Mineral Systems Research Articles

Three-Dimensional Electrical Structure and Metallogenic Background of the Southeastern Hubei Ore Concentration Area

The Southeastern Hubei Ore Concentration Area (SHOCA) is located in the west section of the Middle and Lower Yangtze River Metallogenic Belt in China, and it is a significant copper and iron mining region in China. Here, 117 pieces of magnetotelluric array data were used to obtain a three-dimensional resistivity model of the SHOCA and to investigate the relationship between the deep electrical features and the genesis of mineral deposits. The model shows that the Qinling-Dabie Orogenic Belt exhibits high-resistivity characteristics, representing Mesozoic granites and high-pressure to ultra-high-pressure metamorphic rocks. There are several low-resistivity anomalies in the upper crust of the SHOCA, which are connected to the widespread low-resistivity anomaly in the middle-lower crust. Near the Yangxin-Changzhou Fault, there is evidence of an electrical gradient zone. The Xiangfan-Guangji Fault, located at the south margin of the Qinling-Dabie Orogenic Belt, also exhibits distinct high- and low-resistivity boundaries at the upper crust. However, the Yangtze Fault and the Tancheng-Lujiang Fault manifest as resistivity gradient zones at the lithospheric scale. These faults are connected the low-resistivity anomaly in the middle to lower crust, possibly serving as upwelling channels of deep thermal fluids, exerting control over shallow diagenesis and mineralization processes. The low-resistivity anomaly in the middle to lower crust of the SHOCA is explained as partial melting resulting from the mixing of crustal and mantle materials. These low-resistivity anomalies play a role as source components in the mineralization system, where mineral-rich hydrothermal fluids migrate upward along intra-basin faults, exerting control over the distribution of shallow mineral deposits.

Knowledge-based query system for the critical minerals

Critical minerals are increasingly used in advanced, modern technologies. Exploration for these minerals require efficient mechanisms to search for the latest geological knowledge about the petrogenesis and spatial distribution of these essential resources. Although the current text-based deposit classification schemes help geoscientists to understand how and where these critical minerals form, they cannot easily be queried by software without extensive natural language processing and knowledge modeling. Ontologies can explicitly specify the knowledge scattered in the texts and tables of these schemes and the Critical Minerals Mapping Initiative (CMMI) database by way of logical structures whose results can automatically be processed and queried. They can also draw new knowledge by inference from the ones that are explicitly specified in them. These qualities make ontologies a perfect choice for digital knowledge storage, search, and extraction. The Critical Minerals Ontology (CMO) is described herein by reusing the logical class and property structures of the top-level Basic Formal Ontology (BFO) and mid-level Common Core Ontologies (CCO) and Relation Ontology (RO). The CMO formally models the knowledge about the critical mineral systems using the latest deposit classification scheme and the CMMI database schema. The ontology specifies the geochemical and geological processes that operate in various geotectonic environments of mineral systems to form the critical minerals in different deposit types. It models the properties of both the host minerals that contain the rare-earth elements and those that bear other types of elements. The CMO also represents uses of specific critical minerals in the manufacturing of industrial products, their alternate substitutes, and countries that produce, import, and export them. A query system, applying the Python programming language, accesses the knowledge modeled in the CMO and allows users through interactive web pages to query the ontology and extract different types of information from it. The ontology and the query system are useful for research in ore mineralogy and critical mineral prospecting. The information modeled by the ontology and served by the query system allows users to classify their ore specimen data into specific deposit types.

Deciphering the U-Pb dates of sedimentary phosphates: A complex example from the Upper Cretaceous-Lower Paleogene series in northwestern Morocco

