Ecological Risk Assessment Methods Research Articles

Occurrence and Contamination Levels of Polychlorinated Dibenzo-P-Dioxins (PCDDs) and Polychlorinated Dibenzofurans (PCDFs) in Soil and Sediment in the Vicinity of Recycled Metal Casting Villages: A Case Study in Vietnam

ABSTRACT This study aims to identify the occurrence and characteristics of PCDD/Fs in soil and sediment samples from secondary copper and aluminum villages in northern Vietnam using the HRGC/MS system. Additionally, it assesses the impact of PCDD/Fs on human health and the potential ecological risks they pose. The residual concentrations of PCDD/Fs in soil and sediment samples collected from the secondary copper Dai Bai village and secondary aluminum Man Xa village were as follows: 0.37 ± 0.29 ng TEQ/kg d.w. (ranging from 0.06 to 0.63 ng TEQ/kg d.w.); 4.88 ± 0.51 ng TEQ/kg d.w. (ranging from 0.512 to 12.17 ng TEQ/kg d.w.); 11.2 ± 5.31 ng TEQ/kg d.w. (ranging from 5.12 to 15.2 ng TEQ/kg d.w.); and 21 ± 12.7 ng TEQ/kg d.w. (ranging from 0.37 to 31.6 ng TEQ/kg d.w.), respectively. The distribution of PCDD/Fs indicated Octa- and Hepta-CDD/Fs as the dominant congeners with high chlorine content. The TEQ levels of PCDD/Fs in all soil and sediment samples were found to be below the allowable limit according to Vietnamese regulations, with the top contributor being 2,3,4,7,8-PeCDF. Samples collected near the production areas exhibited higher levels of PCDD/Fs compared to those collected farther away. The UNEP toolkit was utilized to determine the permissible dioxin TEQ concentrations suitable for livestock farming. The lifetime average daily doses (LADD) of PCDD/Fs via soil ingestion in Man Xa and Dai Bai were calculated as 0.04 × 10−3 and 1.54 × 10−3 pg TEQ/kg d.w. respectively. The relative cancer risks for humans were estimated at 0.05 × 10−12 and 2.05 × 10−12. Furthermore, the ecological risk assessment method indicates that dioxin in all soil and sediment samples near the aluminum recycling craft village had a negative impact on the ecosystem. In contrast, sediment samples taken away from the aluminum recycling craft village and all sediment soil samples in the bronze casting village did not show negative impacts on the ecosystem.

Oil-based drilling cutting pyrolysis residues-recycled fine powder sintered ceramsite: Basic properties, microsintering mechanism, lightweight concrete application and heavy metals solidification

Oil-based Drilling Cutting Pyrolysis Residue (ODPR) is a waste produced during oilfield drilling using oil-based mud. Recycled Fine Powder (RFP) consists of particles less than 0.16 mm, crushed and sieved from waste concrete. China's solid waste is characterized by high production, low utilization rates, and high pollution levels. This study explores the feasibility of preparing ceramsite from ODPR and RFP. By examining the effects of varying temperatures and proportions on the macroscopic and microscopic properties of ODPR-RFP ceramsite (ORC), the optimal process was determined: ODPR: RFP = 7:3, 2 % borax flux, 10 minutes ball milling, 1200℃ sintering temperature, and 30 minutes insulation. The resulting ORC, with a bulk density of 1120 kg/m³, cylinder compression strength of 10.50 MPa, and water absorption rate of 7.8 %, meets the "Lightweight aggregates and its test methods (GT/B17431.2)" standard. Batch production of ORC products of various sizes was conducted to evaluate their practical application in LC30 lightweight aggregate concrete. Replacing the aggregate in lightweight concrete with ORC yielded a concrete with excellent mixing performance, reaching a maximum strength of 31.2 MPa after 7d and 44.8 MPa after 28d. The damage pattern of ORC lightweight concrete is characterized by longitudinal splitting, with varied crack initiation and expansion paths. In the interfacial transition zone of ORC concrete, the ORC form a strong bond with the cement mortar, enhancing the strength of the lightweight concrete. Additionally, the leaching of heavy metals (HMs) from the ORC was examined to assess potential environmental pollution. The results indicated that preparing ORC from these two types of solid waste can effectively immobilize HMs, with a solidification rate of up to 92.10 %. Pb with high content is mainly solidified in the form of solid solution to form (Ba, Pb) SO4. The ecological risk assessment method for HMs shows that using this solid waste and process to prepare ORC does not pose HMs risks and is an environmentally friendly building material.

