Microscopic Pore Research Articles

Analysis of Spontaneous and Dynamic Imbibition Characteristics of Silica-Based Nanofluid in Microscopic Pore Structure of Tight Oil Reservoirs.

Imbibition behavior plays a crucial role in tight oil reservoir development, to increase tight oil production, a novel sodium lauryl ether sulfate (SLES) nanofluid was developed. Spontaneous and dynamic imbibition performance of nanofluid and the relative influencing factors were systematically investigated using the online low-field nuclear magnetic resonance (LF-NMR) technique. The microscopic mobilization characteristics and mechanism of nanofluid-enhanced matrix crude oil recovery in tight oil reservoirs were further explored. The experimental results showed that the proposed SLES nanofluid achieved the highest imbibition efficiency, and appropriate concentrations of nanoparticle and surfactant were helpful in enhancing the imbibition recovery. Excessive concentrations of chemical agents may block the tiny pores. A reasonable injection rate and shut-in time should be determined to fully leverage capillary forces for water phase imbibition and oil phase displacement as well as the displacement effect of the viscous force and increased water wetness of the rock surface provided by the nanofluid. In addition, NMR T2 cutoff was applied to distinguish the imbibition and displacement regions during dynamic imbibition process. The pore sizes corresponding to the T2 cutoff values after nanofluid and deionized (DI) water flooding were 0.6 and 5 μm, indicating that nanofluid considerably increased the movable crude oil in pores of tight oil reservoirs compared with DI water. Furthermore, imbibition behavior was dominant in micropores (<0.1 μm) and mesopores (0.1-1 μm), and displacement principally occurred in microfractures and macropores. Finally, the underlying mechanisms responsible for nanofluid enhanced oil recovery were related to wettability alteration, capillary pressure, and viscous force. This work provides further understanding of spontaneous and dynamic imbibition when employing nanofluid in tight oil reservoirs.

Experimental research on the flexural properties and pore structure characteristics of engineered geopolymer composites prepared by calcined natural clay

The synthesis of high ductility geopolymer composites using excavated natural clay is an economical and environmentally friendly method to realize the utilization of excavated natural clay. This paper presents an experimental research on the flexural properties and pore structure characteristics of engineered geopolymer composites (EGC) prepared by calcined natural clay. The EGC with different slag and fiber contents were prepared and the four-point bending tests were conducted on the EGC. The effect of slag and fiber content on the flexural strength, flexural deflection and flexural toughness were discussed. The microscopic pore structure characteristics of EGC were further analyzed. The optimal mixture ratio of calcined clay-based EGC with the highest flexural toughness was proposed. The results show that fiber can significantly enhance the flexural properties and cracking control ability of EGC. The ultimate flexural strength, flexural deflection, flexural strengthening index and flexural toughness of EGC all increase with increasing fiber content. The results also show the addition of 10.0% slag can increase the flexural strength and flexural toughness, while excessive slag content reduces the flexural properties. The EGC with 10.0% slag content and 2.5% fiber content exhibits excellent flexural properties and cracking control ability. The ultimate flexural strength and flexural toughness index reach 9.75 MPa and 486.11, showing the highest flexural toughness.

Investigation on the impact of CO2-Induced precipitation on microscopic pore structure of low-permeable reservoirs

CO2 injection into reservoirs might induce organic or inorganic precipitation in microscopic pores, and some of the pores are blocked by the precipitates, resulting in a decrease in the connectivity of pores and affecting oil recovery. In this paper, a set of experiments on CO2 displacement and CO2-water-oil-rock interaction are conducted to study the microscopic mechanisms of reservoir damage. In-situ Nuclear Magnetic Resonance (NMR) technology is applied to conduct the microscopic analysis of CO2-EOR and reservoir damage at real reservoir conditions. The results reveal that the particle size and the amount of inorganic precipitates formed in the formation water will increase with the rise of CO2 injection pressure, and the inorganic precipitates primarily consist of siderite and kaolinite. The change of NMR T2 spectra of the core samples reveals that the inorganic precipitates primarily block the small pores less than 0.89 μm. However, as a result of stronger mineral dissolution and solute transport, the pore volume of the large pores (greater than 0.89 μm) increases after the CO2-water-rock reaction. Ultimately, this interaction results in a 5.4% increment in pore volume. In addition, the displacement efficiency of water-saturated cores is improved after the first CO2 displacement, which indicates that CO2-water-rock interaction can effectively improve the seepage properties of reservoirs. Nevertheless, the reservoir damage caused by asphaltene precipitation during CO2 flooding is more significant. The asphaltene precipitation percentage in formation oil increases with the rise of CO2 injection pressure, reservoir temperature, and asphaltene content in virgin oil. CO2-induced asphaltene precipitation causes more severe blockage on small pores in comparison with large pores. After 2 h of CO2 injection to the oil-saturated core, permeability and oil recovery caused by CO2-induced precipitation decreased by 17.6% and 11.4%, respectively.