Uranium‑lead geochronology rapidly generates dates of rock deposition/formation with reasonable precision and accuracy using laser ablation inductively coupled plasma mass spectrometry, which is needed for bracketing stratigraphy. However, previous radiometric U-Pb dating of biogenic (i.e., bones and teeth) and sedimentary phosphate minerals have had limited success, probably because of the nanometric to micrometric crystallites that generate open system behavior. Sediment lithification inhibiting trace element exchange between minerals and porewaters and thus forcing phosphorus-rich crystallites to adopt a closed system behavior has been suggested for interpreting U-Pb dating of carbonate fluorapatite (CFA). Despite these insights, what remains lacking is extensive U-Pb CFA dating at the regional scale to test whether several processes influence the timing of U-Pb system closure by inhibiting U and Pb exchanges. Here, we report U-Pb CFA dating from four sampling sites in northwestern Morocco to understand better the meaning of U-Pb dates in CFA. The Upper Cretaceous-Lower Paleogene phosphate series yields anomalously low 207Pb/206Pb initial ratios and young dates ranging from 37.3 ± 2.4 Ma to 22.7 ± 0.7 Ma, which does not agree with the terrestrial lead model composition for Paleogene ages and the known biostratigraphic ages, respectively. We argue that ancient radiogenic Pb from leached polymetallic mineralizations of the regional environment have been incorporated into CFA and that a 25 to 40 Ma-long widespread resetting of the U-Pb system has affected the northwestern Moroccan phosphates. Neither CFA-hosted CO32− concentrations nor rare earth element and yttrium contents indicate post-depositional modifications of the chemical nature of phosphate-bearing rocks. Burial diagenesis promoting sediment lithification is one of the mechanisms that have triggered final closure of the U-Pb system of CFA minerals and, interestingly, the sedimentation rate was probably not a controlling factor. Unexpectedly, U-Pb dates of ∼23 Ma from three stratigraphic levels separated by several million years seem to be concomitant with the regional emersion and generalized continentalization of northwestern Morocco, allowing CFA to behave as a closed system. We conclude that the laser ablation inductively coupled mass spectrometry U-Pb dating of biogenic and sedimentary CFA minerals must be carefully employed to date the timing of fossilization or sediment deposition.

Composite Materials as the Basis of Concrete Canvas

Statement of the problem. Composite materials based on mineral components and organic and mineral systems are gradually expanding their presence in the domestic market of materials and building techno-logies. Concrete fabric, as one of the varieties of textile-concrete, can be considered as a composite material whose properties depend both on those of polymeric materials that form its enclosing surfaces and those of the core material, and on the nature of the interaction between the facing and core materials. The purpose of the research presented in the article is to evaluate the main strength characteristics of the concrete canvas, as well as to study the effect of the content of Portland cement, plasticizer and modifying additive on the properties of fine-grained concrete as the basis of the concrete canvas, as well as to evaluate the possible areas of application of the concrete canvas with the obtained properties. Results. In the process of processing the results of the experiment and analytical optimization of the response functions, the fundamentals of the methodology for selecting the composition of modified fine-grained concrete as the basis of the concrete canvas were developed. As a result of the tests, the following characteristics of the material were established: average density ––1450––1500 kg/m3; compressive strength –– not less than 36––38 MPa, puncture strength –– not less than 3 kN; ultimate strength in ben-ding 16––20 MPa. Conclusions. Despite the fact that the thickness of the concrete canvas in the hardened state does not exceed 10 mm, its properties are not inferior to those of other types of textile concrete, i.e., they have high strength characteristics with a relatively small thickness. The most promising areas of application of the concrete canvas are the repair and waterproofing of reinforced concrete structures of hydraulic structures, and the strengthening of slopes.

Exploration of sodium thiosulfate for leaching of cobalt-containing pyrite: A DFT study

The paper presents the theoretical calculation results of exploratory research relating to the leaching of cobalt-containing pyrite using sodium thiosulfate as a lixiviant. It is well known that density functional theory (DFT) calculations can qualitatively evaluate the exchange of matter and energy between the mineral system and the surroundings, which greatly expands the breadth and depth of leaching process. Thus, DFT method was used to determine the effectiveness of sodium thiosulfate (Na2S2O3) as a lixiviant for the leaching of cobalt-containing pyrite in this study. The analyses of DFT calculations illustrated that thiosulfate can be well adsorbed on the surface of cobalt-containing pyrite due to the formation of S-Fe and O-Co bonds between the S 3p orbital and O 2p orbital in sodium thiosulfate and the Fe 3d orbital and Co 3d orbital in cobalt-containing pyrite. Analysis of crystal orbital Hamilton population (COHP) indicated that Fe-S and S-Co bonds became longer when the thiosulfate adsorbed on the surface of the cobalt-containing pyrite, resulting in the weakening of interactions between S and Fe or Co atoms. Overall, the findings suggested that sodium thiosulfate was a promising lixiviant，favored the dissolution of Fe and Co.

