meV Gap Research Articles

Searching for redshifted 2.2 MeV neutron-capture lines from accreting neutron stars: Theoretical X-ray luminosity requirements and INTEGRAL/SPI observations

Accreting neutron stars (NSs) are expected to emit a redshifted 2.2 MeV line due to the capture of neutrons produced through the spallation processes of 4He and heavier ions in their atmospheres. Detecting this emission would offer an independent method for constraining the equation of state of NSs and provide valuable insights into nuclear reactions occurring in extreme gravitational and magnetic environments. Typically, a higher mass accretion rate is expected to result in a higher 2.2 MeV line intensity. However, when the mass accretion rate approaches the critical threshold, the accretion flow is decelerated by the radiative force, leading to a less efficient production of free neutrons and a corresponding drop in the flux of the spectral line. This makes the brightest X-ray pulsars unsuitable candidates for γ-ray line detection. In this work, we present a theoretical framework for predicting the optimal X-ray luminosity required to detect a redshifted 2.2 MeV line in a strongly magnetized NS. As the INTErnational Gamma-Ray Astrophysics Laboratory (INTEGRAL) mission nears its conclusion, we have undertaken a thorough investigation of the SPectrometer on board INTEGRAL (SPI) data of this line in a representative sample of accreting NSs. No redshifted 2.2 MeV line was detected. For each spectrum, we have determined the 3σ upper limits of the line intensity, assuming different values of the line width. Although the current upper limits are still significantly above the expected line intensity, they offer valuable information for designing future gamma-ray telescopes aimed at bridging the observational MeV gap. Our findings suggest that advancing our understanding of the emission mechanism of the 2.2 MeV line, as well as the accretion flow responsible for it, will require a substantial increase in sensitivity from future MeV missions. For example, for a bright X-ray binary such as Sco X−1, we would need at least a 3σ line point source sensitivity of ≈10−6 ph cm−2 s−1, that is, about two orders of magnitude better than that currently achieved.

Властивості вихідних та опромінених фосфідо-галієвих світлодіодів

Spectral features of the original and irradiated with electrons with E = 2 MeV GaP light emitting diodes (LEDs) were studied. Recombination lines of the exciton bound on the N isoelectronic center and on the pair complexes NN1 were detected. The change in the spectral composition of radiation when passing through a section of negative differential resistance is analyzed. Dose dependences of luminescence intensity were obtained for green GaP(N) and red GaP(Zn-O) LEDs. The maximum critical radiation dose was established, after which the LEDs lost their characteristic exciton emission mechanism. The results of the annealing of irradiated LEDs are given.

Evaluation of the performance of a CdZnTe-based soft γ\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\gamma $$\\end{document}-ray detector for CubeSat payloads

The low-energy γ\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\varvec{\\gamma }$$\\end{document}-ray (0.1-30 MeV) sky has been relatively unexplored since the decommissioning of the COMPTEL instrument on the Compton Gamma-Ray Observatory (CGRO) satellite in 2000. However, the study of this part of the energy spectrum (the “MeV gap”) is crucial for addressing numerous unresolved questions in high-energy and multi-messenger astrophysics. Although several large MeV γ\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\varvec{\\gamma }$$\\end{document}-ray missions like AMEGO and e-ASTROGAM are being proposed, they are predominantly in the developmental phase, with launches not anticipated until the next decade at the earliest. In recent times, there has been a surge in proposed CubeSat missions as cost-effective and rapidly implementable “pathfinder” alternatives. A MeV CubeSat dedicated to γ\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\varvec{\\gamma }$$\\end{document}-ray astronomy has the potential to serve as a demonstrator for future, larger-scale MeV payloads. This paper presents a γ\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\varvec{\\gamma }$$\\end{document}-ray payload design featuring a CdZnTe crystal calorimeter module developed by IDEAS. We report the detailed results of simulations to assess the performance of this proposed payload and compare it with those of previous γ\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\varvec{\\gamma }$$\\end{document}-ray instruments.

Inelastic Neutron Scattering Study of Phonon Dispersion Relation in Higher Manganese Silicides

We report inelastic neutron scattering (INS) measurements of the phonon dispersion relation in higher manganese silicides (HMSs). A large ingot of HMS is synthesized using a slow cooling method, which is found to have Mn15Si26 as the primary phase. The sample is composed of highly oriented crystallites as confirmed by a neutron pole-figure study and thermal conductivity data. Our INS results are mostly consistent with earlier experimental and theoretical phonon studies in HMS, including the presence of a low-lying twisting mode. However, some discrepancies are also observed. Most notably, a 5 meV gap at the zone center and the softer dispersion relation of the low-lying twisting mode. We discuss the potential origins of these observations and their implications for the thermal properties of HMS.

