Mid-ocean Ridge Basalt Geochemistry Research Articles

Heterogeneous mantle melting and magmatic processes at the East Pacific Rise (2.6–3.1°S): Evidence from mid-ocean ridge basalt geochemistry and Sr–Nd–Pb isotopes

ABSTRACT We present the major and trace elements and Sr, Nd, and Pb isotopes in mid-ocean ridge basalts (MORB) from the East Pacific Rise (EPR) at 2.6–3.1°S. These samples are low-K tholeiites and show significant variation in their major element compositions (e.g. 4.60–8.18 wt% MgO, 8.34–12.12 wt% CaO, 9.78–14.25 wt% Fe2O3, and 0.06–0.34 K2O wt%). Trace element abundances of the 2.6–3.1°S MORB are variably depleted (e.g. (La/Sm), N = 0.51–0.78, Zr/Y = 2.35–3.42, Th/La = 0.035–0.056, and Ce/Yb = 2.38–3.96) but closely resemble the average N-MORB. In the compatible elements (Ni and Cr) against incompatible element Zr plots, the 2.6–3.1°S MORB show well-defined negative correlations, together with a liquid line of descent (LLD) modelling and petrographic observations, implying a significant role of olivine, plagioclase and clinopyroxene fractionation during magma evolution. When compared to global MORB and peridotites, the 2.6–3.1°S MORB and most of the other axial lavas from the South EPR show similar Zn/Fe, Zn/Mn, and Fe/Mn ratios, attesting to a peridotite-dominated mantle lithology. However, the relationships between incompatible trace element ratios, such as Zr/Rb and Nb/Sm, and the negative correlation between Zr/Nb and 87Sr/86Sr indicate a geochemically heterogeneous mantle source. The mantle beneath the South EPR likely consists of two components, with the enriched component residing as physically distinct domains (e.g. veins or dikes) in the depleted peridotite matrix. In the Sr–Nd–Pb isotope space, the South EPR MORB lie along the mixing lines between the depleted MORB mantle (DMM) and the ‘C’-like Pukapuka endmember. We infer that low-F melts derived from these enriched materials may cause localized mantle heterogeneity (veins or dikes) via an infiltration process. Subsequent melting of the refertilized mantle may impart an isotopically distinct characteristic to South EPR MORB.

Intrusive age and geochemistry of the Kebne Dyke Complex in the Seve Nappe Complex, Kebnekaise Massif, arctic Sweden Caledonides

The Seve Nappe Complex of the Scandinavian Caledonides is predominately metamorphosed rift-related igneous and sedimentary rocks formed during Rodinia breakup in the Neoproterozoic. The Kebne Dyke Complex of the Kebnekaise Massif, arctic Sweden, is one such unit within the Seve Nappe Complex and is mostly composed of dolerite dykes metamorphosed and thrust onto Baltica during the Caledonian orogeny. Structurally adjacent to the dyke complex are geochemically similar amphibolites that have a common origin as the metadolerite dykes. Collectively, these rocks have transitional mid-ocean ridge basalt geochemistry similar to correlative Seve Nappe Complex rocks to the north (Indre Troms dykes) and south (Sarek Dyke Swarm). U–Pb single-crystal chemical abrasion–thermal ionization mass spectrometry of zircon from a metagabbro and a metagranitoid, showing co-mingling magmatic textures with the metadolerite, produced 11 concordant analyses with 206Pb/238U ages ranging from 608 to 596 Ma, which includes the magmatic age of the dyke complex. These results support the idea that the Kebne Dyke Complex, Sarek Dyke Swarm and Indre Troms dykes constitute the tholeiitic continent–ocean transition subdivision within the Seve Nappe Complex. However, the Kebne Dyke Complex differs from the Sarek Dyke Swarm and Indre Troms dykes as it is the least enriched among these, nearly lacks rift-related metasedimentary rocks, and may be younger than the Sarek Dyke Swarm by up to 14 Myr.