Regional ecological risk assessment through the application of production-living-ecology land use function indicators: a case study of the eco-economic zone of Yellow River Delta.

To date, land use structure information has been employed extensively for ecological risk assessment (ERA) purpose in regional/landscape scales; in contrast, land use function (LUF) information-based ERA research is still scarce. Therefore, it is necessary to carry out more ERA case studies in macroscale with the help of pertinent LUF indicators. As an important way to construct production-living-ecology LUF indexes, this study employs the weighted stacking method and related economic statistical data for regional ecological risk assessment (RERA) purpose within Yellow River Delta High-efficiency Eco-economic Zone (YRDHEZ), China. This YRDHEZ-RERA research pointed out that (1) it was rational to use a series of economic statistical data to more comprehensively and precisely characterize regional production and living function grades in YRDHEZ. (2) The Yellow River Delta had lower agriculture and non-agriculture production functions, whereas the rest of the zone had higher production functions. (3) Most people lived in the south part, whereas north coastal zone had very low population density; the east part had higher per capita disposable income of urban/rural households than that of west. (4) The south part of the zone had higher production/living functions and integrated ecological risk source intensity than those of north coastal zone, whereas the coastal zone had higher ecology function, eco-environmental vulnerability, and final integrated ecological risk than those of inland region. As for regional ecological risk management, establishing nature reserve with strict spatial governance for coastal/estuarine wetlands and coordinating production/ecology functions of coastal salterns/breeding ponds are relevant feasible measures.

Ecological and geological security risk assessment of underground space development in cold and arid canyon cities-Taking Ping'an District, Haidong City, Qinghai Province, as an example.

The ecological and geological problems caused by the rise of groundwater level due to the development of underground space in cold and arid canyon cities are particularly typical. Reasonably assessing the ecological and geological security risks of utilizing underground space is conducive to reducing the occurrence of ecological and geological problems during the construction and operation of underground engineering projects. Taking Ping'an District of Haidong City as an example, the topography and geomorphology of the research area were investigated in the field, and the distribution of topography and geomorphology in the research area was understood; through geological drilling and geotechnical engineering testing, the distribution of different strata in the research area was obtained; through pumping and seepage experiments, the recharge, runoff, and discharge relationship between surface water and groundwater in the research area and the water abundance of different strata are obtained, and the causes and mechanisms of geological safety risks in forest and grassland ecosystems, farmland ecosystems, and human settlements ecosystems were analyzed based on literature. Corresponding ecological geological safety risk assessment index systems and methods were established, and the ecological geological safety risks before and after the development of underground rail transit projects along both banks of the Huangshui River in the study area were evaluated. PRACTITIONER POINTS: The development of underground space in canyon type cities can easily lead to ecological and geological problems. Taking Haidong City, Qinghai Province, as an example, this study investigates the causes of ecological and geological problems caused by the development of underground spaces in canyon type cities. An ecological geological security risk assessment index system and method for canyon-type cities were established. An evaluation was conducted on the ecological and geological safety risks before and after the development of the underground rail transit projects on both sides of the research area.

Ecological risk assessment of dissolved heavy metals in the Yangtze River Estuary and Zhejiang coastal waters, China

The study applied a tiered ecological risk assessment method to evaluate the long-term status and trend of the ecological risks of dissolved heavy metals from 2011 to 2019 in the Yangtze River Estuary and Zhejiang coastal waters, China. The results for spring, summer, and autumn of 2019 indicated that Pb, Cd, and Zn posed no adverse ecological risk, Cu posed a potential ecological risk, and As posed an ecological risk. The annual results from 2011 to 2019 suggested that Pb, Cd, and Zn posed no adverse ecological risks, and As and Cu posed an ecological risk. The trend analysis in the nine years showed that the ecological risk of Cu is gradually decreasing, while that of As is still a concern. The overall trend is attributed to the environmental protection policies that reduced these contaminants' terrestrial sources and atmospheric sources.

