Metamorphic Province Research Articles

Orogen‐scale uniformity of recorded granulite facies conditions due to thermal buffering and melt retention

AbstractGranulite facies metapelitic gneisses collected over a km exposed area of the Kakamas Domain of the Namaqua–Natal Metamorphic Province in southern Namibia all contain similar garnet–sillimanite–cordierite–biotite–quartz–K‐feldspar–ilmenite plagioclase magnetite mineral assemblages. These assemblages are interpreted to have equilibrated at suprasolidus retrograde conditions, and most samples contain distinct biotite‐ or sillimanite‐free peak assemblages. Pseudosection modelling constrains extremely uniform residuum solidus conditions of kbar and °C for the entire Kakamas Domain. Estimated peak metamorphic conditions overlap with these but are more smeared out at between 4 and 7 kbar at 760°C to potentially more than 900°C. The uniformity of residuum solidus conditions is not coincidental, but is a consequence of retrograde re‐equilibration due to minor melt retention after peak metamorphism. Re‐equilibration could only stop once all retained melt had crystallized, which required the concomitant growth of a hydrous mineral to account for its H2O component. Biotite is the most stable hydrous mineral in these rocks, such that the residuum – conditions in the Kakamas Domain reflect the upper‐ stability of biotite, and also corresponds to the intersection of the well‐known biotite–sillimanite melting reaction that consumed all biotite during prograde metamorphism. The calculated melt fertility of the sample suite indicates that the variable amounts of heat consumed to overcome the latent heat of fusion could have caused a 25°C spread in the peak temperature achieved by the most and least fertile samples. Peak temperature in the Kakamas Domain may have been as much as 100°C higher than residuum solidus conditions for specific samples but cannot be confidently constrained as it is obscured by the effects of both thermal buffering during prograde metamorphism and melt retention during retrograde metamorphism. Both processes are an inescapable part of the evolution of all granulite facies rocks, but their effects are most pronounced in fertile rocks like metapelites that are traditionally the preferred lithology for quantifying the – history of exhumed terranes.

Geology of the Mutis Complex, Miomaffo, West Timor

Mesozoic forearc assemblages are widespread across Indonesia, and these are also exposed in the overthrust terranes on Timor. The oldest rocks in the allochthonous Mutis Complex, West Timor are Mesozoic basaltic volcaniclastic rocks and melange containing blocks of normal mid-ocean ridge basalt (N-MORB) basalt (194 ± 5 Ma), amphibolite (metamorphism at 184 ± 6 Ma), garnet and actinolite-bearing schists, arkosic sandstone and volcanogenic sedimentary rocks. Based on the large component of Jurassic material, these rocks were probably derived from the Woyla terrane. The eastern part of the Miomaffo massif is complexly deformed with a dominant foliation overprinted by several fold and fault events including late normal cataclastic zones. This sequence is intruded by calc-alkaline andesitic dykes (possibly in the Eocene). The Central Sector of the massif is a block of high-strain greenschist facies rocks where the primary texture can no longer be recognised, but the bulk composition is the same as the volcaniclastic rocks in the east. Further west is an amphibolite facies metamorphic province. Amphibolite from the Western Sector have the same N-MORB composition as the basalt in the east, but the gneissic rocks have a higher proportion of arc-sourced protoliths. The peak metamorphic conditions were 650 °C and 0.9 GPa. This metamorphic event occurred at 37 Ma, reflecting subduction on the southeast margin of Sundaland, whereas the low-grade Mesozoic metamorphism of the Eastern Sector of the massif occurred in the accretionary prism along the Woyla Arc. The Mutis Complex at Miomaffo demonstrates the complex geological history of Mesozoic rocks in eastern Indonesia.

