Microwave Limb Sounder Research Articles

Stratospheric Transit Time Distributions Derived From Satellite Water Vapor Measurements

AbstractStratospheric transit time distributions (age‐of‐air spectra) are estimated using time series of satellite water vapor (H2O) measurements from the Microwave Limb Sounder over 2004 to 2021 assuming stationary transport. Latitude‐altitude dependent spectra are derived from correlations of interannual H2O anomalies with respect to the tropical tropopause source region, fitted with an inverse Gaussian distribution function. The reconstructions accurately capture interannual H2O variability in the “tropical pipe” and near‐global lower stratosphere, regions of relatively fast transport (∼1–2 years) in the Brewer‐Dobson circulation. The calculations provide novel observational estimates of the corresponding “short transit‐time” part of the age spectrum in these regions, including the mode. However, the H2O results do not constrain the longer transit‐time “tail” of the age spectra, and the mean age of air and spectral widths are systematically underestimated compared to other data. We compare observational results with parallel calculations applied to the WACCM chemistry‐climate model and the CLaMS chemistry‐transport model, and additionally evaluate the method in CLaMS by comparing with spectra from idealized pulse tracers. Because the age spectra accurately capture H2O interannual variations originating from the tropical tropopause, they can be used to identify “other” sources of variability in the lower stratosphere, and we use these calculations to quantify H2O anomalies in the Southern Hemisphere linked to the Australian New Years fires in early 2020 and the Hunga volcanic eruption in 2022.

Investigating the vertical extent of the 2023 summer Canadian wildfire impacts with satellite observations

Abstract. Pyrocumulonimbus clouds (pyroCbs) generated by intense wildfires can serve as a direct pathway for the injection of aerosols and gaseous pollutants into the lower stratosphere, resulting in significant chemical, radiative, and dynamical changes. Canada experienced an extremely severe wildfire season in 2023, with a total area burned that substantially exceeded those of previous events known to have impacted the stratosphere (such as the 2020 Australian fires). This season also had record-high pyroCb activity, which raises the question of whether the 2023 Canadian event resulted in significant stratospheric perturbations. Here, we investigate this anomalous wildfire season using retrievals from multiple satellite instruments, ACE-FTS (Atmospheric Chemistry Experiment – Fourier transform spectrometer), OMPS LP (Ozone Mapping and Profiler Suite Limb Profiler), and MLS (Microwave Limb Sounder), to determine the vertical extents of the wildfire smoke along with chemical signatures of biomass burning. These data show that smoke primarily reached the upper troposphere, and only a nominal amount managed to penetrate the tropopause. Only a few ACE-FTS occultations captured elevated abundances of biomass-burning products in the lowermost stratosphere. OMPS LP aerosol measurements also indicate that any smoke that made it past the tropopause did not last long enough or reach high enough to significantly perturb stratospheric composition. While this work focuses on Canadian wildfires given the extensive burned area, pyroCbs at other longitudes (e.g., Siberia) are also captured in the compositional analysis. These results highlight that despite the formation of many pyroCbs in major wildfires, those capable of penetrating the tropopause are extremely rare; this in turn means that even a massive area burned is not necessarily an indicator of stratospheric effects.

The Evolution of the Hunga Hydration in a Moistening Stratosphere

AbstractThe 2022 Hunga eruption caused unprecedented stratospheric hydration. Aura Microwave Limb Sounder (MLS) measurements show that the stratospheric water vapor mass remains essentially unchanged as of early 2024 and that the Hunga hydration occurred atop a robust (possibly accelerating) moistening trend in the stratosphere. Enhanced by the excess Hunga water vapor, dehydration via polar stratospheric cloud sedimentation in the 2023 Antarctic vortex exceeded climatological values by 50%. Simple projections based on modeled exponential decay illustrate that the timing of the return to humidity levels that would have been expected absent the Hunga hydration depends on the ongoing stratospheric water vapor trend. With the Hunga hydration compounding an underlying moistening trend, the stratosphere could remain anomalously humid for an extended period.

