Micro-orifice Uniform Deposit Impactor Research Articles

WSOC in accumulation mode aerosols: Distribution and relationship with BrC light absorption at an urban background site

This paper presents the outcomes of a one-month long campaign (Jan 11, 2021 to Feb 11, 2021) of size segregated particulate matter (PM) in the accumulation mode (AM). Samples were collected at an urban background station (southeastern Iberian Peninsula) using a micro-orifice uniform deposit impactor (MOUDI). PM mass and water-soluble organic carbon (WSOC) were subsequently measured. The main goals of this research were: (1) to explore differences in WSOC mass size distributions under different meteorological conditions and (2) to determine the most efficient size for light absorption by WSOC. For the second objective, measurements of absorption coefficients (σap,λ) were obtained by means of an Aethalometer (AE33). Significant differences in WSOC concentrations and σap,λ values during stagnation episodes compared to non-event days were observed. Increases in WSOC concentrations during these episodes were most likely associated with the photochemical production of secondary compounds (in small-size ranges of the AM) and with water uptake (in large-size ranges of the AM). The average σap,λ value during this type of event was 2.6 higher than for non-event days. No significant increases in WSOC levels were detected under Saharan dust events. The average contribution of BrC to light absorption at 370 nm was ∼35%, revealing a significant influence of BrC on the absorption process. High contributions from BrC to light absorption were associated with AAE values above 1.5 and, in general, with high WSOC concentrations. WSOC in the smallest size mode (0.25 μm) was mainly emitted from biomass burning (BB) and showed the highest light absorption efficiency.

Size-Resolved Identification and Quantification of Micro/Nanoplastics in Indoor Air Using Pyrolysis Gas Chromatography-Ion Mobility Mass Spectrometry.

Humans are exposed to differing levels of micro/nanoplastics (MNPs) through inhalation, but few studies have attempted to measure <1 μm MNPs in air, in part due to a paucity of analytical methods. We developed an approach to identify and quantify MNPs in indoor air using a novel pyrolysis gas chromatographic cyclic ion mobility mass spectrometer (pyr-GCxcIMS). Four common plastic types were targeted for identification, namely, (polystyrene (PS), polyethylene (PE), polypropylene (PP), and polymethyl methacrylate (PMMA). The method was applied to size-resolved particulate (56 nm to 18 μm) collected from two different indoor environments using a Micro-Orifice Uniform Deposit Impactors (MOUDI) model 110 cascade impactor. Comprehensive two-dimensional separation by GCxcIMS also enabled the retrospective analysis of other polymers and plastic additives. The mean concentrations of MNP particles with diameters of <10 μm and <2.5 μm in the laboratory were estimated to be 47 ± 5 and 27 ± 4 μg/m3, respectively. In the private residence, the estimated concentrations were 24 ± 3 and 16 ± 2 μg/m3. PS was the most abundant MNP type in both locations. Nontargeted screening revealed the presence of plastic additives, such as TDCPP (tris(1,3-dichloro-2-propyl)phosphate) whose abundance correlated with that of polyurethane (PU). This is consistent with their use as flame retardants in PU-based upholstered furniture and building insulation. This study provides evidence of indoor exposure to MNPs and underlines the need for further study of this route of exposure to MNPs and the plastic additives carried with them.

A methodology for occupational exposure assessment of organic pollutants emitted through aerosols from recycling of e‐waste

AbstractEmission of airborne particulate matter is produced by the industrial processes of metal extraction from electronic waste (e‐waste). These aerosols can transport organic contaminants, such as polyaromatic hydrocarbons (PAHs) and polybrominated biphenyls. These pollutants are proven to have long‐term effects on workers' health. In this work, we characterize aerosol particles and dust deposited from a recycling process of printed circuit boards in a recycling plant. This study also explores the significance of the secondary aerosol sources, and their importance, as an additional burden compared to primary sources. A Scanning Mobility Particles Counter and Sizer (SMPCS) was used to measure the size distributions of ultrafine particles. A Micro‐Orifice Uniform Deposition Impactor (MOUDI) collected aerosol particle samples for chemical analysis. All plant compartments checked are subject to high particulate matter concentrations during work hours. Concentrations of organic pollutants in the machinery compartments do not pose a short or long‐term health risk according to US Occupational Safety and Health Administration (OHSA). The application of the model presented in this work revealed that the accumulation of contaminants in other compartments should be considered in an occupational exposure assessment because it can present an equally important burden to workers’ health.

