Methanol Transitions Research Articles

First detection of the J−1 → (J − 1)0 − E methanol maser transitions at J = 7 and 10

Context. Class I methanol masers provide sensitive information about the shocked environment around star-forming regions. Among the brightest Class I methanol masers, we have those in the J−1 → (J − 1)0 − E line series, currently reported for the J = 4 − 9 transitions, with the only exception being the J = 7 one at 181.295 GHz, and never expanded to higher J transitions. Aims. We aim to search for population inversion in the 7−1 → 60 − E and 10−1 → 90 − E methanol transition lines at 181.295 and 326.961 GHz, respectively, and also extend the number of known low-mass star-forming sources harboring Class I methanol masers. Methods. We employed the Atacama Pathfinder Experiment (APEX) 12 m telescope to survey low-mass Galactic sources, focusing on methanol emission lines. We built rotation diagrams for all sources with detected J = 7 methanol line transitions, while employing radiative transfer modeling (both in and out of local thermodynamic equilibrium) to characterize methanol excitation conditions in detail for one specific source with detected masers. Results. We detected the 7−1 → 60 − E and 10−1 → 90 − E methanol transitions in 6 out of 19 sources. Among them, we firmly determined the 10−1 → 90 − E maser nature in CARMA 7, L1641N, NGC 2024, and Serpens FIRS, and we show evidence for the presence of inverted population emission in the 7−1 → 60 − E line toward CARMA 7 and L1641N. This represents the first report of methanol maser emission in these particular transitions. Our study supports previous works indicating that conditions for Class I methanol maser emission are satisfied in low-mass star-forming regions and expands the range of detectable frequencies toward higher values.

Torsion-Rotational Transitions in Methanol as a Probe of Fundamental Physical Constants—Electron and Proton Masses

We report on the using of torsion-rotational transitions in the CH3OH and 13CH3OH molecules to evaluate possible variations of the electron-to-proton mass ratio μ = me/mp from spectral observations of emission lines detected in the microwave range towards the dense molecular cloud Orion-KL. An estimate of the upper limit on the relative changes in μ is obtained by two independent ways with 13CH3OH lines and with the combination of 13CH3OH and CH3OH lines. The calculated upper limit Δμ/μ < 1.1 × 10–8(1σ) is in line with the most stringent constraints on the variability of fundamental physical constants established by other astrophysical methods.

The C2H4O isomers in the oxidation of ethylene

A combined rotational spectroscopy, thermochemistry, and kinetic modeling study explores the mechanism of acetaldehyde (ethanal), vinyl alcohol (ethenol), and ethylene oxide (oxirane) formation in the oxidation of ethylene (ethene). Multiplexed quantitative detection of oxidation intermediates and products exiting a SiO2/SiC microreactor at 1700 K is demonstrated with the BrightSpec W-band chirped-pulse Fourier transform millimeter-wave spectrometer. The broadband rotational spectrum contains transitions of formaldehyde (CH2O), methoxy (CH3O), methanol (CH3OH), ketene (CH2CO), acetaldehyde (CH3CHO), syn-vinyl alcohol (syn-CH2CHOH), anti-vinyl alcohol (anti-CH2CHOH), oxirane (c-CH2OCH2), propyne (CH3CCH), and syn-propanal (syn-CH3CH2CHO). We focus on the three C2H4O species and deduce their concentration ratio [CH3CHO]:[CH2CHOH]:[c-CH2OCH2] = 1:0.7(2):0.06(2) by comparing the observed line intensities to those simulated with the PGOPHER software. Detailed thermochemistry of the C2H4O isomers and conformers is provided by Active Thermochemical Tables. The observed excess concentrations of vinyl alcohol and oxirane relative to the more stable acetaldehyde compared to the equilibrium ratio at 1700 K (1:0.087:0.000024), point to direct chemical pathways to these higher energy isomers. The mechanism for the formation of the three C2H4O isomers is analyzed using a 0-D homogenous reactor kinetics simulation for ethylene oxidation. The ratios of the C2H4O isomers concentrations predicted by the kinetic model are compared to the experimental values.

