In the field of precision machining, with the popularity of brittle and hard materials such as infrared windows, it has become difficult for conventional diamond grinding wheels to effectively perform high-quality machining. The structuring of traditional diamond grinding wheels using a pulsed laser is a key technology to effectively improve the grinding quality of grinding wheels. In this paper, three new shark fin diamond grinding wheels (SFSGW) with different slot widths are designed based on the excellent drag-reducing and channelizing properties of shark dorsal fins. The grinding performance of traditional grinding wheels (USGW) and SFSGW on magnesium fluoride ceramics was compared. The effects of SFSGW on the surface quality, surface roughness and wheel damage of the workpiece were investigated. The results showed that the surface roughness of ceramics after grinding by SFSGW was reduced by 22.15 % compared with USGW, and the surface quality was better. Proper construction increases the material removal rate of the wheel and improves the wear resistance and service life of the wheel.