Microstructure Of Duplex Stainless Steel Research Articles

Effect of nitrogen content on microstructure and mechanical properties of duplex stainless steels via wire arc additive manufacturing

Effect of nitrogen content on microstructure and mechanical properties of duplex stainless steels via wire arc additive manufacturing

On the correlation between fatigue behaviour and the multiphase microstructure of a super duplex stainless steel

This work investigates the relationship between the multiphase microstructure and the macroscale fatigue behaviour of a cast super duplex stainless steel (SDSS). The microstructure of a cast SDSS is typically composed of a FCC γ-phase and a BCC δ-phase. However, deleterious secondary phases (SP), such as sigma and chi, may precipitate when SDSS is exposed to high-temperature ranges, jeopardising its mechanical properties, namely fatigue performance. The purpose of this investigation was to quantify the correlation between SP amounts and fatigue life of a cast SDSS (CD3MWCuN, ASTM A890). Fatigue tests were conducted using miniature specimens taken from a cast C-Ring with different SP amounts. A numerical model was proposed to calibrate the fatigue test parameters. After the tests, SEM and EBSD techniques were used to quantify the SP and analyse the fatigue-crack propagation. The microstructural analysis was complemented with hardness and tensile tests. Regression models were developed to correlate the percentage of SP, the fatigue resistance and the number of cycles to failure, and to predict the microstructural stress concentration from the amount of SP. In addition, a methodology is proposed for predicting S-N curves as a function of the amount of SP, showing a high correspondence in the increase of the percentage of SP with the decrease in fatigue life. Furthermore, the fatigue strength, for a given number of cycles to failure, tends to decrease linearly with increasing the SP, while the microstructural stress concentration factor tends to increase with an increase in SP. These findings contribute to further knowledge on predicting the behaviour of cast SDSS under different cyclic conditions, which can be valuable for optimizing design and performance in various applications.

Influence of the direction of ferrite-austenite banding on hydrogen embrittlement of 2205 duplex stainless steel

In this study, the fracture behavior of 2205 duplex stainless steel (DSS) under in-situ hydrogen charging is evaluated. For this purpose, fracture toughness tests are performed on single-edge notched bending specimens, in which hydrogen is introduced electrochemically in-situ, using an acid and a saline electrolyte at different current densities. The hydrogen content of both electrochemically and gaseous pre-charged specimens is measured to assess the influence of the aggressiveness of the environment. Three environments are evaluated: realistic, severe and highly severe. As the microstructure of DSS is characterized by the presence of ferrite and austenite bands, the influence of directionality on fracture toughness is also studied. For this purpose, specimens are machined in two directions, being crack growth parallel to the bands in one case, while crack growth is perpendicular to the bands in the other case. Fracture toughness was found to decrease with increasing current density and in a more aggressive environment, and to increase when crack growth was perpendicular to the bands. The fracture surface was also evaluated, revealing splits in the direction of the bands in all in-situ tests. The origin and propagation of these splits were studied using electron backscatter diffraction scans, concluding that splits propagated through the ferrite-austenite interface.

Microstructure, Mechanical Properties, and Corrosion Resistance of ER2209 Duplex Stainless Steel Manufactured by Plasma Arc Welding

Microstructure, Mechanical Properties, and Corrosion Resistance of ER2209 Duplex Stainless Steel Manufactured by Plasma Arc Welding

The Effects of Heat Inputs on LDSS 2101 GTAW and SMAW Weld Microstructure and Mechanical Behavior