Assessment of Heavy Metal Contamination and Ecological Risk in Soil within the Zheng–Bian–Luo Urban Agglomeration

As urbanization accelerates, the contamination of urban soil and the consequent health implications stemming from urban expansion are increasingly salient. In recent years, a plethora of cities and regions nationwide have embarked on rigorous soil geological surveys with a focus on environmental quality, yielding invaluable foundational data. This research aims to develop scientifically robust and rational land-use planning strategies while assessing the levels of heavy metal pollution and associated risks. The urban agglomeration encompassing Zhengzhou, Luoyang, and Kaifeng (referred to as Zheng–Bian–Luo Urban Agglomeration) in Henan Province was designated as the study area. Leveraging the Nemerow comprehensive index method alongside the Hakanson potential ecological risk assessment method, this study delved into the pollution levels and potential ecological ramifications of nine heavy metals, namely Cr, Mn, Ni, Cu, Zn, As, Cd, Pb, and Co. Research indicates that the hierarchy of individual potential ecological risks ranges from most to least significant as follows: Cd > Pb > Cr > Ni > Cu > Zn > As > Mn > Co. The concentrations of Cd in both Zhengzhou and Kaifeng surpassed the established background levels. Furthermore, the mean single-factor pollution index values for the heavy metals Cd and Zn exceeded 1, signifying a state of minor pollution. The Nemerow comprehensive index P of Cd and Zn is between 1 < Pcomp ≤ 2, which is considered mild pollution. The comprehensive P values of the other seven metal elements are all less than 0.7, reaching a clean (alert) level. Predominantly, the primary potential risk factor in the superficial soil of the Zheng–Bian–Luo urban agglomeration is Cd, while the ecological risk implications associated with other heavy metal elements are comparatively minimal. The soil environmental quality within the designated study area remains secure, although certain localized areas pose potential risks of heavy metal pollution. A comprehensive assessment of the current state of soil heavy metal pollution is essential to establish a theoretical foundation and provide technical support for soil environmental protection, pollution mitigation, and sustainable utilization.

Assessment of the impact of chemical pollution on endangered migratory fish in two major rivers of France, including spawning grounds

Water pollution is a one of the most contributors to aquatic biodiversity decline. Consequently, ecological risk assessment methods have been developed to investigate the effects of existing stresses on the environment, including the toxic effects of chemicals. One of the existing approaches to quantify toxic risks is called “Potentially Affected Fraction of species” (PAF), which estimates the potential loss of species within a group of species studied. In this study, the PAF method was applied to the Garonne catchment (southwest France) due to the limited information available on the involvement of water pollution in the decline of diadromous fish populations. This approach was used to quantify the potential toxic risk associated with chemical contamination of water for fish species. The objectives were to quantify this risk (1) in the Garonne and Dordogne rivers and (2) in the spawning grounds of two endangered anadromous fish species: the allis shad and the European sturgeon during the development period of their early life stages. Environmental pollution data was provided for 21 sites within the Garonne catchment between 2007 and 2022, and toxicity data was obtained specifically from freshwater toxicity tests on fish species. Then, for each site and each year, the potential toxic risk for a single substance (ssPAF) and for a mixture of substances (msPAF) was calculated and classified as high (>5 %), moderate (>1 % and < 5 %) or low (<1 %). Potential toxic risks were mostly moderate and mainly associated with: metals > other industrial pollutants and hygiene and care products > agrochemicals. In summary, this study highlights the probable involvement of water contamination on the decline, fate and restoration of diadromous fish populations in the Garonne catchment, focusing notably on the toxic effects on early life stages, a previously understudied topic.

Chemical Speciation, Leaching Behavior, and Environmental Risk Assessment of Trace Elements in the Bottom Ash from Biomass Power Plant.

