Metropolitan Area Of Sao Paulo Research Articles

Long-term trends and probability distribution functions of air pollutant concentrations in the megacity of São Paulo

Air quality conditions in many urban areas have improved in the last decades as a consequence of air pollution control policies and regulations. Mitigation strategies have been successful in reducing the concentration of primary pollutants like inhalable particulate matter (PM10), but the control of secondary pollutants like tropospheric ozone (O3) is still challenging in megacities like the Metropolitan Area of São Paulo (MASP) in Brazil. To support the development of effective mitigation strategies, it is crucial to characterize the statistical behavior of air pollutant concentrations and its long-term evolution. Probability Density Functions (PDF) can be useful to model site-specific air quality conditions, providing estimates for the frequency of extreme pollution events and exceedance of air quality standards. The current study aims to characterize which PDF model better fits and characterizes the variability of PM10 and O3 concentrations in the MASP. For that, daily maximum moving average concentrations were analyzed between 2000 and 2023, characterizing the long-term trends and the frequency of exceedance of air quality standards. PM10 concentrations followed a lognormal PDF, with an expected value of 31 ± 15 µg.m-3. O3 followed a Gamma PDF, with an expected value of 68 ± 25 µg.m-3. A consistent long-term decrease was observed for PM10 (-1.04 ± 0.09 µg.m-3.yr-1), while O3 showed an increasing trend of 0.51 ± 0.04 µg.m-3.yr-1 in the summer. In recent years (2021-2023), the probability of exceedance of the World Health Organization guideline was 17.4 and 11.0%, respectively, for PM10 and O3. In 2020, a statistically significant increase in O3 expected values was observed, possibly associated with changes in the emission patterns of precursors due to the mobility restrictions imposed by the COVID-19 pandemic.

Radar, Lightning, and Synoptic Observations for a Thunderstorm on 7 January 2012 during the CHUVA-Vale Campaign

Thunderstorms can generate intense electrical activity, hail, and result in substantial economic and human losses. The development of very short-term forecasting tools (nowcasting) is essential to provide information to alert systems in order to mobilize most efficiently the population. However, the development of nowcasting tools depends on a better understanding of the physics and microphysics of clouds and lightning formation and evolution. In this context, the objectives of this study are: (a) to describe the environmental conditions that led to a genesis of a thunderstorm that produce hail on 7 January 2012, in the Metropolitan Area of São Paulo (MASP) during the CHUVA-Vale campaign, and (b) to evaluate the thunderstorm microphysical properties and vertical structure of electrical charge. Data from different sources were used: field campaign data, such as S-band radar, and 2- and 3-dimensional lightning networks, satellite data from the Geostationary Operational Environmental Satellite-13 (GOES-13), the Meteosat Second Generation (MSG), and reanalysis of the European Centre for Medium-Range Weather Forecasts Reanalysis v5 (ERA5). The thunderstorm developed in a region of low-pressure due to the presence of a near-surface inverted trough and moisture convergence, which favored convection. Convective Available Potential Energy (CAPE) of 1053.6 J kg−1 at the start of the thunderstorm indicated that strong convective energy was present. Microphysical variables such as Vertically Integrated Liquid water content (VIL) and Vertically Integrated Ice (VII) showed peaks of 140 and 130 kg m−2, respectively, before the hail reached the surface, followed by a decrease, indicating content removal from within the clouds to the ground surface. The thunderstorm charge structure evolved from a dipolar structure (with a negative center between 4 and 6 km and a positive center between 8 and 10 km) to a tripolar structure (negative center between 6 and 7.5 km) in the most intense phase. The first lightning peak (100 flashes in 5 min−1) before the hail showed that there had been a lightning jump. The maximum lightning occurred around 18:17 UTC, with approximately 350 flashes 5 min−1 with values higher than 4000 sources 500 m−1 in 5 min−1. Likewise, the vertical cross-sections indicated that the lightning occurred ahead of the thunderstorm’s displacement (maximum reflectivity), which could be useful in predicting these events.