The welding has been utilized to stabilize the phase fractions in the microstructure of lean duplex stainless steel (LDSS) to build massive mechanical structures. The influence of heat input on the microstructure, mechanical properties, and corrosion behavior of LDSS 2101 during the gas tungsten arc welding (GTAW) and shielded metal arc welding (SMAW) processes is investigated in the present work. Specifically, we compared the outcomes between low heat input (LHI) at 0.85 kJ/mm and high heat input (HHI) at 1.3 kJ/mm for both welding techniques. Throughout the welding process, ER2209 filler wire was utilized. To assess the microstructural changes in the weldments, we employed an optical microscope, a scanning electron microscope, and X-ray diffraction. The results revealed that the volume phase fraction of ferrite was significantly higher in the LHI sample of GTAW compared to HHI GTAW and all SMAW welds. LHI GTAW welds have 18.2% greater Charpy impact toughness than LHI SMAW, whereas HHI GTAW has 35.7% higher than HHI SMAW specimens. The microhardness of the LHI GTAW weldments increased (from 230 ± 3.2 to 252 ± 4.8 HV10), whereas the microhardness of the LHI SMAW weldments increased (from 227 ± 2.8 to 246 ± 5.2 HV10). GTAW exhibited a fine grain structure, showcasing favorable tensile properties and higher hardness compared to SMAW. Conversely, the SMAW welds and their heat-affected regions exhibited coarse grain structures. These findings highlight the superior performance of GTAW in terms of microstructural characteristics, and mechanical properties when working with LD SS 2101 in comparison to SMAW.

Study on the Composition Design, Microstructure, Wear and Corrosion Resistant of Duplex Stainless Steels Based on Machine Learning

Study on the Composition Design, Microstructure, Wear and Corrosion Resistant of Duplex Stainless Steels Based on Machine Learning

Effect of annealing process on microstructure, residual stress, and fatigue behaviour of AISI 2205 duplex stainless steel

ABSTRACT This study investigated the microstructure, residual stress, and fatigue behavior of duplex stainless steels that have been annealed with different annealing processes. A cold-rolled AISI 2205 Duplex Stainless Steel (DSS) sample was annealed in three ways for this purpose. In modes 1 and 2, samples were annealed at 500°C for 6 and 8 hours, respectively. The sample was annealed for 6 hours at 950°C for mode 3.The Optical Microscopy (OM) technique was used to determine the crystallographic texture and microstructural characteristics. An X-ray Diffraction (XRD) analysis was used to determine the residual stresses in austenite and ferrite phases on pre- and post-heat-treated samples. The Scanning Electron Microscope (SEM) technique was utilized to assess fatigue cracks. The results showed that the texture microstructure of the specimens using mode 1 and 2 were remained; the grain had a smaller fragmentation. The elongation grains of the specimen after mode 3 were smaller, relatively spheroidal, and more homogeneous. There was a reduction in residual stress after mode 3 annealing process. The fatigue strength of the specimens that under applied this process was 11.1% higher than that of specimens in the as-received state.

Advancing Duplex Stainless Steel Microstructure: Synergistic Ferrite Grain Refinement and Austenite Formation Through Permanent Magnet Stirring

Advancing Duplex Stainless Steel Microstructure: Synergistic Ferrite Grain Refinement and Austenite Formation Through Permanent Magnet Stirring

Corrosion Study on Duplex Stainless Steel UNS S31803 Subjected to Solutions Containing Chloride Ions.

In the present work, the influence of a corrosive environment and temperature on the corrosion resistance properties of duplex stainless steel S31803 was evaluated. The corrosive process was carried out using solutions of 1.5% HCl (m/m) and 6% FeCl3 (m/m), at temperatures of 25 and 50 °C. The microstructure of UNS S31803 duplex stainless steel is composed of two phases, ferrite and austenite, oriented in the rolling direction, containing a ferrite percentage of 46.2% in the rolling direction and 56.1% in the normal direction. Samples, when subjected to corrosive media and temperature, tend to decrease their mechanical property values. It was observed, in both corrosive media, that with increasing test temperature, there is an increase in the corrosion rate, both uniform and pitting. The sample in HCl solution obtained a uniform corrosion rate of 0.85% at 25 °C and 0.92% at 50 °C and pitting rates of 0.77% and 1.47% at the same temperatures, respectively. When tested in FeCl3 solution, it obtained uniform corrosion of 0.0006% and 0.93% and pitting of 0.53% and 18.5%, at the same temperatures. A reduction in dissolution potentials is also noted, thus characterizing greater corrosion in the samples with increasing temperature.

