Microwave Ignition Research Articles

Microwave Ignition of Thermites

AbstractThis study investigates the microwave ignition behavior of a range of thermites of aluminum, boron, titanium, and tantalum fuels with oxides of Bi2O3, CuO, and Fe2O3. In order to gain insight into the modes of energy transfer leading to ignition, thermites are heated in either a purely electric or magnetic field environment within a single‐mode 2.45 GHz resonant cavity with electric field strengths of 40 to 110 kV/m and magnetic field strengths of 22 to 258 A/m. Thermite stoichiometry is varied as well as particle size and thermite mass. The shortest ignition delays in electric and magnetic fields were found to be 1.37 s (nAl and CuO) and 0.87 s (nAl and CuO), respectively. The use of a variety of carbon susceptors to shorten ignition delay is also studied. Carbon susceptors are found to appreciably shorten ignition delays to as short as 140 and 170 ms for the E and B field respectively (nAl and CuO with multiwalled carbon nanotubes). The results of this work are informative on thermite component choice and the preferred mechanism (electric vs magnetic field) of heating for various thermite compositions for consideration of the increasingly popular ignition via electromagnetic fields.

“Fireworks” ignition and combustion of metal nanoparticles: Based on the rapid conversion and transmission of microwave energy by energetic ionic liquids

The metal nanoparticles (MNPs) are widely used to improve the output performance of various explosives and propellants, which ignition is an important link for the energy release of fuel. The microwaves have been recognized as a safer and smart ignition method. However, it is difficult to achieve rapid ignition of MNPs under microwave radiation due to the low heating rate. The ADN energetic ionic liquids could efficiently absorb microwaves owing to excellent polarity. This work proposes a method of fast “fireworks” ignition and combustion of MNPs under microwave radiation, by employing ADN as the “central hub” for microwave energy conversion. The dispersion of Al and Ti NPs in ADN endowed the solution with nanofluid properties and significantly improved the thermal conductivity. The solution boiled violently under microwave radiation, causing the temperature of MNPs to rise continuously. Meanwhile, the acidic components produced by ADN pyrolysis destroyed the oxide shell of MNPs, further accelerating the ignition process. The ignition phenomenon of Al and Ti NPs were different due to distinct microwave absorption properties and ignition temperature. When the expanding liquid film broken, the shock wave blew the Al NPs into the air to realize the “fireworks” ignition and combustion. The Ti NPs was ignited in the solution, which further ignited the ADN solution, allowing the system for controllable ignition and combustion. The “fireworks” ignition and combustion performance of MNPs could be modulated by the input microwave power. In summary, the new ignition and combustion method of MNPs will have a profound impact on the design of ignition sequence, the improvement of microwave energy utilization and the expansion of the application of ADN-based liquid propellants.

Experimental Study on the Influence of Microwave Energy Pulse Width and Duty Cycle on Evaporation and Ignition Characteristics of ADN-Based Liquid Propellant Droplets

This study investigates the evaporation and ignition characteristics of a single droplet of ammonium dinitramide (ADN)-based liquid propellant utilizing a waveguide resonant cavity device, in conjunction with a high-speed photographic imaging system and testing system. Experimental methods are employed to analyze the impact of microwave pulse width and duty cycle on the puffing and meicro-explosion phenomena of the droplet, as well as the delay time and duration of ignition. The experimental findings reveal that increasing the duty cycle enhances the ignition success rate and diminishes flame development time. Specifically, elevating the microwave duty cycle from 60% to 80% reduces the ignition delay time of the droplet from 132.8 ms to 88.1 ms, and the ignition duration from 23.1 ms to 19.9 ms. Furthermore, an increase in microwave energy pulse width expedites the combustion process of the flame and influences plasma generation. Increasing the pulse width of microwave energy from 20 µs to 40 µs prolongs the ignition delay time from 140.3 ms to 200.5 ms and extends the ignition duration from 56.7 ms to 77.8 ms. Additionally, it is observed that a higher duty cycle leads to a more pronounced puffing phenomenon that initiates earlier. In contrast, a higher pulse width results in a more pronounced puffing phenomenon that commences later. This study provides a thorough investigation into the microwave ignition mechanism of ADN-based liquid propellants, offering theoretical insights into the ignition and combustion stability of such propellants in microwave-assisted ignition systems.