Significant changes in size distribution of aerosols in Beijing after clean air actions

Over the past few years, the physicochemical characteristics and sources of aerosols have changed following the implementation of strict clean air policies in Beijing. In this study, size-segregated particulate matters (PM) were collected using a micro-orifice uniform deposit impactor (MOUDI) in Beijing from July 2021 to June 2022 to understand the responses of particle size distribution and chemical composition to the implemented emission reduction measures. The results showed that although particulate pollution greatly improved, it is still severe in Beijing, especially in autumn and winter, with the annual average PM1.8 (aerosol particle with aerodynamic diameter less than 1.8 μm) concentration reaching 46.7 ± 37.4 μg/m3. NO3− was the most abundant ion in the particles throughout all seasons, and its proportion to water-soluble inorganic ions increased significantly with the aggravation of pollution. This highlights the importance and urgency of controlling mobile sources in future control measures. The highest concentration of SO42− occurring during summer demonstrates the effectiveness of fossil fuel combustion control in winter. The measured size distributions of PM and secondary inorganic ions were trimodal, which significantly differed from the observations conducted in Beijing using MOUDI before 2017, in which the measured size distributions of PM and secondary inorganic ions were bimodal. The enhancement of atmospheric oxidation and reduction of gaseous precursors can affect the formation path of aerosols, and thus, their particle size distribution. Aerosol aqueous-phase reactions play a vital role in pollution development, with the droplet mode further growing hygroscopically into a coarse mode during pollution maintenance.

Characterization of the Emissions and Crystalline Silica Content of Airborne Dust Generated from Grinding Natural and Engineered Stones.

In this study, we systematically characterized the airborne dust generated from grinding engineered and natural stone products using a laboratory testing system designed and operated to collect representative respirable dust samples. Four stone samples tested included two engineered stones consisting of crystalline silica in a polyester resin matrix (formulations differed with Stones A having up to 90wt% crystalline silica and Stone B up to 50wt% crystalline silica), an engineered stone consisting of recycled glass in a cement matrix (Stone C), and a granite. Aerosol samples were collected by respirable dust samplers, total dust samplers, and a Micro-Orifice Uniform Deposit Impactor. Aerosol samples were analyzed by gravimetric analysis and x-ray diffraction to determine dust generation rates, crystalline silica generation rates, and crystalline silica content. Additionally, bulk dust settled on the floor of the testing system was analyzed for crystalline silica content. Real-time particle size distributions were measured using an Aerodynamic Particle Sizer. All stone types generated similar trimodal lognormal number-weighted particle size distributions during grinding with the most prominent mode at an aerodynamic diameter of about 2.0-2.3 μm, suggesting dust formation from grinding different stones is similar. Bulk dust from Stone C contained no crystalline silica. Bulk dust from Stone A, Stone B, and granite contained 60, 23, and 30wt% crystalline silica, respectively. In Stones A and B, the cristobalite form of crystalline silica was more plentiful than the quartz form. Only the quartz form was detected in granite. The bulk dust, respirable dust, and total dust for each stone had comparable amounts of crystalline silica, suggesting that crystalline silica content in the bulk dust could be representative of that in respirable dust generated during grinding. Granite generated more dust per unit volume of material removed than the engineered stones, which all had similar normalized dust generation rates. Stone A had the highest normalized generation rates of crystalline silica, followed by granite, Stone B, and Stone C (no crystalline silica), which likely leads to the same trend of respirable crystalline silica (RCS) exposure when working with these different stones. Manufacturing and adoption of engineered stone products with formulations such as Stone B or Stone C could potentially lower or eliminate RCS exposure risks. Combining all the effects of dust generation rate, size-dependent silica content, and respirable fraction, the highest normalized generation rate of RCS consistently occurs at 3.2-5.6 µm for all the stones containing crystalline silica. Therefore, removing particles in this size range near the generation sources should be prioritized when developing engineering control measures.