Additive friction stir deposition of super duplex stainless steel: Microstructure and mechanical properties

Additive Friction Stir Deposition (AFSD) is an emerging solid-state metal additive manufacturing (AM) process that offers several key benefits, including high deposition rates and wrought-equivalent mechanical properties even in the as-deposited condition. The work presented is the first study to report on the development of microstructure and mechanical properties of AFSD-processed duplex stainless steel (DSS2507). The banded microstructure of the starting material was remarkably affected by AFSD processing; the austenite grains exhibited a refined and equiaxed morphology, while the ferrite grains appeared slightly larger and elongated. Microstructural observations revealed that the potential mechanism of microstructure evolution in austenite was discontinuous dynamic recrystallization (DDRX), while in ferrite, it was continuous dynamic recrystallization (CDRX). The occurrence of multiple thermal cycles during the AFSD process resulted in σ phase precipitation, which in turn led to considerable variation in mechanical properties with respect to the build direction. The top region of the as-built part with an insignificant σ phase fraction showed improved tensile strength and ductility combination compared to the as-received DSS2507 as well as other AM-processed DSS2507 alloys.

Evaluation of hydrogen interactions with defects induced by deformation in the duplex stainless steel microstructure: An internal friction study

Despite their good corrosion resistance and optimal mechanical properties, duplex stainless steels are affected by hydrogen embrittlement. Therefore, understanding the hydrogen-defect interactions in these steels is crucial. This study uses internal friction to evaluate the interactions of hydrogen with microstructural defects. Analysis of the internal friction spectra of the steels subjected to straining and hydrogen charging, together with thorough microstructural characterization, gives new insights in hydrogen interactions with defects present in the different phases, i.e. ferrite (body centered cubic) and austenite (face centered cubic).While no significant effect of tensile deformation can be observed by thermal desorption spectroscopy, the internal friction spectra show a clear influence of the presence of defects. Detailed analysis of these spectra reveals the interactions in the austenite as dominant, while no indications for hydrogen-dislocation interactions in ferrite are observed. This can be related to limited trapping in ferrite due to the austenite sink action or to limited dislocation formation in ferrite. Indications for hydrogen interactions with dislocations in the austenite are found, possibly suggesting enhanced dislocation mobility when surrounded by hydrogen. Moreover, a pronounced influence of hydrogen charging on the vacancy cluster related peaks is observed, indicating strong interactions between hydrogen and vacancy clusters in austenite. This can be put in contrast to behavior of pure ferritic steels, where dislocations provided the strongest hydrogen interactions. As these specific defects are of primary interest in the hydrogen embrittlement mechanisms, internal friction is concluded to provide important unique insights in hydrogen-defect interactions, even for complicated multiphase microstructures.

Influence of Shielding Gas on the Microstructure and Mechanical Properties of Duplex Stainless Steel in Wire Arc Additive Manufacturing

Influence of Shielding Gas on the Microstructure and Mechanical Properties of Duplex Stainless Steel in Wire Arc Additive Manufacturing

Impact of process parameters and gas atmospheres on density and microstructure of super duplex stainless steel produced by Laser Powder Bed Fusion

Super duplex stainless steel (2507 SDSS) is an alloy renowned for its excellent corrosion resistance and mechanical properties. This unique combination arises from a duplex microstructure characterized by austenite and ferrite. However, when processed using the laser powder bed fusion (LPBF) process, this steel contains only the ferritic phase due to the rapid cooling rates inherent in LPBF, which suppresses the formation of the austenitic phase. This study explores a parameter process optimization for this steel in two different atmospheres, Ar and N, with the latter being an austenite-stabilizing element intended to enhance the formation of the austenitic phase. A comparison of the optimal process windows between the two atmospheres is conducted, and the amount of austenitic content is evaluated as a function of the process parameters and the shielding gas employed. Findings demonstrate that utilizing a nitrogen atmosphere, in conjunction with process parameters that reduce normalized enthalpy and material evaporation, increases austenite content post-manufacture. Additionally, nitrogen as the processing gas effectively minimizes and stabilizes nitrogen content within the samples.