Biomass combustion for power generation stands as a pivotal method in energy utilization, offering a promising approach for renewable energy utilization. However, the substantial volume of slag produced by biomass burning plants poses environmental challenges, impeding sustainable energy practices. This article systematically studies the characteristics of ash generated from typical biomass direct combustion power plant ash and analyzes the chemical composition, trace element content characteristics, leaching characteristics, and chemical forms of biomass bottom ash. Furthermore, it assesses the environmental ecology and bioavailability of trace elements in bottom ash using the ecological risk assessment method and RAC method. The results demonstrate that the biomass bottom ash contains plant nutrients, such as K, Ca, Mg, and P, while the content of harmful trace elements is lower than the relevant Chinese standards. In dissolution experiments, the leaching rate of nearly all elements remains exceptionally low, primarily due to the distribution of trace elements within the lattice structure of stable minerals. Trace elements predominantly exist in the residual phase, Cu and Zn primarily found in organic compounds and sulfide bound states, while other elements mostly exist in the form of iron manganese oxide bound states. Ecological risk assessment indicates a significant risk level for Cd, contrasting with the slight risk associated with other elements. RAC results indicated no ecological risk of all of the trace elements. Consequently, the utilization of bottom ash in agricultural and forestry soils is deemed to be viable. These findings serve as a crucial foundation for biomass bottom ash resource utilization and underpin the sustainable utilization of biomass energy.

Landscape ecological risk assessment across different terrain gradients in the Yellow River Basin

The Yellow River Basin is an important ecological barrier zone in China, and the landscape pattern has changed greatly due to intense human activities. It is of great significance to explore the dynamic forecasting of ecological risk based on terrain gradient for the ecological security of the Yellow River Basin. In this study, the distribution characteristics of ecological risk from 2000 to 2040 are evaluated by CA-Markov and ERI models. We put forward a new method of landscape ecological risk assessment based on terrain gradient and further analyzed the relationship between ecological risk and terrain index. The results showed that the proportion of the cultivated land and the grassland in the Yellow River basin is more than 73%, with the largest dynamic change in 2020. The ecological risk in the study area showed a spatial pattern of “high in the northwest and southwest, low in the east and south-central.” During the study period, the overall ecological risk showed a decreasing trend, and the high risk was reduced by four times. The future ecological risk of all terrain gradient will show a decreasing trend, the high risks mainly occurred in areas with “flat terrain with low terrain gradient and low vegetation coverage.” This study will provide a new perspective for the dynamic forecasting of ecological risk and the analysis of the change of ecological risk through terrain gradients.

Assessment of heavy metals and radionuclides (U and Th) contamination, and source identification of the Lékié Watershed sediments, Cameroon

This study aims to assess the pollution levels and sources of heavy metals (Al, Mn, Co, Ni, Sc and V) and radionuclides (Th and U) in sediments of Lékié Watershed in Cameroon. Surface sediment samples were collected from 14 stations across different areas of the Lékié Watershed. The heavy metal and radionuclide analysis on sediments were carried out and pollution indices such as enrichment factor (EF), contamination factor (CF), degree of contamination (DC), pollution load index (PLI), potential ecological risk assessment and multivariate statistical methods were utilized to evaluate the degree of contamination and estimate the source of metals in the sediments of Lékié Watershed. The results show that the mean concentrations are lower than those of the upper continental crust (UCC) reference values except those of Mn, Co, Ni, and V. The values of EF varied from moderate to severe enrichments (from 4 to 44). The contamination factor (1 < CF < 3), potential ecological risk (<40) and degree of contamination (<8) revealed a low to moderate degree of contamination. The majority of stations have PLI > 1, indicating pollution. The application of multivariate analysis to these metallic elements reveals contaminations attributed to anthropogenic activities, including the release of domestic, artisanal mining, and industrial effluents, as well as natural sources originating from the leaching of local surrounding soils and geological factors. To mitigate more pollution in this watershed which is closed from urbanization, it is crucial for local authorities to implement wastewater treatment measures.