The 107 GHz Methanol Transition Is a Dasar in G0.253+0.016

We present observations of population anti-inversion in the 31 − 40 A + transition of CH3OH (methanol) at 107.013831 GHz toward the Galactic center cloud G0.253+0.016 (“The Brick”). Anti-inversion of molecular level populations can result in absorption lines against the cosmic microwave background (CMB) in a phenomenon known as a “dasar.” We model the physical conditions under which the 107 GHz methanol transition dases and determine that dasing occurs at densities below 106 cm−3 and column densities between 1013 and 1016 cm−2. We also find that for this transition, dasing does not strongly depend on the gas kinetic temperature. We evaluate the potential of this tool for future deep galaxy surveys. We note that other works have already reported absorption in this transition (e.g., in NGC 253), but we provide the first definitive evidence that it is absorption against the CMB rather than against undetected continuum sources.

Physical Environments of the Luminosity Outburst Source NGC 6334I Traced by Thermal and Maser Lines of Multiple Molecules

We have conducted a systematic line survey, primarily focused on transitions of the methanol and ammonia molecules, and monitoring observations of masers toward the high-mass star-forming region NGC 6334I. These observations were undertaken between 2019 and 2022 in the C, K, Ka, and Q bands with the Tianma Radio Telescope. In total, 63 CH3OH (including 11 class I and nine class II maser or maser candidate), 18 13CH3OH, and 34 NH3 (including seven maser or maser candidate) transitions were detected. The emission is likely associated with the luminosity outburst source MM1. Rotation diagram analysis of multiple ammonia transitions shows that the gas temperature in the molecular core was a factor of 2 higher than that measured in previous observations in the pre-burst stage. This suggests that the molecular core has likely been heated by radiation originating from the luminosity outburst. Maser variability in the methanol and excited-state OH masers shows a general trend that the maser components associated with the luminosity outburst have decreased in their intensity since 2020. The decay in the maser luminosity indicates that the outburst is possibly declining, and as a result, the duration of the MM1 luminosity outburst may be shorter than the predicted 40 yr duration. Compared to the masers detected toward another luminosity outburst source, G358.93-0.03, abundant class I methanol masers and strong water maser flares were also detected toward NGC 633I, but masers from rare class II methanol transitions and new molecules were absent toward NGC 6334I. The large number of detections of maser transitions toward the two burst sources provided a database for further maser modeling to explore the physical environments associated with accretion burst events.

New Methanol Maser Transitions and Maser Variability Identified from an Accretion Burst Source G358.93-0.03

The high-mass young stellar object G358.93-0.03 underwent an accretion burst during the period from 2019 January to June. Given its extraordinary conditions, a number of new maser transitions may have been naturally excited during the burst stage. Searching for new maser lines and monitoring maser variability associated with the accretion burst event are important for understanding the complex conditions of the massive star formation toward G358.93-0.03. In this work, using the Shanghai 65 m Tianma Radio Telescope, we continuously monitored the multiple maser (including methanol and water) transitions toward G358.93-0.03 during the burst in the period from 2019 March 14 to May 20. There were 23 CH3OH maser transitions and one H2O maser transition detected from the monitoring. Nearly all the detected maser transitions toward this source have dramatic variations in their intensities within a short period of ∼2 months. Eight new methanol transitions from G358.93-0.03 were identified to be masering in our observations based on their spectral profile, line width, intensity, and the rotation diagram. During the monitoring, the gas temperature of the clouds in the case of saturated masers can show a significant decline, indicating that the maser clouds were going through a cooling process, possibly associated with the propagation of a heat wave induced by the accretion burst. Some of the maser transitions were even detected with the second flares in 2019 April, which may be associated with the process of the heat-wave propagation induced by the same accretion burst acting on different maser positions.