Análise Multivariada de Ilha de Calor Urbana na Região Metropolitana de São Paulo, Brasil

Abstract The Urban Heat Island (UHI) effect, where urban regions experience higher temperatures than their rural counterparts, is a well-observed phenomenon with consequences such as health issues and increased energy consumption. In the Metropolitan Area of São Paulo (MASP), a dense urban zone with over 20 million inhabitants, the UHI effect is intensified due to rapid and unplanned urbanization. This research utilized meteorological data from MASP's weather stations and employed the k-means clustering algorithm to identify regions with pronounced UHI intensity. The study revealed four distinct clusters, with Cluster A exhibiting the most significant UHI effect. This effect was related with land use patterns, particularly the dominance of residential and commercial areas and a lack of green spaces. Seasonal variations in the UHI effect were also observed. The findings highlight the impact of urban development on localized climate change and provide valuable insights for urban planning and policy-making in MASP. Future studies could expand on these findings by including more variables and examining other global urban regions.

Chemical Characterization and Optical Properties of the Aerosol in São Paulo, Brazil

Air pollution in the Metropolitan Area of São Paulo (MASP), Brazil, is a serious problem and is strongly affected by local sources. However, atmosphere column composition in MASP is also affected by biomass burning aerosol (BB). Understanding the impacts of aerosol particles, from both vehicles and BB, on the air quality and climate depends on in-depth research with knowledge of some parameters such as the optical properties of particles and their chemical composition. This study characterized fine particulate matter (PM2.5) from July 2019 to August 2020 in the eastern part of the MASP, relating the chemical composition data obtained at the surface and columnar optical parameters, such as aerosol optical depth (AOD), Ångström Exponent (AE), and single-scattering albedo (SSA). According to the analyzed data, the mean PM2.5 concentration was 18.0 ± 12.5 µg/m3; however, daily events exceeded 75 times the air quality standard of the World Health Organization (15 µg/m3). The mean black carbon concentration was 1.8 ± 1.5 µg/m3 in the sampling period. Positive matrix factorization (PMF) identified four main sources of aerosol: heavy vehicles (42%), followed by soil dust plus local sources (38.7%), light vehicles (9.9%), and local sources (8.6%). AOD and AE presented the highest values in the dry period, during which biomass burning events are more frequent, suggesting smaller particles in the atmosphere. SSA values at 440 nm were between 0.86 and 0.94, with lower values in the winter months, indicating the presence of more absorbing aerosol.

Emission factors for a biofuel impacted fleet in South America's largest metropolitan area

The Metropolitan Area of São Paulo (MASP) is among the largest urban areas in the Southern Hemisphere. Vehicular emissions are of great concern in metropolitan areas and MASP is unique due to the use of biofuels on a large scale (sugarcane ethanol and biodiesel). In this work, tunnel measurements were employed to assess vehicle emissions and to calculate emission factors (EFs) for heavy-duty and light-duty vehicles (HDVs and LDVs). The EFs were determined for particulate matter (PM) and its chemical compounds. The EFs obtained for 2018 were compared with previous tunnel experiments performed in the same area. An overall trend of reduction of fine and coarse PM, organic carbon (OC), and elemental carbon (EC) EFs for both LDVs and HDVs was observed if compared to those observed in past years, suggesting the effectiveness of vehicular emissions control policies implemented in Brazil. A predominance of Fe, Cu, Al, and Ba emissions was observed for the LDV fleet in the fine fraction. Cu presented higher emissions than two decades ago, which was associated with the increased use of ethanol fuel in the region. For HDVs, Zn and Pb were mostly emitted in the fine mode and were linked with lubricating oil emissions from diesel vehicles. A predominance in the emission of three- and four-ring polycyclic aromatic hydrocarbons (PAHs) for HDVs and five-ring PAHs for LDVs agreed with what was observed in previous studies. The use of biofuels may explain the lower PAH emissions for LDVs (including carcinogenic benzo[a]pyrene) compared to those observed in other countries. The tendency observed was that LDVs emitted higher amounts of carcinogenic species. The use of these real EFs in air quality modeling resulted in more accurate simulations of PM concentrations, showing the importance of updating data with real-world measurements.