Structural and electronic structure evolution of K x Fe2− y Se2 from semiconducting phase to superconducting phase

The structural parameters, magnetic property and electronic structure of K0.875+a Fe1.5+b Se2 have been studied by first principles calculations. An increase of K or Fe content leads to the evolution of the magnetic property and electronic structure of K0.875Fe1.5Se2. The introduction of extra K brings a slight rigid shift of the minority states, while the introduction of extra Fe breaks the vacancy order of Fe atoms, forming 1D chains, and causes the Fermi surfaces to display an obvious nesting feature. The K0.875Fe1.5Se2 is proven to be a semiconductor with a 61 meV gap, and the evolution from semiconducting phase to superconducting phase is mainly due to the suppression of a rhombus iron vacancy order and antiferromagnetic order with an increase in Fe content.

Improving the Low-energy Transient Sensitivity of AMEGO-X using Single-site Events

AMEGO-X, the All-sky Medium Energy Gamma-ray Observatory eXplorer, is a proposed instrument designed to bridge the so-called “MeV gap” by surveying the sky with unprecedented sensitivity from ∼100 keV to about 1 GeV. This energy band is of key importance for multimessenger and multiwavelength studies but it is nevertheless currently underexplored. AMEGO-X addresses this situation by proposing a design capable of detecting and imaging gamma rays via both Compton interactions and pair production processes. However, some of the objects that AMEGO-X will study, such as gamma-ray bursts and magnetars, extend to energies below ∼100 keV where the dominant interaction becomes photoelectric absorption. These events deposit their energy in a single pixel of the detector. In this work we show how the ∼3500 cm2 effective area of the AMEGO-X tracker to events between ∼25 and ∼100 keV will be utilized to significantly improve its sensitivity and expand the energy range for transient phenomena. Although imaging is not possible for single-site events, we show how we will localize a transient source in the sky using their aggregate signal to within a few degrees. This technique will more than double the number of cosmological gamma-ray bursts seen by AMEGO-X, allow us to detect and resolve the pulsating tails of extragalactic magnetar giant flares, and increase the number of detected less-energetic magnetar bursts—some possibly associated with fast radio bursts. Overall, single-site events will increase the sensitive energy range, expand the science program, and promptly alert the community of fainter transient events.

Multiple energy scales and anisotropic energy gap in the charge-density-wave phase of the kagome superconductor CsV3Sb5

Kagome metals AV3Sb5 (A = K, Rb, and Cs) exhibit superconductivity at 0.9-2.5 K and charge-density wave (CDW) at 78-103 K. Key electronic states associated with the CDW and superconductivity remain elusive. Here, we investigate low-energy excitations of CsV3Sb5 by angle-resolved photoemission spectroscopy. We found an energy gap of 70-100 meV at the Dirac-crossing points of linearly dispersive bands, pointing to an importance of spin-orbit coupling. We also found a signature of strongly Fermi-surface and momentum-dependent CDW gap characterized by the larger energy gap of maximally 70 meV for a band forming a saddle point around the M point, the smaller (0-18 meV) gap for a band forming massive Dirac cones, and a zero gap at the Gamma-centered electron pocket. The observed highly anisotropic CDW gap which is enhanced around the M point signifies an importance of scattering channel connecting the saddle points, laying foundation for understanding the nature of CDW and superconductivity in AV3Sb5.

Cadmium copper selenite chloride, CdCu2(SeO3)2Cl2, an insulating spin gap system

Novel copper cadmium selenite chloride has been synthesized via vapor transport reaction as well as by solid state process. CdCu2(SeO3)2Cl2 crystallizes in a monoclinic space group I2/a with cell constants a ​= ​7.8057(3) Å, b ​= ​9.6036(4) Å, c ​= ​10.7817(5) Å and β ​= ​102.362(4)°, Z ​= ​4. Its crystal structure can be described as an open channel three-dimensional framework, formed by [CdO2Cl4] and [CuO4Cl2] polyhedra interconnected by pyramidal SeO3 groups. The copper polyhedra form magnetically isolated dimers with a spin gap Δ ​= ​38.7 ​± ​0.8 ​meV, as defined from magnetic susceptibility measurements. The electron band gap estimated by diffuse reflectance method Eg ​= ​2.82 ​± ​0.02 ​eV is in agreement with the yellow-green color of the substance. Density functional theory provides the values of electron (2.4 ​eV) and spin (36.6 ​meV) gaps consistent with experimental observations.