Spatial distribution, ecological risk and health risk assessment of heavy metals in agricultural soil from Ankang basin, Shaanxi Province

In order to assess the heavy metal pollution features, ecological dangers, and health risk status posed to human beings by soils in the Ankang Basin, a study was conducted. This involved the collection of 38 surface soil samples, followed by the determination of elemental levels of arsenic, mercury, copper, cadmium, lead, chromium, nickel, and zinc. The concentrations of arsenic, mercury, copper, cadmium, lead, chromium, nickel, and zinc were quantified through the collection of 38 surface soil samples. The data obtained from the study was subjected to analysis and evaluation utilizing various academic methodologies, including the geo-accumulation index method, potential ecological risk assessment method, human health risk assessment model, and Monte Carlo simulation method. The findings indicated that the concentrations of the eight heavy metals in the soil above the background levels, with only Cadmium (Cd) marginally surpassing the threshold set for controlling soil pollution risks. The ground accumulation index revealed a higher degree of soil pollution with mercury, cadmium, copper, and zinc components. According to the possible ecological risk index, the presence of mercury and cadmium elements poses significant ecological hazards. The geographical distribution analysis suggests that these risks mostly stem from the combined impacts of human activities and the topographical and geomorphological characteristics of the river valley. The findings of the human health risk assessment indicated that the non-carcinogenic risk fell within acceptable limits. Additionally, it was observed that the carcinogenic risk associated with arsenic, mercury, cadmium, and nickel was comparatively greater for children as compared to adults. The results of the Monte Carlo simulations indicate that the non-carcinogenic hazards have a negligible effect on human health. However, it was seen that arsenic and nickel have a greater likelihood of presenting a substantial carcinogenic risk to humans, particularly in relation to the pediatric population, hence exerting a more pronounced impact on their health. In general, it is observed that conventional deterministic risk assessments tend to overstate the potential health risks associated with a given situation. Conversely, the utilization of Monte Carlo simulations has been found to effectively mitigate uncertainties in health risk assessments. It has been observed that children exhibit a higher vulnerability to both carcinogenic and non-carcinogenic health impacts resulting from exposure to heavy metals present in soil, in comparison to adults. It is recommended that residents prioritize the surveillance of soil heavy metals in relation to potential impacts on human health.

Occurrence of sulfonamides and tetracyclines in the coastal areas of the Yangtze River (China) Estuary.

Antibiotics have attracted global attention due to the ecological risks to environment. In this paper, solid-phase extraction and ultra-performance liquid chromatography triple quadrupole mass spectrometry (LC-MS/MS) were utilized to analyze the fugitive characteristics of 10 antibiotics of sulfonamides (sulfadiazine, sulfamethazine, sulfadimidine, sulfathiazole, sulfapyridine, sulfamethoxazole) and tetracyclines (tetracycline, oxytetracycline, chlortetracycline and doxycycline) in the coastal waters and surfece sediments of the Yangtze River Estuary and the ecological risks of antibiotics in water were estimated using ecological risk assessment method. The results have showed that 7 of the 10 antibiotics were detected in the water, with total concentrations ranging from 0.652 to 434.47ng/L. 8 antibiotics were detected in the sediment, with total concentrations ranging from 0.091 to 499.23ng/g. The main antibiotic species detected in the sediment and water varied seasonally. Higher concentrations in spatially distributed areas where rivers meet and where human activities have a more significant impact. The ecological risks were found to be higher in spring and autumn than those in winter and summer. Spatial variation in individual microbial communities was not evident in the sediments. The relationship between antibiotics and microorganisms in the environment was predominantly positive. Physical and chemical factors were significantly correlated for both antibiotics and microbial communities. This study can provide research ideas for other types of antibiotics and provide a basis for the prevention of antimicrobial resistance (AMR).