Abundance and Partitioning of OH in a High-pressure Magmatic System: Megacrysts from the Monastery Kimberlite, South Africa

Concentrations of OH, and major and trace elements were determined in a suite of mantle-derived megacrysts that represent the crystallization products of a kimberlite-like magma at ~5 GPa and ~1400–1100°C. OH concentrations, determined by single-crystal Fourier transform infrared spectroscopy, display the following ranges (ppmw H2O): olivine 54–262, orthopyroxene 215–263, garnet 15–74, clinopyroxene 195–620, and zircon 28–34. High OH concentrations in olivine imply mantle conditions of origin, with limited H loss during ascent. OH is consistently correlated with megacryst composition, exhibiting trends with Mg-number that are similar to those of other minor and trace elements and indicating a record of high-pressure magmatic evolution. H substitution is not coupled to minor elements in olivine, but may be in ortho- and clinopyroxene. The OH–Mg-number trends of garnet and clinopyroxene show inflections related to co-precipitation of ilmenite, suggesting minor element (Ti) influence on OH partitioning. During differentiation, relative OH enrichment in clinopyroxene and olivine is consistent with proportional dependence on water activity, whereas that in garnet suggests a higher power-law dependence and/or influence of temperature. Inter-mineral distribution coefficients for OH between cpx, opx, olivine and zircon are thus constant, whereas partitioning between these minerals and garnet shows a factor 4–10 variation, correlated regularly with composition (and temperature). Calculation of solid–melt partition coefficients for H at 5 GPa over a range of magmatic evolution from 1380 to 1250°C yields: ol 0·0053–0·0046, opx 0·0093–0·0059, cpx 0·016–0·013, gt 0·0014–0·0003, bulk (garnet lherzolite–melt) 0·0063–0·0051. These are consistent with experimental studies and similar to values inferred from mid-ocean ridge basalt geochemistry, confirming the moderate incompatibility of H in mantle melting.

Plume capture by divergent plate motions: implications for the distribution of hotspots, geochemistry of mid-ocean ridge basalts, and estimates of the heat flux at the core–mantle boundary

The coexistence of stationary mantle plumes with plate-scale flow is problematic in geodynamics. We present results from laboratory experiments aimed at understanding the effects of an imposed large-scale circulation on thermal convection at high Rayleigh number (10 6≤Ra≤10 9) in a fluid with a temperature-dependent viscosity. In a large tank, a layer of corn syrup is heated from below while being stirred by large-scale flow due to the opposing motions of a pair of conveyor belts immersed in the syrup at the top of the tank. Three regimes are observed, depending on the ratio V of the imposed horizontal flow velocity to the rise velocity of plumes ascending from the hot boundary, and on the ratio λ of the viscosity of the interior fluid to the viscosity of the hottest fluid in contact with the bottom boundary. When V≪1 and λ≥1, large-scale circulation has a negligible effect on convection and the heat flux is due to the formation and rise of randomly spaced plumes. When V>10 and λ>100, plume formation is suppressed entirely, and the heat flux is carried by a sheet-like upwelling located in the center of the tank. At intermediate V, and depending on λ, established plume conduits are advected along the bottom boundary and ascending plumes are focused towards the central upwelling. Heat transfer across the layer occurs through a combination of ascending plumes and large-scale flow. Scaling analyses show that the bottom boundary layer thickness and, in turn, the basal heat flux q depend on the Peclet number, Pe, and λ. When λ>10, q∝Pe 1/2 and when λ→1, q∝(Pe λ) 1/3, consistent with classical scalings. When applied to the Earth, our results suggest that plate-driven mantle flow focuses ascending plumes towards upwellings in the central Pacific and Africa as well as into mid-ocean ridges. Furthermore, plumes may be captured by strong upwelling flow beneath fast-spreading ridges. This behavior may explain why hotspots are more abundant near slow-spreading ridges than fast-spreading ridges and may also explain some observed variations of mid-ocean ridge basalt (MORB) geochemistry with spreading rate. Moreover, our results suggest that a potentially significant fraction of the core heat flux is due to plumes that are drawn into upwelling flows beneath ridges and not observed as hotspots.

Oxygen-isotope evidence for recycled crust in the sources of mid-ocean-ridge basalts

Mid-ocean-ridge basalts (MORBs) are the most abundant terrestrial magmas and are believed to form by partial melting of a globally extensive reservoir of ultramafic rocks in the upper mantle. MORBs vary in their abundances of incompatible elements (that is, those that partition into silicate liquids during partial melting) and in the isotopic ratios of several radiogenic isotope systems. These variations define a spectrum between 'depleted' and 'enriched' compositions, characterized by respectively low and high abundances of incompatible elements. Compositional variations in the sources of MORBs could reflect recycling of subducted crustal materials into the source reservoir, or any of a number of processes of intramantle differentiations. Variations in (18)O/(16)O (principally sensitive to the interaction of rocks with the Earth's hydrosphere) offer a test of these alternatives. Here we show that (18)O/(16)O ratios of MORBs are correlated with aspects of their incompatible-element chemistry. These correlations are consistent with control of the oxygen-isotope and incompatible-element geochemistry of MORBs by a component of recycled crust that is variably distributed throughout their upper mantle sources.