Source apportionment and evolution of N-containing aerosols at a rural cloud forest in Taiwan by isotope analysis

Abstract. Ammonium and nitrate are major N-containing aerosol components. The deposition of N-containing aerosols has impacts on regional ecology and the biogeochemical cycle. In this study, aerosols in a rural cloud forest (Xitou in Taiwan) were studied using 15N and 18O isotope analysis to assess the sources and formation pathways of the local N-containing aerosols linking to a metropolitan. Aerosol samples of different size ranges were collected using a micro-orifice uniform deposit impactor (MOUDI) on a half-day basis in December 2018. The chemical functional groups were analyzed using a Fourier-transform infrared spectroscopy with attenuated total reflection (FTIR-ATR) technique, while the isotope analysis was performed using a gas chromatography–isotope ratio mass spectrometer (GC–IRMS). The average measured aerosol concentration (PM10) was 0.98 (ranging from 0.15 to 3.31) and 0.25 (ranging from 0.00 to 1.51) µg m−3 for NH4+ and NO3-, respectively. In general, a higher concentration than nighttime was observed during the daytime by a factor of 1.5–6, likely due to the transportation of pollutants from upper-stream urban and industrial regions through the local sea breeze combined with valley wind. The presence of fog can further elevate the concentration by a factor of 2–3, resulting from the stronger inversion and lower boundary layer height. The higher NH4+ concentration in fine particles under foggy conditions corresponds to submicron-sized NO3- formation via aqueous-phase dissolution with NH4+ neutralization. Furthermore, the higher RH during fog events shifted the mass distribution of aerosol functional groups to a larger mode size. By comparing the δ15N value directly or through the analysis using a statistical isotope mixing model, MixSIAR, NH4+ probably originated from the industries, coal-fired power plants (CFPPs), or fertilizer plants, while NO3- might be contributed from the CFPP, industrial or urban sources. The overall δ18O of NO3- is +72.66 ‰ ± 3.42 ‰, similar to that in other winter Asian studies, suggesting the major formation pathway via O3 oxidation (δ18O=+72.5 ‰ to 101.67 ‰). However, a lower δ18O (&lt;+67 ‰) for particles less than 0.56 µm during foggy daytime suggests the local contribution via the peroxyl radical oxidation before partitioning into aerosol phase under foggy conditions. Overall, the δ15N and δ18O distribution profiles as a function of particle size in the studied rural forest site reveal the evolution of aerosol composition from remote coastal regions with chemical processes along the transport process, which can be further affected by weather conditions such as fog events.

Per- and polyfluoroalkyl substances in the atmosphere of waste management infrastructures: Uncovering secondary fluorotelomer alcohols, particle size distribution, and human inhalation exposure.

Per- and polyfluoroalkyl substances (PFAS) have been applied in numerous industrial and consumer products, the majority of which flow into waste management infrastructures (WMIs) at the end of their life cycles, but little is known about atmospheric releases of PFAS from these facilities. In this study, we addressed this key issue by investigating 49 PFAS, including 23 ionic and 26 neutral and precursor PFAS, in the potential sources (n=4; within or adjacent to WMIs) and reference sites (n=2; coastal and natural reserve sites) in urban and rural areas of Hong Kong, China. Duplicate samples of air and size-segregated particulate matter were collected for 48h continuously using a 11-stage Micro-Orifice Uniform Deposit Impactor (MOUDI). In general, fluorotelomer alcohols (FTOHs) and perfluoroalkane sulfonamides were the predominant PFAS classes found across sampling sites. We also demonstrated the release of several less frequently observed semivolatile intermediate products (e.g., secondary FTOHs) during waste treatment. Except for perfluorooctane sulfonate, the size-segregated distributions of particulate PFAS exhibited heterogeneity across sampling sites, particularly in the WMIs, implying combined effects of sorption affinity and emission sources. A preliminary daily air emission estimation revealed that landfill was a relatively important source of PFAS relative to the wastewater treatment plant. A simplified International Commission on Radiological Protection model was used to estimate lung depositional fluxes, and the results showed that inhaled particulate PFAS were mainly deposited in the head airway while fine and ultrafine particles carried PFAS deeper into the lung alveoli. The cumulative daily inhalation dose of gaseous and particulate PFAS ranged from 81.9 to 265pg/kg/d. In-depth research is required to understand the health effect of airborne PFAS on workers at WMIs.

Disposable E-Cigarettes and Associated Health Risks: An Experimental Study.