Charge Density Waves in Electron-Doped Molybdenum Disulfide

We present the discovery of a charge density wave (CDW) ground state in heavily electron-doped molybdenum disulfide (MoS2). This is the first observation of a CDW in any d2 (column 6) transition metal dichalcogenide (TMD). The band structure of MoS2 is distinct from the d0 and d1 TMDs in which CDWs have been previously observed, facilitating new insight into CDW formation. We demonstrate a metal–insulator transition at 85 K, a 25 meV gap at the Fermi level, and two distinct CDW modulations, (2√3 × 2√3) R30° and 2 × 2, attributable to Fermi surface nesting (FSN) and electron–phonon coupling (EPC), respectively. This simultaneous exhibition of FSN and EPC CDW modulations is unique among observations of CDW ground states, and we discuss this in the context of band folding. Our observations provide a route toward the resolution of controversies surrounding the origin of CDW modulations in TMDs.

Accurate Measurement of the Gap of Graphene/h-BN Moiré Superlattice through Photocurrent Spectroscopy.

Monolayer graphene aligned with hexagonal boron nitride (h-BN) develops a gap at the charge neutrality point (CNP). This gap has previously been extensively studied by electrical transport through thermal activation measurements. Here, we report the determination of the gap size at the CNP of graphene/h-BN superlattice through photocurrent spectroscopy study. We demonstrate two distinct measurement approaches to extract the gap size. A maximum of ∼14 meV gap is observed for devices with a twist angle of less than 1°. This value is significantly smaller than that obtained from thermal activation measurements, yet larger than the theoretically predicted single-particle gap. Our results suggest that lattice relaxation and moderate electron-electron interaction effects may enhance the CNP gap in graphene/h-BN superlattice.

Symmetry-Resolved Two-Magnon Excitations in a Strong Spin-Orbit-Coupled Bilayer Antiferromagnet.

We used a combination of polarized Raman spectroscopy and spin wave calculations to study magnetic excitations in the strong spin-orbit-coupled bilayer perovskite antiferromagnet Sr_{3}Ir_{2}O_{7}. We observed two broad Raman features at ∼800 and ∼1400 cm^{-1} arising from magnetic excitations. Unconventionally, the ∼800 cm^{-1} feature is fully symmetric (A_{1g}) with respect to the underlying tetragonal (D_{4h}) crystal lattice which, together with its broad line shape, definitively rules out the possibility of a single magnon excitation as its origin. In contrast, the ∼1400 cm^{-1} feature shows up in both the A_{1g} and B_{2g} channels. From spin wave and two-magnon scattering cross-section calculations of a tetragonal bilayer antiferromagnet, we identified the ∼800 cm^{-1} (1400 cm^{-1}) feature as two-magnon excitations with pairs of magnons from the zone-center Γ point (zone-boundary van Hove singularity X point). We further found that this zone-center two-magnon scattering is unique to bilayer perovskite magnets which host an optical branch in addition to the acoustic branch, as compared to their single layer counterparts. This zone-center two-magnon mode is distinct in symmetry from the time-reversal symmetry broken "spin wave gap" and "phase mode" proposed to explain the ∼92 meV (742 cm^{-1}) gap in resonant inelastic x-ray spectroscopy magnetic excitation spectra of Sr_{3}Ir_{2}O_{7}.

Fundamental Spin Interactions Underlying the Magnetic Anisotropy in the Kitaev Ferromagnet CrI_{3}.

We lay the foundation for determining the microscopic spin interactions in two-dimensional (2D) ferromagnets by combining angle-dependent ferromagnetic resonance (FMR) experiments on high quality CrI_{3} single crystals with theoretical modeling based on symmetries. We discover that the Kitaev interaction is the strongest in this material with K∼-5.2 meV, 25 times larger than the Heisenberg exchange J∼-0.2 meV, and responsible for opening the ∼5 meV gap at the Dirac points in the spin-wave dispersion. Furthermore, we find that the symmetric off-diagonal anisotropy Γ∼-67.5 μeV, though small, is crucial for opening a ∼0.3 meV gap in the magnon spectrum at the zone center and stabilizing ferromagnetism in the 2D limit. The high resolution of the FMR data further reveals a μeV-scale quadrupolar contribution to the S=3/2 magnetism. Our identification of the underlying exchange anisotropies opens paths toward 2D ferromagnets with higher T_{C} as well as magnetically frustrated quantum spin liquids based on Kitaev physics.