Impact of extreme wildfires from the Brazilian Forests and sugarcane burning on the air quality of the biggest megacity on South America

Recently, extreme wildfires have damaged important ecosystems worldwide and have affected urban areas miles away due to long-range transport of smoke plumes. We performed a comprehensive analysis to clarify how smoke plumes from Pantanal and Amazon forests wildfires and sugarcane harvest burning also from interior of the state of São Paulo (ISSP) were transported and injected into the atmosphere of the Metropolitan Area of São Paulo (MASP), where they worsened air quality and increased greenhouse gas (GHG) levels. To classify event days, multiple biomass burning fingerprints as carbon isotopes, Lidar ratio and specific compounds ratios were combined with back trajectories modeling. During smoke plume event days in the MASP fine particulate matter concentrations exceeded the WHO standard (>25 μg m−3), at 99 % of the air quality monitoring stations, and peak CO2 excess were 100 % to 1178 % higher than non-event days. We demonstrated how external pollution events such as wildfires pose an additional challenge for cities, regarding public health threats associated to air quality, and reinforces the importance of GHG monitoring networks to track local and remote GHG emissions and sources in urban areas.

Future Ozone Levels Responses to Changes in Meteorological Conditions under RCP 4.5 and RCP 8.5 Scenarios over São Paulo, Brazil

Since the implementation of emission control policies in 1983, the Metropolitan Area of São Paulo (MASP) has experienced a significant decrease in the annual mean concentration of air pollutants, except for ozone, which has remained relatively stable. This work analyzes the future impact on surface ozone formation in the MASP caused by changes in atmospheric conditions. The authors performed air quality simulations using the weather research and forecasting with chemistry (WRF-Chem) model under two representative concentration pathway (RCP) atmospheric conditions. A base case simulation from September and October 2018 was compared to scenarios for the same months in 2030, using the same anthropogenic emissions. Results show an average increase in peak ozone concentrations (0.43% for RCP 4.5 and 5.92% for RCP 8.5) with variations depending on the month and location. However, under the RCP 4.5 scenario, peak ozone concentrations in October were higher in urban areas than under the RCP 8.5. These outcomes can assist decision-makers in understanding the potential future impacts of high ozone formation, which has historically occurred in September and October in São Paulo by considering the effects of changing meteorological conditions, such as increased temperatures, higher surface radiation, and reduced cloudiness.

Air Quality Impact Estimation Due to Uncontrolled Emissions from Capuava Petrochemical Complex in the Metropolitan Area of São Paulo (MASP), Brazil

In the second quarter of 2021, the companies at the Capuava Petrochemical Complex (CPC, Santo André, Brazil) carried out a 50-day scheduled shutdown for the maintenance and installation of new industrial equipment. This process resulted in severe uncontrolled emissions of particulate matter (PM) and volatile organic compounds (VOCs) in a densely populated residential area (~3400 inhabitants/km2). VOCs can be emitted directly into the atmosphere in urban areas by vehicle exhausts, fuel evaporation, solvent use, emissions of natural gas, and industrial processes. PM is emitted by vehicle exhausts, mainly those powered by diesel, industrial processes, and re-suspended soil dust, in addition to that produced in the atmosphere by photochemical reactions. Our statistical analyses compared the previous (2017–2020) and subsequent (2021–2022) periods from this episode (April–May 2021) from the official air quality monitoring network of the PM10, benzene, and toluene hourly data to improve the proportion of this period of uncontrolled emissions. Near-field simulations were also performed to evaluate the dispersion of pollutants of industrial origin, applying the Gaussian plume model AERMOD (steady-state plume model), estimating the concentrations of VOC and particulate matter (PM10) in which the population was exposed in the region surrounding the CPC. The results comparing the four previous years showed an increase in the mean concentrations by a factor of 2 for PM10, benzene, and toluene, reaching maximum values during the episode of 174 µg m−3 (PM10), 79.1 µg m−3 (benzene), and 58.7 µg m−3 (toluene). Meanwhile, these higher concentrations continued to be observed after the episode, but their variation cannot be fully explained yet. However, it is worth highlighting that this corresponds to the post-pandemic period and the 2022 data also correspond to the period from January to June, that is, they do not represent the annual variation. A linear correlation indicated that CPC could have been responsible for more than 60% of benzene measured at the Capuava Air Quality Station (AQS). However, the PM10 behavior was not fully explained by the model. AERMOD showed that the VOC plume had the potential to reach a large part of Mauá and Santo André municipalities, with the potential to affect the health of more than 1 million inhabitants.