Build orientation and heat treatment effect on microstructure, mechanical and corrosion performance of super duplex stainless steel fabricated by laser powder bed fusion

Build orientation and heat treatment effect on microstructure, mechanical and corrosion performance of super duplex stainless steel fabricated by laser powder bed fusion

Microstructure and corrosion resistance of 23Cr9Ni4Mo2Mn filler duplex stainless steel 2205 fabricated by wire arc additive manufacturing with subsequent severe shot peening and Ni58Cr20Fe5Mo10 plasma spray coating

In the current study, 23Cr9Ni4Mo2Mn (FeAs) filler and duplex stainless steel 2205 materials were used in multi-layer deposition processes for wire arc additive manufacturing (WAAM) process. The WAAM samples were prepared with WAAM coated (WAAM-C) and Post-shot peening coated WAAM (PSPC-WAAM) in order to improve the microstructure and surface properties. The severe shot peening process and Ni58Cr20Fe5Mo10 plasma spray coating was increase the corrosion resistance and outer layer strength, whereas different types of structure were observed in the WAAM-DSS plates: Solid phase martensite (SPM), acicular austenite phase (AAS), FeCr2O4, martensite-austensite phase (MAP) and multi-phase ferrite structure. The severe shot peening procedure and Ni58Cr20Fe5Mo10 plasma spray coating samples were clearly visible in the Electron Backscatter Diffraction (EBSD) analyses, which also showed that the outer and inner surface layers of the samples contained CrFe2O4, NiFe2O4 cubic ferromagnetic oxide, and BiFeO3 phase. Direct mixing of the 23Cr9Ni4Mo2Mn filler with the base materials produced a homogenous structure with a high bonding strength. Bi1<001>, Bi2<111>, and Bi3<110> of the BiFeO3 crystal structure were discovered in the inner surface layer according to the PSPC-WAAM sample of angle 0–1800 texture results, whereas the WAAM-C sample of the outer layer revealed that As1<001>, As2 < 100>, and As3 < 111> of the α-martensite structure were exposed at the outer surface layer. PSPC-WAAM had a 6 % increase in hardness over WAAM-C in both the inner and outer surface regions. Hardness value of PSPC-WAAM was 286 HV on NiCr bulk structure demanded, whereas ferrite secondary phase of WAAM-C have increased the hardness value at 224 HV compared to the base materials. Both the PSPC-WAAM and WAAM-C samples achieved improved corrosion resistance and strong surface bonding. The WAAM, WAAM-C, and PSPC-WAAM samples were the subject of potential dynamic experiments, AFM and wear properties.

Sigma phase kinetics in DSS filler metals: A comparison of sigma phase formation in the as-welded microstructure of super duplex stainless steel and hyper duplex stainless steel

This study investigates and compares the kinetics of sigma phase formation in established Super Duplex Stainless Steel (SDSS) and recently developed Hyper Duplex Stainless Steel (HDSS) filler metal wires. Experimental sigma phase time-temperature-transformation (TTT) maps were developed, revealing nearly equivalent interface area/volume, resulting in similar sigma phase kinetics for 1% volume despite the higher Cr and Mo content in HDSS. However, the growth rate to 5% and 10% sigma phase volumes was slightly higher in HDSS. The sigma phase kinetics in both SDSS and HDSS were analyzed using the exponential Johnson-Mehl-Avrami-Kolmogorov (JMAK) approach based on experimental TTT data. Linearized plots from the JMAK calculations showed a transition in kinetics mechanism from eutectoid decomposition and interface-controlled growth to a diffusion-controlled growth stage in both materials. The higher volumes and morphologies of the sigma phase were found to be diffusion-dependent, mainly occurring during the second kinetics stage. The influence of HDSS's higher Cr and Mo content on the growth rate was observed for these higher volumes. For applications within the 1% sigma phase limit, both wires exhibited equivalent susceptibility to sigma phase formation, regardless of the higher alloying in HDSS.

Effect of welding processes on ferrite content, microstructure and mechanical properties of super duplex stainless steel 2507 welds

Abstract Super duplex stainless steel (SDSS) plates of 6 mm thickness have been welded using tungsten inert gas, activated tungsten inert gas, electron beam welding and friction stir welding processes. Among these, in the first two, melting and solidification of material occurs slowly whereas, it is faster in electron beam welding process and no melting occurs in friction stir welding. Macro and microstructural studies, hardness surveys, tensile tests and percentage of ferrite content were compared for all the welds. The ferrite–austenite phase balance is 50 % each, with electron beam weld metal at about 65 % ferrite. This showed the hardness of the weld metal and heat affected zones to be higher than base metal. The weldment joint efficiencies are more than 90 %. The fracture location is found to be in the weld metal for tungsten inert gas and activated tungsten inert gas weld, in the nugget for friction stir welds and in the base metal for electron beam welds. The ductility of electron beam weld joints is 32 % while it is around 20 % for the others. The preferred order while choosing the welding process should be activated tungsten inert gas welding, tungsten inert gas welding, electron beam welding, and friction stir welding.

