additionally, these differences may also reflect variations in the preservation or modification processes that operated later in the evolution of the Svecokarelian orogeny, also featuring remobilisation of REEs and sulphidic minerals. The insights gained from all available evidence synthesised herein, from micro-scale to province-scale, help define key proxies for prospectivity mapping. The combined evidence supports that the primary ore-forming stages in the mineral system coincided with felsic volcanism and associated sub-volcanic to plutonic processes at around 1.9 Ga.

Genesis of the Kateba’asu gold deposit, Western Tianshan, China: Constraints from pyrite trace element, sulfur isotope, and quartz H-O isotopes

The Kateba’asu gold deposit, situated in the Western Tianshan of China, is one of the most significant discoveries in the world-class Tianshan gold belt. The deposit features two distinct mineralization styles. The early, subordinate skarn-type copper–gold mineralization occurs in the contact zone between monzogranite, diorite, and Silurian limestone, composed of garnet, diopside, epidote, chalcopyrite, pyrite, and gold. The later, primary lode-gold mineralization is hosted in the altered monzogranite characterized by pervasive quartz-pyrite-sericite-chlorite-K-feldspar alteration and a well-develped veining systems.Pyrite is the dominant sulfide mineral related to gold mineralization in the Kateba’asu gold deposit, with four types identified: Py0 from the early skarn copper–gold mineralization, and Py1 to Py3 from the later lode-gold mineralization. All types of pyrite are homogeneous and contain very low levels of lattice-bound gold. Py0 is euhedral and fine-grained, with relatively high Cu, Au, Co, and Ni contents, and displays a magmatic sulfur isotopic signature with δ34S ranging from 0.8 to 4.3 ‰. Py1 occurs as euhedral to subhedral, coarse-grained crystals within pyrite-quartz veins with higher concentrations of Co and Ni. Py2, which develops in the quartz-pyrite veins, is medium to coarse-grained and contains elevated levels of As, Cu, Zn, and Bi relative to Py1. Py3, found in polymetallic sulfide veins of the main lode-gold stage, is anhedral and medium to fine-grained with higher contents of As, Ag, Cu, Zn, Se, Te and lowest Co and Ni concentrations compared to Py1 and Py2. The positive correlations between Au-Te, Au-Bi, Au-Cu, and Pb-Bi across all pyrite types, along with the presence of visible gold in Py3, indicate that most gold occurs as micro-/nano-sized inclusions and as fissure gold. The δ34S values of Py1, Py2, and Py3 (7.6 to 11.8 ‰, 10.1 to 12.6 ‰, and 9.8 to 12.4 ‰, respectively) were attributed to an initial magmatic source and mixed with external sulfur subsequently from the wall rocks. The H and O isotopic compositions (δDH2O = −84.1 to −93.5 ‰; δ18OH2O = 1.8 to 6.6 ‰) of quartz from the lode-gold mineralization imply that ore-forming fluids were predominantly of magmatic origin, with a additional contribution from meteoric water. Taken together, a two-episode mineralization model was proposed for the formation of the Kateba’asu gold deposit. The early skarn mineralization stage is associated with the emplacement of diorite during the Early Carboniferous. In contrast, the subsequent lode-gold mineralization, occurring between the Late Carboniferous and Permian periods, represents a overprinted magmatic-hydrothermal gold system potentially linked to a deep-seated magmatic intrusion.

Geochronology and decoupling controls of Sn-(Ta-Li) and W-(Sn) mineralization in the Iberian Variscan Massif, Spain and Portugal