The use of electronic nicotine delivery systems (ENDS), including disposable e-cigarettes, has been prevalent. Existing chemical analyses of ENDS focused on e-liquids rather than aerosols and failed to consider particle sizes and aerosol respiratory deposition fractions, which are key factors for inhalation doses. This study investigated the organic chemical and metal constituents in size-segregated ENDS aerosol and assessed the deposited doses and health risks of these substances. Aerosol chemical analyses were conducted on two popular disposable ENDS products: Puff Bar (Grape) and Air Bar (Watermelon Ice). An ENDS aerosol was generated and delivered into a Micro-Orifice Uniform Deposit Impactor to collect size-segregated aerosol samples, in which organic chemicals and metals were analyzed. Daily and lifetime doses for each chemical were estimated. Cancer and non-cancer risk assessments were conducted based on the deposited doses. We found that e-cigarette aerosol contains certain harmful organic chemicals and metals documented to result in respiratory problems. Estimated respiratory cancer risks corresponding to chromium from both ENDS products and nickel from Air Bar (Watermelon Ice) were substantially above the conventionally acceptable risk. The method, findings, and implications can contribute to the extant literature of ENDS toxicity studies as well as inform tobacco regulation and future large-scale studies.

Mexican agricultural soil dust as a source of ice nucleating particles

Abstract. Agricultural soil erosion, both mechanical and eolic, may impact cloud processes, as some aerosol particles are able to facilitate ice crystal formation. Given the large agricultural sector in Mexico, this study investigates the ice nucleating abilities of agricultural dust collected at different sites and generated in the laboratory. The immersion freezing mechanism of ice nucleation was simulated in the laboratory via the Universidad Nacional Autónoma de México (UNAM) microorifice uniform deposit impactor (MOUDI) droplet freezing technique (DFT), i.e., UNAM-MOUDI-DFT. The results show that agricultural dust from the Mexican territory promote ice formation in the temperature range from −11.8 to −34.5 ∘C, with ice nucleating particle (INP) concentrations between 0.11 and 41.8 L−1. Furthermore, aerosol samples generated in the laboratory are more efficient than those collected in the field, with T50 values (i.e., the temperature at which 50 % of the droplets freeze) higher by more than 2.9 ∘C. Mineralogical analysis indicated a high concentration of feldspars, i.e., K-feldspar and plagioclase (&gt;40 %), in most of the aerosol and soil samples, with K-feldspar significantly correlated with the T50 of particles with aerodynamic diameters between 1.8 and 3.2 µm. Similarly, the organic carbon (OC) was correlated with the ice nucleation efficiency of aerosol samples from 3.2 to 5.6 and from 1.0 to 1.8 µm. Finally, a decrease in INP efficiency after heating the samples at 300 ∘C for 2 h indicates that the organic matter from agricultural soils plays a predominant role in the ice nucleating abilities of this type of aerosol sample.

Characteristics of Particles and Debris Released after Implantoplasty: A Comparative Study.

Titanium particles embedded on peri-implant tissues are associated with a variety of detrimental effects. Given that the characteristics of these detached fragments (size, concentration, etc.) dictate the potential cytotoxicity and biological repercussions exerted, it is of paramount importance to investigate the properties of these debris. This study compares the characteristics of particles released among different implant systems (Group A: Straumann, Group B: BioHorizons and Group C: Zimmer) during implantoplasty. A novel experimental system was utilized for measuring and collecting particles generated from implantoplasty. A scanning mobility particle sizer, aerodynamic particle sizer, nano micro-orifice uniform deposit impactor, and scanning electron microscope were used to collect and analyze the particles by size. The chemical composition of the particles was analyzed by highly sensitive microanalysis, microstructures by scanning electron microscope and the mechanical properties by nanoindentation equipment. Particles released by implantoplasty showed bimodal size distributions, with the majority of particles in the ultrafine size range (<100 nm) for all groups. Statistical analysis indicated a significant difference among all implant systems in terms of the particle number size distribution (p < 0.0001), with the highest concentration in Group B and lowest in Group C, in both fine and ultrafine modes. Significant differences among all groups (p < 0.0001) were also observed for the other two metrics, with the highest concentration of particle mass and surface area in Group B and lowest in Group C, in both fine and ultrafine modes. For coarse particles (>1 µm), no significant difference was detected among groups in terms of particle number or mass, but a significantly smaller surface area was found in Group A as compared to Group B (p = 0.02) and Group C (p = 0.005). The 1 first minute of procedures had a higher number concentration compared to the second and third minutes. SEM-EDS analysis showed different morphologies for various implant systems. These results can be explained by the differences in the chemical composition and microstructures of the different dental implants. Group B is softer than Groups A and C due to the laser treatment in the neck producing an increase of the grain size. The hardest implants were those of Group C due to the cold-strained titanium alloy, and consequently they displayed lower release than Groups A and B. Implantoplasty was associated with debris particle release, with the majority of particles at nanometric dimensions. BioHorizons implants released more particles compared to Straumann and Zimmer. Due to the widespread use of implantoplasty, it is of key importance to understand the characteristics of the generated debris. This is the first study to detect, quantify and analyze the debris/particles released from dental implants during implantoplasty including the full range of particle sizes, including both micro- and nano-scales.