Re-evaluating metamorphism in the southern Natal Province, South Africa

Abstract The metamorphic conditions of the Natal Metamorphic Province (NMP) have been the focus of previous studies to assist with Rodinia reconstructions but there are limited constraints on the age of metamorphism. We use a combination of modern techniques to provide new constraints on the conditions and timing of metamorphism in the two southernmost terranes: the Mzumbe and Margate. Metamorphism reached granulite facies, 780–834°C at 3.9–7.8 kbar in the Mzumbe Terrane and 850–892°C at 5.7–6.1 kbar in the Margate Terrane. The new pressure and temperature constraints are supportive of isobaric cooling in the Margate Terrane as previously proposed. Peak metamorphism of the two terranes is shown to have occurred c. 40 myr apart, which contrasts strongly with previous assumptions of coeval metamorphism. While the age of peak metamorphism of the Margate Terrane (1032.7 ± 4.7 Ma) coincides with the tectonism and magmatism associated with the emplacement of the Oribi Gorge Suite ( c. 1050–1030 Ma), the age of metamorphism of the Mzumbe Terrane (987.4 ± 8.1 Ma) occurs c. 30–40 myr after tectonism is previously thought to have finished. We propose that models of advective cooling during transcurrent shearing can explain the metamorphic conditions and timing of the NMP.

The genesis of hydrothermal veins in the Aukam valley SW Namibia– A far field consequence of Pangean rifting?

High purity fluorite veins (acid grade > 97 % CaF2) are generally rare in a global context. The fluorite-(±quartz-calcite) veins in the Aukam Valley mining district in SW Namibia have not previously been studied but due to their excellent exposure they are an ideal natural laboratory to study such mineralization. These veins cross-cut Mesoproterozoic high-grade gneisses and granites (Namaqua-Natal Metamorphic Province) close to the unconformity with the overlying late-Neoproterozoic Nama Group sedimentary rock cover. Based on the regional context, their genesis has been assumed to be related to nearby fluorite-bearing pegmatites. However, the present contribution provides new microthermometry data from vein fluorite (with 25.0–25.6 wt% NaCl and Th of 270–300 °C) that indicate precipitation from a mixed fluid with two chemically contrasting end-members for the early paragenetic fluorite stage. However, it was not possible to identify the chemical composition of the endmembers. Based on the chemical composition of the fluid mixture and the regional geological context, we propose that these end-members are F-rich brines sourced from the Namaqua basement and Ca-rich limestone-derived formation fluids of the Nama Group. A fluorite-overgrowing quartz precipitation is likely the effect of post-mixing fluid cooling as the fluid inclusions hosted in quartz show lower homogenization temperatures (Th 230–260 °C) with similar salinity. Locally, late-stage calcite is recognized with fluid inclusion compositions (0.2–2.7 wt% NaCl and Th of 60–92 °C) different from those observed in the fluorite and quartz. With significantly lower homogenization temperatures, they likely represent precipitates formed during the shutdown and collapse of the hydrothermal system. The fluorite veins are hosted in post-Cambrian N-trending brittle structures that probably formed during the opening of the South Atlantic in late Mesozoic times. Interestingly, similar massive fluorite mineralization on both sides of the Atlantic Ocean is also likely associated with Pangea rifting and known from numerous mining districts operating on unconformity-related hydrothermal veins in Central and North America, northern Africa and Europe.

Tectonic evolution of the Aggeneys-Gamsberg Ore District, South Africa, and implications for the geodynamic setting of the Namaqua Sector