The Impacts of Molybdenum Exploration on Cd and Zn Contents in Surface Water: Evidence from a Molybdenum Mine in the Xiaoqinling Mountains

In order to study the impact of molybdenum ore development in a large molybdenum mining area in the Xiaoqinling Mountains on the water and sediment quality of the Wenyu stream, surface water, sediment, and surrounding rock samples were collected, and the Cd and Zn contents were analyzed. The pollution status and ecological risk degree of river water and sediment samples in the Wenyu stream watershed were evaluated using the single element pollution index method, geoaccumulation index method, Hakanson potential ecological risk assessment method, potentially toxic elements (PTEs) health risk assessment, and PTEs pollution comprehensive index method. Finally, the impact of mining development on the contents of Cd and Zn in the Wenyu stream were discussed, and the sources of pollution were identified. The study revealed that the levels of Cd and Zn in 23 water samples collected from the primary channel of the Wenyu stream were markedly higher compared to the unaffected contrast area. Similarly, the concentrations of Cd and Zn in the 17 sediment samples were significantly elevated compared to the average values in the reference area. These findings indicated that The Wenyu stream was heavily impacted by the molybdenum mining activities, resulting in a high ecological risk associated with the sediment in the primary channel. Acid mine drainage in the mining area, sediment release activities, and atmospheric dust fall are considered to be the main sources of PTEs polluting the Wenyu stream watershed. Relevant personnel should complete a thorough river water quality investigation and perform ecological environment restoration so as to ensure sustainable economic development.

A novel ecological risk assessment approach applied to Jiangsu coastal zone, China

Natural and anthropogenic risk factors contribute to ecological risks in coastal zones; however, the response of ecological entities (receptors) to disturbances varies with the risk source. We used the risk causal law as a guide to construct an ecological risk assessment method for Jiangsu coastal zone, China, with different ecological receptors as the research subjects. We screened the evaluation indicators for natural and anthropogenic risks, validated the evaluation results, and designed a method to map the integrated coastal ecological risk. The five typical ecological receptors exhibited different risk responses when faced with different disturbances. Among the natural risks, invasive species and seawater pollution had the largest differences in risk values. Of the anthropogenic risks, the largest differences in risk values were for reclamation sea farming and industry. The results of the habitat risk assessment model, which were based on the exposure–consequence framework, and those of the hazard–vulnerability–damage model showed a strong positive correlation. Furthermore, the T-test results were tested with P values of less than 0.05, and were not significantly different at the 95% confidence level; thus, the results were valid. The variability in the evaluation results of different ecological receptors was used to map the integrated ecological risk. High- and very-high-risk areas were distributed along the coastline and the edge of the radiating sand ridge, and moderate-risk areas were distributed within the high-risk mudflat areas. The ecological risk values were quantified for each shore section; very-high-risk areas were mainly distributed in the central and estuaries shore sections, and moderate-risk areas were mainly distributed in the southern shoreline sections. The exposure and consequence values calculated using InVEST-HRA model were used to select ten primary factors represented by coastal erosion and sewage discharge as well as five secondary factors represented by green tides and coastal engineering. Finally, we suggested future ecological protection and risk prevention measures based on the shore sections and primary and secondary factors. This study takes the causal relationship of the risk occurrence process as a guideline, and combines the reflected difference characteristics among the risk elements to provide scientific support for the practice of ecological risk prevention and governance in the coastal zone.

A prospective ecological risk assessment method based on exposure and ecological scenarios (ERA-EES) to determine soil ecological risks around metal mining areas

Soil heavy metal (HM) contamination around metal mining areas (MMAs) is a global concern that requires a cost-effective ecological risk assessment (ERA) method for preventive management. Traditional ERAs, comparing environmental HM concentrations with benchmarks, are labor- and cost-intensive in field investigations and chemical analyses, which challenge the management demands of numerous MMAs. In this study, a prospective ecological risk assessment method based on exposure and ecological scenario (ERA-EES) was developed to predict the eco-risk levels (low/medium/high) around MMAs prior to field sampling. Five exposure scenario indicators related to soil HM exposure and three ecological scenario indicators reflecting the soil bioreceptor response were selected and combined with the analytic hierarchy process and fuzzy comprehensive evaluation methods for ERA-EES development. Case application and performance evaluation with 67 MMAs in China demonstrated that the ERA-EES method had an overall effective and conservative performance when referring to potential ecological risk index (PERI) levels, with an accuracy of 0.87, kappa coefficient of 0.7, and low or medium eco-risk levels in PERI classified to high levels in ERA-EES. Overall, the selected scenario indicators could efficiently reflect the risk levels of soil HM pollution from mining activities. Besides, more regulatory efforts should be paid to the MMAs of nonferrous metals, underground and long-term mining and those located in southern China. This work provided a convenient and cost-effective prospective ERA method under the trend of ERA being tiered and refined, facilitating the risk management of various MMAs.