Sn-W mineralization in the Iberian Variscan Massif (corresponding with the western zone of the Iberian Peninsula, in Spain and Portugal) occurs closely related to metaluminous to peraluminous granitoids of Variscan age. The deposits are grouped into two main styles of mineralization; Sn-(Ta-Li) and W-(Sn) deposits. Within this work we present a first attempt to correlate timing of W-Sn mineralization and plutonic events at a regional scale. We report new 40Ar/39Ar dates of muscovite related to the quartz-muscovite alteration of eleven deposits, molybdenite Re-Os dates from six deposits and two new zircon U-Pb dates of granitoids genetically related to the mineralization. The dates obtained support the relationship between W-Sn mineralization with specific, but not uniquely just one, granite suites. The dominant S-type peraluminous Variscan granitic suites in Iberia, the S1-type dated at ca. 330–311 Ma and the S2-type at ca. 314–296 Ma, are related to both, Sn-(Ta-Li) and W-(Sn) mineralization. A subgroup of deposits of the W-(Sn) group, generally enriched only in W but not in Sn is associated with the youngest but volumetrically less abundant I-type (ca. 303–280 Ma) metaluminous magmatism. The relationship of both the Sn-rich and W-(Sn)-rich deposits with the highly peraluminous S-type granites suggest that the ultimate source of the melts is not related to the decoupling between Sn and W. Therefore, the causes of W and Sn separation may be related to late-stage magmatic and magmatic-hydrothermal processes.

Two-episode mineralization in the Haerdaban Pb–Zn deposit, NW China: Insights from sulfide trace elements, in situ S–Pb isotopes, and Rb–Sr geochronology

The Haerdaban Pb–Zn deposit, located in the eastern West Tianshan Orogen, hosts stratiform and vein-type mineralization within Precambrian carbonate rocks. However, there has been limited research on the distinctions and relationships between these two mineralization styles. In this study, we compared trace element distributions, fluid conditions, material sources, and mineralization ages between stratiform and vein-type mineralization and reconstructed a detailed genetic model. Two episodes and four stages of mineralization were identified, including five generations of pyrite and two generations of sphalerite. The sedimentary exhalative episode represents stratiform mineralization including Stage I pyrite–pyrrhotite layers (Py-1, Py-2a, Py-2b, and Py-3) and Stage II sphalerite–galena layers (Sph-1). The magmatic–hydrothermal episode represents vein-type mineralization including Stage III pyrite–quartz–calcite veins (Py-4) and Stage IV sphalerite–galena–quartz–calcite veins (Sph-2). LA–ICP–MS analysis of Se–Co–Ni–As–Ag–Sb–Bi contents in pyrite suggests that Py-1 to Py-3 formed under relatively low temperatures (280 ± 8 °C) and high ƒO2 sedimentary conditions. Py-4 formed under relatively high temperatures (339 ± 18 °C) and low ƒO2 hydrothermal conditions. Variations in Fe–Mn–In–Ga–Ge–Cd–Cu contents in sphalerite indicate that Sph-1 formed under relatively low temperature (211 ± 7 °C), intermediate ƒS2 (logƒS2 = −11.1 ± 0.5), and moderate pH sedimentary exhalative conditions. Sph-2 formed under relatively high temperature (292 ± 5 °C), high ƒS2 (logƒS2 = −7.4 ± 0.2), and low pH hydrothermal conditions. In situ analysis of sulfide S–Pb suggests that ore-forming materials for stratiform mineralization were primarily derived from marine sediments, while those for vein-type mineralization primarily originated from magmatic sources. Sph-1 from stratiform mineralization yielded an Rb–Sr isochron age of 719 ± 16 Ma, while Sph-2 from vein-type mineralization exhibited an Rb–Sr isochron age of 380.3 ± 7.7 Ma. Random Forest classification of trace elements in pyrite and sphalerite predicted that stratiform mineralization is of sedimentary genesis, whereas vein-type mineralization is of magmatic–hydrothermal genesis. Based on our results, we identified a two-episode mineralization history for the Haerdaban Pb–Zn deposit: Neoproterozoic syngenetic sedimentary exhalative mineralization overprinted by Devonian epigenetic magmatic–hydrothermal mineralization. The results of this study highlight the importance of considering multiple geological events in ore-forming processes and will facilitate the exploration of similar deposits in the West Tianshan Orogen.

