Steel slag is a promising secondary resource necessitating recycling and high-value utilization. This study innovatively converted steel slag into micronano FePO4 and well-performing LiFePO4/C through a selective two-step leaching process followed by fast coprecipitation in HMCRR under superior mass transfer, and a subsequent in situ carbothermal reduction afterward, thereby realizing a waste-to-resource conversion pathway. Besides, a metal leaching mechanism was proposed based on comprehensive slag composition analysis, affirming the process selectivity. Thermomechanical analysis for precipitation underscored the importance of controlling reaction pH to prevent the formation of impure sediments. Leveraging efficient leaching and superior mass transfer during precursor preparation, the further-made carbon-coated LiFePO4/C derived from steel slag exhibited favorable morphology and enhanced discharge capacity, especially at high rates, owing to fast ion diffusion kinetics, minimized Li+ migration distance, and improved structure stability. Notably, the discharge capacity could reach 167.44, 153.56, and 119.62 mAh/g at 0.1, 1, and 10 C, respectively.
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