Stratigraphy and sequence stratigraphy of the Neoproterozoic (Cryogenian–Ediacaran) Stuart Shelf, South Australia

The Stuart Shelf is part of the Adelaide Superbasin overlying the Gawler Craton and Cariewerloo Basin in South Australia. The basin is of interest for sediment-hosted copper mineralisation known to be hosted in numerous stratigraphic intervals across the region. Therefore, facies analysis and understanding of spatial distribution of host units are essential for exploration targeting and mineral systems research. Our study presents improved and new definitions of Cryogenian and Ediacaran Stuart Shelf stratigraphy, and a detailed, regional-scale sequence stratigraphic analysis. The Cryogenian non-glacial interlude was of particular interest, as it includes the Tapley Hill Formation, a known host for copper mineralisation. The succession of Tapley Hill Formation (including Sturtian cap carbonates), Brighton Limestone and Angepena Formation represents a third-order depositional cycle, an equivalent to the lowermost cycle of the Cryogenian non-glacial interlude in the adjacent Adelaide Rift Complex. The Ediacaran post-glacial succession includes the Nuccaleena Formation and Tent Hill Formation and is interpreted as a second-order depositional cycle. The Sturtian and Marinoan cap carbonates form regional stratigraphic marker horizons and were deposited in a transgressive systems tract. Variations in facies and thickness can be linked to development of localised depocentres and topographic highs, such as the Pernatty High. Modelling of 3D surfaces reveals a shift in the basin orientation between the Cryogenian and Ediacaran sedimentation from an NNW–SSE axis towards a N–S axis. The Stuart Shelf sequence stratigraphic framework provides new insights in the basin sedimentology and evolution, which aids sediment-hosted mineral systems analysis and improves the understanding of Cryogenian and Ediacaran basin evolution in Australia.

SOME CHARACTERISTICS AND CAUSES OF CHANGES IN THE RATE OF DISCOVERY OF NEW MINERALS SINCE 1800

ABSTRACT Construction of a discovery curve for Earth's minerals illustrates an abrupt inflection in rates of discovery and acceptance of new species that occurred in the middle of the 20th century. Prior to that time new mineral discovery is found to have accelerated at a modest pace of 0.3 species / year2. Since 1950 the rate of acceptance has accelerated at an average of 1.04 species / year2 such that the first two decades of the 21st century have been characterized by the acceptance of over 100 new minerals per year. Despite this rapid acceleration of discovery, the relative distribution among the 10 mineral classes of the Nickel-Strunz classification system of minerals identified prior to and after 1950 are nearly identical. Variation in the rates of attestation of the divisions, families, and mineral groups show distinct differences in that the maximum rates of discovery of minerals populating higher taxonomic levels occurred prior to 1950 while the attestation curve of newly recognized groups closely follows that defined by the identification of mineral species. The application of any hierarchical classification system to the mineral species is somewhat arbitrary and subject to biases or inconsistencies associated with the systematics of classification. Therefore, the discovery of new minerals is also considered within the context of the mathematically defined crystallographic space group symmetries. The space group attestation curve has a shape similar to those exhibited by the higher taxonomic levels within the Nickel-Strunz system. However, not all space groups are represented by naturally occurring minerals. Minerals discovered before and after the inflection in rates of new mineral discovery illustrate significantly different patterns of paragenesis. Nearly all of the species have been associated with one or more of 57 distinct paragenetic modes. Minerals that have long been known tend to have a higher number of paragenetic modes than those more recently discovered such that the average number of paragenetic modes is shown to have decreased linearly from 1950 to 2022. Further, the earliest known occurrence of over 80% of the currently accepted mineral species has been tabulated by the International Mineralogical Association. For species discovered prior to the inflection of 1950 a linear distribution of oldest ages is observed indicating that these minerals have earliest ages of occurrence that are uniformly distributed across the interval 0 to 4700 Ma. Conversely, approximately 70% of the species identified since 1950 have oldest known occurrences of less than 600 Ma and the age distribution of these post-1950 minerals exhibit an exponential distribution suggesting increasing efforts in new mineral discovery in tectonically active settings. Despite the differences in the pre- and post-1950 oldest age distributions, both populations exhibit similar temporal excursions in rates of new mineral creation that likely reflect substantial changes in Earth system processes responsible for new mineral formation.

Volatile budgets and evolution in porphyry-related magma systems, determined using apatite

Volatile-bearing minerals, such as apatite, Ca5(PO4)3(OH,F,Cl), can record changes in dissolved magmatic volatile species during differentiation and, unlike melt inclusions, are sensitive to the presence of an exsolved fluid phase. Populations of apatite crystals from an individual sample can therefore be used to define the progressive volatile evolution of melt ± fluid during magma differentiation. Despite the importance of fluid chemistry in mineralisation processes, this approach remains relatively underdeveloped for porphyry mineralisation scenarios. Here, we present a model, including a standalone MATLAB app, for melt + apatite ± fluid fractionation that incorporates non-ideal, temperature-dependent KDs for OH-Cl-F exchange and permits an analysis of uncertainty arising from non-unique parameter combinations. We apply the model to apatite from the Fe-Cu-Au Corrocohuayco porphyry-skarn system and analyse differences in volatile saturation state and fluid salinity between different units. We find that there is little difference in the overall fluid salinity, and thus the fluid copper loads, but that the more primitive unit (i.e. the gabbrodiorites) reached fluid saturation much later (after around 50% crystallisation) than the more evolved units, implying that the melt volatile concentration recorded by the apatites in the gabbrodiorites is not representative of the initial magma volatile budget. This work demonstrates that apatite can be a good alternative means of reconstructing the evolving magmatic fluid salinity within mineralising systems, and linking this to the trace metal content of the melt.