Magnetite geochemistry of giant alkalic-type epithermal gold deposits: Insights into the magmatic evolution of mineralized alkaline systems

Magnetite, a common mineral in alkaline magmatic complexes hosting giant epithermal Au deposits, is examined to obtain insights into the magmatic evolution and ore fertility of alkaline systems. Textural and compositional analyses of magmatic magnetite from Cripple Creek, USA, and Lihir Island, Papua New Guinea, reveal distinct magma sources and evolution paths. High HFSE concentrations and high La/Yb ratios in magnetite from Cripple Creek suggest relatively low-degree partial melting of lithospheric and asthenospheric mantle sources, whereas magnetite from Lihir Island indicates higher degree partial melting from subduction-modified mantle. Chromium concentrations track magma evolution, while V systematics record decreasing oxygen fugacity with magma differentiation. Sulfide saturation is observed at Cripple Creek, potentially affecting ore fertility. Magnetite itself bears the capability to scavenge Au from melts as indicated by Au concentrations of up to 40 ng/g. This might point towards elevated Au concentrations in the parental magmas, although experimental data on Au partitioning is lacking. Magnetite compositions overlap across different mineralization styles, challenging its reliability as an exploration tool but analysis of noble metals in magnetite and its inclusion cargo could offer promising alternative approaches. Overall, magnetite serves as a valuable tool for investigating ore deposit petrogenesis and holds potential for exploration.

A revised stratigraphic model for the ∼ 1910–1835 Ma Tanami Group, the Northern Territory, Australia: Implications for exploration targeting

The Paleoproterozoic Tanami Group of the Granites—Tanami Orogen hosts a known endowment of > 20 Moz of gold mineralization across numerous deposits. Throughout the region, host lithologies impart a first-order control on the style, grade and endowment of mineralization. However, the genetic relationship and regional distribution of three regionally correlative formations (the Dead Bullock, Mount Charles and Stubbins formations) remains enigmatic. Here, we combine lithostratigraphic analysis, lithogeochemistry, detrital zircon geochronology and geophysical observations to propose a new evolutionary model for the Tanami Group. We find that the Tanami Group was deposited in a continental back-arc basin setting and developed in four stages. Package A marked the onset of the rifting of the continental Archean basement. Sedimentary rocks within Package A are dominantly felsic in composition and display a unimodal detrital zircon age population at ∼ 2530 Ma. Package B marks the onset of mafic volcanism; consequently, volcaniclastic and sedimentary rocks within Package B display a distinct mafic geochemical signature. Detritus shed from an Archean basement persisted throughout this period, and a unimodal detrital age component at ∼ 2530 Ma persists. Package C marked the waning stages of voluminous mafic volcanism across the Tanami Basin. Sedimentary volcaniclastic rocks within Package C display a mixed mafic and felsic composition. Detrital zircon age spectra record multiple peaks at ∼ 2500, 3000 and 3350 Ma, which may reflect erosion of older Archean basement domains or changes in paleo-drainage. Package D marked a significant change in the source of detritus entering the basin from dominantly Archean to Paleoproterozoic, with dominant detrital age peaks at ∼ 1860 Ma. Despite significant lithofacies variations, the presented model highlights multiple correlations between the Dead Bullock and Mount Charles formations. The Mount Charles Formation likely represents a volcanic source-proximal, high-energy depocenter. In contrast, the Dead Bullock Formation was deposited in a lower energy setting, distal to volcanic centers. These observations are important to mineral exploration. Notably, the Mount Charles Formation is distributed over a significantly greater area than previously thought, and the under-represented Hangingwall and Footwall sequences of this formation are interpreted to host significant gold mineralization at the Oberon and Groundrush deposits.