Development of a thermal spray coating aerosol generator and inhalation exposure system

Thermal spray coating involves spraying a product (oftentimes metal) that is melted by extremely high temperatures and then applied under pressure onto a surface. Large amounts of a complex metal aerosol (e.g., Fe, Cr, Ni, Zn) are formed during the process, presenting a potentially serious risk to the operator. Information about the health effects associated with exposure to these aerosols is lacking. Even less is known about the chemical and physical properties of these aerosols. The goal was to develop and test an automated thermal spray coating aerosol generator and inhalation exposure system that would simulate workplace exposures. An electric arc wire-thermal spray coating aerosol generator and exposure system was designed and separated into two areas: (1) an enclosed room where the spray coating occurs; (2) an exposure chamber with different measurement devices and controllers. The physicochemical properties of aerosols generated during electric arc wire-thermal spray coating using five different consumable wires were examined. The metal composition of each was determined by inductively coupled plasma-atomic emission spectroscopy (ICP-AES), including two stainless-steel wires [PMET720 (82 % Fe, 13 % Cr); PMET731(66 % Fe, 26 % Cr)], two Ni-based wires [PMET876 (55 % Ni, 17 % Cr); PMET885 (97 % Ni)], and one Zn-based wire [PMET540 (99 % Zn)]. The particles generated regardless of composition were poorly soluble, complex metal oxides and mostly arranged as chain-like agglomerates and similar in size distribution as determined by micro-orifice uniform deposit impactor (MOUDI) and electrical low-pressure impactor (ELPI). To allow for continuous, sequential spray coating during a 4-hr exposure period, a motor rotated the metal pipe to be coated in a circular and up-and-down direction. In a pilot animal study, male Sprague-Dawley rats were exposed to aerosols (25 mg/m3 × 4 h/d × 9 d) generated from electric arc wire- thermal spray coating using the stainless-steel PMET720 consumable wire. The targeted exposure chamber concentration was achieved and maintained during a 4-hr period. At 1 d after exposure, lung injury and inflammation were significantly elevated in the group exposed to the thermal spray coating aerosol compared to the air control group. The system was designed and constructed for future animal exposure studies to generate continuous metal spray coating aerosols at a targeted concentration for extended periods of time without interruption.

Characterization of Ambient Particulate Matters in an Industry-Intensive Area in Central Taiwan

Atmospheric particulate matters (PMs) were measured in an industry-intensive region in central Taiwan in order to investigate the characteristics and possible sources of PMs. The samplings were simultaneously conducted using a 10- and 3-stage Micro Orifice Uniform Deposit Impactor (MOUDI) from 2017 to 2018. In this study, the characteristics of PMs in this region were evaluated by measuring the mass concentration of PMs and analyzing water-soluble ions and metallic elements, as well as dioxins. Additionally, principal component analysis (PCA) was used to identify the potential sources of PMs. The results showed that the mean concentration of coarse (&gt;1.8 μm), fine (0.1–1.8 μm), and ultrafine (&lt;0.1 μm) particles were 13.60, 14.38, and 3.44 μg/m3, respectively. In the industry-intensive region, the size distribution of ambient particles showed a bi-modal distribution with a high concentration of coarse particles in the spring and summer, while fine particles were dominant in the autumn and winter. The most abundant water-soluble ions of PMs were NO3−, Cl−, and SO42−, while the majority of metallic elements were Na, Fe, Ca, Al, and Mg in different particle sizes. The results of Pearson’s correlation analysis for metals indicated that the particles in the collected air samples were related to the iron and steelmaking industries, coal burning, vehicle exhausts, and high-tech industries. The dioxin concentration ranged from 0.0006 to 0.0017 pg I-TEQ/Nm3. Principal component analysis (PCA) revealed that the contribution to PMs was associated with sea salt, secondary pollutants, and industrial process.