Pollution Characteristics, Source Analysis, and Risk Assessment of Heavy Metals in the Surrounding Farmlands of Manganese Mining Area

In order to understand the status of heavy metal pollution and the resulting ecological risk of farmland soil surrounding the manganese mining area, 174 soil samples were collected, and the heavy metals(Cu, Zn, Pb, Cr, Ni, Mn, As, and Hg) were analyzed. Principal component analysis (PCA) and the positive matrix factorization (PMF) model were used to determine the source of heavy metals in the soils. The single-factor pollution index method, geo-accumulation index method, potential ecological risk assessment method, and US EPA health risk assessment model were used to evaluate the ecological environment risk of heavy metals. The results showed that the average values of Cu, Zn, Cr, Ni, Mn, and Hg exceeded the background value of Guizhou. 100% of Zn samples and 38.86% of Cu samples exceeded the risk screening value for agricultural land soil pollution. Source analysis revealed that the main sources of soil heavy metals were mining emission, mixed agricultural activity and transportation, nature, and agricultural activities. The risk evaluation showed that Ni, Cr, Pb, and As belonged to the clean level, Hg and Cu were in a light pollution stage, Zn fell into the category of moderate contamination, and Mn reached the heavy pollution level. Cu, Zn, Pb, Cr, Ni, Mn, As, and Cd posed low potential ecological risk, while Hg caused a considerable potential ecological risk. In total, the integrated potential ecological risk of heavy metals was ranked "strong", eight types of heavy metals had carcinogenic risks and non-carcinogenic risks for children aged 0-5 years, and the main contributing factors were Cr and Mn, respectively.

The Impact of Molybdenum Mining on Cd Pollution along Wenyu Stream in Qinling Mountains, Northwest China

Mining has brought many environmental problems to the surrounding soil, water, and air, with toxic elements contaminating surface water, threatening ecological balance and human health. This study selected the Wenyu watershed downstream from a large molybdenum mine in the Qinling Mountains as the study area, aiming to explore the impact of molybdenum mining on surface water quality. The content characteristics of Cd, Pb, Cu, Cr and Hg in surface water, sediment, and rock samples were analyzed by field sampling and chemical testing. The results showed only obvious Cd pollution. The pollution status and ecological risk level of surface water and sediment samples in the Wenyu Stream watershed were evaluated using the single pollution index method, geo-accumulation index method, and Hakanson potential ecological risk assessment method. Finally, the sources of Cd pollution and the impact of mining on Cd distribution in the Wenyu Stream were comprehensively discussed. The research results showed that Cd content in the Wenyu Stream was significantly affected by mining activity and the coefficient of variation of Cd content reached 99.44%. Among 22 surface water samples, 21 samples met the Class II water standard, indicating a clean overall water quality of the Wenyu Stream, and only one sample exceeded the Class II water standard with a mild pollution level. All 15 sediment samples were polluted to varying degrees and the most severely polluted sample had reached a moderate to strong pollution level. Most of the samples were at a moderate pollution level. The potential ecological hazard indexes of Cd content were at medium to very strong risk level, indicating that the overall sediment in the main ditch of the Wenyu Stream was under a strong ecological risk level. The main sources of Cd pollution, including acid mine drainage, regional geological background, sediment release, and atmospheric dry and wet deposition, were discussed.