Microscale geochemical variations in metamorphic-hydrothermal scheelite and insights into trace element sources (Otago Schist, New Zealand)

ABSTRACT Scheelite (CaWO4) trace elements are frequently used to fingerprint sources of mineralising fluids or styles of mineralisation. However, the chemistries of scheelite from hydrothermal-metamorphic Otago Schist scheelite-quartz veins have complicated parageneses. Coarse (>1 cm) single grains from three deposits contain zones that fluoresce orange or blue in cathodoluminescence. Laser ablation analysis shows the orange zones to be richer in REE but the blue zones to be richer in Sr. With one exception, which may be due to incorporation of calcite, the internally homogenous in-situ 87Sr/86Sr and low Rb/Sr indicate isotopic equilibrium at the time of scheelite precipitation. Micro-drilled cores extracted, dissolved and measured for trace elements and 143Nd/144Nd isotopic compositions, together with the ingrowth history of 87Sr/86Sr and 143Nd/144Nd in the deposit host rocks, indicate that the scheelite isotopic ratios have distal or multiple sources to the Sr and Nd. Other trace elements therefore also likely have complicated paragenetic histories, which mean that these do not necessarily indicate either the element source or the style of mineralisation. A positive aspect is that the internal Sm/Nd variation means that single-grain isochrons resolve ages of 114 ± 50 Ma (Alta Lode) and 136 ± 45 Ma (Macraes) that overlap published ages.

ORIGIN OF VOLCANIC-HOSTED MAGNETITE AT THE LAGUNA DEL MAULE COMPLEX, CHILE: A NEW EXAMPLE OF ANDEAN IRON OXIDE-APATITE MINERALIZATION

Abstract Iron oxide-apatite (IOA) deposits, also known as magnetite-apatite or Kiruna-type deposits, are a major source of iron and potentially of rare earth elements and phosphorus. To date, the youngest representative of this group is the Pleistocene (~2 Ma) El Laco deposit, located in the Andean Cordillera of northern Chile. El Laco is considered a unique type of IOA deposit because of its young age and its volcanic-like features. Here we report the occurrence of similarly young IOA-type mineralization hosted within the Laguna del Maule Volcanic Complex, an unusually large and recent silicic volcanic system in the south-central Andes. We combined field observations and aerial drone images with detailed petrographic observations, electron microprobe analysis (EMPA), and 40Ar/39Ar dating to characterize the magnetite mineralization—named here “Vetas del Maule”—hosted within andesites of the now extinct La Zorra volcano (40Ar/39Ar plateau age of 1.013 ± 0.028 Ma). Five different styles of magnetite mineralization were identified: (1) massive magnetite, (2) pyroxene-actinolite-magnetite veins, (3) magnetite hydrothermal breccias, (4) disseminated magnetite, and (5) pyroxene-actinolite veins with minor magnetite. Field observations and aerial drone imaging, coupled with microtextural and microanalytical data, suggest a predominantly hydrothermal origin for the different types of mineralization. 40Ar/39Ar incremental heating of phlogopite associated with the magnetite mineralization yielded a plateau age of 873.6 ± 30.3 ka, confirming that the emplacement of Vetas del Maule postdated that of the host andesite rocks. Our data support the hypothesis that the magnetite mineralization formed in a volcanic setting from Fe-rich fluids exsolved from a magma at depth. Ultimately, Vetas del Maule provides evidence that volcanic-related IOA mineralization may be more common than previously thought, opening new opportunities of research and exploration for this ore deposit type in active volcanic arcs.

Lithological Control to the Gold Mineralization in the Main Ridge Complex of the Bakan Gold District, Northern Sulawesi, Indonesia

Abstract Main Ridge complex is characterized by prominent high sulfidation epithermal-style mineralization with windows of porphyry style mineralization in the deeper zone. Several lithologic features play important controlling role in the occurrences of those mineralization. The oldest rock observed in the Main Ridge complex is unmineralized hornblende diorite (IDO-1) which encompasses the whole Bakan district. Several late intrusive stocks were concealed below the current topographic as mentioned as the microdiorite (IDO-2) and quartz diorite (IDO-3) in which the latter exhibits windows of porphyry-style mineralization. Those intrusive units were then covered by two unconformable volcanic tuff sequences which are andesitic tuff and dacitic tuff in compositions. Dacitic tuff is more favourable unit for gold mineralization compared to andesitic tuff which shown by near-surface ‘mushroom-like’ deposit form. In more peripheral area, the mineralization is also controlled by the bedding features of dacitic tuff which underlain by the less-mineralized andesitic tuff. In the latest stage, diatreme breccia cut all the lithologic units and becomes the most favourable host rock in sub-vertical deposit form. The comprehensive understanding of the lithological features is important to understand the mineralization control for further exploration target.