The Influence of Stratospheric Hydration From the Hunga Eruption on Chemical Processing in the 2023 Antarctic Vortex

AbstractWe use measurements of trace gases from the Microwave Limb Sounder and polar stratospheric clouds (PSCs) from the Cloud‐Aerosol Lidar with Orthogonal Polarization to investigate how the extraordinary stratospheric water vapor enhancement from the 2022 Hunga eruption affected polar processing during the 2023 Antarctic winter. Although the dynamical characteristics of the vortex itself were generally unexceptional, the excess moisture initially raised PSC formation threshold temperatures above typical values. Cold conditions, especially in early July, prompted ice PSC formation and unusually severe irreversible dehydration at higher levels (500–700 K), while atypical hydration occurred at lower levels (380–460 K). Heterogeneous chemical processing was more extensive, both vertically (up to 750–800 K) and temporally (earlier in the season), than in prior Antarctic winters. The resultant HCl depletion and ClO enhancement redefined their previously observed ranges at and above 600 K. Albeit unmatched in the satellite record, the early‐winter upper‐level chlorine activation was insufficient to induce substantial ozone loss. Chlorine activation, denitrification, and dehydration processes ran to completion by July/August, with trace gas evolution mostly following the climatological mean thereafter, but with chlorine deactivation starting slightly later than usual. While cumulative ozone losses at 410–550 K were relatively large, probably because of the delayed chlorine deactivation, they were not unprecedented. Thus, ozone depletion was unremarkable throughout the lower stratosphere. Although Hunga enhanced PSC formation and chemical processing in early winter, saturation of lower stratospheric denitrification, dehydration, and chlorine activation (as is typical in the Antarctic) prevented an exceptionally severe ozone hole in 2023.

Movement of decaying quasi-2-day wave in the austral summer-time mesosphere

The quasi-2-day wave (Q2DW) is a large temperature disturbance in the austral summer-time mesosphere. Its decay-phase movement and phase-speed are poorly understood. Q2DW events observed by the microwave limb sounder (MLS) onboard the NASA Aura satellite reveal that during the temperature Q2DW’s decay-phase, the Q2DW temperature disturbance is still substantial, but its phase-speed reduces exponentially, on average, from around −70 to −20 m/s in around 30-days. Observations also reveal significant interannual variability in these phase-speed values. Q2DW events simulated by the extended Canadian middle atmosphere model (eCMAM) reveal that during the Q2DW decay-phase, the temperature Q2DW phase-speed is strongly correlated with the summer mesosphere easterly jet (SMEJ) wind values. eCMAM also shows that the phase-speed interannual variabilities partially reflect the interannual variabilities of the SMEJ. Planetary-wave diagnostics indicate that during the Q2DW’s decay phase, there is still an active transfer of momentum from the SMEJ into Q2DW. The model simulations therefore indicate that the SMEJ plays a substantial role in the decaying temperature Q2DW phase-speed variabilities observed by MLS. This adds to our knowledge of how the SMEJ affects the Q2DW.

Prolonged Quasi‐6‐Day Wave Activities in the Northern Hemisphere MLT Region Due To Antarctic Stratospheric Minor Warming Around September Equinox of 2013 and 2014