FAUST

Aims. Methanol is a ubiquitous species commonly found in the molecular interstellar medium. It is also a crucial seed species for the build-up of chemical complexity in star forming regions. Thus, understanding how its abundance evolves during the star formation process and whether it enriches the emerging planetary system is of paramount importance. Methods. We used new data from the ALMA Large Program FAUST (Fifty AU STudy of the chemistry in the disc/envelope system of solar protostars) to study the methanol line emission towards the [BHB2007] 11 protobinary system (sources A and B), where a complex structure of filaments connecting the two sources with a larger circumbinary disc has previously been detected. Results. Twelve methanol lines have been detected with upper energies in the [45–537] K range along with one 13CH3OH transition and one methyl formate (CH3OCHO) line blended with one of the methanol transitions. The methanol emission is compact (FWHM ~ 0.5″) and encompasses both protostars, which are separated by only 0.2″ (28 au). In addition, the overall methanol line emission presents three velocity components, which are not spatially resolved by our observations. Nonetheless, a detailed analysis of the spatial origin of these three components suggests that they are associated with three different spatial regions, with two of them close to 11B and the third one associated with 11A. A radiative transfer analysis of the methanol lines gives a kinetic temperature of [100–140] K, an H2 volume density of 106–107 cm−3 and column density of a few 1018 cm−2 in all three components with a source size of ~0.15″. Thus, this hot and dense gas is highly enriched in methanol with an abundance as high as 10−5. Using previous continuum data, we show that dust opacity can potentially completely absorb the methanol line emission from the two binary objects. Conclusions. Although we cannot firmly exclude other possibilities, we suggest that the detected hot methanol is resulting from the shocked gas from the incoming filaments streaming towards [BHB2007] 11A and B, respectively. Higher spatial resolution observations are necessary to confirm this hypothesis.

Three-month Monitoring of the Variability toward W51 IRS2 with Ammonia, Water, and Methanol Transitions

A four-epoch monitoring program spanning ∼three months (from 2020 January 8 to April 7) for ammonia, water, and methanol transitions toward the high-mass star-forming region W51 IRS2 was conducted using the Shanghai 65 m Tianma Radio Telescope with its K-band (18–26.5 GHz) receiver. In total, 33 ammonia transitions and 16 methanol transitions were detected toward the target at least once during this monitoring program. Among them, 14 ammonia and 4 methanol transitions show maser emission characteristics. Rapid variabilities (including both increases and decreases) in the ammonia and methanol transitions were detected from both maser and thermal emissions during the three months of the monitoring. In addition, H2O masers with obvious variability were also detected. The results of the rotation diagram analysis for the ammonia and methanol quasi-thermal transitions show the variations in their rotational temperatures during the monitoring. The derived temperatures from the transitions with larger upper energies (E u /κ) generally decreased over the whole monitoring period, from January 8 to April 7, but those with smaller E u /κ first increased from January 8 to April 1, then rapidly decreased from April 1 to April 7. These findings support the suggestion that an inside-out heatwave propagation in W51 IRS2 was involved with the accretion burst over a short duration (only on the order of months) and caused the drastic variability behaviors of the different line transitions during high-mass star formation.

Emission from HCN and CH3OH in comets

Aims. The aim of this work is to characterise HCN and CH3OH emission from recent comets. Methods. We used the Onsala 20-m telescope to search for millimetre transitions of HCN towards a sample of 11 recent and mostly bright comets in the period from December 2016 to November 2019. Also, CH3OH was searched for in two comets. The HCN sample includes the interstellar comet 2I/Borisov. For the short-period comet 46P/Wirtanen, we were able to monitor the variation of HCN emission over a time-span of about one month. We performed radiative transfer modelling for the observed molecular emission by also including time-dependent effects due to the outgassing of molecules. Results. HCN was detected in six comets. Two of these are short-period comets and four are long-period. Six methanol transitions were detected in 46P/Wirtanen, enabling us to determine the gas kinetic temperature. From the observations, we determined the molecular production rates using time-dependent radiative transfer modelling. For five comets, we were able to determine that the HCN mixing ratios lie near 0.1% using contemporary water production rates, ${Q_{{{\rm{H}}_2}{\rm{O}}}}$, taken from other studies. This HCN mixing ratio was also found to be typical in our monitoring observations of 46P/Wirtanen but here we notice deviations of up to 0.2% on a daily timescale which could indicate short-time changes in outgassing activity. From our radiative transfer modelling of cometary comae, we find that time-dependent effects on the HCN level populations are of the order of 5–15% when ${Q_{{{\rm{H}}_2}{\rm{O}}}}$ is around 2 × 1028 mol s−1. The effects may be stronger for comets with lower ${Q_{{{\rm{H}}_2}{\rm{O}}}}$. The exact details of the time-dependent effects depend on the amount of neutral and electron collisions, radiative pumping, and molecular parameters such as the spontaneous rate coefficient.