Ignition performance and mechanism of Ti/CuFe2O4 composites with high microwave sensitivity

The microwave ignition holds potential in the ignition of weapons due to its simple structure, non-contact property, and simultaneous ignitions of large area. However, the long ignition delay time of the current ignition agents cannot meet the microwave weaponry advancements. To address the issues, a microwave sensitive oxide-CuFe2O4 (CUFO) which was firstly discovered to be easily ignited by microwaves compared many ferrites, was coupled with Ti nanoparticles (n-Ti) to form Ti/CUFO microwave ignition agents by electrostatic spray granulation. The characterization of microwave ignition, volumetric combustion, burning rate and DSC were used to determine its ignition delay time and the energy release properties. It indicates that the microwave sensitivity, maximum peak pressure and pressure pressurization rate of Ti/CUFO first increases and then decreases with the promoting content of n-Ti. The Ti/CUFO at Φ = 3.5 exhibits the lowest ignition delay time by 79.24 ms compared to the 98.7 ms of n-Ti, meanwhile, its maximum peak pressure and pressurization rate reach the highest by 338.54 kPa and 8.57 kPa/ms, respectively. The DSC results indicate that Ti/CUFO exhibits much lower reaction peak temperature by 320–335 °C compared to 488 °C of n-Ti, which suggests Ti-CUFO reaction maybe much easier be activated. The dielectric loss of n-Ti and CUFO under strong electric field transfer the energy of microwaves to heat, reaching to its reaction temperature. The XPS and XRD results of CUFO after microwave radiation disclosing the crystal transition, formation of divalent iron and oxygen vacancies, as well as the released bright light under microwave radiation, suggest the thermal breakdown mechanism of CUFO. When Ti/CUFO exposes into microwaves, CUFO generates oxygen vacancies due to heat loss and n-Ti is dielectric heated, followed by the generated oxygen reacting with n-Ti, improving the combustion performance of n-Ti. This result provides new insight for the designing of microwave ignition.

Experimental study on microwave ignition of ADN-based liquid propellant droplets doped with alumina nanoparticles

The objective of this study was to investigate the effects of alumina (Al2O3) nanoparticles on the evaporation, ignition, and combustion of ammonium dinitramide (ADN)-based liquid propellants under microwave irradiation. The alumina nanoparticles were uniformly dispersed in the ADN-based propellant at mass ratios of 25, 50, and 100 ppm, resulting in the formation of nano-fuel. Experimental methods were employed to examine the influence of alumina nanoparticles on the micro-explosion intensity, ignition delay time, combustion duration, critical ignition power, and emission spectra of the nano-fuel droplets. The experimental findings revealed a significant increase in the intensity and frequency of micro-explosion events with the inclusion of alumina nanoparticles. Compared to pure propellant, the nano-fuel with a concentration of 25 ppm exhibited a reduction of 33.5% in ignition delay time and a decrease of 9% in critical ignition power. Furthermore, the emission spectra characteristics of the pure propellant and nano-fuel were analyzed, indicating that alumina nanoparticles notably enhanced the thermal decomposition of ADN and the exothermic reaction of methanol combustion. This study provides an effective approach to improve the evaporation and combustion performance of ADN-based liquid propellants, offering potential possibilities for future applications.

Microwave ignition characteristics and distinction of typical nanothermites under different electromagnetic radiation

As a commonly used agent in micro-nano satellites and other small pyrotechnics, it is crucial to understand the response of nanothermite to microwave due to the growing interest in space and the increasingly complex electromagnetic environment. Microwaves can penetrate typical energetic materials and interact with them spatially and holistically. There are two ways of microwave radiation to the samples: microwave drill (contact) and single mode resonator (non-contact). To date, all previous studies were carried out in a single environment, and only for a single thermite system. In this work, the ignition performance of three representative nanothermite systems (Al/CuO, Al/MnO2, Al/Fe3O4) under two microwave ignition devices (custom-made microwave drill and single mode resonator) was first systematically studied, which contain both magnetic and non-magnetic, as well as high and low reactivity. The results showed that the relationship between ignition delay time and power basically accorded with exponential function. The ignition delay time decreased rapidly with the increase of power and finally stabilized within a fixed range. Compare to the metal oxide, pure Al was insensitive to microwave. However, the mechanism of the two ignition processes was different. The ignition sequence of the nanothermites was the same as metal oxides, indicating that the metal oxide was the decisive factor and driver of nanothermite ignition under microwave drill. For the ignition in resonator, the nanothermite behaved like bulk metal, reflecting most of the electromagnetic energy away. The ignition sequence was consistent with the aluminum content in the composites, implying nAl was the determining factor. To further analyze the ignition mechanism, the hot wire and laser sensitivity of nanothermites were also compared.