AbstractThe geopotential height observations from the Aura Microwave Limb Sounder show that the quasi‐6‐day wave (Q6DW) events with westward zonal wavenumber 1 (W1) in the Northern Hemisphere (NH) mesosphere and lower thermosphere (MLT) during September 2013 and 2014 had a prolonged lifetime of ∼45–50 days and reached their maximum amplitudes after the September equinox, while the climatological Q6DW‐W1 is completely dissipated in the background atmosphere before the equinoxes. The Eliassen‐Palm flux diagnostic results indicate that Q6DW‐W1 during September 2013 and 2014 obtained an additional source at ∼60°‐80°S and ∼40–50 km as the September equinox approached, which is related to the baroclinic/barotropic instability in this region. Further investigation on the background atmosphere reveals that several stratospheric minor warming (SMW) events occurred in the Antarctic region during September 2013 and 2014 due to the enhancement of wavenumber 1 activities, accompanied by the increase in the stratospheric temperature, changes in the shape of the polar vortex and the reversal in the zonal mean circulation. The strong planetary wave breaking during the September 2013 and 2014 Antarctic SMW events significantly weakened the strength of the polar night jet (PNJ) and made its peak height descend below ∼35 km, which generated the baroclinic/barotropic instability at the new upper boundary of the PNJ (∼60°‐80°S and ∼40–50 km) by an anomalous double‐jet configuration in the background winds. This unusual instability provided additional wave source and energy for the trans‐equatorial propagation of Q6DW‐W1, which finally led to prolonged wave activities in the NH MLT region.

The Influence of Space Traffic on AIM/CIPS PMC Frequencies at 80°N

AbstractWe explore the effects of lower thermospheric water vapor deposited by launch vehicle plumes on polar mesospheric cloud (PMC) frequencies at 80°N. We use July‐averaged PMC frequencies from 2007 to 2022 from the Cloud Imaging and Particle Size (CIPS) instrument on NASA's Aeronomy of Ice in the Mesosphere (AIM) satellite. Launch sites worldwide are typically located near northern mid‐latitudes. Using the orbital launch record for the same time period, we find that the number of launches correlates with PMC frequencies with a coefficient of r = 0.60, which increases to r = 0.75 when only selecting launches from 2.5 to 21.5 local time (LT), indicating a weak LT dependence on global‐scale transport to 80°N. To support our findings, we use meridional winds from the Michelson Interferometer for Global High‐resolution Imaging experiment on NASA's Ionospheric Connection Explorer satellite and winds from the Horizontal Wind Model climatology to interpret the northward motion of air parcels at 105 km. We find the launch LT window that maximizes the correlation coefficient to be consistent with the expected maximum northward motion from the diurnal variation of mid‐latitude meridional winds. Comparisons with Microwave Limb Sounder satellite observations of upper mesospheric temperature and water vapor reveal a strong dependence of cloud frequency on water vapor (r = 0.86) but not on temperature (r = −0.26), indicating that water vapor is the primary source of PMC variability for the bright PMCs at 80°N. We therefore find that launch vehicle plumes originating primarily from northern mid‐latitudes modulate PMC frequency at 80°N in July.

Impact of ENSO on the UTLS chemical composition in the Asian Summer Monsoon Anticyclone

The changes in the convection and background dynamics over the Asian Summer Monsoon (ASM) are mainly responsible for the changes in the concentrations of the tropospheric pollutants within the Asian Summer Monsoon Anticyclone (ASMA). In this study, we have investigated the structural and chemical composition changes of the ASMA during different El Niño–Southern Oscillation (ENSO) conditions by making use of reanalysis products and Microwave Limb Sounder (MLS) satellite observations. Our analysis mainly concentrates on the July and August months of 2015 (El Niño) and 2022 (La Niña), which are the cold (Nino Index 3.4 exceeding −0.5 in magnitude throughout the year) and warm (Nino Index exceeding +0.5 in magnitude throughout the year) phase of the ENSO. The ASMA structure during different phases of the ENSO is found to be different when compared with the long-term (2005–2023) mean. The ASMA is found to have a larger zonal extent during La Niña (2022), extending from 20° to 140° E compared to El Niño (2015), which is from 20° to 100–105°E. A significant decrease (increase) in the concentration of the tropospheric species (CO and WV) is noticed within the ASMA in El Niño (La Niña). The decrease in the tropospheric species is clearly evident throughout the upper troposphere. The northeastern edge of the ASMA at 100 hPa and 150 hPa showed quite distinct behaviour with an enhancement (reduction) in the tropospheric species during La Niña (El Niño). Interestingly, there is an increase in O3 concentrations over the northeastern edge of ASMA during 2015, which is attributed to the stratospheric intrusion. Our results also revealed the enhancement of the tropospheric species over the western Pacific region during 2015 but not in 2022. Current findings highlight dynamic shifts linked to varying ENSO phases, leading to notable alterations in both the ASMA structure and Upper Troposphere and Lower Stratosphere (UTLS) chemical composition.