Magnetic field mixing and splitting of bright and dark excitons in monolayer MoSe2

Monolayers of semiconducting transition metal dichalcogenides (TMDCs) with unique spin-valley contrasting properties and remarkably strong excitonic effects continue to be a subject of intense research interests. These model 2D semiconductors feature two fundamental intravalley excitons species–optically accessible ‘bright’ excitons with anti-parallel spins and optically inactive ‘dark’ excitons with parallel spins. For applications exploiting radiative recombination of bright excitons or long lifetime dark excitons, it is essential to understand the radiative character of the exciton ground state and establish the energy separation between the lowest energy bright and dark excitons. Here, we report a direct spectroscopic measure of dark excitons in monolayer MoSe2 encapsulated in hexagonal boron nitride. By applying strong in-plane magnetic field, we induce mixing and splitting of bright and dark exciton branches, which enables an accurate spectroscopic determination of their energies. We confirm the bright character of the exciton ground state separated by a 1.5 meV gap from the higher energy dark exciton state, much smaller compared to the previous theoretical expectations. These findings provide critical information for further improvement of the accurate theoretical description of TMDCs electronic structure.

Charge carrier migration and hole extraction from MAPbI3

Linear as well as time resolved absorption measurements were performed on 40 nm and 170 nm thick MAPbL films with PEDOT:PSS hole extraction layer, spin-coated on quartz substrate. From linear absorption measurements exciton binding energy of 18 – 19 meV and band gap of 1.60 - 1.62 eV was deduced. Transient absorption spectra after the excitation at 1.77 eV showed a strong difference in carrier recombination dynamics for the two MAPbI3 films of different thicknesses. From the analysis on the decay dynamics, hole population lifetime of 0.3 ns and 3.5 ns for 40 nm and 170 nm films, respectively, are determined. A numerical 1D diffusion model was used to model the carrier relaxation dynamics yielding hole diffusion constants of 0.025 - 0.030 cm2s−1, which results in a hole mobility of 1 cm2(Vs)−1 in these MAPbI3 films.

Electronic properties of polymorphic two-dimensional layered chromium disulphide.

Two-dimensional (2D) Cr-based layered and non-layered materials such as CrI3, Cr2Ge2Te6, Cr2S3, CrSe, and CrOX (X = Cl and Br) have attracted considerable attention due to their potential application in spintronics. Despite few experimental studies, theoretical studies reported that 2D chromium dichalcogenide (CrS2) materials show unique properties such as valley polarization, piezoelectric coupling, and phase dependent intrinsic magnetic properties. Here, we report for the first time the synthesis of 2D layered CrS2 flakes down to the monolayer via the chemical vapor deposition (CVD) method, its phase structures and electronic properties. We observed the 2H, 1T, and 1T' phases coexisting in CVD grown monolayer CrS2. The formation of 1T' phases from 1T phases is described by dimerization of metal atoms at room temperature according to our molecular dynamics studies. The coexistence of 1T and 1T' phases with 2H phases is referred to as the 1T and 1T' puddling phenomenon. We theoretically showed that the monolayer 2H-CrS2 is a direct bandgap semiconductor with a gap of approximately 0.95 eV predicted by the PBE functional, while the 1T- and 1T'-CrS2 are metallic and semi-metallic with approximately 10 meV gap, respectively. Furthermore, 2H CrS2 exhibits nonmagnetic semiconducting properties while for ferromagnetic spin configuration, the 1T and 1T' CrS2 show magnetic characteristics with 0.531μB and 2.206μB magnetic moment per Cr atom respectively, for ferromagnetic spin configuration as predicted from DFT+U calculation. Importantly, CrS2-based field-effect transistors exhibit a p-type behavior. Our study would stimulate further exploration of 2D layered CrS2 with astonishing properties and open up a whole new avenue for the urgent need for developing multifunctional 2D materials for nanoelectronics, valleytronics, and spintronics.

Topological Spin Excitations in Honeycomb Ferromagnet .

In two-dimensional honeycomb ferromagnets, bosonic magnon quasiparticles (spin waves) may either behave as massless Dirac fermions or form topologically protected edge states. The key ingredient defining their nature is the next-nearest-neighbor Dzyaloshinskii-Moriya interaction that breaks the inversion symmetry of the lattice and discriminates chirality of the associated spin-wave excitations. Using inelastic neutron scattering, we find that spin waves of the insulating honeycomb ferromagnet ( ) have two distinctive bands of ferromagnetic excitations separated by a ∼4 meV gap at the Dirac points. These results can only be understood by considering a Heisenberg Hamiltonian with Dzyaloshinskii-Moriya interaction, thus providing experimental evidence that spin waves in can have robust topological properties potentially useful for dissipationless spintronic applications.