Redshifted methanol absorption tracing infall motions of high-mass star formation regions

Context. Gravitational collapse is one of the most important processes in high-mass star formation. Compared with the classic blue-skewed profiles, redshifted absorption against continuum emission is a more reliable method to detect inward motions within high-mass star formation regions. Aims. We aim to test if methanol transitions can be used to trace infall motions within high-mass star formation regions. Methods. Using the Effelsberg-100 m, IRAM-30 m, and APEX-12 m telescopes, we carried out observations of 37 and 16 methanol transitions towards two well-known collapsing dense clumps, W31C (G10.6−0.4) and W3(OH), to search for redshifted absorption features or inverse P-Cygni profiles. Results. Redshifted absorption is observed in 14 and 11 methanol transitions towards W31C and W3(OH), respectively. The infall velocities fitted from a simple two-layer model agree with previously reported values derived from other tracers, suggesting that redshifted methanol absorption is a reliable tracer of infall motions within high-mass star formation regions. Our observations indicate the presence of large-scale inward motions, and the mass infall rates are roughly estimated to be ≳10−3 M⊙ yr−1, which supports the global hierarchical collapse and clump-fed scenario. Conclusions. With the aid of bright continuum sources and the overcooling of methanol transitions leading to enhanced absorption, redshifted methanol absorption can trace infall motions within high-mass star formation regions hosting bright H II regions.

Methanol at the Edge of the Galaxy: New Observations to Constrain the Galactic Habitable Zone

Abstract The Galactic Habitable Zone (GHZ) is a region believed hospitable for life. To further constrain the GHZ, observations have been conducted of the J = 2 → 1 transitions of methanol (CH3OH) at 97 GHz, toward 20 molecular clouds located in the outer Galaxy (R GC = 12.9–23.5 kpc), using the 12 m telescope of the Arizona Radio Observatory. Methanol was detected in 19 out of 20 observed clouds, including sources as far as R GC = 23.5 kpc. Identification was secured by the measurement of multiple asymmetry and torsional components in the J = 2 → 1 transition, which were resolved in the narrow line profiles observed (ΔV 1/2 ∼ 1–3 km s−1). From a radiative transfer analysis, column densities for these clouds of N tot = 0.1–1.5 × 1013 cm−2 were derived, corresponding to fractional abundances, relative to H2, of f (CH3OH) ∼ 0.2–4.9 × 10−9. The analysis also indicates that these clouds are cold (T K ∼ 10–25 K) and dense (n(H2) ∼ 106 cm−3), as found from previous H2CO observations. The methanol abundances in the outer Galaxy are comparable to those observed in colder molecular clouds in the solar neighborhood. The abundance of CH3OH therefore does not appear to decrease significantly with distances from the Galactic Center, even at R GC ∼ 20–23 kpc. Furthermore, the production of methanol is apparently not affected by the decline in metallicity with galactocentric distance. These observations suggest that organic chemistry is prevalent in the outer Galaxy, and methanol and other organic molecules may serve to assess the GHZ.

The candidates for Class I methanol masers

The collisional excitation of methanol molecule in non-dissociative magnetohydro-dynamic shock waves is considered. All essential chemical processes that determine methanol abundance in the gas are taken into account in the shock model. The large velocity gradient approximation is used in the calculations of energy level populations of the molecule. We calculate the optical depth for inverted methanol transitions, and present the list of candidates for Class I methanol masers that have collisional pumping mechanism.

Molecular line search towards the flaring 6.7-GHz methanol masers of G 24.33+0.13 and G 359.62−0.24: rare maser transitions detected

ABSTRACT We have performed a molecular line search towards the flaring 6.7-GHz masers G 24.33+0.13, and G 359.6−0.24 using the Australia Telescope Compact Array. We present spectra of the 6.7-GHz class II methanol and 22.2-GHz water masers towards these sources and provide a comparison with other recent flaring events these sources have experienced. We also detect the fourth example of a 23.4-GHz class I methanol maser and the 11th example of a 4.8-GHz formaldehyde maser towards G 24.33+0.13. Alongside these results, we also observe the previously detected ammonia (3,3) emission and report upper limits on the presence of various other cm-wavelength methanol, ammonia, and OH transitions. Our results are consistent with the flaring of G 24.33+0.13 being driven by a variable accretion rate in the host high mass young stellar object.