Observations, Remote Sensing, and Model Simulation to Analyze Southern Brazil Antarctic Ozone Hole Influence

This paper presents the observational, remote sensing, and model simulation used to analyze southern Brazil Antarctic ozone hole influence (SBAOHI) events that occurred between 2005 and 2014. To analyze it, we use total ozone column (TOC) data provided by a Brewer spectrophotometer (BS) and the OMI (Ozone Monitoring Instrument). In addition to the AURA/MLS (Microwave Limb Sounder) instrument, satellite ozone profiles were utilized with DYBAL (Dynamical Barrier Localization) code in the MIMOSA (Modélisation Isentrope du Transport Mésoéchelle de l’Ozone Stratosphérique par Advection) model Potential Vorticity (PV) fields. TOC has 7.0 ± 2.9 DU reductions average in 62 events. October has more events (30.7%). Polar tongue events are 19.3% in total, being more frequently observed in October (50% of cases), with medium intensity (58.2%), and in the stratosphere medium levels (55.0%). Already, polar filament events (80.7%) are more frequent in September (32.0%), with medium intensity (42.0%), and stratosphere medium levels (40.7%).

The Spread of the Hunga Tonga H2O Plume in the Middle Atmosphere Over the First Two Years Since Eruption

AbstractThe eruption of Hunga in January 2022 injected a large amount of water into the stratosphere. Satellite measurements from Aura Microwave Limb Sounder (MLS) show that this water vapor (H2O) has now spread throughout the stratosphere and into the lower mesosphere, resulting in an increase of >1 ppmv throughout most of this region. Measurements from three ground‐based Water Vapor Millimeter Wave Spectrometer (WVMS) instruments and MLS are in good agreement, and show that in 2023 there was more H2O in the lower mesosphere than at any time since the WVMS measurements began in the 1990's. At Table Mountain, California all WVMS H2O measurements at 54 km since June 2023, and all of the measurements from Mauna Loa, Hawaii, since the resumption of measurements in September 2023, show larger mixing ratios than any previous measurements. At 70 km several recent WVMS retrievals since September 2023 show the largest anomalies ever measured. The MLS measurements show that maximum H2O anomalies over the 2004–2023 record have occurred throughout almost all of the stratosphere and lower mesosphere since the eruption. As of November 2023, almost all of the ∼140 Tg of water originally injected into the stratosphere by the Hunga eruption remains in the middle atmosphere at pressures below 83 hPa (altitudes above ∼17 km). The eruption occurred during a period when stratospheric H2O was already slightly elevated above the 2004–2021 MLS average, and the November 2023 anomaly of ∼160 Tg represents ∼15% of the total mass of H2O in this region.

Quasi-10-day waves in temperature and polar mesospheric clouds: Results of AIM/SOFIE and Aura/MLS observations

Planetary waves, including quasi-2, -5, -10, −16-day waves, play significant roles in stratospheric dynamics. However, the existing knowledge on quasi-10-day waves (Q10DWs) at high latitudes is limited. This paper investigated the interannual and seasonal variations of Q10DWs with zonal wave numbers varying from the −3 (westward propagation) to 3 (eastward propagation) modes from 2008 to 2022, using temperature data measured by the Microwave Limb Sounder instrument (316−0.001 hPa, corresponding to an altitude of approximately 8–97 km) and temperature/ice water content data measured by the Solar Occultation for Ice Experiment (SOFIE) instrument (10−100 km at latitudes >55°). The findings revealed that the amplitude of Q10DWs in winter was higher than that in other seasons. The amplitude of Q10DWs was observed to substantially decrease with an increase in wavenumber. In addition, the amplitude of stationary Q10DWs in the northern polar region exceeded that in the southern polar region. Moreover, we used observational data from the SOFIE instrument, which simultaneously measures temperature and ice water content (IWC) in the mesosphere, to examine the variations of Q10DWs with respect to the temperature and IWC. Our findings suggest that in the northern polar region, the maximum value of Q10DWs in IWC was occasionally observed earlier than the lowest value of Q10DWs in temperatures.