Magnetic exchange parameters and anisotropy of the quasi-two-dimensional antiferromagnetNiPS3

Neutron inelastic scattering has been used to measure the magnetic excitations in powdered NiPS$_3$, a quasi-two dimensional antiferromagnet with spin $S = 1$ on a honeycomb lattice. The spectra show clear, dispersive magnons with a $\sim 7$ meV gap at the Brillouin zone center. The data were fitted using a Heisenberg Hamiltonian with a single-ion anisotropy assuming no magnetic exchange between the honeycomb planes. Magnetic exchange interactions up to the third intraplanar nearest-neighbour were required. The fits show robustly that NiPS$_3$ has an easy axis anisotropy with $\Delta = 0.3$ meV and that the third nearest-neighbour has a strong antiferromagnetic exchange of $J_3 = -6.90$ meV. The data can be fitted reasonably well with either $J_1 < 0$ or $J_1 > 0$, however the best quantitative agreement with high-resolution data indicate that the nearest-neighbour interaction is ferromagnetic with $J_1 = 1.9$ meV and that the second nearest-neighbour exchange is small and antiferromagnetic with $J_2 = -0.1$ meV. The dispersion has a minimum in the Brillouin zone corner that is slightly larger than that at the Brillouin zone center, indicating that the magnetic structure of NiPS$_3$ is close to being unstable.

Specific heat of FeSe: Two gaps with different anisotropy in superconducting state

We present detailed study of specific heat of FeSe single crystals with critical temperature Tc=8.45K at 0.4−200K in magnetic fields 0−9T. Analysis of the electronic specific heat at low temperatures shows the coexistence of isotropic s-wave gap and strongly anisotropic extended s-wave gap without nodes. It was found two possibilities of superconducting gap parameters which give equally description of experimental data: (i) two gaps with approximately equal amplitudes and weight contribution to specific heat: isotropic Δ1=1.7 meV (2Δ1/kBTc=4.7) and anisotropic gap with the amplitude Δ2max=1.8 meV (2Δ2max/kBTc=4.9 and anisotropy parameter m=0.85); (ii) two gaps with substantially different values: isotropic large gap Δ1=1.65 meV (2Δ1/kBTc=4.52) and anisotropic small gap Δ2max=0.75 meV (2Δ2max/kBTc=2) with anisotropy parameter m=0.71. These results are confirmed by the field behavior of the residual electronic specific heat γr.

Band gap of corundumlike α−Ga2O3 determined by absorption and ellipsometry

The electronic structure near the band gap of the corundumlike $\ensuremath{\alpha}$ phase of ${\mathrm{Ga}}_{2}{\mathrm{O}}_{3}$ has been investigated by means of optical absorption and spectroscopic ellipsometry measurements in the ultraviolet (UV) range (400--190 nm). The absorption coefficient in the UV region and the imaginary part of the dielectric function exhibit two prominent absorption thresholds with wide but well-defined structures at 5.6 and 6.3 eV which have been ascribed to allowed direct transitions from crystal-field split valence bands to the conduction band. Excitonic effects with large Gaussian broadening are taken into account through the Elliott-Toyozawa model, which yields an exciton binding energy of 110 meV and direct band gaps of 5.61 and 6.44 eV. The large broadening of the absorption onset is related to the slightly indirect character of the material.

Prospects for indirect dark matter searches with MeV photons

Over the past decade, extensive studies have been undertaken to search for photon signals from dark matter annihilation or decay for dark matter particle masses above ∼1 GeV. However, due to the lacking sensitivity of current experiments at MeV–GeV energies, sometimes dubbed the ‘MeV gap’, dark matter models with MeV to sub-GeV particle masses have received little attention so far. Various proposed MeV missions (like, e.g., e-ASTROGAM or AMEGO) are aimed at closing this gap in the mid- or long-term future. This, and the absence of clear dark matter signals in the GeV–TeV range, makes it relevant to carefully reconsider the expected experimental instrumental sensitivities in this mass range. The most common two-body annihilation channels for sub-GeV dark matter are to neutrinos, electrons, pions or directly to photons. Among these, only the electron channel has been extensively studied, and almost exclusively in the context of the 511 keV line. In this work, we study the prospects for detecting MeV dark matter annihilation in general in future MeV missions, using e-ASTROGAM as reference, and focusing on dark matter masses in the range 1 MeV–3 GeV. In the case of leptonic annihilation, we emphasise the importance of the often overlooked bremsstrahlung and in-flight annihilation spectral features, which in many cases provide the dominant gamma-ray signal in this regime.