COVID-19 Pandemic: Impacts on Air Quality during Partial Lockdown in the Metropolitan Area of São Paulo

Air pollution has become one of the factors that most affect the quality of life, human health, and the environment. Gaseous pollutants from motor vehicles have a significantly harmful effect on air quality in the Metropolitan Area of São Paulo (MASP)—Brazil. Motor vehicles emit large amounts of particulate matter (PM), carbon monoxide (CO), nitrogen oxides (NOx), and volatile organic compounds (VOCs), the last three acting as the main tropospheric ozone (O3) precursors. In this study, we evaluated the effects of these pollutants on air quality in the MASP during the partial lockdown that was imposed to ensure the social distancing necessitated by the COVID-19 pandemic. We compared the monthly data for nitrogen dioxide (NO2) from the Ozone Monitoring Instrument (OMI) and CO, SO2, and BC from MERRA-2 for the period between April and May 2020 (during the pandemic) with the average for the same period for the (pre-pandemic) years 2017 to 2019 in the southeast region of Brazil. The meteorological and pollutant concentration data from the CETESB air quality monitoring stations for the MASP were compared with the diurnal cycle of three previous years, with regard to the monthly averages of April and May (2017, 2018, and 2019) and the same period in 2020, when the partial lockdown was first imposed in southeast Brazil. Our findings showed that there was a decrease in NO2 concentrations ranging from 10% to more than 60% in the MASP and the Metropolitan Area of Rio de Janeiro (MARJ), whereas in the Metropolitan Area of Belo Horizonte and Vitoria (MABH and MAV, respectively), there was a reduction of around 10%. In the case of the concentrations of CO and BC from MERRA-2, there was a considerable decrease (approx. 10%) during the period of partial lockdown caused by COVID-19 throughout almost the entire state of São Paulo, particularly in the region bordering the state of Rio de Janeiro. The concentration of SO2 from MERRA-2 was 5 to 10% lower in the MASP and MARJ and the west of the MABH, and there was a decrease of 30 to 50% on the border between the states of São Paulo and Rio de Janeiro, while in the MAV region, there was an increase in pollutant levels, as this region was not significantly affected by the COVID-19 pandemic. Sharp reductions in the average hourly concentrations of CO (38.8%), NO (44.9%), NO2 (38.7%), and PM2.5 (6%) were noted at the CETESB air quality monitoring stations in the MASP during the partial lockdown in 2020 compared with the hourly average rate in the pre-pandemic period. In contrast, there was an increase of approximately 16.0% in O3 concentrations in urban areas that are seriously affected by vehicular emissions, which is probably related to a decrease in NOx.

Atmospheric Formaldehyde Monitored by TROPOMI Satellite Instrument throughout 2020 over São Paulo State, Brazil

We aimed to study the daily formaldehyde (HCHO) columns over urban and forested areas in São Paulo State, Brazil, from rhe TROPOMI spectrometer onboard the Sentinel-5P satellite during 2020. Nineteen specific areas were defined in four regions: 3 areas in each of two preserved Atlantic Forests (PEMD and PETAR), 3 in a sugarcane growing region (NERG) and 10 in the Metropolitan Area of São Paulo (MASP), among which 2 areas are in the Morro Grande reserve, which is a significant remnant of Atlantic Forest outside the densely urbanized area of MASP. An analysis of variance and Tukey’s test showed that the mean annual columns over the Morro Grande reserve (1.69±1.05×10−4 mol/m² and 1.73±1.07×10−4 mol/m²) presented greater statistical similarity with the forest and rural areas of the state (<1.70×10−4 mol/m²) than with MASP (>2.00×10−4 mol/m²), indicating few effects from megacity anthropogenic emissions. Case studies addressing selected days in 2020 showed that fires in and around the state were related to episodes of maximum density of HCHO columns. The results showed significant seasonality, with lower concentrations during summer (wet season) and higher concentrations during winter and spring (dry and transition dry–wet seasons).