Study on the pore structure and permeability evolution of tight sandstone under liquid nitrogen freezing‐thawing cycles based on NMR technology

To further raise the gas extraction efficiency of the tight sandstone, the liquid nitrogen (LN2) freezing-thawing cycles method can be employed to improve the permeability of the low-permeability reservoirs. Permeability is generally regarded as a macroscopic description of the pore structure and usually has functional relationship to pore structure properties. The permeability of the rock is closely related to the change of microscopic pore structure. The permeability of rock depends on how the subzero temperatures changed the microscopic pore structure of rock, but it has not yet been confirmed obviously. In this study, the nuclear magnetic resonance (NMR) technique was adopted to investigate the pore structure evolution law and permeability of the tight sandstone with different LN2 freezing-thawing cycles. The results demonstrate that the LN2 freezing-thawing cycles promotes pore development and micro-fracture connection, and enhances the pore connectivity. The proportion of meso-pores, macro-pores and micro-fractures in the sandstone samples increases significantly, which provides a channel for the sandstone gas flow and extraction. Total porosity and effective porosity of the samples present a trend of rapid increase as the number of LN2 freezing-thawing cycles increasing, while the residual porosity decreases as the number of LN2 freezing-thawing cycles increasing. Coates model, SDR model (mean T2 model) and PP model were used to calculate and evaluate the permeability of the samples subjected to different LN2 freezing-thawing cycles. Furthermore, PP model can provide a better permeability estimate than the classical Coates and SDR model.

The influence of pore throat heterogeneity and fractal characteristics on reservoir quality: A case study of chang 8 member tight sandstones, Ordos Basin

The Chang 8 member of the Yanchang Formation in the Ordos Basin exhibits extensive development of tight sandstone reservoirs. In comparison to conventional reservoirs, these tight sandstone reservoirs demonstrate smaller pore-throat systems and stronger heterogeneity due to interactions between inherent sedimentary components and various diagenetic processes. To further investigate the influence of microscopic pore throat structure on macroscopic physical properties and oil content within the reservoir, a comprehensive study was conducted utilizing high pressure mercury injection, nuclear magnetic resonance, X-CT scanning, and other pore throat testing methods. This study was complemented by observation techniques such as polarizing microscope, scanning electron microscopy, and laser confocal imaging, to study the pore throat system of reservoirs under the influence of different sedimentary components and diagenesis. By comparison, it is observed that the radius of the primary pore throat system in the tight sandstone reservoir ranges from 0.01 to 1 μm. The structural characteristics of the pore throat system significantly impact the macroscopic physical properties of the reservoir. Due to variations in testing methods, high pressure mercury injection, nuclear magnetic resonance (NMR), and X-ray computed tomography (X-CT) reveal different fractal dimensions of the reservoir's pore throat system. Therefore, it is better to respectively utilize fractal dimension Df2, Df2-NMR, Df2-CT, and pore throat parameters to characterize the microscopic pore throat system with a radius ranging from 0.01 to 1 μm. The decrease in the average pore throat radius and the increased irregularity of pore shape contribute to heightened heterogeneity in the micro-pore throat structure within the reservoir. This negatively impacts its physical properties and oil content. Furthermore, it is important to note that the minimum threshold of pore throat radius plays a crucial role as a primary factor determining the fluid seepage capacity within this reservoir. Moreover, when isolated pores exist, reduced fluid mobility ensues, which further worsens the seepage conditions of the reservoir. The chlorite rims development reservoir shows a low fractal dimension in its micro-pore throats, contributing to superior macroscopic petrophysical properties and oil content. However, compression, siliceous cementation, and calcite cementation negatively impact the average pore throat radius by increasing micropores, inaccessible pores, and narrow throat content. This results in a stronger heterogeneity of the pore throat structure, leading to poor seepage conditions and lower oil content.