Effect of aging on the microstructure and properties of ASTM A890 3A duplex stainless steel

Exposure of duplex stainless steels to high temperatures could result in microstructure changes generating precipitated phases and significantly affecting material properties. In this paper, the effects of aging at 450–850 °C on the microstructure and properties of ASTM A890 3A duplex stainless steel were studied. The microstructures were different after aging at different temperatures: only γ2 was precipitated after aging at 450 and 550 °C, γ2, M23C6, and σ phases were observed at 650 °C, and an additional phase of χ was found at 750 °C. Aging at 450 °C increased the strength of duplex stainless steel while aging at other temperatures negligibly affected strength. Aging at 450 °C and 650–850 °C significantly decreased the impact toughness. Correspondingly, the fracture was partially or completely transformed from a ductile fracture mode before aging to a brittle fracture mode after aging. Aging deteriorated the corrosion resistance of duplex stainless steel. Aging at 750 °C had the most significant effect: the breakdown potential decreased by 28%, and the membrane resistance decreased by 81.9% relative to those without aging. The above changes in properties were closely related to the embrittlement of duplex stainless steel at 475 °C and the precipitation of the σ-phase and χ-phase.

Effect of heat treatment atmospheres on microstructure evolution and corrosion resistance of 2205 duplex stainless steel weldments

The effects of post heat treatment atmosphere on microstructure and corrosion resistance of duplex stainless steel welded joints were investigated. Post weld heat treatment (PWHT) was carried out with and without protective atmospheres. Nitrogen and argon are used as protective gases individually. Detailed microstructure examination (optical and SEM) demonstrates that nitrides precipitates are highly observed in the welded zones for nitrogen protected samples. An observed drop of ferrite volume fraction in post weld heat treated samples compared with welded samples without heat treatment leading to corrosion resistance enhancement of heat treated welded joints. An exception for using nitrogen as heat treatment atmosphere a decreased corrosion resistance of weldments is investigated due to nitride precipitates. An increase in the weld zone hardness for post weld heat treated samples compared with base alloy. The initial hardness of duplex stainless steel was 286 Hv while average hardness of weld zone was 340, 411, 343, and 391 Hv for as welded, PWHT using air, argon, and nitrogen atmospheres, respectively. Weld zone hardness increased to 33, 44, 20, and 37%. A significant decrease in the ultimate tensile strength and elongation after PWHT. The initial Ultimate tensile strength duplex stainless steel base material was 734.9 MPa while Ultimate tensile strength of the welded joints was 769.3, 628.4, 737.8, and 681.4 MPa for the following conditions: as welded, PWHT using air, argon, and nitrogen atmospheres, respectively.

Effect of Heat Input on the Microstructure and Mechanical Properties of Local Dry Underwater Welded Duplex Stainless Steel

Duplex stainless steel welded metals were underwater local dry prepared on S32101 lean duplex stainless steel trapezoidal groove plates with a self-made drain cover employing Supercore 2205P flux-cored filler wire. Different heat inputs were employed to investigate the effects on mechanical characteristics and the microstructure of welded metals. The results demonstrated that as the heat was applied, austenite concentrations in the weld metals increased. It was found that the austenite concentration and the fraction of Σ3-austenite twin-grain boundaries followed the same trends. With increasing heat input, the recrystallized ferrite and austenite grains initially decreased and subsequently increased, whereas the fraction of interphase boundaries between special ferrite and austenite exhibited the reverse trend. With a heat input of 1.4 kJ/mm, the toughness and plasticity of the weld metals were enhanced by an increase in austenite content, Σ3 recrystallized grains, and austenite twin-grain boundaries. The plasticity and tensile strength values of the welded metal changed more when the heat input was raised from 1.0 to 1.2 kJ/mm than when it was raised from 1.2 to 1.4 kJ/mm. Considering energy conservation, it is recommended to adopt 1.2 kJ/mm for welding heat input.