A remote sensing‐based approach for spatiotemporal refined assessment of freshwater wetland ecological risk in coastal zones: A case in Jiangsu's coastal zone

AbstractRapid, long‐term, and robust wetland ecological risk assessment is critical for managing coastal zones. In view of the characteristics of frequent human activities and broken plots in the coastal zone, the traditional assessment method is not fine enough. Satellite earth observation provides an unparalleled source of data for rapidly monitoring and assessing coastal wetland ecological risks through time and across a large spatial range. With the support of multi‐source remote sensing data such as precipitation, temperature, night light, land cover products, etc., a wetland ecological risk assessment method is established in this paper, and the wetland ecological risk is evaluated year by year by a grid. The evaluation results indicate that the ecological risk level of coastal wetlands in Jiangsu Province has shown an upward trend since 2015, with a high ecological risk in the north and a low ecological risk in the south, and the source area mainly appears in the northwest. Meanwhile, the year‐by‐year grid assessment can not only accurately describe the spatial and temporal distribution of wetland ecological risks but also clarify the spatial and temporal characteristics of risk source areas. Additionally, the results obtained by year‐on‐year assessment of consecutive years and clustering and zoning according to the time‐series can better represent the risk status of the time period and exclude the impact of accidental factors on the evaluation results. Although optimization for different types of wetlands can improve the accuracy of assessment, more wetland risk assessment with a longer term and a larger scale, combined with carbon emissions, will provide a basis for global wetland management.

Identification of aquatic ecological risk of bisphenol S in four Asian countries based on the SSD and alternative toxicity data of model species Danio rerio.

Bisphenol S (BPS), an organic compound and bisphenol analog, is commonly used as a substitute for bisphenol A. BPS is widely used in epoxy glues, can coatings, and thermal receipt papers; however, its risks have not been fully determined and the probability of its toxicity has been continuously suggested. In this study, we conducted BPS toxicity tests on aquatic plants (acute), cladocerans (acute and chronic), and fish (chronic) to determine its adverse effects, and calculated the toxicity values. Additionally, we conducted an ecological risk assessment of BPS in freshwater ecosystems with toxicity data from previous studies using the species sensitivity distribution method and BPS exposure data from 14 rivers in four countries in Asia (China, Japan, India, and South Korea). The chronic-based risk quotient (RQ) values of BPS in one river in China and two rivers in India were > 1, indicating a high ecological risk of BPS to aquatic organisms. The other four rivers in China showed medium ecological risk (0.1 < RQ < 1) and those in Japan and South Korea showed negligible chronic risk (RQ < 0.1) to aquatic organisms. We also suggest sensitive indicators in the model organism Danio rerio and highlighted the importance of the development of new method of ecological risk assessment. This study could provide new information that will assist in managing BPS and bisphenol analogs in freshwater ecosystems.

Initiatives on exploring the mechanism of eco‐hydrological response to land surface change and adaptive regulation in the Yellow River Basin

AbstractThe Yellow River Basin faces water scarcity and ecological fragility. Changes on the land surface, characterized by large‐scale soil and water conservation measures, have a significant impact on river runoff and ecological environment. However, there are still great uncertainties in the scientific understanding of the mechanisms by which multiple driver impact eco‐hydrological processes due to the diversity of land surfaces and the complexity of the coupling processes. As an international scientific frontier on interdisciplinary studies in climatology, hydrology, ecology, and other related fields, it is significant to study the mechanisms and assess the impacts of land surface change on eco‐hydrological risk to support ecological restoration plan and sustainable water resources utilization in the Yellow River Basin. Taking the Yellow River Basin as the study area, this study proposes several important research initiatives, focusing on addressing the ecological and water resources problems in the Loess Plateau. These initiatives include (1) to quantify the individual effect of land surface elements (e.g., vegetation, terraces, and check dam) and reveal the nonlinear driving mechanisms of multiple drivers on eco‐hydrological processes; (2) to construct a distributed eco‐hydrological model that couples dynamic land surface features, and simulate eco‐hydrological processes in a changing environment; (3) to improve the ecological risk assessment indicator system and methods for assessing the impacts of land surface changes on eco‐hydrological synergistic functions and ecological risk; (4) to establish an ecological regulation model based on multiobjective game theory and adopt an adaptive regulation mode for ecological risk management. The research could enrich the scientific understanding and theory of eco‐hydrology, and prompt disciplinary studies of ecology, hydrology, climatology, and other fields. The expected academic achievements will innovate eco‐hydrological simulation and assessment techniques in a changing environment, and strongly support the implementation of the national strategy for ecological protection and high‐quality development in the Yellow River Basin.