Enhanced sensitivity and broadband response in porous triple periodic minimal surface piezoresistive sensors for telemedicine applications

Wearable pressure sensors with outstanding performance have garnered significant attention in fields such as telemedicine. However, the development of sensors that achieve both adjustable high sensitivity and a wide response range remains a formidable challenge. To address these issues, we propose the development of a flexible piezoresistive sensor featuring simultaneous macro- and microstructures. This is achieved by constructing a complex macro-topological skeleton using Fused Deposition Molding (FDM) technology and integrating supercritical carbon dioxide (ScCO2) foaming technology for microscopic pore creation. The unique conductive network structure, coupled with the Triple Periodic Minimal Surface (TPMS) metamaterial framework and microscopic pore architecture, endows the piezoresistive sensors with exceptional sensing performance, including high sensitivity (12.13 MPa−1), a broad response range (exceeding 30 MPa), and long-term fatigue resistance (over 26,000 s cycles). In addition, the sensors are shielded from electromagnetic interference, with a maximum EMI shielding effectiveness of 53.2 dB for the TMFM with a thickness of 2.3 mm. The effects of varying porosities and foaming pressures on sensitivity were analyzed using finite element simulations. Owing to these remarkable features, multiple foot movement recognition was successfully demonstrated with volunteer participants by assembling sensing unit array modules. Based on this, an intelligent fall warning recognition system is developed using machine learning. This system accurately distinguishes four types of activity behaviors—standing, walking, spraining foot, and falling—with accuracy rates of 98.9 %, 97.1 %, 98.9 %, and 95.1 %, respectively. The system automatically generates an alarm pattern for detected fall behaviors. These findings suggest that the combination of TPMS skeleton and micropores structure offers a promising strategy for developing sensors with adjustable sensitivity and wide detection range for wearable devices. This technology holds significant potential for applications in telemedicine assistance, particularly for the elderly and other vulnerable populations.

Constant temperature and humidity combined with vacuum-steam pulsed steaming of Polygonatum cyrtonema rhizome: Quality attribute and browning mechanism

The quality of Polygonatum cyrtonema rhizome is considerably influenced by steaming, a post-harvest procedure; however, the mechanisms behind this quality formation are not well understood. This study explored two innovative streaming methods for Polygonatum cyrtonema rhizome: constant temperature and humidity steaming and drying (CTHSD) and constant temperature and humidity combined with vacuum-steam pulsed steaming and drying (CTH + VSPSD). Traditional atmospheric steaming, simmering, and drying (ASD) were also used. We evaluated the microstructure, colour and polysaccharide, reducing sugar, 5-hydroxymethylfurfural, amino acid, phenolics and diosgenin contents as well as its antioxidant capacity. Results indicated that all methods enhanced antioxidant activity, released phenolic compounds and disrupted the microscopic pore wall structure. The processed samples exhibited increased browning values owing to non-enzymatic browning reactions between amino acids and reducing sugars.Notably, the CTH + VSPSD method yielded the highest antioxidant capacity, better preservation of polysaccharides and lower levels of 5-hydroxymethylfurfural compared to other methods. Additionally, CTH + VSPSD reduced production time by 66.7 % while achieving a comparable colour profile to that of conventional ASD technology. Therefore, the CTH + VSPSD method shows great promise for producing high-quality Polygonatum cyrtonema rhizome products.

Study on the Impact of Microscopic Pore Structure Characteristics in Tight Sandstone on Microscopic Remaining Oil after Polymer Flooding.