Understanding the deformation history of the structurally complex Aggeneys-Gamsberg Ore District (A-GOD), in the Namaqua Sector of the Mesoproterozoic Namaqua-Natal Metamorphic Province of South Africa, is key to discovering additional metasediment-hosted base metal sulphide mineralization. Although several studies have examined the structure of the main ore deposits and outcrops in the district, and others have investigated the timing of sedimentation, magmatism, and metamorphism, no previous studies have focused on integrating these two datasets. We therefore combine structural observations and the resulting relative timeline of events with new and existing zircon U-Pb geochronology, to yield a temporally constrained tectonic history for the district.The regionally recognized Paleoproterozoic D1 deformation is not recorded in the A-GOD, which preserves only Mesoproterozoic rocks. The largely stratiform base metal deposits occur near the top of a sequence of metamorphosed siliciclastic sediments (Wortel and Hotson Formations), deposited after 1261 ± 5 Ma (youngest reliable detrital zircons). These metasediments are tectonically interleaved with the intrusive ∼ 1190 Ma Little Namaqualand Suite (Aroams Gneiss) and younger ∼ 1175–1145 Ma metagranitoids (Achab Gneiss, Hoogoor Gneiss, aplite sills). Magmatism occurred early during D2a deformation, which created kilometre-scale isoclinal folds and thrusts during S/SW-directed contraction, as recorded at the Swartberg and Broken Hill-Deeps deposits. Associated M2a metamorphism is dated at ∼ 1200 Ma (metamorphic zircon rims), but this was not the peak metamorphic episode as previously thought. The sequence was then exhumed, and the unconformably overlying clastics and bimodal volcanics of the Koeris Formation were deposited in local transtensional pull-apart basins at ∼ 1130 Ma. Thrust stacking in the Aggeneys Mountains may have occurred during subsequent D2c contraction, associated with ∼ 1075 Ma M2c metamorphism, but evidence remains cryptic. The entire sequence is affected by kilometre-scale sheath folds that close downwards to the ∼ ENE (as at Gamsberg and the Quarry Fold Nappe), associated with ∼ ENE-trending open, upright folds. These developed during D3a ∼ ENE-directed extensional to constrictional shearing at peak M3 amphibolite-facies conditions, which re-used the gently dipping D2 regional fabric and overprinted it with new ∼ E-W trending D3 linear features. Abundant metamorphic zircon dates suggest an age of ∼ 1025 Ma for D3a and M3. Ongoing extension at retrograde conditions reactivated earlier structures, such as the Swartberg Thrust, as D3b low-angle, ductile–brittle detachment faults. Finally, dextral transform motion created local D4 monoclines and dextral strike-slip faults, possibly associated with ∼ 1000 Ma M4 metamorphic zircon growth and emplacement of a regional pegmatite swarm.The A-GOD has traditionally been fitted into a regional tectonic model involving accretion of distinct terranes onto the Kaapvaal Craton, during the polyphase ∼ 1.2–1.0 Ga Namaquan Orogeny. In contrast, recent studies propose that the entire Namaqua Sector instead occupied a back-arc setting between ∼ 1.35 and < 1.1 Ga. Our results support a hybrid model, involving accretion and translation of previously extended crustal fragments against the craton, with initially the entire Namaqua Sector - but later only the western portion - located in a hot back-arc setting influenced by subducting slab dynamics.

The Ordovician System of South Africa: a review

AbstractOutcrops of the Ordovician System in South Africa are extensive; they cover significant portions of the Northern, Western and Eastern Cape provinces as part of the Cape Fold Belt as well as the KwaZulu-Natal Province as supracrustal cover overlying the Natal sector of the Paleoproterozoic Namaqua-Natal metamorphic province. Within the Cape Fold Belt, Ordovician rocks of the Table Mountain Group (Piekenierskloof, Graafwater, Peninsula, Pakhuis and Cedarberg formations as well as the enigmatic Sardinia Bay Formation) outcrop extensively whilst pre-Cape rocks of the Kansa Group (Vaartwell, Uitvlug, Gezwinds Kraal and Schoongezigt formations) and Schoemanspoort Formation are present within the Kango Inlier encapsulated by the fold belt. The Natal Group (Durban and Mariannhill formations) is entirely located within KwaZulu-Natal. For the most part, these metasiliciclastic rocks are markedly unfossiliferous except for the world class fossil deposits of the Cedarberg Formation and important trace fossil sites in the Graafwater, Peninsula and Pakhuis formations. The lack of palaeontological material and other accurate geochronological proxies in these successions (as well as those of the Kansa and Natal groups and Schoemanspoort Formation) makes estimations of relative age constraints tenuous at best and difficult to correlate with global Ordovician chronostratigraphic frameworks. Regardless of the challenges faced in correlating these rocks within global frameworks, these rocks provide a unique low latitude glimpse into Earth surface processes and the feedback loops that ensued within the biological realm along the southern margin of Gondwana.

Provenance of metasedimentary rocks of the Kheis Terrane and Kakamas Domain: support for accretionary tectonics during the development of the western Namaqua-Natal metamorphic province