Reaction calorimetry and structural crystal properties of non-ideal binary rhabdophane solid solutions (Ce1−xREExPO4·nH2O)

Rhabdophane is a hydrous phosphate that commonly replaces monazite as a weathering product in critical mineral deposits during the alteration of rare earth elements (REE) bearing carbonatites and alkaline igneous complexes. It is an important host to the light (L)REE (i.e., La to Gd) but the stability and structure of binary solid solutions between the Ce and the other LREE endmembers have not yet been determined experimentally. Here we present room temperature calorimetric experiments that were used to measure the enthalpy of precipitation of rhabdophane (Ce1−xREExPO4·nH2O; REE = La, Pr, Nd, Sm, Eu, and Gd). The solids were characterized using X-ray diffraction, scanning electron microscopy, Raman spectroscopy, and the role of water in the rhabdophane structure was further determined using thermogravimetric analysis coupled with differential scanning calorimetry. The calorimetric experiments indicate a non-ideal behavior for all of the binary solid solutions investigated with an excess enthalpy of mixing (ΔHex) described by a 2- to 3-term Guggenheim parameters equation. The solid solutions were categorized into three groups: 1) binary Ce-La and Ce-Pr which display positive ΔHex values with a slight asymmetry; 2) binary Ce-Nd and Ce-Sm which display negative ΔHex values with a nearly symmetric shape; 3) Ce-Eu and Ce-Gd which display both negative and positive ΔHex values with nearly symmetric shape. The excess Gibbs energy (ΔGex) of the solid solutions was further investigated using a thermodynamic analysis approach of aqueous-solid solution equilibria and the optimization programs GEMS and GEMSFITS. The resulting ΔGex values combined with the calorimetric ΔHex values indicate that there is likely an excess entropy contribution implying important short-range structural modifications in the solid solutions dependent on the deviation of the REE ionic radii from the size of Ce3+. These observations corroborate with the trends in the Raman v1 stretching bands of the PO4-site. The excess molar volumes determined from X-ray diffraction analysis further indicate an overall asymmetric behavior in all of the studied binary solid solutions, which becomes increasingly important from La to Gd. The pronounced short-range order–disorder occurring in groups 2 and 3 solid solutions mimics some of the behavior observed from previous studies in anhydrous monazite solid solutions. This study highlights the potential to use the chemistry and the structural modifications of rhabdophane as potential indicators of formation conditions in geologic systems and permits improving our modeling capabilities of REE partitioning in critical minerals systems.

A reinterpretation of the mineralization processes involved in the formation of the Tomnadashan sulfide deposit, Loch Tay, Scotland, UK

The Tomnadashan sulfide deposit, which is located on the southern margin of Loch Tay (Scotland, UK), was mined for copper during the 19th century. The genetic processes at Tomnadashan remain poorly understood, and the mineralization has never been dated. To gain an improved understanding of this mineral system, we have dated the molybdenite at Tomnadashan using the Re–Os chronometer. Furthermore, we have contextualized these ages within a paragenetic interpretation. Our results show that the age of the molybdenite is c. 423–419 Ma, and it occurs early in the paragenesis (the second stage out of six). Based on the paragenesis of molybdenite, this age is likely to reflect the initial Caledonian mineralization event at Loch Tay. Our new data and literature review suggest that although Tomnadashan is a magmatic-related ore deposit, the porphyry that crops out is unlikely to have provided the mineralizing fluids associated with the mineralization. A concealed intrusion or granitic dykes within the porphyry may be the source of the magmatic–hydrothermal fluids. The age data indicate that the Tomnadashan mineralization is coeval with gold mineralization at Cavanacaw in Northern Ireland, giving rise to the possibility of a previously unrecognized mid-Silurian magmatic–hydrothermal episode of gold and base metal mineralization throughout the Grampian Terrane. Thematic collection: This article is part of the Early Career Research collection available at: https://www.lyellcollection.org/topic/collections/early-career-research

Quantification of classical and non-classical crystallization pathways in calcite precipitation