As a non-renewable resource, oil faces increasing demand, and the remaining oil recovery rates in existing oil fields still require improvement. The primary objective of this study is to investigate the impact of pore structure parameters on the distribution and recovery of residual oil after polymer flooding by constructing a digital pore network model. Using this model, the study visualizes the post-flooding state of the model with 3DMAX-9.0 software and employs a range of simulation methods, including a detailed analysis of the pore size, coordination number, pore-throat ratio, and wettability, to quantitatively assess how these parameters affect the residual oil distribution and recovery. The research shows that the change in the distribution of pore sizes leads to a decrease in cluster-shaped residual oil and an increase in columnar residual oil. An increase in the coordination number increases the core permeability and reduces the residual oil; for example, when the coordination number increases from 4.3 to 6, the polymer flooding recovery rate increases from 24.57% to 30.44%. An increase in the pore-throat ratio reduces the permeability and causes more residual oil to remain in the throat; for example, when the pore-throat ratio increases from 3.2 to 6.3, the total recovery rate decreases from 74.34% to 63.72%. When the wettability changes from oil-wet to water-wet, the type of residual oil gradually changes from the difficult-to-drive-out columnar and film-shaped to the more easily recoverable cluster-shaped; for example, when the proportion of water-wet throats increases from 0.1:0.9 to 0.6:0.4, the water flooding recovery rate increases from 35.63% to 51.35%. Both qualitative and quantitative results suggest that the digital pore network model developed in this study effectively predicts the residual oil distribution under different pore structures and provides a crucial basis for optimizing residual oil recovery strategies.

Cellulose dissolution strategy modulates hierarchical porous structure of biomass derived carbon for supercapacitors

The vast majority of biomass derived carbon is prepared using a top-down process, however, this process lacks the freedom to design the microstructure of the derived carbon. To address this shortcoming, this study proposes a special bottom-up preparation strategy based on cellulose dissolution and breaks away from the constraints of the top-down preparation process. Research shows that this special preparation strategy can regulate the microscopic pore structure of derived carbon for application in supercapacitors. The target sample not only possesses excellent specific capacitance (512 F g−1 at 1 A g−1) and rate performance (71.1 % capacitance retention at 20 A g−1) in the three-electrode system, but also exhibits outstanding energy density (37.7 Wh kg−1 at 750 W kg−1) and cycle stability (capacity loss is 5.8 % after 5000 cycles) in the symmetric full capacitor. These exciting results herald the potential of the special preparation strategy proposed in this study to prepare high-quality biomass derived carbon suitable for supercapacitors.

Investigation on microscopic pore structure optimization and Lattice Boltzmann seepage law in coal modified by N-methylpyrrolidone composite solvents

This study evaluated the impact of composite solvents (1-butyl-3-methylimidazolium tetrafluoroborate [Bmim]BF4, sodium dodecyl sulfate (SDS), and N-methyl pyrrolidone (NMP)) on microscale pore-fracture structures and mesoscopic gas seepage in coal samples; by employing fractal theory and the Lattice Boltzmann method (LBM). Under combined application of three composite solvents: (1) there was a substantial 23.66 % increase in the scanning electron microscopy fractal dimension of the samples, which signifies enhanced complexity and nonhomogeneity of the samples; (2) the percentages of mesopores and macropores in the samples experienced a 10.64 % increase, resulting in a 20.45 % increase in overall porosity; (3) the effective pore fractal dimension (Da) and seepage pore fractal dimension (Ds) exhibited respective decreases of 3.05 % and 0.57 %; and (4) the average gas seepage velocity substantially increased by 53.57 %, with the optimal flow channel development position along the x-direction being closer to the exit (x = 170). These phenomena were attributed to the following: (1) introducing SDS reagents enhanced coal hydrophilicity; (2) NMP and [Bmim]BF4 aqueous solvents could more easily infiltrate the minuscule pores; (3) the synergy of the composite solvents disrupted the pore-fracture structures of the coal matrix, leading to a substantial increase in the aperture and area of the open pores; and (4) this process enhanced the connectivity, consequently increasing the average seepage velocity.