PM2.5 removal by urban trees in areas with different forestry conditions in São Paulo using a big-leaf modeling approach

Air pollution is one of the main environmental problems in megacities, such as the metropolitan area of São Paulo (MASP), in Brazil. Urban forests can alleviate air pollution by providing a surface for the dry deposition of particles and trace gases. To benefit from this environmental service and design future green structures, it is crucial to estimate the removal rate of air pollutants by trees. The removal rates of fine particulate matter (PM2.5) by urban trees were quantitatively assessed for the first time in Brazil. A big-leaf modeling approach was adopted, using the i-Tree Eco software. In situ dendrometric data, hourly PM2.5 concentrations, and meteorological variables were used as inputs to the model. PM2.5 removal fluxes ranged between 0.06 and 0.21 g/m2/year in three study areas with contrasting urban forestry conditions. The neighborhood with the greatest canopy cover and tree diversity had the highest removal rates. The evergreen character of the urban forest in the MASP possibly contributed to the relatively high PM2.5 removal fluxes, as compared to other cities around the world. Removal rates were higher in the austral summer, when high precipitation rates restricted the resuspension of deposited particles back to the atmosphere. When extrapolated to the whole metropolitan area, assuming homogeneous forestry conditions, the estimated PM2.5 removal rates were comparable to the magnitude of vehicular emissions, showing that air pollution removal by trees can be substantial in the MASP. The results demonstrate the contribution of urban trees to the improvement of air quality and can boost the development of public policies on urban afforestation in the MASP.

Microphysical and Dynamical Climatology of Precipitating Systems Inferred by Weather Radar Polarimetric Measurements in Brazil

This work presents the climatology of the microphysics and the dynamics of weather systems in two coastal areas of São Paulo and the Espírito States at high spatial-temporal resolution as measured by two dual Doppler weather radars during the summer and early fall of 2015. Averages and respective standard deviations of polarimetric variables, namely, reflectivity (Z), differential reflectivity (ZDR), differential phase (ϕDP), specific differential phase (KDP), copolar correlation coefficient (ρoHV), radial velocity (Vr), and the spectral width (W) were obtained within a 240-km range on plan position indicator (PPI), constant altitude plan position indicator (CAPPI) and vertical cross-sections to analyze overall horizontal and vertical precipitation microphysics and mesoscale circulation of prevailing weather systems, and their peculiarities over coastal and oceanic, and urban and rural areas. Overall, raindrops tend to be larger over the Metropolitan area of São Paulo from the surface to up to 6 km altitude indicating more vigorous updrafts caused by the heat island effect and the local sea breeze. The vertical microphysical structure is remarkably distinct over the Metropolitan Area of São Paulo (MASP) where thunderstorms can reach 20-km altitude in summertime under sea breeze and heat island effects. On the other hand, there is a dominancy of smaller drop sizes though larger ones observed close to the surface by the coast of Espírito Santo and at the land-ocean interface influenced by the local low-level jet and oceanic-type CCN. Convective cells tend to be smaller associated with Easterlies and more organized with Westerlies. The results indicate distinct features on hydrometeor types and circulation characteristics under these different surface and boundary-layer conditions in close agreement with previous results in the literature.

FATORES DE EMISSÃO E DE ENRIQUECIMENTO DA CROSTA PARA ELEMENTOS TRAÇO (MP2,5) EMITIDOS PELA FROTA VEICULAR NA REGIÃO METROPOLITANA DE SÃO PAULO, BRASIL

EMISSION AND CRUST ENRICHMENT FACTORS FOR TRACE ELEMENTS (PM2.5) EMITTED BY THE VEHICLE FLEET IN THE METROPOLITAN AREA OF SÃO PAULO, BRAZIL. Air pollution can cause several negative impacts on health and the environment. In large urban centers, this pollution is directly related to anthropogenic activities, mainly activities in the transportation sector. This study analyzed data on black carbon, fine particulate material (PM2.5) and its main trace elements from automotive vehicles (S, P, K, V, Cr, Fe, Cu, Ni, Zn, Cd, Br and Pb), collected during a long sampling period, carried out in the Metropolitan Area of São Paulo (MASP), Brazil. The filters used were analyzed by various analytical techniques, enabling the identification of the different elements present in the samples, their respective concentrations and the main sources of these pollutants and their contributions to the sampled total. Thus, it was possible to separate the total contributions of each source and use only the contributions of anthropogenic origin to define the emission factors (EF) and the crustal enrichment factors (EFc) for the different studied pollutants. We used these factors to compare different environments/studies. We chose two studies carried out previously, also in the MASP, in the Jânio Quadros (TJQ) and Rodoanel (TRA) tunnels, and found that these tunnels are respectively 2.3 and 3.8 times more polluted than the region from our study