Abstract The ~1 200 to 1 000 Ma Namaqua-Natal Metamorphic Province (NNMP) is part of a major orogenic belt in the west-central parts of South Africa and most likely formed during the convergence of the Laurentia and Kalahari cratons during the assembly of Rodinia. Controversy exists regarding the mode of formation of the Namaqua sector of the NNMP, with some supporting the idea of accretion of different crustal fragments while others argue that it formed in a continental back-arc setting. Here we address this controversy and provide information regarding the provenance of two metasedimentary successions that are preserved to the east and west of the Trooilapspan shear zone, which represents the Eastern Namaqua Front. 207Pb/206Pb SHRIMP ages for detrital zircon grains sampled from the Keis supergroup, which is preserved in the Kheis Terrane and situated on the Kalahari Craton, support derivation from Archaean to Paleoproterozoic source areas on the Kaapvaal Craton. In contrast, SHRIMP ages from detrital zircon grains of the Korannaland Group, which forms the metamorphosed supracrustal sequence of the Kakamas Domain, show derivation from late-Paleoproterozoic to Mesoproterozoic source areas like the Bushmanland and Richtersveld domains as well as the gneissic basement of the Kakamas Domain. The zircon age distribution data show that the metasedimentary rocks of the Keis supergroup and Korannaland Group did not obtain detrital material from the same source areas during their deposition, and that the Keis supergroup never served as a source for the detrital material in the Korannaland Group. This indicates that these successions had different geological histories prior to the formation of the NNMP, which supports the accretionary model for the development of the Namaqua Sector of the NNMP.

A Comparison between the ∼1.08–1.13 Ga Volcano-Sedimentary Koras Group and Plutonic Keimoes Suite: Insights into the Post-Collisional Tectono-Magmatic Evolution of the Eastern Namaqua Metamorphic Province, South Africa

A Comparison between the ∼1.08–1.13 Ga Volcano-Sedimentary Koras Group and Plutonic Keimoes Suite: Insights into the Post-Collisional Tectono-Magmatic Evolution of the Eastern Namaqua Metamorphic Province, South Africa

Lithostratigraphy of the Mesoproterozoic Twakputs Gneiss

Abstract The Twakputs Gneiss is a garnetiferous, K-feldspar megacrystic, biotite granite-granodiorite orthogneiss. It represents a major unit in the Kakamas Domain of the Mesoproterozoic Namaqua-Natal Metamorphic Province extending about 250 km between Riemvasmaak in South Africa and Grünau in southern Namibia. The Twakputs Gneiss occurs as foliation-parallel, sheet-like bodies tightly infolded together with granulite-facies paragneisses into which it intrudes along with a variety of other pre-tectonic granite and leucogranite orthogneisses. These rocks were subsequently intruded by late-tectonic garnet-leucogranites, granites and charnockites. The Twakputs Gneiss is a distinctive unit characterised by large ovoid to elongate megacrysts of twinned perthitic K-feldspar, set in a coarse-grained matrix of garnet, biotite, quartz and feldspar. It contains a penetrative foliation defined by the alignment of K-feldspars and streaks of biotite that developed during the main phase D2 of the Namaqua Orogeny (~1.2 to 1.1 Ga). The foliation and an accompanying elongation lineation are more intensely developed along lithological contacts, especially at the margins of the mega-scale F3 domes and basins that refold the regional fabrics. U-Pb zircon dating of the Twakputs Gneiss has yielded concordia ages of between ~1192 and 1208 Ma. Whole-rock geochemistry shows consistent major, trace and REE elemental trends, and thus reflect chemical variability from a single fractionating magma. The Twakputs Gneiss has a granitic to granodiorite composition and is strongly peraluminous. The geochemistry and the ubiquitous presence of garnet and pelitic xenoliths indicate an S-type granite protolith. The Twakputs Gneiss is the most voluminous and widespread member of the Eendoorn Suite which comprises seven textural variants of garnetiferous, K-feldspar-megacrystic granitoid orthogneiss of the same age.

Polyphase Deformation of the High-Grade Metamorphic Rocks along the Neusspruit Shear Zone in the Kakamas Domain: Insights into the Processes during the Namaquan Orogeny at the Eastern Margin of the Namaqua Metamorphic Province, South Africa