Experimental study on the macroscopic and microscopic properties of cement paste backfill after treatment with carbon dioxide carbonize filling slurries during the mixing process

Introducing CO2 during the mixing process of filling slurry for wet carbonation enables simultaneous carbonation and hydration reactions of the carbonated filling slurry (CSL). This study evaluates the microstructural evolution and strength development of carbonated cemented paste backfill (CCPB) under different carbonation times, and discusses the carbonation products and carbon sequestration of CCPB. The results reveal that introducing 99% pure CO2 at a flow rate of 1 L/min for 10 min into the filling slurry in a non-sealed container effectively optimizes the microscopic pore structure and mechanical properties of CCPB, achieving a carbon sequestration rate of 6.42%. Short-term carbonation leads to a continuous decrease in the T2 relaxation signal of CSL in the early hydration stage, enhancing pore structure by converting secondary pores to micropores. The main carbonation product is calcite crystalline CaCO3, which forms a dense carbonation layer on the surface of the tailings particles. However, prolonged carbonation results in the formation of microscopic pore encapsulation layer, hindering further CO2 diffusion, reducing carbonation efficiency, and deteriorating the mechanical properties of CCPB. With a carbonation time of 10 min, the UCS and EM of CCPB with different cement-to-tailings ratios show significant improvement, and the specimens exhibit lower fragmentation and fewer secondary cracks, maintaining better integrity after failure. In conclusion, the wet carbonation of filling slurry not only enhances the strength of the filling material but also achieves the reutilization of gaseous and solid wastes through carbon sequestration filling method, providing an efficient and eco-friendly solution for mine backfilling.

Experimental Study on the Frost Resistance of Basalt Fiber Reinforced Concrete.

In this paper, the effect of basalt fiber (BF) on the frost resistance of concrete under different curing conditions was investigated, and its frost resistance mechanism was analyzed. Three different curing conditions (normal curing, short-term curing, and seawater curing) were adopted, and concrete with different BF volume contents was designed. Freeze-thaw (FT) tests were carried out using the rapid freezing method to test the frost resistance of basalt fiber reinforced concrete (BFRC). Additionally, the mass loss rate (MLR), relative dynamic modulus of elasticity (RDME) change, and compressive strength reduction of specimens during the freeze-thaw cycles (FTCs) were evaluated. The results show that when the BF content is 0.15%, under normal curing, short-term curing, and seawater curing conditions, the residual compressive strength of BFRC after FTCs was increased by 5.4%, 28.1%, and 30.9%, respectively, compared to plain concrete. By incorporating BF into concrete, the development of microcracks can be effectively retarded, and damage generation during FTCs can be reduced. In addition, the microscopic morphological characteristics and pore structure characteristics of concrete further elucidate the frost resistance mechanism of BFRC from a microscopic perspective.

Polymer‐Sorbent Direct Air Capture Contactors with Complex Geometries 3D‐Printed via Templated Phase Inversion

AbstractLow‐cost direct air capture (DAC) systems require efficient gas–solid contactors. These contactors provide rapid rates of heat and mass transport with minimal pressure drops. Triply periodic minimal surfaces (TPMS) are a class of geometries that are shown to have heat transfer properties that exceed those of other geometries, and these benefits are expected to manifest in mass transfer as well due to the analogies between heat and mass transfer. However, creating TPMS contactors is difficult using conventional manufacturing techniques such as injection molding. Non‐solvent‐induced phase separation (NIPS) of a polymeric ink containing the adsorbent is one way to construct adsorption contactors with excellent mass transport rates, but contactors have to date only been fabricated in simple geometries (e.g., films, fibers). This study demonstrates that NIPS of polymeric inks occurs within a simultaneously‐dissolving, water‐soluble, 3D‐printed template. This templated phase inversion (TPI) technique can create seemingly unlimited macroscopic architectures, including TPMS contactors, using a variety of potential DAC adsorbents, including zeolite, silica, activated carbon, and metal–organic frameworks. SEM, micro‐computed tomography, and nitrogen adsorption experiments reveal the microscopic pore structures and macroscopic geometries of the resulting sorbent contactors. TPMS DAC contactors with poly(ethyleneimine)/silica adsorbents are shown to have CO2 capture performances that rival or exceed other contactor geometries.