Genesis of the Mahour Base Metal Deposit, Iran: Constraints from Fluid Inclusions and Sulfur Isotopes

The Mahour base metal deposit is located northeast of Badroud in the middle of the Urumieh–Dokhtar magmatic arc in the Isfahan province of Iran. The main host rocks to the ores are Eocene volcanic and volcaniclastic rocks. Hypogene ore minerals constituting the main ore body are galena, sphalerite, pyrite, and chalcopyrite. In addition to gangue quartz, a variety of supergene minerals comprising gypsum, goethite, hematite, “limonite”, malachite, azurite, covellite, and chalcocite are also present; gangue minerals are quartz, barite, calcite, sericite, and chlorite. Silicification, intermediate argillic, and propylitic are the main wall-rock alteration types. The presence of fluid inclusions with different vapor/liquid ratios in quartz and sphalerite could indicate a boiling process. The primary liquid-rich fluid inclusions suggest that the homogenization temperature was between 107 and 298 °C from fluids with salinities from 1.5 to 13.7 wt.% NaCl equiv. These data suggest that the ore-forming fluids were magmatic with a contribution from meteoric waters. The δ34S values of sulfides range from 1.9 to 3.4‰, those of barite range from 12.1 to 13.2‰, and those of gypsum range from 4.3 to 5.6‰. These data suggest that sulfur was mostly of magmatic origin with a minor contribution from sedimentary rocks. Our data suggest that the boiling of fluids formed an intermediate-sulfidation style of epithermal mineralization for the Mahour deposit.

U–Pb LA-ICP-MS and Re–Os dating of wolframite and molybdenite: Constraints on multiple mineralization and cooling history (40Ar/39Ar) for the magmatic–hydrothermal system at Borralha, northern Portugal

The Borralha area (Iberian Massif, Portugal) reflects a long-lived and multiphase magmatism (ca. 316 to 300 Ma), characterized by three types of granite emplacement during two different extensional events (E1 and E2) and one compressional event (C3) within the Variscan orogeny. The W (Cu) mineralization styles correspond to veinlets and quartz veins (i.e., São António and Santa Helena), and disseminations in the Santa Helena breccia pipe. Molybdenite coexists with an Fe-bearing wolframite–quartz assemblage in the Venise breccia pipe and quartz veins (i.e., São José and São Paulo).The geochemistry and geochronology of wolframite and molybdenite samples were studied by electron probe microanalysis (EPMA), in-situ U–Pb laser ablation-inductively coupled plasma mass spectrometry (LA-ICP-MS) and Re–Os thermal ionization mass spectrometry (TIMS). The wolframite yields a U–Pb age (sample WBV1) of 315.2 ± 4.7 Ma (2σ), representing the first recognized episode of W deposition in the Iberian Massif. Wolframite samples (WBV1, WB1, and WB4) have a ferberite composition with a hübnerite/ferberite ratio of < 29. High amounts of Nb (up to 3703 ppm) with low Ta (up to 123 ppm) and REEs (up to 11.4 ppm) and conversely, low amounts of Nb (up to 471 ppm) with high Ta (up to 190 ppm) and REEs (up to 53.7 ppm) were measured in wolframite samples. The REEs normalized patterns of the wolframite samples record a mixed signature. Large and positive Eu/Eu* and Er/Er* anomalies were identified (sample WBV1), whereas negative Ce/Ce* and Nd/Nd* anomalies were observed in samples WB1 and WB4.Molybdenite Re–Os dating yields absolute ages ranging from 305.1 to 303.8 ± 2.2 Ma (2σ), which are coeval with the emplacement of E2 biotite granite (Penedos; I-type; <305 Ma). Low amounts of Re (<1 ppm), W, Co, Ni, As, Cu, Bi, Fe, Mn V and Se (<0.005 wt%) were detected in the molybdenite structure.Constraints between the timing of W- and Mo-deposition and a protracted cooling history of the host rocks are confirmed by 40Ar/39Ar white mica dating. The 40Ar/39Ar ages obtained for secondary white micas collected from Mo veins (Venise breccia pipe; 277 ± 3 and 287 ± 4 Ma 2σ) and W (Cu) dissemination (Santa Helena breccia pipe; 287 ± 2 and 279.0 ± 6 Ma 2σ) record the isotopic resetting by later hydrothermal overprints and cooling /exhumation history after E2 Gerês biotitic granite emplacement.The W-ore deposition did occurred during the final E1 extensional tectonic stage (315 Ma) and E2 extensional tectonic stage for Mo-ore deposition, where a temporal offset was needed for the adjustment of tectonic conditions after the C3 compressional and E2 extensional stage started.