Crystal precipitation from aqueous solution occurs through multiple pathways. Besides the classical ion-by-ion addition, non-classical crystallization mechanisms, such as multi-ion polymer and nano-particle attachment, could be significant. These non-classical crystallization processes have been observed with advanced microscopy, yet detailed quantification of their contributions remains challenging. Building from paired Ca and Sr isotope observations, we develop a theoretical framework to quantify the contributions of classical and non-classical crystallization pathways on the precipitation of the calcium carbonate mineral calcite, a common precipitate in nature. We demonstrate that the classical crystallization pathway alone is insufficient to account for the observed isotope behaviors and, thus, the entire calcite precipitation process. We further present a surface kinetic model that incorporates non-classical crystallization pathways. This model enables the characterization of the roles of classical and non-classical crystallization mechanisms in calcite precipitation. The results suggest that the relative contribution of non-classical crystallization pathways increases with saturation state and can, under high supersaturation levels, be comparable to or greater than the classical pathway. The presented theoretical framework readily explains observed trace element partitioning and isotope fractionation behaviors during calcite precipitation and can be further expanded onto other mineral systems to gain insights into crystal growth mechanisms.

Effect of equilibrium contact angle on water equilibrium film thickness for the carbon dioxide–brine–mineral system based on surface force theory

The thickness of the thin wetting film depends on disjoining pressure forces, and it evolves with pH evolution due to brine acidification at the physical and chemical conditions of geological carbon dioxide storage becoming thinner in response to dewetting. In the literature, molecular dynamic simulation (MDS) studies have been employed to understand the effect of pressure/capillary pressure on the thin wetting film evolution. In this paper, a theoretical approach based on the Frumkin–Derjaguin Equation (FDE), models of electric double layer repulsion, and van der Waals forces have been used for the calculation of the wetting film thickness. The approach excluded hydration forces contribution to disjoining pressure forces due partly to its poorly understood nature, and partly to the high salinity conditions encountered in geological carbon storage. Due to its promising global storage capacity compared to other lithologies, the carbon dioxide–brine–silica systems was chosen to simulate sandstone saline aquifers. The validation of the model benefited much from literature resources on data and a universal model of carbon dioxide–brine interfacial tension. Calculated results confirm pH-induced dewetting and they follow trends controlled by pH and pressure as found in the literature. The novelty of the paper can be seen from the fact that it has demonstrated a theoretical supplement to MDS studies in addition to justifying the fundamental utility and versatility of the FDE. Moreover, the paper links for the first time, a transcendental equation to the thin wetting film theory encountered in the carbon dioxide–solid–brine system found in geological carbon storage.

Ranking mineral exploration targets in support of commercial decision making: A key component for inclusion in an exploration information system

An exploration information system (EIS) is a way of creating, and managing exploration targets and should include the entire process from conceptual mineral system models to, modelling the mineral system using available data, to generation of targets or prospect areas. The main goal for any EIS is to help find new mineral deposits that are economic to mine and process at the financial conditions of the time. Prioritisation and management of exploration targets is a key to success in mineral exploration, particularly with the increasing use of mineral potential modelling techniques, including AI, which can generate a large number of targets in a study area for testing. In this paper, we present ideas for the components for an EIS designed to optimise the mineral exploration process and provide critical decision-making support. The Macquarie Arc porphyry copper-gold mineral system in New South Wales is used as an example to illustrate how such a system can be developed and implemented. Accepted mineral potential mapping workflows are used coupled with a targeting process that generates, attributes, and ranks prospect areas to produce exploration targets. The proposed front-end of the EIS is an Exploration Management Dashboard, which can be used by executives and managers to facilitate informed decision-making and optimal allocation of capital. We advocate for a standardised system capable of accommodating various commodities, input datasets, and diverse analytical techniques, including AI-driven methods and validation tools. Flexibility for user customisation, especially for non-technical users, and real-time data integration are seen as an essential part of any EIS. Furthermore, the system is designed to be dynamic, with continuous updates and improvements as new data are collected, ensuring that exploration is always focussed on the areas with the greatest potential prospectivity.