Particulate Matter as a Giant Fraction of Fossil Fuel in Urbanized Areas

Fossil fuel injects particulate matter into a clean environment which has diverse effects on the biosphere. It is the cry of the masses which stimulates investigation of the local ambient environment for Particulate Matter (PM) and its sources. The purpose has been achieved by using versatile techniques such as Micro-Orifice Uniform Deposit Impactor (MOUDI™) for collection, Fourier Transform Infrared (FTIR) Spectrometry for characterization by Size Mass Concentration, and Atomic Absorption Spectroscopy techniques were utilized to identify and quantify different PM in the study area. The urban territories (different locations of Okara) were found contaminated with coarse, fine, and ultra-fine Particulate matter because of local industries and vehicular emissions. Coarse particles (PM10) of size 3.2 µm and 10 µm, fine particles (PM2.5) and Ultra-fine particles (0.056 µm) were quantified around 8 ?g/m3, 10 ?g/m3 and 25 ?g/m3 respectively. The obtained results could be linked with the widespread use of low-quality fossil fuels and the increased number of vehicles. The ultimate solution to the prevailing scenario can be in hand by switching over to renewable energies such as solar, hydrogen, and wind.

Outdoor/Indoor Contaminant Transport by Atmospheric Dust and Aerosol at an Active Smelter Site

Activities associated with mining operations including smelting, ore handling, and mine tailings management have been identified as sources of dust and aerosol that may contain metal and metalloid contaminants, such as lead (Pb) and arsenic (As). Previous studies on contaminant transport have concentrated on the potential impact of these particulate emissions in outdoor environments. The purposes of this study were (i) to quantify the effect of dust and aerosol particle size on contaminant transport from outdoor-to-indoor environments and (ii) to document the changes in particle chemical composition during transport through the outdoor/indoor barrier. Outdoor and indoor particulate samples were collected at a high school equipped with mechanical air filtration systems from 2016 to 2019. The school is located near a set of mine tailings and an active copper smelter in Hayden, Arizona. Particle size segregated samples were collected using a ten-stage micro-orifice uniform deposit impactor (MOUDI). Results show that airborne fine particles (aerodynamic diameters less than 1 micron) can penetrate to the indoor environment but in a reduced amount due to mechanical filtration. Aerosol in the fine fraction particulate air concentrations was around 50% of the corresponding outdoor values, but their mass concentration of contaminants was similar to outdoor values. Indoor coarse particles (> 1 micron) comprised close to 20% of the levels found in outdoor coarse particles. These results highlight the need to consider the impact of particle diameter when assessing indoor exposure and potential health effects in communities living under the direct influence of mining and smelter activities.

Measurement report: Ice nucleating abilities of biomass burning, African dust, and sea spray aerosol particles over the Yucatán Peninsula

Abstract. Most precipitation from deep clouds over the continents and in the intertropical convergence zone is strongly influenced by the presence of ice crystals whose formation requires the presence of ice nucleating particles (INPs). Although there are a large number of INP sources, the ice nucleating abilities of aerosol particles originating from oceans, deserts, and wildfires are poorly described at tropical latitudes. To fill this gap in knowledge, the National Autonomous University of Mexico micro-orifice uniform deposit impactor droplet freezing technique (UNAM-MOUDI-DFT) was constructed to measure the ice nucleating activity of aerosol samples that were collected in Sisal and Mérida, Yucatán (Mexico) under the influence of cold fronts, biomass burning (BB), and African dust (AD) intrusions during five short-term field campaigns between January 2017 and July 2018. The three different aerosol types were distinguished by their physicochemical properties. Marine aerosol (MA), BB, and AD air masses were found to contain INPs; the highest concentrations were in AD (from 0.071 to 36.07 L−1 at temperatures between −18 and −27 ∘C), followed by MA (from 0.068 to 18.90 L−1 at temperatures between −15 and −28 ∘C) and BB (from 0.063 to 10.21 L−1 at temperatures between −20 and −27 ∘C). However, MA had the highest surface active site densities (ns) between −15 and −30 ∘C. Additionally, supermicron particles contributed more than 72 % of the total INP concentration independent of aerosol type.