The central part of the Namaqua Metamorphic Province was subjected to intense deformation under high-grade metamorphic conditions up to granulite facies, but also shows greenschist facies overprints denoting the metamorphic nature during the 1.2–1.0 Ga Namaquan Orogeny. This study examines the structural development of the central Kakamas Domain of the eastern Namaqua Metamorphic Province, which has not been extensively studied previously. The compressional orogenic phase is associated with D1 and D2 deformation events during which northeast–southwest-directed shortening resulted in southwest-directed thrusting illustrated by an intra-domain thrust and southwest-verging isoclinal folds. The post-tectonic Friersdale Charnockite of the Keimoes Suite is emplaced during the D3 deformation event. Late reactivation of the intra-domain thrust in the Kakamas Domain to form the Neusspruit Shear Zone during the D4 event is of a monoclinic nature and is described as a deeply rooted structure with shear direction towards the east. This structure, together with the more local Neusberg Thrust Fault, forms part of an intensely flattened narrow basin in the eastern Namaqua Metamorphic Province. Strain and vorticity indices suggest a transpressional shearing across the Neusspruit Shear Zone and adjacent regions probably initiated during the reactivation of the intra-domain thrust. The ~1.2 to 1.8 km-wide, northwest–southeast striking dextral-dominated Neusspruit Shear Zone constitutes a western regional boundary for the supracrustal Korannaland Group and is composed of steep, narrow zones of relatively high strain, characterised by ductile deformation and penetrative strain.

Late-Orogenic Juvenile Magmatism of the Mesoproterozoic Namaqua Metamorphic Province, South Africa, and Relationships to Granulite-Facies REE-Th and Iron Oxide Mineralizations

Abstract The Bushmanland Subprovince of the Mesoproterozoic Namaqua-Natal orogenic belt in southern Africa hosts numerous occurrences of monazite-magnetite-(biotite-apatite-sulfide)-bearing veins and granitoid dykes, including the Steenkampskraal vein system, which is one of the highest-grade REE-Th ore deposits in the world. Here, we provide whole-rock geochemical data along with zircon and monazite U-Pb dates and monazite Sm-Nd isotope analyses of these REE-Th-rich veins and granitoid dykes. The U-Pb geochronology indicates that the monazite-rich veins and granitoid dykes formed between 1050 and 1010 Ma, contemporaneously with late-Namaqua granulite-facies metamorphism. They are also coeval with the Koperberg Suite mafic magmas at 1060–1020 Ma and the late stage of a major event of A-type granitoid magmatism that occurred from 1100 to 1030 Ma (i.e. the Spektakel Suite). Similar to the mafic intrusive rocks from the Koperberg Suite, monazite-rich veins and granitoid dykes, located in the southern part of the Bushmanland Subprovince, have more radiogenic Nd isotopic compositions (ɛNd(t) ∼ −1 to zero) than equivalent dykes and veins to the north (ɛNd(t) ∼ −12 to −6). Mafic rocks of the Koperberg Suite reach Th and La concentrations of &amp;gt;400 ppm that significantly exceed those of other rock types from the region, except for the monazite-rich veins and granitoid dykes, which suggests a genetic link between these rocks. Within veins and granitoid dykes, monazite, biotite and magnetite are commonly anhedral and occur interstitially between the felsic minerals; they are, thus, late crystallizing phases. The whole-rock REE-Th concentrations of the granitoid dykes increase with Fe-Mg contents. Therefore, their incompatible element enrichment is not linked to assimilation-fractional crystallization processes. The Nd isotopic signature as well as Fe-Mg- and REE-Th-rich character of the Koperberg Suite and monazite-rich granitoid dykes might reflect partial melting of lithospheric mantle domains, metasomatized during previous Namaqua subduction events, and the mixing of mantle-derived melts with REE-Th-rich metamorphic fluids during their ascent through the crust. We propose that the monazite-magnetite vein mineralizations represent Fe-P-rich immiscible liquids that exsolved from mantle-derived magmas with compositions similar to the most mafic and monazite-rich granitoid dykes. Within this petrogenetic model, conjugate silicate-rich immiscible liquids formed the more felsic granitoid dykes characterized by lower modal abundances of biotite, magnetite and monazite. Although they do not reach similarly high REE-Th concentrations, other A-type granitoids from the region, represented by the Spektakel Suite, also share geochemical affinities with mafic igneous rocks from the Koperberg Suite; they may have originated by melting of underplated equivalents of these late-orogenic mafic rocks.

The Garies wollastonite deposit, Namaqualand, South Africa: High-Temperature metamorphism of a low-δ18O skarn?