Evaluation of Coarse Gold-Bearing Conglomerate Mineralisation at Beatons Creek, Pilbara, Western Australia: Sampling for Resource Development and Grade Control

Many styles of gold mineralisation are challenging to sample because of the presence of coarse gold and a high spatial heterogeneity. The coarse gold-bearing conglomerates of the Beatons Creek deposit provide some challenges related to the presence of gold particles up to 8 mm and gold particle clusters (up to 500 mm3) at low in situ grades (&lt;2 g/t Au). Novo has attempted to address these issues over the last six years of exploration, resource development and mining. The Beatons Creek open pit operation was the first Pilbara conglomerate-hosted gold deposit to go into production. Between January 2021 and September 2022, it produced 2.5 Mt at 1.2 g/t Au for 87,300 oz Au recovered. Gold is present within a matrix of multiple, narrow-stacked oxide and fresh (sulphide) conglomeritic reef horizons, which are interbedded with unmineralised conglomerate, sandstones and grits. It is strongly associated with detrital pyrite and authigenic nodules. Several sampling techniques have been applied across the project, including diamond core and RC drilling, trench channel sampling and bulk sampling. Assay methods applied include fire assay, screen fire assay, LeachWELL™ and more recently PhotonAssay™. The dominant sampling protocol applied for resource development and grade control utilised 0.5 m length RC samples; a 50% rig split (c. 8.5 kg) and laboratory crushing to 3 mm, followed by a 2.5 kg split and total assay via PhotonAssay™. For part of the 2022 RC programme, the detectORE™ technique was used to screen primary RC samples and reduce the feed to the laboratory. Novo operated a sampling and assay programme that aimed to reduce the impact of coarse gold on sample and assay preparation biases and to improve estimation.

The Zaozigou orogenic gold-antimony deposit, West Qinling Orogen, China: Structural controls on multiple mineralization events

Orogenic gold deposits are generally thought to represent one perhaps protracted event. However, recent research on orogenic gold deposits increasingly offers evidence for some deposits forming through multiple and clearly discreet hydrothermal episodes. The giant Zaozigou orogenic Au-Sb deposit in the Triassic to Cretaceous West Qinling Orogen, central China, includes both steeply dipping and gently dipping orebodies. The two distinct mineralization styles provide a valuable setting for investigating a multiple mineralization model by integrating structural analysis within a robust geochronological framework. Through fieldwork and geochronology, we define a progression of major tectonic events in the area of the Zaozigou deposit. The deposit is hosted within a well-bedded sequence of Early Triassic metasedimentary rocks of the South Qinling Terrane. Pre-mineralization E-W shortening (D1) during subduction of the Mianlue oceanic slab include folding with resulting axial planes striking N-S, emplacement of Triassic ENE-striking and WNW-striking dacite dikes accompanied by Middle Triassic greenschist facies metamorphism. Late Triassic gold-stibnite quartz vein and disseminated mineralization formed along ENE-striking and steeply dipping D2 brittle to ductile sinistral faults. Their orientations suggest a link to the regional NNE-SSW maximum principal stress coinciding with transpression caused by the Late Triassic collision between the South China Block and South Qinling Terrane. Overprinting Early Cretaceous quartz-stibnite veins developed along gently dipping (20° to 40°) brittle D3 normal fault zones, which exhibit a NE-SW minimum principal stress. This younger deformation event is interpreted to be related to the Early Cretaceous tectonic transition from shortening to extension of the West Qinling Orogen. Therefore, the Zaozigou deposit reveals a model of multiple orogenic gold mineralizing events, with migration of hydrothermal fluids during discrete deformation episodes and the resulting formation of a single composite deposit formed along overprinting structures at separate times of orogenesis.