A study of submillimeter methanol absorption toward PKS 1830−211:

Context. Methanol is an important tracer to probe physical and chemical conditions in the interstellar medium of galaxies. Methanol is also the most sensitive target molecule for probing potential space-time variations of the proton-electron mass ratio, μ, a dimensionless constant of nature. Aims. We present an extensive study of the strongest submillimeter absorption lines of methanol (with rest frequencies between 300 and 520 GHz) in the z = 0.89 molecular absorber toward PKS 1830−211, the only high-redshift object in which methanol has been detected. Our goals are to constrain the excitation of the methanol lines and to investigate the cosmological invariance of μ based on their relative kinematics. Methods. We observed 14 transitions of methanol, five of the A-form and nine of the E-form, and three transitions of A-13CH3OH, with ALMA. We analyzed the line profiles with a Gaussian fitting and constructed a global line profile that is able to match all observations after allowing for variations of the source covering factor, line opacity scaling, and relative bulk velocity offsets. We explore methanol excitation by running the non local thermal equilibrium radiative transfer code RADEX on a grid of kinetic temperatures and H2 volume densities. Results. Methanol absorption is detected in only one of the two lines of sight (the southwest) to PKS 1830−211. There, the excitation analysis points to a cool (∼10 − 20 K) and dense (∼104 − 5 cm−3) methanol gas. Under these conditions, several methanol transitions become anti-inverted, with excitation temperatures below the temperature of the cosmic microwave background. In addition, we measure an abundance ratio A/E = 1.0 ± 0.1, an abundance ratio CH3OH/H2 ∼ 2 × 10−8, and a 12CH3OH/13CH3OH ratio 62 ± 3. Our analysis shows that the bulk velocities of the different transitions are primarily correlated with the observing epoch due to morphological changes in the background quasar’s emission. There is a weaker correlation between bulk velocities and the lower level energies of the transitions, which could be a signature of temperature-velocity gradients in the absorbing gas. As a result, we do not find evidence for variations of μ, and we estimate Δμ/μ=(−1.8 ± 1.2) × 10−7 at 1-σ from our multivariate linear regression. Conclusions. We set a robust upper limit |Δμ/μ| &lt; 3.6 × 10−7 (3σ) for the invariance of μ at a look-back time of half the present age of the Universe. Our analysis highlights that systematics need to be carefully taken into account in future radio molecular absorption studies aimed at testing Δμ/μ below the 10−7 horizon.

A global view on star formation: the GLOSTAR Galactic plane survey

The Cygnus X complex is covered by the Global View of Star Formation in the Milky Way (GLOSTAR) survey, an unbiased radio-wavelength Galactic plane survey, in 4–8 GHz continuum radiation and several spectral lines. The GLOSTAR survey observed the 6.7 GHz transition of methanol (CH3OH), an exclusive tracer of high-mass young stellar objects. Using the Very Large Array in both the B and D configurations, we observed an area in Cygnus X of 7° × 3° in size and simultaneously covered the methanol line and the continuum, allowing cross-registration. We detected thirteen sources with Class II methanol maser emission and one source with methanol absorption. Two methanol maser sources are newly detected; in addition, we found four new velocity components associated with known masers. Five masers are concentrated in the DR21 ridge and W75N. We determined the characteristics of the detected masers and investigated the association with infrared, (sub)millimeter, and radio continuum emission. All maser sources are associated with (sub)millimeter dust continuum emission, which is consistent with the picture of masers tracing regions in an active stage of star formation. On the other hand, only five masers (38 ± 17%) have radio continuum counterparts seen with GLOSTAR within ~1″, testifying to their youth. Comparing the distributions of the bolometric luminosity and the luminosity-to-mass ratio of cores that host 6.7 GHz methanol masers with those of the full core population, we identified lower limits LBol ~ 200 L⊙ and LBol/Mcore ~ 1 L⊙M⊙−1 for a dust source to host maser emission.

Microwave Zeeman effect of methanol

Zeeman effect of the rotational spectrum of methanol has been measured in a magnetic field of 7.0 kG produced by rectangular bar magnets of neodymium. Thirty low J, K (J ≤ 10, K ≤ 3) rotational transitions, including those in the excited torsional states, were observed. Their Zeeman effect splittings were measured with uncertainties of about 5%, and the four diagonal elements of the rotational g tensor, including the effect of internal rotation of the methyl group, were determined. Using this g tensor, the g factors of low J, K levels can be calculated with an uncertainty of about 5%. They allow us to calculate Zeeman shifts of rotational transitions of methanol observed in interstellar space.