ABSTRACT The Garies wollastonite deposit is located in the Bushmanland terrane of the Namaqualand Metamorphic Province and is part of a discontinuous calc-silicate unit bounded by granulite facies gneiss that experienced peak metamorphic temperatures above 800 °C. In bulk, the deposit is dominated by wollastonite, but varied proportions of garnet, diopside, quartz, calcite, and vesuvianite are also present. Mineral chemistry variations across the deposit are minor, and the absence of inclusions indicates textural and chemical equilibrium. The wollastonite-bearing rocks have unusually low mineral δ18O values: –0.6 to +2.2‰ for garnet, –0.2 to +2. 6‰ for clinopyroxene, and –0.2 to +0.4‰ for wollastonite. Calcite δ18O values range from 6.8 to 11. 8‰ and δ13C values from –6.4 to –3.2‰. Calcite δ18O values are unusually low for calc-silicate rocks, but Δcalcite-garnet values from 3 to 12‰ indicate O-isotope disequilibrium between calcite and the silicate minerals. Garnet-biotite metapelitic and diopside gneisses have unexpectedly low δ18O values (&amp;lt;7‰). The approach to O-isotope equilibrium displayed by coexisting silicate minerals, and low mineral δ18O values in calc-silicate and metapelite and metapsammite gneisses, is consistent with low δ18O values being acquired before peak metamorphism. Low δ18O values in the minerals of the calc-silicate rocks require interaction with external fluid at high water/rock ratio. We suggest that the deposit represents a metamorphosed skarn that developed at the contact between the original carbonate rocks and intruding felsic magmas.

Mesoproterozoic HT-UHT granulites from the central Bushmanland Domain, Namaqua Metamorphic Province, South Africa: Metamorphic P-T evolution and geochronological constraints

The Bushmanland Domain of the western Namaqua-Natal Metamorphic Province encompasses Paleoproterozoic to Mesoproterozoic intrusives as well as metamorphosed volcano-sedimentary supracrustal rocks. In this largest domain of the Namaqua Sector of the Namaqua-Natal Province, high-grade metamorphism prevails, with granulite-facies rocks occupying the central and southern parts. Previous studies of the granulites have revealed evidence for peak metamorphism reaching conditions that are at least transitional to ultrahigh temperatures (UHT). We present first evidence for coexisting sapphirine and quartz, and related peak conditions of 1000℃ – 1050℃ and 7 – 8 kbar. The contrast to previous P-T estimates and a clockwise P-T path possibly point to an older M1 metamorphic cycle that predates the well-established 1040 – 1020 Ma Namaquan (M2) cycle, characterised by lower-T and lower-P granulite-facies metamorphism. This M2 metamorphism shows a general anticlockwise P-T path as recorded in mafic rocks of the study area, with peak conditions of 770 – 830℃ and 4.9 – 6.4 kbar. Zircon and monazite geochronology yields two distinct age groups, with a Late Mesoproterozoic group confirming the ~ 1040 to 1020 Ma metamorphic age of the Namaquan orogeny related to M2, and a Paleoproterozoic group with a relatively narrow age range of ~1787 – 1773 Ma. This latter group encompasses the zircon cores and relates to magmatic crystallisation of felsic host rocks. The magmatic zircons had been through a stage of clastic transport before obtaining their metamorphic overgrowth within the Bushmanland Group supracrustal sequence. In the compiled zircon age spectrum for the Bushmanland Domain, this particular age group had not shown up prominently before. It points to a significant source area which is either not exposed, or could not be localized yet

Petrogenesis of Mesoproterozoic Granites of the Swartoup Hills Region, Kakamas Domain, Namaqua Belt, South Africa