Three-dimension soft X-ray tomographic reconstruction of particulates emitted from a diesel engine

The diesel particulate matter (PM) is typically agglomerates of soot coated with condensed organic compounds. Three-dimensional (3D) measurement of PM particle structures is currently not undertaken as established techniques usually damage the structure of PM particles by dissociating or evaporating the condensed organic compounds absorbed on the soot. In this work, PM particles emitted from a diesel engine were sampled by a micro-orifice uniform deposit impactor and their soot content was measured by a thermo-gravimetric analyzer. The morphology and microstructure of individual PM particle were non-destructively studied using synchrotron soft X-ray tomography (SXT). The 3D tomographic reconstruction from the aligned tilt-series images yielded useful information about PM volumetric characters. Fractal-like agglomerate of soot and the condensed organic compounds were identified. The results showed that the agglomerates are constituted by loosely attached aggregates which are composed of spherules holding tightly to each other. Aggregate size distributions exhibited no specific trend with respect to the engine load and PM size in this work, while soot volume fractions calculated based on the 3D images of PM particles, decreased with increasing load and PM size. The fractal dimensions of agglomerates and PM particles were for the first time presented and calculated by image analysis. The essential properties of PM particles, agglomerates and aggregates are characterized. The population-averaged fractal dimension of agglomerates was smaller and more sensitive to engine load and PM size than that of aggregates, indicating that agglomerates was less compact than aggregates. This work demonstrated the significant advantages of SXT in the description of actual PM morphologies with high accuracy.

Contrasting the size-resolved nature of particulate arsenic, cadmium, and lead among diverse regions

This study examines the mass size distributions and crustal enrichment factors (EFs) of arsenic (As), cadmium (Cd), and lead (Pb) for diverse regions: coastal marine (Marina, California), arid mining facility (Hayden, Arizona), arid urban (Tucson, Arizona), free troposphere (Mt. Lemmon, Arizona), and coastal urban (Manila, Philippines). Micro-orifice uniform deposit impactor (MOUDI) measurements revealed several notable features. All sites showed a bimodal profile with a peak in the submicrometer and supermicrometer diameter range except for Manila, which peculiarly lacked a peak above 1 μm. Enrichment factor analysis revealed contaminated dust at all sites, even the free tropospheric site, with greater contamination in the submicrometer range. The most extensive dataset in Manila allowed for seasonal analysis, which revealed differences among the same species based on seasonally-dependent transport patterns. Sites experiencing biomass burning influence (Manila and Marina) generally exhibited suppressed concentrations and crustal EFs during burning periods presumably because soil emitted from fires is fresh without extensive processing time to become contaminated. These results have important implications for a variety of aerosol effects dependent on aerosol size (e.g., public health, biogeochemical cycling, heterogeneous chemistry) and underscore the importance of accounting for the coarse aerosol mode as more dust emissions are expected in warmer climate scenarios.

The Composition of Emissions from Sanding Corian® with Different Sandpapers.

Laboratory tests were conducted to characterize the composition of emissions from sanding Corian®, a solid-surface composite material mainly composed of alumina trihydrate (ATH) and acrylic polymer. Three sandpaper materials (ceramic, silicon carbide, and aluminum oxide) were tested to distinguish the contribution of aluminum-containing dust in the emission from Corian® and sandpaper itself. The result can help identify the main cause of the pulmonary fibrosis from exposure to aluminum-containing dust while sanding Corian®. Airborne dust samples were measured using direct-reading instruments and collected using a Micro-Orifice Uniform Deposit Impactor (MOUDI) for estimating the normalized dust generation rate. The size-classified dust samples from MOUDI were analyzed for elemental aluminum content. Additionally, air samples were analyzed for characterizing methyl methacrylate (MMA). The results from the direct-reading instruments reveal that the size distribution of particulate from sanding Corian® differs from that of sawing Corian®, showing that the size distribution of dust is affected by the fabrication process. The normalized respirable dust generation rate indicates that more respirable dust was generated during sanding Corian® board. However, the use of aluminum oxide sandpaper does not result in a higher aluminum content in the respirable dust from sanding Corian®, suggesting that the aluminum content of the respirable dust is primarily originated from Corian® itself. The generation rates of MMA from sanding did not vary much among all types of sandpapers, and they were much lower than that of sawing, likely due to the higher temperature in the sawing process.