Global automotive catalyst market (2020–2028) – Size, share and analysis report

Fourteen years of regulated air pollutants concentrations were analyzed in order to characterize the benefits of Brazil's emission control policies on air quality conditions and to evaluate the temporal patterns between 1996 and 2009 over the Metropolitan Area of São Paulo (MASP). MASP includes one of the largest cities in the world (São Paulo) and its light-duty vehicular fleet has a very important characteristic in that it uses, on a large scale, fuels such as ethanol derived from sugar cane and compressed natural gas. Nowadays, ethanol makes up more than 50% of the fuel used in Brazil. The frequent episodes with high ozone and PM10 concentration values in the MASP are mostly associated with vehicular emissions – primary emission of particles and gases enrolled in ozone photochemical production and formation of secondary fine particles. Although the fleet has increased at a substantial rate, annual mean values show a diminishing tendency for all pollutants except for ozone, which presents no significant tendency. This diminishing tendency in the analyzed period is due to the vehicular emission control program established by the Brazilian Government in 1986, called PROCONVE (Program for the Control of Vehicular Emission). Monthly mean values, as expected, show higher concentrations of all pollutants except for ozone during wintertime. The diurnal cycle of the pollutants in most of the stations shows two peaks, associated with rush hours, except for ozone, whose peak follows the maximum radiation incidence. Secondary (nocturnal) ozone concentration maxima were sometimes verified around three and four LST. Average values for weekdays and weekends showed that the different air quality stations showed different patterns for the pollutants. For ozone the concentrations were higher during the weekend when compared to weekdays.

Incorporating gridded concentration data in air pollution back trajectories analysis for source identification

The identification of air pollution sources is a challenging task due to the confounding effects of local and transboundary emitters. While the Potential Source Contribution Function (PSCF) is a useful tool for trajectory analysis and source identification, it can overestimate the impact of less polluted areas in which a trajectory event passed through. In this work, we propose incorporating air pollutant concentration fields from reanalysis data to improve the PSCF method's performance that avoids the overcontribution of less polluted areas. We develop the 3D-PSCF-CONC based on an updated three-dimensional version of the PSCF method (3D-PSCF). We used as a test case the Metropolitan Area of São Paulo (MASP) in Brazil, one of the most polluted regions in the world, for comparing the results of the conventional and the new PSCF method. A monitoring station in Vitória - Espírito Santo, Brazil which has smaller local emissions than MASP was used as an auxiliary test case. Hourly carbon monoxide (CO) and sulfur dioxide (SO2) concentrations from 2015 to 2019 of monitoring stations were analyzed. The daily average concentrations of CO and SO2 were used as a threshold on the probability calculations. An overall of 1825 backward trajectories from HYSPLIT version 4 was processed using the three models. CO and SO2 surface concentrations from MERRA-2, with a resolution of 0.5° x 0.625° was incorporated in the 3D-PSCF-CONC to correct the potential contribution calculation based on the air pollutant concentration field. Our results revealed that the 3D-PSCF-CONC reached a more consistent identification of local and regional sources, rather than emphasizing mostly the regional sources as the other PSCF methods. The 3D-PSCF-CONC reduced the potential contribution of less polluted and high precipitation areas. The analysis suggests a contribution of vehicular sources close to the receptor site in MASP and long-range transport of industrial emissions and biomass burning from the land clearing of sugarcane production. This work presents an important tool for understanding the air pollution process and source identification.