Systematic trends in the substitution mechanisms of minor elements in cassiterite

A dataset of 4751 EPMA point analyses on cassiterite crystals from 18 localities spanning a range of different granite-related Sn-bearing mineral systems was investigated and compared with thermodynamic considerations from speciation and lattice strain models. The existence of previously inferred charge balanced coupled substitution mechanisms of Fe3+, Fe2+, Mn2+, Nb5+, Ta5+ and W6+ for Sn4+ are confirmed. The homo­valent substitution of Sn4+ by Ti4+ and Zr4+ is also confirmed, and the first evidence for homovalent substitution of Nb4+ and W4+ in natural cassiterite is presented. The preferred substitution mechanisms for Ti, Fe, Mn, Nb, Ta, W and Zr vary systematically as a function of the mineralising environment. Cassiterite precipitated from silicate liquid dominated systems (such as in pegmatites) primarily display a coupled Fe–(Nb,Ta) substitution mechanism with a 1:2 stoichiometry, whereas cassiterite precipitated in systems dominated by autometasomatic processes (such as greisens) more closely follow a 1:1 stoichiometry, as well as increased levels of Ti. Cassiterite precipitated solely from hydrothermal fluids (such as Sn–(W) quartz vein systems) exhibit the highest Ti concentrations, with lower contents of Fe–(Nb,Ta) coupled substitutions, instead displaying a switch to the incorporation of Fe3+ via FeO.OH stoichiometry. Hydrothermally precipitated cassiterite from skarn systems display the highest Fe3+ contents, and the lowest Nb, Ta and Ti contents. These systematic changes define a continuous trend in a Ti–(Fe + Mn)–(Nb,Ta) ternary diagram, allowing for classification of the primary source of alluvial cassiterite.

The importance of being molten: 100 Myr of synmagmatic shearing in the Yilgarn Craton (Western Australia). Implications for mineral systems

Between the Neoarchean and the early Proterozoic, plate tectonics was gradually established on our planet. How this transition took place, and what kind of geodynamic paradigm dominated before, is a matter of debate, and systematic multidisciplinary studies help improving our understanding of such a transitional period of Earth’s evolution.The Yilgarn Craton of Western Australia exposes upper-crustal granite–greenstone terranes that are juxtaposed along large-scale, Neoarchean shear zones, which mainly developed during the 2730 – 2660 Ma Yilgarn Orogeny. By combining structural, microstructural and geochemical data, we present here a systematic study of the main shear zones occurring in the best-exposed, northwestern half of the craton. Our structural data demonstrate that large granitic magma sheets were emplaced during shearing. Although these shear zones exhibit a variety of fabrics that developed over a wide range of temperatures, all preserve memory of at least one stage of shearing at near-solidus temperatures. Our results allow tracing a c. 100 Myr-long tectonomagmatic evolution of this portion of the Archean crust, with implications for lithosphere rheology, crustal evolution, and mineral systems. The major synorogenic structures can be interpreted as inclined transpressional shear zones, along which the bulk of the 3D deformation was efficiently partitioned between greenstones and crystallizing granitic sheets within the shear zones, with the latter accommodating large amounts of orogen‐parallel strain through suprasolidus viscous flow. The positive feedback between protracted magmatism and transpression promoted the extraction and upward transfer of syntectonic magma originated between the uppermost mantle and the mid-crust, as demonstrated by our geochemical dataset. This synkinematic mode of granitic magma transfer contrasts fundamentally to the diapiric mode that was dominant during the lithospheric extension phase that pre-dated the Yilgarn orogeny. Our study suggests that the shear zone system studied here likely played a major role in controlling magma/fluid pathways throughout the late Archean lithosphere, therefore playing a critical role in controlling the development of near-surface mineral systems.

Mineralogy and a New Fertility Index of Alunite in the Fanshan Lithocap, Luzong Basin, Anhui Province, China

Alunite is used as a representative mineral for indicating deposits in lithocaps, and lithocaps are generally related to the porphyry–(high-sulfidation) epithermal mineralization system. The study of alunite is of theoretical and exploration significance for prospecting potential underlying porphyry and epithermal deposits. Studies on alunite geochemistry have made breakthroughs, but there is little research on alunite mineralogy, for example, using scanning electron microscopy (SEM) images, differential thermal analysis (DTA), and Fourier-transform infrared spectroscopy (FT-IR). This study mainly focuses on alunite micromorphological characteristics, weight loss changes with temperature, and ionic group structure, aiming to identify the relationship between these features and indications for prospecting. The Fanshan lithocap is located in the northwest part of the Luzong basin, Anhui province of China, and it can potentially be used for exploring porphyry and epithermal deposits. Fanshan alunite is formed in two stages with three types of alunite. IA alunite is formed in the early hydrothermal stage and replaces felsic minerals in the Zhuanqiao Formation, IB alunite is formed in the later hydrothermal stage and fills in open spaces with bladed particles, and II alunite is the product of pyrite oxidation and reaction with other minerals in the supergene stage. Alunite electron microprobe data and energy-dispersive spectroscopy data further confirm temperature decreases with hydrothermal evolution, and the presence of a high-sulfidation epithermal system in the Luzong basin. Aside from the forming environment, SWIR, and geochemistry of alunite, there are other indication indexes; for example, the larger peak values at 3480 cm−1 and smaller peak values at 1080 cm−1 in FT-IR spectra and the deeper exothermic valleys at 750 °C and steeper weight loss slopes in the DTA curve suggest a favorable formation environment for alunite and provide valuable indications for deposit exploration and assessments of mineralization potential.