Experimental study on microwave-induced puffing, micro-explosion, and combustion characteristics of ammonium dinitramide-based liquid propellant droplets

Microwave ignition technology has the advantages of high ignition energy, stable ignition, and spatial multi-point ignition. These advantages make this technology promising for future application in green single-component propellants. In this paper, the ignition characteristics of ammonium dinitramide (ADN)-based liquid propellant droplets under the influence of microwaves at room temperature are investigated using experimental methods. The effects of microwave power on puffing, micro-explosion, and combustion behavior of ADN-based liquid propellant droplets were studied. The droplet and flame diameters were statistically related to time, and the microwave-assisted droplet ignition mechanism was analyzed. A new rectangular waveguide resonant cavity was designed in which the droplet is placed at the maximum electric field strength of the device. The droplet morphology and flame profile inside the resonant cavity were photographed with a high-speed camera. The experimental results showed that the microwave positively influenced the puffing, micro-explosion, and combustion behavior of droplets. When the microwave power was increased from 200 to 280 W, the total droplet evaporation time and ignition delay time were reduced by 56.5% and 35.2%, respectively. The positive effects of microwaves on combustion have been summarized as the thermal effect of microwaves on polar molecules and the promotion of fuel oxidation reactions by microwave-induced plasma. The plasma was found to control the development of the initial flame propagation front and to influence the temperature during the combustion reaction process. In this paper, we propose the mode of droplet combustion under microwave induction as a plasma discharge and several stages of the droplet combustion process. This research provides novel insight into the study of the microwave ignition mechanism of liquid fuels.

Microwave ignition of a combustible gas mixture with a critical streamer discharge in a high-speed flow

Ignition of combustible air/propane mixture in a high-speed flow with a microwave streamer discharge is considered. The experimental results of structure of streamer discharge and quantities at various pressures are presented. Pressure and temperature measurements in various sections of the streamer discharge in high-speed flow are analysed. The results obtained demonstrate the possibility of ignition of air/propane combustible mixture. The main physical mechanisms responsible for heating the discharge plasma to the ignition temperature of the combustible mixture and their characteristic time scales are discussed. The minimum time and minimum level of microwave radiation required to ignite a combustible mixture under various conditions are determined.

First H- beam extracted from the non-caesiated external RF-coil ion source at ISIS

A high power, high duty-cycle, non-caesiated negative hydrogen ion source is in development at the ISIS pulsed spallation neutron and muon facility. Stable operation of an inductively-coupled plasma pulsing at 50 Hz, 1 ms, 70 kW has been perfected with no apparent lifetime issues. Novel features compared to similar H- sources include a very low power microwave ignition gun, an adjustable permanent magnet filter field and multiple large 3D-printed components. This paper details the initial commissioning efforts required to generate a beam. An H- beam current of 10 mA was extracted on the first try in pure volume-production mode. Parameter sweeps and optimisation to reach the required 35 mA were put on hold to address ancillary equipment problems. Mitigation of RF pickup required major mechanical changes such as additional screening and magnetic shielding. Extraction voltage holding capabilities were investigated to cope with co-extracted electron current loading in excess of 0.7 A. Preliminary studies of the biased plasma electrode current showed that co-extracted electrons could be suppressed by increasing the magnetic filter field and gas flow.

Microwave controlled ignition and combustion characteristics of ADN-based ionic liquid propellant with fast response and environmental friendliness

The ADN-based ionic liquid propellants have been successfully implemented in liquid rocket engines, owing to high specific impulse and thrust, low toxicity and environmental friendliness. However, the traditional catalyst ignition of ADN-based propellant suffers from the problems of catalyst deactivation problems in the heating process. Microwaves could interact with the material holistically due to excellent penetration ability. Compared with solid materials, ionic liquids are natural microwave receptors on account of great polarity. To date, the possibility of microwave ignition of ionic liquid materials has not been explored. In this work, two kinds of ionic liquids: ADN and [AMIM][DCA] were used as oxidant and fuel of liquid propellant to achieve the maximum microwave absorption effect. The microwave controlled ignition and combustion of ADN-based liquid propellant was first realized and systematically studied. Compared to single component, the heat release, gas production, conductivity and heating rate of the mixed system was greatly enhanced. The sample (ADN/[AMIM][DCA] 10%) was successfully ignited by microwaves, displaying a decreased ignition delay time at higher power inputs. The ignition was generated in the gas phase and rapidly diffused into the solution, and the extinguishment was highly consistent with the input cessation of microwaves. The ignition delay was significant reduced in repeated ignition, resulted from the faster moving speeds of ions. The successful realization of microwave controlled ignition and combustion of ADN-based IL propellant will broaden the scope of their applications in space fuel and provide a new direction for the reform of liquid engines.