Physical and chemical properties of urban aerosols in São Paulo, Brazil: links between composition and size distribution of submicron particles

Abstract. In this work, the relationships between size and composition of submicron particles (PM1) were analyzed at an urban site in the Metropolitan Area of São Paulo (MASP), a megacity with about 21 million inhabitants. The measurements were carried out from 20 December 2016 to 15 March 2017. The chemical composition was measured with an Aerodyne Aerosol Chemical Speciation Monitor and size distribution with a TSI Scanning Mobility Particle Sizer 3082. PM1 mass concentrations in the MASP had an average mass concentration of 11.4 µg m−3. Organic aerosol (OA) dominated the PM1 composition (56 %), followed by sulfate (15 %) and equivalent black carbon (eBC, 13 %). Four OA classes were identified using positive matrix factorization: oxygenated organic aerosol (OOA, 40 % of OA), biomass burning organic aerosol (BBOA, 13 %), and two hydrocarbon-like OA components (a typical HOA related to vehicular emissions (16 %) and a second HOA (21 %) representing a mix of anthropogenic sources). Particle number concentrations averaged 12 100±6900 cm−3, dominated by the Aitken mode. The accumulation mode increased under relatively high-PM1 conditions, suggesting an enhancement of secondary organic aerosol (SOA) production. Conversely, the contribution of nucleation-mode particles was less dependent on PM1 levels, consistent with vehicular emissions. The relationship between aerosol size modes and PM1 composition was assessed by multilinear regression (MLR) models. Secondary inorganic aerosols were partitioned between Aitken and accumulation modes, related to condensation particle growth processes. Submicron mass loading in the accumulation mode was mostly associated with highly oxidized OOA and also traffic-related emissions. To the authors' knowledge, this is the first work that uses the MLR methodology to estimate the chemical composition of the different aerosol size modes. The chemical composition with size-dependent PM provides innovative information on the properties of both primary and secondary organic aerosols, as well as inorganic aerosols in a complex urban environment. The results emphasize the relevance of vehicular emissions to the air quality at MASP and highlight the key role of secondary processes on the PM1 ambient concentrations in the region since 56 % of PM1 mass loading was attributed to SOA and secondary inorganic aerosol.

How mobility restrictions policy and atmospheric conditions impacted air quality in the State of São Paulo during the COVID-19 outbreak

Mobility restrictions are among actions to prevent the spread of the COVID-19 pandemic and have been pointed as reasons for improving air quality, especially in large cities. However, it is crucial to assess the impact of atmospheric conditions on air quality and air pollutant dispersion in the face of the potential variability of all sources. In this study, the impact of mobility restrictions on the air quality was analyzed for the most populous Brazilian State, São Paulo, severely impacted by COVID-19. Ground-based air quality data (PM10, PM2.5, CO, SO2, NOx, NO2, NO, and O3) were used from 50 automatic air quality monitoring stations to evaluate the changes in concentrations before (January 01 - March 25) and during the partial quarantine (March 16 - June 30). Rainfall, fires, and daily cell phone mobility data were also used as supplementary information to the analyses. The Mann-Whitney U test was used to assess the heterogeneity of the air quality data during and before mobility restrictions. In general, the results demonstrated no substantial improvements in air quality for most of the pollutants when comparing before and during restrictions periods. Besides, when the analyzed period of 2020 is compared with the year 2019, there is no significant air quality improvement in the São Paulo State. However, special attention should be given to the Metropolitan Area of São Paulo (MASP), due to the vast population residing in this area and exposed to air pollution. The region reached an average decrease of 29% in CO, 28% in NOx, 40% in NO, 19% in SO2, 15% in PM2.5, and 8% in PM10 concentrations during the mobility restrictions period compared to the same period in 2019. The only pollutant that showed an increase in concentration was ozone, with a 20% increase compared to 2019 during the mobility restrictions period. Before the mobility restrictions period, the region reached an average decrease of 30% in CO, 39% in NOx, 63% in NO, 12% in SO2, 23% in PM2.5, 18% in PM10, and 16% in O3 concentrations when compared to the same period in 2019. On the other hand, Cubatão, a highly industrialized area, showed statistically significant increases above 20% for most monitored pollutants in both periods of 2020 compared to 2019. This study reinforces that the main driving force of pollutant concentration variability is the dynamics of the atmosphere at its various time scales. An abnormal rainy season, with above average rainfall before the restrictions and below average after it, generated a scenario in which the probable significant reductions in emissions did not substantially affect the concentration of pollutants.