Pyrite geochemical fingerprinting on skarn ore-forming processes: A case study from the Huangshaping W–Sn–Cu–Pb–Zn deposit in the Nanling Range, South China

Pyrite geochemistry has been extensively used to reveal ore-forming processes in diverse ore deposits, but its application in skarn systems is not well understood. The Huangshaping deposit in the Nanling Range (South China) uniquely develops W–Sn–Pb–Zn and Cu–Pb–Zn skarn mineralization systems, and both two systems have formed multi-types of pyrite, which provides a good window to reveal the mineralization histories of different skarn systems using pyrite trace element geochemistry. In the Cu–Pb–Zn system, texturally homogeneous Py1 mainly occurs in calcite veins within the host rock, whereas texturally homogeneous Py2 in the calcite-sulfide stage mainly occurs in skarn orebodies. Py3 in the siderite-sulfide stage replaces Py2 and commonly develops abundant pores or fractures, resembling the “bird's eye” texture. In the W–Sn–Pb–Zn system, Py4 in calcite veins can be divided into the oscillatory-zoned Py4a and irregular Py4b under BSE, and Py4b commonly replaces Py4a as veins or overgrowth. Texturally homogeneous Py5 in the calcite-sulfide stage occurs in skarn orebodies and is replaced by Py6 with a “bird's eye” texture in the siderite-sulfide stage.In the Cu–Pb–Zn system, Py1 may have formed by fluid cooling during its ascent along the hydraulic fractures indicated by its enrichment of Co, Ni, As, Sb, and Tl, whereas Py2 is likely formed under higher temperature and pH conditions caused by intense fluid-rock interactions evidenced by its depletion of Co, Ni, As, Sb, and Tl as well as its enrichment of Zn and Ag. In the W–Sn–Pb–Zn system, Py4b has higher contents of Co, Ni, As, Sb, and Tl than Py4a and similar contents of Ag, Zn, and Mo with Py4a, suggesting that decreasing temperature may have controlled the formation of Py4b. Py5 is featured by the depletion of As, Sb, Tl, and Mo as well as the enrichment of Zn and Ag, indicating that Py5 is likely formed under higher temperature and pH conditions resulting from the intense fluid-rock interactions. Marcasite replaces pyrrhotite and then is replaced by pyrite may be an important precipitation mechanism for pyrite with a “bird's eye” texture (Py3 and Py6) in both two skarn systems at Huangshaping. This study demonstrates that fluid-rock interaction is an important mechanism for sulfide precipitation at Huangshaping, which shows that pyrite geochemistry has good potential to reveal mineralization histories in skarn systems.

Loss of nutrients from meadow-brown soils during irrigation of apple trees in the conditions of the dry subtropics of Azerbaijan

The article presents the results of studies on the effect of water consumption, depending on the length (96, 144 and 192) meters of irrigation furrow with a slope of relief tg = 0.021 on the leaching of nitrogen, phosphorus and humus from irrigated soils of the dry subtropics of Azerbaijan under apple trees. Under conditions of leaching of nutrients, the effect of mineral and organic fertilizer systems on apple yields has also been studied. With a 96-meter furrow and a water consumption of 0.2 l/sec, the content of leached nutrients (N, P) and gross humus with soil was 0.01 % nitrogen and phosphorus, 0.02 % gross humus. Increase in water consumption from 0.2 l/sec. up to 0.4 l/sec. It has a negative effect on the leaching of humus, nitrogen and phosphorus from the soil. With a water consumption of 0.4 l/sec, these indicators increased markedly by 0.01 % for humus, nitrogen and phosphorus. Along the length of the irrigation furrow in both water consumption rates, the leaching of nutrients and humus from the soil increases. It was found that with an increase in the length of the furrow to 192 meters at a water consumption of 0.4 l/sec, the leaching was greater than the 96-meter furrow in humus by 0.22 %, nitrogen by 0.07 % and phosphorus by 0.04 %. The use of an organomineral fertilizer system (Background+ N120P120K90) had a positive effect on the yield of apple trees. Thus, in the non-maneuverable version on a 94–meter furrow, the yield of the apple tree was 274.2 c/ha - when the furrow was lengthened to 192 m, the yield gradually decreased due to the high content of leached nutrients and humus (268.5 c/ha). When using N120P120K90 + 10 t/ha of manure, 278.4 c/ha yield was established at 96 m furrow and 0.2 l/sec of water consumption. Whereas, when the furrow was lengthened to 192 m at the same rate of fertilizers and water consumption, the yield decreased to 278.2 c/ha, that is, furrow lengthening was ineffective at slopes tg = 0.021. It was found that at high slopes, the shorter the furrow, the less nutrients are washed out.