High‐Speed, microwave ignition: Antenna igniters with frequency and bandwidth selectivity

AbstractThis effort demonstrates the development of (1) dielectric breakdown igniters and (2) bridgewire igniters powered by half‐wavelength dipole microwave microstrip antennas with bandwidth selectivity for use in standoff ignition applications. Dielectric igniters utilized a dielectric epoxy filled with up to 30 wt. % nanothermite cast between the gap of two quarter wavelength microstrips. Bridgewire igniters employed a wire soldered across the gap of two quarter wavelength microstrips. A variety of different bridgewire materials were tested in diameters ranging from 76 μm to 203 μm. The ignition delay of resonant microwave igniters is measured from high‐speed video observation of the microwave illumination process within a free‐space anechoic microwave cavity driven by a 2 kW continuous magnetron source. Dielectric breakdown igniters produced ignition delays ranging from 400 ms to 850 ms. Ignition delay decreased with higher loading of thermite. Bridgewires were found to be highly efficient and measured ignition delays ranged from 17 ms to 271 ms (24.4 J to 457.1 J ignition energy). Smaller diameter bridgewires and high resistivity metals were found to produce the shortest ignition delays. We demonstrate through S‐parameter measurements the bandwidth selectivity of bridgewire igniters and show that control of dipole geometry enables tuning of igniter center frequency and bandwidth and demonstrate experimentally the ability of bridgewire igniters to reject accidental ignition from an off frequency high power microwave field. The tunability, bandwidth selectivity, and low energy requirements, in particular of bridgewires, make them attractive for a number of new and challenging ignition applications.

Remote microwave heating and ignition with an embedded receiving antenna within nanocomposites

This study demonstrates the use of a receiving antenna within a material to transmit microwave energy resulting in dielectric heating and ignition in a direct writing process. The wire antennas themselves do not heat, but rather the induced electric field results in dielectric heating of the sample, and with sufficient electric field strength, triggers ignition. With different length of embedded receiving antenna, local hot spots were generated at the ends of the receiving antenna as imaged with an IR camera. Simulation of a monopole source and receiving antennas, shows a spatial correspondence of the calculated electric field and the measured hot spots. We also demonstrate that receiving antennas can be incorporated to trigger ignition at desired locations, with multiple ignition points from which flame propagations can be induced. This study provides a new way to design and remote control the location of the hot spots and ignition.

Effect of moisture on microwave ignition of bituminous coal.

The interaction between water and microwave is of vital importance to reveal the microwave ignition mechanism of water-bearing coal. This study used two group of bituminous coal after drying and water saturation treatment, for experimental testing and contrastive analysis. During the experiment, permeability of coal samples was obtained based on nuclear magnetic resonance(NMR) test, then different power of microwaves were applied to coal samples, and the occurrence of hot spots within coal samples was regarded as a sign of microwave ignition. Microwave ignition of water-saturated coal is mainly affected by microwave power and coal permeability. The pore water in low permeability coal is conducive to microwave ignition, while the pore water in high permeability coal will prolong the ignition time. There is a permeability threshold, above which the average ignition time of water-saturated coal samples is longer than that of dry coal samples, but below which the opposite is true. These insights can be used to evaluate the safety of microwave technology when applied to coal engineering.