The Swartoup and Polisiehoek plutons in the Swartoup Hills (South Africa) formed during an episode of significant magma emplacement in the Mesoproterozoic Namaqua Sector of the Namaqua Metamorphic Province. They intruded into mid-crustal metasedimentary rocks of the metapelitic Koenap and mafic to carbonate-bearing Bysteek Formations during and shortly after the ∼1,200–1,220 Ma regional metamorphic peak that reached ultrahigh temperatures. Subsequent to pluton emplacement, the crust underwent regional high-temperature deformation during slow near-isobaric cooling. A further episode of pluton emplacement associated with fluid circulation truncated the first-order regional tectonic structures at ∼1,100 Ma. Based on their petrography, the Swartoup pluton is subdivided into leuco-granitoids with biotite as the sole mafic phase, pyroxene granitoids, and garnet-bearing granitoids, which may contain significant biotite. These subgroups display distinctive geochemical variations from one another, and from the Koenap Formation migmatites and the Polisiehoek granites, which are exposed nearby. Incompatible trace element distributions suggest that the Swartoup and Polisiehoek granitoids represent modified A-type granite magma, consistent with derivation from partial melting of quartzo-feldspathic crust. The magmas incorporated significant amounts of juvenile mantle-derived magma (εNd1200 of ∼−5, and LREE-depleted), but do not require older, early to late Paleoproterozoic crust. Particularly close to contacts to the calcic Bysteek Formation, localized contamination of the Swartoup granites by supracrustal carbonates is evident. A relatively pervasive alkali metasomatic effect is manifested strongly in the initial 87Sr/86Sr and LILE profiles of the Polisiehoek granites in particular, as well as in some of the Swartoup pyroxene granitoids, which could be either a symptom of CO2 metasomatism related to the Bysteek Formation carbonates, or to post-magmatic fluid metasomatism, perhaps linked to regional shearing. The comparison of our results with literature data suggests that similar sources, A-type granitic, Meso- to Paleoproterozoic crustal, and enriched mantle, have contributed, in locally differing proportions, to granites in most parts of the Namaqua Sector. Most likely, these plutons were generated during crustal and mantle melting in a long-lived hot continental back-arc environment.

77Namibian Journal forResearch, Science andTechnologyVol 2, December2020NJRST 2 (2020): 77-89 Geological Mapping and Major Elements Characterization of the Tschaukaib Granitic Suite, South West Namibia

ABSTRACTOngoing studies in the Namaqua Sector, situated in the Namaqua-Natal Metamorphic Province (NNMP), have been vital in understanding the geological activities that occurred during the Rodinia supercontinent assembly. These geological activities are usually key to discovering new mineral raw materials. The Tschaukaib Granitic Suite, which is believed to be part of the Gordonia Thrust Stack (GTS) of the Kakamas Domain, crops out within Tschaukaib Mountains and was characterized in this study on the basis of surface mapping, petrographic and major element geochemistry. Three types of granites were identified, namely: granodiorite, quartz monzonite and granite with SiO2 content ranging from 64.9 wt % to 69.8 wt %. Whole rock geochemistry further shows that they are calc-alkaline, alkali-calcic, ferroan, peraluminous (Al2O3 &gt; K2O + Na2O + CaO) and have &gt;1 % Cross, Iddings, Pirsson and Washington (CIPW) corundum. The geochemical characteristics indicates that the granitoids were emplaced during the continental collision and are formed from partial melting of recycled crustal material which took place during the Rodinia supercontinent. The geochemistry shows a conspicuous fractional crystallization signature. Geological mapping and structural analysis of the Tschaukaib Granitic Suite area shows a NW-SE and E-W trending regional foliation in the Tschaukaib Augen Gneiss (quartz monzonite) which corresponds to the main D2 Namaqua metamorphic event. Several shear zones were mapped and are consistent to the Pofadder Shear Zone which runs in the NW-SE and E-W directions, parallel to the study area. Petrographic analysis of the granitoids has identified mineral assemblages which shows that the granitoids have undergone high strain and alterations, however, it is not clear which Namaqua deformation episode brought about these features.

Variscan ultra‐high‐pressure eclogite in the Upper Allochthon of the Rhodope Metamorphic Complex (Bulgaria)

AbstractThe Rhodope Metamorphic Complex (RMC) in Bulgaria has been established as a Mesozoic ultra‐high‐pressure metamorphic province by findings of microdiamond in gneisses. Additionally, Variscan ultra‐high‐pressure metamorphism has been proposed for the Ograzhden/Vertiskos Unit in the Upper Allochthon of the RMC, based on findings of coesite, graphite pseudomorphs after diamond and indirect age constraints. We confirm ultra‐high‐pressure metamorphism of eclogites in this unit using thermobarometry, phase‐equilibrium modelling and the Variscan age of metamorphism using Lu–Hf garnet–whole‐rock dating. In Belica (southern Rila Mountains), kyanite‐ and phengite‐bearing eclogite enclosed in high‐grade gneisses records P‐T conditions of 3.0–3.5 GPa and 700–750°C. Lu–Hf dating of eclogite samples from Belica and Gega (Ograzhden Mountain), where coesite was found, yielded ages of 334.1 ± 1.8 and 334.0 ± 2.2 Ma, respectively, interpreted as the age of garnet growth during post‐collisional subduction of continental crust after closure of the Rheic Ocean.