Spatial and Temporal Variations in Mid-Ocean Ridge Basalt Geochemistry Along the 9°–10°N East Pacific Rise

Temporal constraints on mid-ocean ridge basalt (MORB) magmatism both on and off-axis are critically needed to better understand problems associated with MORB petrogenesis and the processes of crustal accretion at the MOR. Using measurements of U-series disequilibria, radiogenic isotopes and majorand trace-element compositions in a suite of MORBs, from 9~176 East Pacific Rise (EPR), we are addressing two questions related to the temporal component of MORB magmatism: 1) How does magma storage time (i.e. the time after which the melt is no longer in equilibrium with its source) affect the degree of crystal fractionation of MORBs and what is the time-scale of this storage? 2) Is MOR magmatism focused at the ridge or is there a significant component of off-axis volcanism?

Palaeoproterozoic rifting and formation of sulphide deposits along the southwestern margin of the Svecofennian Domain, southern Sweden

A mineralized Palaeoproterozoic volcanic sequence has been identified southwest of Vetlanda in southern Sweden. The sequence, which is defined as the Fröderyd Group, is surrounded by 1.78 Ga granitoids and may be considered as the southernmost segment of Svecofennian crust in Sweden. The Fröderyd Group has a bimodal geochemical character and is dominated by pillow basalts and associated gabbros but rhyolites, thin intercalations of marble and stratiform sulphide ores do also occur. The carbonate intercalations and the stratiform sulphide ores are interpreted as submarine exhalites formed syngenetically with the volcanic activity. The mafic rocks have a typical mid-ocean ridge basalt geochemistry with flat rare earth elements patterns. The lead isotopic compositions of the mafic rocks and the associated stratiform sulphide ores support such a close affinity to juvenile sources with mantle character. In contrast, the rhyolites display more evolved geochemical signatures and isotopic patterns and are interpreted to represent remelted products of slightly older sialic crust. A model for the formation of the Fröderyd Group is presented, suggesting rifting along a continental margin which may have occurred in the final stage of the Svecofennian crust-forming period.

Helium isotope geochemistry of mid-ocean ridge basalts from the South Atlantic

We report new helium isotope results for 49 basalt glass samples from the Mid-Atlantic Ridge between 1°N and 47°S. 3He/ 4He in South Atlantic mid-ocean ridge basalts (MORB) varies between 6.5 and 9.0 R A (R A is the atmospheric ratio of 1.39 × 10 −6 ), encompassing the range of previously reported values for MORB erupted away from high 3He/ 4He hotspots such as Iceland. He, Sr and Pb isotopes show systematic relationships along the ridge axis. The ridge axis is segmented with respect to geochemical variations, and local spike-like anomalies in 3He/ 4He , Pb and Sr isotopes, and trace element ratios such as (La/Sm) N are prevalent at the latitudes of the islands of St. Helena, Tristan da Cunha and Gough to the east of the ridge. The isotope systematics are consistent with injection beneath the ridge of mantle “blobs” enriched in radiogenic He, Pb and Sr, derived from off-axis hotspot sources. The variability in 3He/ 4He along the ridge can be used to refine the hotspot source-migrating-ridge sink model. MORB from the 2–7°S segment are systematically the least radiogenic samples found along the mid-ocean ridge system to date. Here the depleted mantle source is characterized by 87Sr/ 86Sr of ∼ 0.7022, Pb isotopes close to the geochron and with 206Pb/ 204Pb of ∼ 17.7, and 3He/ 4He of 8.6–8.9 R A. The “background contamination” of the subridge mantle, by radiogenic helium derived from off-ridge hotspots, displays a maximum between ∼ 20 and 24°S. The He Pb and He Sr isotope relations along the ridge indicate that the 3He/ 4He ratios are lower for the hotspot sources of St. Helena, Tristan da Cunha and Gough than for the MORB source, consistent with direct measurements of 3He/ 4He ratios in the island lavas. Details of the He Sr Pb isotope systematics between 12 and 22°S are consistent with early, widespread dispersion of the St. Helena plume into the asthenosphere, probably during flattening of the plume head beneath the thick lithosphere prior to continental breakup. The geographical variation in the He/Pb ratio deduced from the isotope systematics suggests only minor degassing of the plume during this stage. Subsequently, it appears that the plume component reaching the mid-Atlantic ridge was partially outgassed of He during off-ridge hotspot volcanism and related melting activity. Overall, the similar behavior of He and Pb isotopes along the ridge indicates that the respective mantle sources have evolved under conditions which produced related He and Pb isotope variations.