Evolution of microscopic pore structure and deterioration mechanism of sandstone subjected to freeze-thaw cycles

Evolution of microscopic pore structure and deterioration mechanism of sandstone subjected to freeze-thaw cycles

Review on the Study of Microscopic Pore Structure and Seepage Characteristics

Pore structure, as the focus of researchers, is also one of the main contents of reservoir geological research, and the characteristics of percolation depend on the micro-pore structure of the reservoir. The study of the characteristics of fluid percolation in the reservoir plays an important role in formulating a reasonable oil and gas exploitation scheme. Understanding the micro pore structure of the reservoir, analyzing the pore throat structure inside the oil and gas reservoir, and systematically studying the micro seepage characteristics of the reservoir have far-reaching influence and great significance for the exploration and development of oil and gas fields.

Quantitative classification evaluation model for tight sandstone reservoirs based on machine learning

Tight sandstone reservoirs are a primary focus of research on the geological exploration of petroleum. However, many reservoir classification criteria are of limited applicability due to the inherent strong heterogeneity and complex micropore structure of tight sandstone reservoirs. This investigation focused on the Chang 8 tight reservoir situated in the Jiyuan region of the Ordos Basin. High-pressure mercury intrusion experiments, casting thin sections, and scanning electron microscopy experiments were conducted. Image recognition technology was used to extract the pore shape parameters of each sample. Based on the above, through grey relational analysis (GRA), analytic hierarchy process (AHP), entropy weight method (EWM) and comprehensive weight method, the relationship index Q1 between initial productivity and high pressure mercury injection parameters and the relationship index Q2 between initial productivity and pore shape parameters are obtained by fitting. Then a dual-coupled comprehensive quantitative classification prediction model for tight sandstone reservoirs was developed based on pore structure and shape parameters. A quantitative classification study was conducted on the target reservoir, analyzing the correlation between reservoir quality and pore structure and shape parameters, leading to the proposal of favourable exploration areas. The research results showed that when Q1 ≥ 0.5 and Q2 ≥ 0.5, the reservoir was classified as type I. When Q1 > 0.7 and Q2 > 0.57, it was classified as type I1, indicating a high-yield reservoir. When 0.32 < Q1 < 0.47 and 0.44 < Q2 < 0.56, was classified as type II. When 0.1 < Q1 < 0.32 and 0.3 < Q2 < 0.44, it was classified as type III. Type I reservoirs exhibit a zigzag pattern in the northwest part of the study area. Thus, the northwest should be prioritized in actual exploration and development. Additionally, the initial productivity of tight sandstone reservoirs showed a positive correlation with the porosity, permeability, sorting coefficient, coefficient of variation, and median radius. Conversely, it demonstrated a negative correlation with the median pressure and displacement pressure. The perimeters of pores, their circularity, and the length of the major axis showed a positive correlation with the porosity, permeability, sorting coefficient, coefficient of variation, and median radius. On the other hand, they exhibited a negative correlation with the median pressure and displacement pressure. This study quantitatively constructed a new classification and evaluation system for tight sandstone reservoirs from the perspective of microscopic pore structure, achieving an overall model accuracy of 93.3%. This model effectively predicts and evaluates tight sandstone reservoirs. It provides new guidance for identifying favorable areas in the study region and other tight sandstone reservoirs.

High-capacity and high-stability capacitive desalination with dual redox-active MnCo2S4/g-C3N4 heterojunction electrode

Capacitive deionization (CDI) utilizing dual redox-active electrodes has shown significant promise in desalinating low-concentration brackish waters, which is crucial for addressing global freshwater shortages. However, improvements in salt adsorption capacity and long-term operational stability are still required. In this study, we introduce, for the first time, a binary metal sulfide MnCo2S4/g-C3N4 (MCS-CN) heterojunction as a CDI electrode. The innovative integration of dual redox-active centers and heterojunction structures in the MCS-CN composite electrodes underscores their potential for achieving both high capacity and stability in capacitive desalination applications. The microscopic morphology, crystal structure, pore structure, and surface valence properties of the MCS-CN heterojunction composite materials were extensively characterized using various analytical techniques. In-situ X-ray diffraction, refined ex-situ X-ray photoelectron spectroscopy, three-electrode electrochemical analysis, and theoretical calculations were employed to elucidate the electrosorption and desorption mechanisms of sodium ions with the MCS-CN electrodes and to clarify the enhanced desalination performance of the binary metal sulfide-based heterojunction structure. As a result, the optimal MCS-CN-40 electrode exhibited the highest salt removal capacity of 71.64 mg g−1 and maintained stable desalination performance over 100 cycles in a 500 mg L−1 NaCl solution. This innovative approach provides a noval perspective for developing heterojunction electrodes with high redox activity and efficient desalination performance.