Effect of Microwave Power and Gas Flow Rate on the Combustion Characteristics of the ADN-based Liquid Propellant

As a new type of energy-containing material, Ammonium dinitramide based liquid propellant has the advantages of being green, having low toxicity, good stability, and high safety performance. Traditional catalytic combustion methods require preheating of the catalytic bed and deactivation of the catalytic particles at high temperatures, while microwave ignition methods can effectively solve these problems. To study the combustion characteristics of ADN-based liquid propellants during microwave ignition, the influence of microwave power and gas flow rates on the combustion process are analyzed using experimental methods. A high-speed camera was used to observe the enhanced effects of microwave power and gas flow on plasma and flame. Combined with temperature measurement, the combustion process of ADN-based liquid propellants under the action of plasma was analyzed. The combustion process in the presence of microwaves was observed by comparing parameters such as flame length, flame temperature, and radical intensity. Those results show that, with the increase in microwave power, the luminous burning area of the flame grows significantly. The microwave power is increased by 250 W each, and the flame jet length is increased by nearly 20%. The increase in microwave power also leads to an increase in propellant combustion temperature, however, this increase gradually slows down. At a gas flow rate of 20 L/min, the ADN-based liquid propellant showed the best combustion performance with a maximum jet length of 14.51 cm and an average jet length increase of approximately 85.9% compared to 14 L/min. Too much gas flow rate will hinder the development of the jet, while the high-velocity airflow will have a cooling effect on the flame temperature. The results provide a basis for the specific parameter design of microwave ignition and promote the application of ADN-based liquid propellants in the aerospace field.

Schlieren imaging and spectroscopic approximation of the rotational-vibrational temperatures of a microwave discharge igniter with a resonating cavity.

A microwave discharge igniter (MDI) with a resonating cavity was developed and optimized for practical applications in an internal combustion engine. In contrast to the typical microwave ignition, the resonating cavity of the MDI induces a discharge through dielectric resonance. Its source of microwave (MW) is a 2.45GHz semiconductor oscillator that is capable of numerous oscillation patterns. To verify and demonstrate the optimum ignition performance and combustion, we varied the oscillation parameters (signal factors) of the MW to optimize the performance of the MDI using the Taguchi method. Plasma spectroscopy was used for ignition condition analysis. Two sets of microwave pulses, a first pulse followed by a second set of pulse bursts, were used to ignite a propane-air fuel. The flame kernel growth rate and O I species generation were used as the response outputs, which were obtained, respectively from Schlieren imaging and emission spectroscopy experiments. The extended pulse periods and higher MW pulse numbers of the second set of pulses improved the response outputs of the MDI. To further analyze the effect of MW oscillation patterns on plasma properties and performance, measurements were done on MW superimposed operation with the high-voltage ignition from spark plugs. The MW transmission on a typical spark plug enhanced the air plasma ignition. Higher input MW energy and more extended MW pulse widths results in increased spectral intensity and radical generation of OH, O, and N 2. An inverse relation between the temperature and spectral intensity functions of the MW pulse width was observed, which was attributed to the cutoff density of the MW-enhanced plasma.

Effect of processing parameters on the microwave assisted aluminothermic reduction of molybdenite

In this work, the microwave assisted aluminothermic reduction of molybdenite (MoS2) was first demonstrated, and then the reaction was optimized using different processing parameters. A self-sustainable combustion front was readily induced in a compressed stoichiometric mixture of MoS2 and Al using microwave ignition. However, the reduction reaction (3MoS2 + 4Al = 3Mo + 2Al2S3) could not be fully completed mainly due to the rapid progress of the combustion front and insufficient available Al to fully reduce MoS2. A leaching process in HCl was also adapted to remove the Al2S3 byproduct and unreacted aluminum. Moreover, the effect of compaction pressure, excess Al and mechanical activation was further investigated to optimize the aluminothermic reduction reaction. Adding excess Al over the stoichiometric ratio shifted the reaction toward producing more Mo metal with lower retained MoS2. While the effect of compaction pressure on the reaction products was found to be negligible, it could affect the ignition temperature and the propagation rate of the combustion front. Mechanical activation had two crucial effects on the aluminothermic reduction of MoS2: decreasing the ignition temperature and increasing the reaction progression. A mechanically activated MoS2/Al powder mixture, which was prepared by 30 min ball milling with 0.5 mol excess Al and compressed at 70 MPa, exhibited the best overall efficiency for aluminothermic reduction of MoS2 to produce Mo metal.