Development of an Orientation-independent Handheld Nebulizer

ABSTRACT This work aimed to develop and evaluate a miniaturized handheld vibrating mesh nebulizer (MHVMN) that functions equally well in any orientation. The MHVMN, which comprises a a power supply unit, a vibrating mesh plate, and a liquid reservoir equipped with either a flat end orifice tube (FEOT) or a traditional wick for delivery, was primarily tested using deionized water and a 0.9% sodium chloride solution. Since our study focused on optimizing the dimensions of the FEOT, which utilizes capillary action to deliver the solution, we examined the effects of the operating parameters, viz., the gap between the reservoir wall and the FEOT (LLR-FEOT), the diameter of the FEOT’s orifice (Dorifice), the orientation of the nebulizer, and the size of the aperture, on the performance of the device. The output rate and the residual volume were determined gravimetrically, and both the concentration and the mass distribution of the aerosolized particles were measured with an aerosol size spectrometer (welas digital 3000) and a Micro-Orifice Uniform Deposit Impactor (MOUDI). The results revealed an optimal LLR-FEOT of 0.225 mm, which achieved similar output rates and residual volumes across various orientations. Additionally, a Dorifice exceeding 0.8 mm was necessary to ensure continuous nebulization, thereby yielding a residual volume of less than 4%. Using the FEOT instead of a traditional wick also significantly decreased the residual volume—a major advantage in delivering costly drugs. The consistently high efficiency of the MHVMN regardless of orientation demonstrates its suitability for administering aerosolized medication, especially to patients lying in bed.

The influence of upslope fog on hygroscopicity and chemical composition of aerosols at a forest site in Taiwan

This study investigated the influence of upslope fog formation on the chemical composition and single hygroscopicity parameter (κ) of rural aerosols from Dec. 1st to Dec. 24th, 2018 at the Xitou forest site (23.67°N, 120.80°E, 1178 m above sea level (a.s.l.)) in central Taiwan. The aerosol chemical compositions were monitored using a mini compact time-of-flight aerosol mass spectrometer (mini-C-ToF-AMS), and the ambient aerosol particles were collected by a 13-stage micro-orifice uniform deposit impactor (MOUDI) for a Fourier-transform infrared spectrometer with an attenuated total reflectance accessory (FTIR-ATR) analysis. κ of aerosols was derived from the comparison of AMS pToF size distribution and FTIR-ATR measurement using the κ-Köhler equation. Our results show that the moderate correlation between OOA and CO provided evidence of upstream anthropogenic emission and time-lagged aged secondary organic aerosol transport by the daytime sea breeze and valley wind. Larger particles (Dva ~800 nm–1.0 μm) had a higher fog scavenging removal efficiency (62% for organic and 81% for nitrate, respectively), and smaller particles (Dva ~100 nm–700 nm) could remain growth through gas-to-aqueous partition. The submicrometer nitrate particles were likely significantly formed via gas-particle partitioning as HNO3(aq) or NH4NO3 while the larger micrometer-sized sea salt-like nitrate particles might be formed via heterogeneous reaction of gaseous HNO3 with deliquesced sea salt particles. The inconsistency of submicrometer nitrate between real-time AMS and offline FTIR-ATR measurements indicates that the evaporation loss of HNO3 or NH4NO3 during MOUDI filter sampling could lead to the unavailable κp−NO3 (κ for nitrate-containing particles) retrieval. The average κp-org (organics-containing particles) was 0.19 ± 0.12 (r2 ≥ 0.8) and nearly overlapped with κp−SO4 (0.22 ± 0.08) (sulfate-containing particles) during misty daytime, indicating that aerosols were more likely internally mixed particles to have similar hygroscopicity and physical mixing state property.