The Sensitivity of Polar Mesospheric Clouds to Mesospheric Temperature and Water Vapor

Polar mesospheric cloud (PMC) data obtained from the Aeronomy of Ice in the Mesosphere (AIM)/Cloud Imaging and Particle Size (CIPS) experiment and Himawari-8/Advanced Himawari Imager (AHI) observations are analyzed for multi-year climatology and interannual variations. Linkages between PMCs, mesospheric temperature, and water vapor (H2O) are further investigated with data from the Microwave Limb Sounder (MLS). Our analysis shows that PMC onset date and occurrence rate are strongly dependent on the atmospheric environment, i.e., the underlying seasonal behavior of temperature and water vapor. Upper-mesospheric dehydration by PMCs is evident in the MLS water vapor observations. The spatial patterns of the depleted water vapor correspond to the PMC occurrence region over the Arctic and Antarctic during the days after the summer solstice. The year-to-year variabilities in PMC occurrence rates and onset dates are highly correlated with mesospheric temperature and H2O. They show quasi-quadrennial oscillation (QQO) with 4–5-year periods, particularly in the southern hemisphere (SH). The combined influence of mesospheric cooling and the mesospheric H2O increase provides favorable conditions for PMC formation. The global increase in mesospheric H2O during the last decade may explain the increased PMC occurrence in the northern hemisphere (NH). Although mesospheric temperature and H2O exhibit a strong 11-year variation, little solar cycle signatures are found in the PMC occurrence during 2007–2021.

Antarctic Vortex Dehydration in 2023 as a Substantial Removal Pathway for Hunga Tonga‐Hunga Ha'apai Water Vapor

AbstractThe January 2022 eruption of Hunga Tonga‐Hunga Ha'apai (HTHH) injected a huge amount (∼150 Tg) of water vapor (H2O) into the stratosphere, along with small amount of SO2. An off‐line 3‐D chemical transport model (CTM) successfully reproduces the spread of the injected H2O through October 2023 as observed by the Microwave Limb Sounder. Dehydration in the 2023 Antarctic polar vortex caused the first substantial (∼20 Tg) removal of HTHH H2O from the stratosphere. The CTM indicates that this process will dominate removal of HTHH H2O for the coming years, giving an overall e‐folding timescale of 4 years; around 25 Tg of the injected H2O is predicted to still remain in the stratosphere by 2030. Following relatively low Antarctic column ozone in midwinter 2023 due to transport effects, additional springtime depletion due to H2O‐related chemistry was small and maximized at the vortex edge (10 DU in column).

Ozone Profile Retrieval Algorithm Based on GEOS-Chem Model in the Middle and Upper Atmosphere