Beyond megacities: tracking air pollution from urban areas and biomass burning in Brazil

Most of the world’s population lives in rural areas or small to medium-sized cities (totalling 68% of the world population), all of which are impacted by distant air pollution sources. In Brazil, primary pollutant emissions have decreased in urban centres because of government actions, while secondary pollutants such as surface ozone (O3) increased. In addition, O3 and its precursors can be worsening air quality in areas already affected by biofuels production, especially ethanol. We provide almost 3 months of hourly data (June 7, 2019 to August 25, 2019) for concentrations of O3, CO2 and other priority pollutants from a mobile station positioned to distinguish among pollutant plumes (biomass burning, metropolitan area of São Paulo (MASP) and other cities). Although the concentrations of O3 and CO2 were highest in the plumes from biomass burning, the MASP accounted for up to 80% of the O3 concentration in communities over 200 km away.

Non-methane hydrocarbons in the vicinity of a petrochemical complex in the Metropolitan Area of São Paulo, Brazil

Volatile organic compounds (VOCs) are fundamental in the atmospheric reactions, producing tropospheric ozone (O3) and secondary organic aerosols (SOA). We evaluated the hydrocarbons (HCs) near a petrochemical and industrial complex (PIC) in the metropolitan area of Sao Paulo (MASP). Air samples were hourly collected in two different sites during different days, 2016–2017. The most abundant compounds were toluene (1.5 ± 1.1 ppbv), cis-2-hexene (1.4 ± 1.9 ppbv), benzene (0.55 ± 0.66 ppbv), and m+p-xylene (0.58 ± 0.3 ppbv). HC concentrations observed at the BTP site (industrial) were approximately two times higher than those at the UFABC site (traffic). The aromatics presented the highest contribution at BTP (58%) and UFABC (56%). In addition, our comparison with other industrial areas worldwide showed a good agreement in the HC profile with Japan and the USA, suggesting the presence of similar emission sources. BTEX (benzene, toluene, ethylbenzene, m+p- and o-xylenes) correlations and ratios showed that despite vehicular emissions were the main sources of these compounds around PIC, there is the influence from industrial sources among others. Finally, to evaluate the potential impacts associated to PIC emissions, the formation of secondary pollutants was analyzed. Aromatic compounds represented ~98% and ~68% of the total SOA and O3 formation estimation, respectively. The lifetime cancer risk (LCR) for benzene was 5.75 × 10−6 and 4.25 × 10−6 for BTP and UFABC, respectively, which exceeds the US EPA recommendation (<1 × 10−6) and could negatively affect the populations health in this region

Physical and chemical characterization of the 2019 “black rain” event in the Metropolitan Area of São Paulo, Brazil

Aerosols emitted from biomass burning in South American tropical forests have been a concern in the last decades. On August 19th, 2019 darkened precipitation was observed over the metropolitan area of São Paulo (MASP), in an unprecedented event termed “black rain”, after intense biomass burning episodes in the South American hinterland. Satellite imagery, back trajectory analyses, and meteorological reports showed air masses transporting thick plumes of biomass burning aerosols originated in part from the Amazon Basin and Bolivia. Rainwater samples were collected in different sites of the metropolitan area, during and after the “black rain” event, and both physically and chemically characterized to assess the possible influence of biomass burning aerosols in the event. The collected samples in the “black rain” event presented high turbidity (above 70 NTU), and biomass burning organic tracers (levoglucosan, mannosan, and galactosan) were observed in higher concentrations in the “black rain” samples than in control ones (e.g. average levoglucosan of 0.33 μg mL−1, compared to 0.02 μg mL−1 after the event), with deposition fluxes more than three times higher during the event (1.04 mg m−2 and 0.31 mg m−2, respectively). The detection of glucose, xylose, and mannose, after hydrolysis of the solid material present in the “black rain” samples, strongly suggested the presence of plant cell wall material derived from the partial combustion of wood and grass matter. Total polycyclic aromatic hydrocarbons (PAHs) concentrations were, in general, higher during the event than in post-event control samples collected in the MASP (on average, almost 15 times higher than after the event), with a higher deposition flux (5.1 and 2.7 mg m−2, respectively). Overall, there are strong pieces of evidence that the long-range transport of smoke produced in South American forest fires was connected to the precipitation of darkened rainwater over the Metropolitan Area of São Paulo.