Equilibrium interactions of biomimetic DNA aptamers produce intrafibrillar calcium phosphate mineralization of collagen

Native and biomimetic DNA structures have been demonstrated to impact materials synthesis under a variety of conditions but have only just begun to be explored in this role compared to other biopolymers such as peptides, proteins, polysaccharides, and glycopolymers. One selected DNA aptamer has been explored in calcium phosphate and calcium carbonate mineralization, demonstrating sequence-dependent control of kinetics, morphology, and crystallinity. This aptamer is here applied to a biologically-relevant bone model system that uses collagen hydrogels. In the presence of the aptamer, intrafibrillar collagen mineralization is observed compared to negative controls and a positive control using well-studied poly-aspartic acid. The mechanism of interaction is explored through affinity measurements, kinetics of calcium uptake, and kinetics of aptamer uptake into the forming mineral. There is a marked difference observed between the selected aptamer containing a G-quadruplex secondary structure compared to a control sequence with no G-quadruplex. It is hypothesized that the equilibrium interaction of the aptamer with calcium-phosphate precursors and with the collagen itself leads to slow kinetic mineral formation and a morphology appropriate to bone. This points to new uses for DNA aptamers in biologically-relevant mineralization systems and the possibility of future biomedical applications. Statement of significanceCollagen is the protein structural component that mineralizes with calcium phosphate to form durable bone. Crystalline calcium phosphate must be infused throughout the collagen fiber structure to produce a strong material. This process is assisted by soluble proteins that interact with both calcium phosphate precursors and the collagen protein and has been proposed to follow a polymer-induce liquid precursor (PILP) model. Further understanding of this model and control of the process through synthetic, biomimetic molecules could have significant advantages in biomedical, restorative procedures. For the first time, synthetic DNA aptamers with specific secondary structures are here shown to influence and direct collagen mineralization. The mechanism of this process has been studied to demonstrate an important equilibrium between the DNA aptamer, calcium phosphate precursors, and collagen.

An introduction to the Bowland Shale Formation, UK: processes and resources

Abstract This volume showcases recent geological, geophysical and geochemical research on the Carboniferous Bowland Shale Formation. The Bowland Shale is a relatively thick and extensive Palaeozoic black shale unit with a long history of debate and controversy in the UK. The Bowland Shale is proven in many of the key Carboniferous basins in the Midlands, northern England and North Wales, and represents a significant, near-continuous temporal record spanning 16 Myr including the important mid-Carboniferous boundary (Mississippian–Pennsylvanian). Since the first geological surveys in the late nineteenth century, the Bowland Shale has been of interest for a variety of reasons, including the search for Irish-type Pb–Zn base metal mineral deposits, and as a source rock in conventional hydrocarbon systems. In the mid-2000s, attention turned to the Bowland Shale as a target for unconventional hydrocarbon extraction, shale gas, following success in the USA. This placed the Bowland Shale at the centre of a series of interconnected controversies and debates from the local to national scale. The geological credibility of the purported shale gas resource in the UK was – and continues to be – highly contentious. This volume contributes to a more updated view of the Bowland Shale, covering topics such as sedimentary, geochemical and physical properties and processes, basin-forming events, hydrocarbon prospectivity, mineralization and heat and fluid flow in the subsurface. The volume also includes a field guide to some of the key localities in the UK. With the benefit of hindsight offered by the latest generation of research, the early regional shale gas assessments failed to attach sufficient weight to the compositional heterogeneity, structural complexity, compartmentalization and highly variable exhumation, erosion and palaeo-heat flow history of the Bowland Shale. The following topics are identified as promising avenues for future research beyond shale gas: (1) the role of the Bowland Shale in the context of mineral systems; (2) the role of the Bowland Shale as a cap rock in the Lower Carboniferous limestone geothermal play and potentially as an analogue of CO 2 or radioactive waste storage in the UK; and (3) pathways and mechanisms for weathering, alteration and trace element release from the Bowland Shale into the surface and/or subsurface environment.