Ozone absorbs ultraviolet radiation, which has a significant impact on research in astrobiology and other fields in that investigate the middle and upper atmosphere. A retrieval algorithm for ozone profiles in the middle and upper atmosphere was developed using the spectral data from the TROPOspheric Monitoring Instrument (TROPOMI). A priori ozone profiles were constructed through the Goddard Earth Observing System-Chem (GEOS-Chem) model. These profiles were closer to the true atmosphere in the spatial and temporal dimensions when compared to the ozone climatology. The TpO3 ozone climatology was used as a reference to highlight the reliability of the a priori ozone profile from GEOS-Chem. The inversion results based on GEOS-Chem and TpO3 climatology were compared with ground-based ozone measurements and the satellite products of the Microwave Limb Sounder (MLS) and the Ozone Mapping and Profiles Suite_Limb Profile (OMPS_LP). The comparisons reveal that the correlation coefficient R values for the inversion results based on GEOS-Chem were greater than 0.90 at most altitudes, making them better than the values based on TpO3 climatology. The differences in subcolumn concentration between the GEOS-Chem inversion results and the ground-based measurements were smaller than those between TpO3 climatology results and the ground-based measurements. The relative differences between the inversion results based on the GEOS-Chem and the satellite products was generally smaller than those between the inversion results based on TpO3 climatology and the satellite products. The mean relative difference between the GEOS-Chem inversion results and MLS is −9.10%, and OMPS_LP is 1.46%, while those based on TpO3 climatology is −14.51% and −4.70% from 20 to 45 km These results imply that using a priori ozone profiles generated through GEOS-Chem leads to more accurate inversion results.

A multi-decadal time series of upper stratospheric temperature profiles from Odin-OSIRIS limb-scattered spectra

Abstract. A new upper stratospheric (35–60 km) temperature data product has been produced using Optical Spectrograph and InfraRed Imager System (OSIRIS) limb-scattered spectra that now spans over 22 years. Temperature is calculated by first estimating the Rayleigh scattering signal and then integrating hydrostatic balance combined with the ideal gas law. Uncertainties are estimated to be 1–5 K, with a vertical resolution of 3–4 km. Correlative comparisons with the Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) and the Microwave Limb Sounder on Aura (MLS) are consistent with these uncertainty estimates and generally have no regions of statistically significant drift. The data product has been publicly released as part of the nominal OSIRIS v7.3 processing.

Quasi-10 d wave activity in the southern high-latitude mesosphere and lower thermosphere (MLT) region and its relation to large-scale instability and gravity wave drag

Abstract. Seasonal variation in westward-propagating quasi-10 d waves (Q10DWs) in the mesosphere and lower thermosphere of the Southern Hemisphere (SH) high-latitude regions is investigated using meteor radar (MR) observations for the period of 2012–2016 and using the Specified Dynamics (SD) version of the Whole Atmosphere Community Climate Model (WACCM). The phase difference in meridional winds measured by two MRs located in Antarctica gives observational estimates of the amplitude and phase of the Q10DW with zonal wavenumber 1 (W1). The amplitude of the observed Q10DW-W1 is large around equinoxes. In order to elucidate the variations in the observed Q10DW-W1 and its possible amplification mechanism, we carry out two SD-WACCM experiments nudged towards the MERRA-2 reanalysis from the surface up to ∼ 60 km (EXP60) and ∼ 75 km (EXP75). Results of the EXP75 indicate that the observed Q10DW-W1 can be amplified around regions of barotropic and/or baroclinic instability in the middle mesosphere around 60–70° S. In the EXP60 experiment, it was also found that the Q10DW-W1 is amplified around the regions of instability, but the amplitude is too large compared to MR observations. The large-scale instability in the EXP60 in the SH summer mesosphere is stronger than that in the EXP75 and Microwave Limb Sounder observations. The larger instability in the EXP60 is related to the large meridional and vertical variations in polar mesospheric zonal winds in association with gravity wave parameterization (GWP). Given uncertainties inherent in GWP, these results can suggest that it is possible for models to spuriously generate traveling planetary waves such as the Q10DW, especially in summer, due to excessively strong large-scale instability in the SH high-latitude mesosphere.