P–T conditions of metamorphic and hydrothermal events at Tick Hill gold deposit, Mount Isa, Queensland, Australia

Tick Hill gold deposit is a unique gold mineralisation style in the Mary Kathleen Fold Belt in the Mount Isa Inlier. The gold at Tick Hill is generally pure without silver and was formed during two discrete metamorphic-deformation events (D1 and D3). Early gold was observed as inclusions or coarse grains hosted within D1 peak-metamorphic diopside, scapolite and hornblende from the garnet–biotite–hornblende (tschemakite)–plagioclase (andesine)–quartz assemblage. Late gold is closely associated with bismuth selenide, chlorite, albite, sericite and K-feldspar, and formed during D3. The syn-D1 garnet–plagioclase–hornblende–quartz–biotite assemblage was used to constrain the pressure and temperature (P–T) conditions of metamorphism and mineralisation using the garnet–plagioclase–hornblende–quartz barometer and the hornblende–plagioclase, garnet–biotite and garnet–hornblende thermometers. The results show that peak metamorphism at Tick Hill reached P–T conditions of 6.0–7.6 kbar and 720–760 °C. These P–T conditions together with gneissic and migmatisation textures recorded in different rock types at the Tick Hill area indicate that the peak metamorphism preserved in the area occurred at the amphibolite–granulite facies, compared with the amphibolite facies at the southern Mary Kathleen and Eastern Fold Belt. The D3 chlorite, which formed during stage 2 to stage 4 mineralisation events, displays a wide range of compositions reflecting a gradual retrograde temperature change from ∼380 °C to ∼130 °C. The pressures during D3 could not be reliably determined, but the presence of various Bi-selenides suggests that towards the waning stages of D3, the rocks may have been exhumed to a pressure less than 1 kbar.

Contrasting Cu mineralization styles across the Dananhu Arc, Eastern Tianshan: insights from the geochronology, geochemistry, and Sr–Nd–Hf isotopes of Carboniferous arc rocks

ABSTRACT The tectonic regime is an important factor controlling the formation of ore deposits, and magmatic rocks generated in different tectonic regimes are characterized by contrasting ore affinities and mineralization styles. A series of early Carboniferous volcanogenic massive sulphide (VMS) deposits occur in the western segment of the Dananhu Arc in the Central Asian Orogenic Belt. In contrast, coeval magmatic rocks in the middle segment are devoid of VMS copper mineralization but host porphyry copper deposits. However, the relationship between tectonic setting and mineralization still needs to be clarified. Herein, we synthesize the new and existing geochemical data of the Carboniferous arc rocks of the Dananhu Arc, showing diverse arc magmatism and contrasting Cu mineralization styles in the western and middle segments. Magmatic rocks in the western segment are consistent with normal island arc origin. In contrast, magmatic rocks in the middle segment of the Dananhu Arc have adakite-like affinities. The magmatic rocks in the western segment were derived from the partial melting of the juvenile lower crust triggered by slab rollback in an extension setting. In contrast, the rocks in the middle segment originated from partial melting of the subducted slab that was triggered by flat subduction. The extension setting coupled with high temperature magmatic activity induced the circulation of the hydrothermal fluids, which were critical to the development of the Xiaorequanzi VMS deposit. Copper would become progressively enriched in the fractionating melt under the high–fO2 condition, and the compressional regime caused by flat subduction reduces the ‘leakage’ of hydrothermal fluids, which are favourable for the formation of the porphyry mineralization in the middle segment. It is, therefore, evident that variations in the tectono-magmatic setting across the Dananhu Arc played an important role in generating the diversity of Cu deposit types and variable ore affinities throughout the Eastern Tianshan.