Doping of Al/CuO with microwave absorbing Ti3C2 MXene for improved ignition and combustion performance

Nanothermites have a wide application in many civil and defense applications, including propulsion and detonations systems, micro-electromechanical (MEMs) and other systems that require fast energy release rate and low ignition temperature. Traditional ignition methods are commonly based on surface excitation (spot ignition), possessing a risk of undesired ignition. Safe and selective microwave (MW)-based igniting systems can interact with an ignitable material (typically a thermite) over its full volume at once. Unfortunately, thermites have low susceptibility to MW due to the presence of Al2O3 oxide shell on Al particles, which would commonly require a high ignition power of MW radiation and long ignition delay times. In this work, Ti3C2 MXene was introduced as a MW susceptor into Al/CuO energetic nanocomposites. The samples were ignited using a MW probe, showing that the introduction of MXene into Al/CuO/MXene could significantly reduce the power required for its MW ignition, as well as shorten the ignition delay time versus the parent Al/CuO nanothermite. Besides, presence of MXene could modulate and control a heat release, gas production and combustion performance of the Al/CuO/MXene composites, substantially extending safety, flexibility and adaptability of new nanothermites to various operational requirements.

Plasma commissioning in a high power external RF-coil volume-type H- ion source

A high power, high duty cycle, negative hydrogen ion source is in development at ISIS. It will operate in pure volume-production mode and is driven by a 52-turn RF-coil mounted external to the plasma chamber. A solid-state amplifier with a maximum output of 100 kW in 50 Hz, 1 ms pulses delivers RF power to the coil via an impedance-matching network. The amplifier has a relatively wide bandwidth, able to deliver full power from 1.8-4.0 MHz. This flexibility allowed straightforward commissioning of the matching network into an inductively-coupled plasma. Striking of the pulsed plasma is facilitated by a compact microwave ignition gun, requiring only 10 W of power at 2.45 GHz to deliver 1 mA seed pulses of electrons. Experiments have shown that it is vital to encapsulate the RF-coil properly to mitigate high voltage sparking. In addition, the location of the coil relative to the ion source’s permanent magnets has a critical effect on the ease of plasma ignition. The result of commissioning work is that a full duty-factor (50 Hz, 800 ^s) plasma has been achieved at nominal operating power (30 kW) and detailed optical studies have begun.

Experimental Research on Microwave Ignition and Combustion Characteristics of ADN-Based Liquid Propellant.

Microwave ignition has attracted much attention due to its advantages of reliable ignition, large ignition area and cold-start capability. In this paper, the experimental method is used to explore the ignition ability of the microwave device to ADN-based liquid propellant. Additionally, we discuss the influence of the inlet power and rate of propellant injected into the ignition system on the height of the combustion jet and the combustion temperature. In the experiment, a microwave-assisted ignition system was established based on a special microwave resonant cavity. The liquid propellant and working gas were sprayed into the resonator cavity through the hollow straight tube beneath the resonant cavity. The test results show that the device can ignite the propellant under the condition of 800 W input power, which proves the feasibility of the microwave ignition device for ADN-based liquid propellant. Microwave power has some influence on the flame spray height at the initial stage of combustion. The spray height at 2000 W is increased by 55.7% in comparison to 1000 W. In the stable combustion stage, the input power has a very significant increase in the average temperature of the flame, which is increased by 25%. The combustion is relatively better when the propellant flow rate is 30 mL/min, and the height of the flame spray increases by 25.2%. The increase in throughput did not have a significant impact on the flame temperature.

Coke-assisted microwave ignition and combustion behaviors of anthracite in a switching atmosphere

Low volatile coal has a large reserve but faces significant challenges in industrial applications. Due to the rapid and selective heating process, microwave-based technology is generally applied in various studies of carbonaceous materials. This work verified a novel non-contact microwave ignition of anthracite mixed with coke, where typical events of ignition or combustion were recorded by a digital camera. Video image analysis showed that the weakening of O2 to the tiny spark discharges between coke particles failed microwave heating. Hence a switching atmosphere (100% N2 firstly, then O2 at a certain proportion added) was used to ensure rapid microwave heating and subsequent ignition. Ignition of mixed anthracite & coke took place in the middle of the sample once the volatile flame appeared, which following the sample locally turned red-hot. The time for the flame burning was prolonged by the microwave power and especially the increase of O2 proportion. Gas products analysis showed a large amount of CO and CO2 instead of CH4 and H2O during the flame burning, which suggested that extra gasification reaction, where CO as product, supported the existence of flame. Moreover, the plasma generated by the violent discharge further expanded the range of the flame, with clear spectral peaks at 589 nm, 766 nm, and 770 nm. In addition, the distribution of coke in the mixture for effective ignition was also discussed. This study may provide a new idea for the application of low volatile coals.