A novel infrared imager for studies of hydroxyl and oxygen nightglow emissions in the mesopause above northern Scandinavia

Abstract. The paper describes technical characteristics and presents the first scientific results of a novel infrared imaging system (imager) for studies of nightglow emissions coming from the hydroxyl (OH) and molecular oxygen (O2) layers in the mesopause region (80–100 km) above northern Scandinavia. The OH imager was put into operation in November 2022 at the Swedish Institute of Space Physics in Kiruna (67.86° N, 20.42° E; 400 m altitude). The OH imager records selected emission lines in the OH(3-1) band near 1500 nm to obtain intensity and temperature maps at around 87 km altitude. In addition, the OH imager registers infrared emissions coming from the O2 IR A-band airglow at 1268.7 nm in order to obtain O2 intensity maps at a slightly higher altitude, around 94 km. This technique allows the tracing of wave disturbances in both horizontal and vertical domains in the mesopause region. Validation and comparison of the OH(3-1) rotational temperature with collocated lidar and Aura Microwave Limb Sounder (MLS) satellite temperatures are performed. The first scientific results obtained from the OH imager for the first winter season (2022–2023) are discussed.

Chemical ozone loss and chlorine activation in the Antarctic winters of 2013–2020

Abstract. The annual formation of an ozone hole in the austral spring has regional and global climate implications. The Antarctic ozone hole has already changed the precipitation, temperature and atmospheric circulation patterns, and thus the surface climate of many regions in the Southern Hemisphere (SH). Therefore, the study of ozone loss variability is important to assess its consequential effects on the climate and public health. Our study uses satellite observations from the Microwave Limb Sounder on Aura and the passive-tracer method to quantify the ozone loss for the past 8 years (2013–2020) in the Antarctic. We observe the highest ozone loss (about 3.5 ppmv) in 2020, owing to the high chlorine activation (about 2.2 ppbv), steady polar vortex, and huge expanses of polar stratospheric clouds (PSCs) (12.6×106 km2) in the winter. The spring of 2019 also showed a high ozone loss, although the year had a rare minor warming in mid-September. The chlorine activation in 2015 (1.9 ppbv) was the weakest, and the wave forcing from the lower latitudes was very high in 2017 (up to −60 km s−1). The analysis shows significant interannual variability in the Antarctic ozone as compared to the immediate previous decade (2000–2010). The study helps to understand the role of dynamics and chemistry in the interannual variability of ozone depletion over the years.

The Chemical Effect of Increased Water Vapor From the Hunga Tonga‐Hunga Ha'apai Eruption on the Antarctic Ozone Hole

AbstractThe eruption of the Hunga Tonga‐Hunga Ha'apai volcano on 15 January 2022 was one of the most explosive eruptions of the last decades. The amount of water vapor injected into the stratosphere was unprecedented in the observational record, increasing the stratospheric water vapor burden by about 10%. Using model runs from the ATLAS chemistry and transport model and Microwave Limb Sounder (MLS) satellite observations, we show that while 20%–40% more water vapor than usual was entrained into the Antarctic polar vortex in 2023 as it formed, the direct chemical effect of the increased water vapor on Antarctic ozone depletion in June through October was minor (less than 4 DU). This is because low temperatures in the vortex, as occur every year in the Antarctic, limit water vapor to the saturation pressure and thus reset any anomalies through the process of dehydration before they can affect ozone loss.

The Responses of Ozone to the Solar Eclipse on the 21st of June 2020 in the Mesosphere and Upper Stratosphere

Microwave Limb Sounder (MLS) observations showed an obvious variation of ozone concentration during the annular solar eclipse on 21 June 2020 in the mesosphere and upper stratosphere. Ozone concentration slightly reduced near 40 km in the regions of 24°N–36°N, and increased in low latitudes at 40 km. In the heights of 45–60 km, the increase in ozone concentration in most of the regions was obvious. The ozone increases and decreases were more obvious between 60–65 km, where enhancement took the leading role. The nighttime ozone variation was weaker than the daytime in most of the heights of 30–65 km. The variation of HO2 and CO is investigated to study the photochemical and dynamical causes of ozone variation. As HO2 decreased at 1 hPa and increased at 60–65 km, ozone variation shows a mostly reversed relationship to HO2 variation. CO increased at 32–39 km and decreased at 52–60 km, which was related to the upwelling at these heights. The dynamic processes also contributed to the decrease in ozone concentration at 40 km and increase at 50–60 km.