A new fractal model for flow-solid-chemical multi-field coupling in underground engineering

The permeation diffusion behavior of chloride ions with seawater is one of the key factors causing damage to reinforced concrete structures due to seawater erosion of steel bars. This study establishes a new mathematical model for chloride ion transport in reinforced concrete structures exposed to seawater. The model captures the effect of chloride ions on underwater tunnel structures effectively and provides a valuable theoretical basis for the maintenance and safety of these structures. The proposed model uniquely incorporates the microscopic pore structure characteristics of concrete and the effects of static water pressure and porosity on chloride ion diffusion. The results show that: (1) the diffusion coefficient of chloride ions first increases rapidly, then remains basically unchanged and gradually decreases; (2) there is a non-linear positive correlation between porosity, static water pressure, and maximum corrosion thickness; and (3) the fractal dimension of pore curvature is opposite to the fractal dimension of pore size and crack length.

Micro-morphology and fractal characteristics of pore structure of aeolian sand concrete under long-term semi-immersion with chloride solution

To investigate the influence of chloride exposure on hydraulic concrete, we investigated the microstructural changes and pore evolution of aeolian sand concrete (ASC) during prolonged semi-immersion in chloride solution. Our analysis included examining the mass loss rate, relative dynamic elastic modulus, and maximum depth of chloride erosion. Utilizing scanning electron microscopy (SEM), X-ray diffraction (XRD), and nuclear magnetic resonance (NMR), we assessed the microscopic morphology and pore structure evolution. Additionally, we employed fractal theory to evaluate pore structure heterogeneity in ASC before and after exposure to chloride erosion. After 450 days of chloride erosion, ASC displayed minimal changes in mass loss rate and relative dynamic elastic modulus, with a maximum erosion depth of 9.8 mm. Chlorides adhered to the immersed end at the concrete's base and migrated from the surface to the exposed top end during erosion. The erosion depth at the top end ranged from 23.9 % to 25.9 % of that at the bottom end. Within ASC, hydration products reacted with chlorides, resulting in the formation of Friedel's salt, a characteristic corrosion crystal. Following erosion, the total porosity of ASC increased, accompanied by shifts in pore size distribution. The internal structure of ASC underwent distinctive evolution, transitioning from small to large pores. ASC consistently exhibited fractal properties both before and after erosion. The fractal dimension D1 demonstrated an inverse relationship with pores of radius (r) less than 0.01 μm, while D2 was directly proportional to pores with r ≤ 0.01 μm and 0.01 <r ≤ 0.1 μm, and inversely proportional to pores with 1 <r ≤ 10 μm and r > 10 μm. This study significantly contributes to the theoretical understanding of ASC's endurance mechanisms in chloride environments.

Impact mechanism of microscopic pore structure on sensitivity and ability of CO2-ECBM based on X-ray nano-CT

To scientifically explain the mechanism of increasing CBM production by CO2 injection pressure from the microscopic scale, and effectively evaluate the CBM production enhancement potential, adopting the fluid intrusion method and ray non-destructive testing technique, this research reconstructed the real coal microscopic pore structure and carried out the microscopic scale numerical simulation of CO2-ECBM. The results indicate that there exists a limit to the magnitude of growth in CO2-ECBM displacement efficiency driven by gas injection pressure. The pressure sensitivity, enhancing potential, and production enhancement ability of CO2-ECBM change continually over time. In high metamorphic coal reservoirs, the disadvantages of the engineering cycle, absolute displacement efficiency, and CBM production-increasing ability are obvious, while pressure sensitivity and enhancing potential are higher in the middle and late stages. The differences exhibited by CO2-ECBM in different metamorphic coals are attributed to the pore structure quality. Specifically, high-quality pores have the characteristics of convenient passage, multiple paths, and higher pore surface areas. The findings can enrich the CO2-ECBM production enhancement mechanism in different coal seams, providing new theoretical viewpoints for accurately assessing its application effect and production enhancement potential.