Simulating the circumstellar H2CO and CH3OH chemistry of young stellar objects using a spherical physical-chemical model

Context. Young stellar objects (YSOs) and their environments are generally geometrically and dynamically challenging to model, and the corresponding chemistry is often dominated by regions in non-thermal equilibrium. In addition, modern astrochemical models have to consider not only gas-phase reactions, but also solid-state reactions on icy dust grains. Solving the geometrical, physical, and chemical boundary conditions simultaneously requires a high computational effort and still runs the risk of false predictions due to the intrinsically non-linear effects that can occur. As a first step, solving problems of reduced complexity is helpful to guide more sophisticated approaches. Aims. The objective of this work is to test a model that uses shell-like structures (i.e., assuming a power-law number density and temperature gradient of the environment surrounding the YSO) to approximate the geometry and physical structure of YSOs, that in turn utilizes an advanced chemical model that includes gas-phase and solid-state reactions to model the chemical abundances of key species. A special focus is set on formaldehyde (H2CO) and methanol (CH3OH) as these molecules can be traced in the gas phase but are produced on icy dust grains. Furthermore, this kind of molecule is believed to be key to understanding the abundance of more complex species. We compare the influence of the geometry of the object on the molecular abundances with the effect induced by its chemistry. Methods. We set up a model that combines a grain-gas phase chemical model with a physical model of YSOs. The model ignores jets, shocks, and external radiation fields and concentrates on the physical conditions of spherically symmetric YSOs with a density and temperature gradient derived from available spectral energy distribution observations in the infrared. In addition, new observational data are presented using the APEX 12 m and the IRAM 30 m telescopes. Formaldehyde and methanol transitions have been searched for in three YSOs (R CrA-IRS 5A, C1333-IRAS 2A, and L1551-IRS 5) that can be categorized as Class 0 and Class 1 objects, and in the pre-stellar core L1544. The observed abundances of H2CO and CH3OH are compared with those calculated by the spherical physical-chemical model. Results. Compared to a standard “ρ and T constant” model, i.e., a homogeneous (flat) density and temperature distribution, using number density and temperature gradients results in reduced abundances for the CO hydrogenation products formaldehyde and methanol. However, this geometric effect is generally not large, and depends on the source and on the molecular species under investigation. Although the current model uses simplified geometric assumptions the observed abundances of H2CO and CH3OH are well reproduced for the quiescent Class 1 object R CrA-IRS 5A. Our model tends to overestimate formaldehyde and methanol abundances for sources in early evolutionary stages, like the pre-stellar core L1544 or NGC 1333-IRS 2A (Class 0). Observational results on hydrogen peroxide and water that have also been predicted by our model are discussed elsewhere.

Seeds of Life in Space (SOLIS)

Aims. The Seeds Of Life In Space IRAM/NOEMA large program aims at studying a set of crucial complex organic molecules in a sample of sources with a well-known physical structure that covers the various phases of solar-type star formation. One representative object of the transition from the prestellar core to the protostar phases has been observed toward the very low luminosity object (VeLLO) L1521F. This type of source is important to study to link prestellar cores and Class 0 sources and also to constrain the chemical evolution during the process of star formation. Methods. Two frequency windows (81.6–82.6 GHz and 96.65–97.65 GHz) were used to observe the emission from several complex organics toward the L1521F VeLLO. These setups cover transitions of ketene (H2CCO), propyne (CH3CCH), formamide (NH2CHO), methoxy (CH3O), methanol (CH3OH), dimethyl ether (CH3OCH3), and methyl formate (HCOOCH3). Results. Only two transitions of methanol (A+, E2) have been detected in the narrow window centered at 96.7 GHz (with an upper limit on E1) in a very compact emission blob (~7′′ corresponding to ~1000 au) toward the northeast of the L1521F protostar. The CS 2–1 transition is also detected within the WideX bandwidth. Consistently with what has been found in prestellar cores, the methanol emission appears ~1000 au away from the dust peak. The location of the methanol blob coincides with one of the filaments that have previously been reported in the literature. The excitation temperature of the gas inferred from methanol is (10 ± 2) K, while the H2 gas density (estimated from the detected CS 2–1 emission and previous CS 5–4 ALMA observations) is a factor &gt;25 higher than the density in the surrounding environment (n(H2) ≥ 107 cm−3). Conclusions. Based on its compactness, low excitation temperature, and high gas density, we suggest that the methanol emission detected with NOEMA is (i) either a cold and dense shock-induced blob that formed recently (≤ a few hundred years) by infalling gas or (ii) a cold and dense fragment that may just have been formed as a result of the intense gas dynamics within the L1521F VeLLO system.

Long-term multi-frequency maser observations of the intermediate-mass young stellar object G107.298+5.639

Context. Periodic flares of maser emission are thought to be induced either by variations of the seed photon flux in young binary systems or the pump rate regulated by stellar and accretion luminosities. Aims. We seek to study the variability of four maser transitions of three different species in G107.298+5.639 to constrain the dominant mechanism of periodic flares. Methods. Light curves of the 6.7 GHz methanol and 22.2 GHz water vapour maser were obtained with the Torun 32 m radio telescope over 39 and 34 cycles, respectively. The target was also monitored at the 1.6 GHz hydroxyl transitions with the Nançay radio telescope over 13 cycles. All these maser lines were imaged using VLBI arrays. Results. The study confirms alternating flares of the methanol and water masers with a period of 34.4 d and reveals the synchronised behaviour of the methanol and hydroxyl masers in this source. The observed spatial distribution of the methanol maser cloudlets and the measured time delays of the flares of individual features imply a ring-like structure of radius 240 au and thickness 30 au. Internal proper motions indicate that the velocity of methanol cloudlets is dominated by a disc-wind component of about 5 km s−1. The methanol emission detected during only one VLBI observation is located in a region about 550 au from a central star, which also exhibits OH maser flares. The erratic appearance of methanol features can be related to a powering object of relatively low luminosity which, during some variability cycles, can excite molecules only in the nearest part of the disc. A careful analysis of the maser and infrared light curves reveal a strong correlation between the 6.7 GHz line and the infrared flux densities supporting a radiative pumping of the maser. Conclusions. The synchronised behaviour of the hydroxyl 1665/1667 MHz and 6.7 GHz methanol transitions indicates a common pumping mechanism for the periodic flares of G107.298+5.639.

36 GHz methanol lines from nearby galaxies: maser or quasi-thermal emission?

Methanol (CH3OH) is one of the most abundant interstellar molecules, offering a vast number of transitions to be studied, including many maser lines. However, while the strongest Galactic CH3OH lines, the so-called class II masers, show no indications for the presence of superluminous counterparts in external galaxies, the less luminous Galactic class I sources appear to be different. Here we report class I 36 GHz (λ ≈ 0.8 cm) CH3OH 4−1 → 30 E line emission from the nearby galaxies Maffei 2 (D ≈ 6 Mpc) and IC 342 (D ≈ 3.5 Mpc), measured with the 100 m telescope at Effelsberg at three different epochs within a time span of about five weeks. The 36 GHz methanol line of Maffei 2 is the second most luminous among the sources detected with certainty outside the Local Group of galaxies. This is not matched by the moderate infrared luminosity of Maffei 2. Higher-resolution data are required to check whether this is related to its prominent bar and associated shocks. Upper limits for M 82, NGC 4388, NGC 5728 and Arp 220 are also presented. The previously reported detection of 36 GHz maser emission in Arp 220 is not confirmed. Nondetections are reported from the related class I 44 GHz (λ ≈ 0.7 cm) methanol transition towards Maffei 2 and IC 342, indicating that this line is not stronger than its 36 GHz counterpart. In contrast to the previously detected 36 GHz CH3OH emission in NGC 253 and NGC 4945, our 36 GHz profiles towards Maffei 2 and IC 342 are similar to those of previously detected nonmasing lines from other molecular species. However, by analogy to our Galactic center region, it may well be possible that the 36 GHz methanol lines in Maffei 2 and IC 342 are composed of a large number of faint and narrow maser features that remain spatially unresolved. In view of this, a search for a weak broad 36 GHz line component would also be desirable in NGC 253 and NGC 4945.