The Grenvillian assembly of Rodinia: Timing of accretion on the western margin of the Kalahari (Kaapvaal) Craton

Abstract During the Grenvillian assembly of Rodinia, the Namaqua-Natal Metamorphic Province (NNMP) was formed as a result of the convergence of the Laurentia and Kalahari cratons. A detailed model for this accretion along the south-eastern margin of the Kalahari Craton has been established, but the tectonic history of the NNMP along the western margin of the Kalahari Craton has remained highly controversial. U-Pb SHRIMP zircon age dating of gneiss in the Kakamas Domain of the NNMP, as well as U-Pb SHRIMP age dating of detrital zircons and 40Ar/39Ar dating of metamorphic muscovite from sediments overlying the gneiss, confirms the presence of at least two separate events during the Namaqua-Natal Orogeny at ~1 166 Ma and 1 116 Ma. These events occurred after the Areachap Terrane was accreted onto the western margin of the Proto-Kalahari Craton during the Kheis Orogeny. 40Ar/39Ar ages derived from metamorphic muscovite formed in the metasediments of the Kheis terrane does not provide evidence for the timing of the Kheis Orogeny but suggests that it most likely only occurred after ~1 300 Ma and not at 1 800 Ma as commonly accepted. A U-Pb concordia age of ~1 166 Ma was derived from granitic gneiss in the Kakamas Domain of the Bushmanland Subprovince, possibly reflecting subduction and the initiation of continent-continent collision between the Proto-Kalahari Craton and the Bushmanland Subprovince. This granitic gneiss is nonconformably overlain by the metasediments of the Korannaland Group that contains metamorphic muscovite with 40Ar/39Ar ages of ~1 116 Ma. This age suggest that complete closure of the ocean between the Proto-Kalahari Craton and Bushmanland Subprovince probably occurred about 50 Ma after the intrusion of the ~1 166 Ma granitic gneisses.

Calculating pressure with elastic geobarometry: A comparison of different elastic solutions with application to a calc-silicate gneiss from the Rhodope Metamorphic Province

Raman elastic geobarometry has increasingly been used complementary to metamorphic phase equilibria to estimate the conditions of recrystallization in metamorphic rocks. The procedure of applying Raman elastic barometry to host-inclusion mineral systems requires several steps that involve various assumptions. One of the most essential assumptions is that the mineral host-inclusion system behaves in an elastic and reversible manner. We discuss the discrepant results obtained by different authors employing different analytical solutions for elasticity and explore the assumptions lying behind each method. Furthermore, we evaluate numerically linear and non-linear elastic solutions and show their discrepancies. Both formulations are tested against recently published experiments on quartz inclusions in garnet (QuiG) at pressures up to 3 GPa, and we find a very good agreement between calculated and experimental pressure values (within 10% relative error). We subsequently apply our new elastic geobarometer to a calc-silicate gneiss from the Rhodope Metamorphic Province (N. Greece). The results of Raman elastic barometry combined with garnet-clinopyroxene geothermometry yield eclogite-facies conditions (~720 ± 40 °C, ~1.5 ± 0.2 GPa). These results are comparable to a high-temperature metamorphic overprint deduced from phase equilibria modeling in surrounding lithologies (730 ± 40 °C, ~1.2 ± 0.1 GPa). Our findings indicate that the estimated pressure from Raman elastic barometry is consistent with a significant viscous relaxation at high temperatures. We conclude that although Raman elastic barometry is a powerful tool for pressure estimation in metamorphic rocks, its pressure estimates do not necessarily correspond to entrapment conditions. Our results are consequential for the estimates of reaction overstepping in high-grade metamorphic rocks.

Lithostratigraphy of the Mesoproterozoic Yas-Schuitdrift Batholith, South Africa and Namibia

Abstract The granitic and leucogranitic Yas and Schuitdrift Gneisses occur together as a large ovoid pre-tectonic batholith that crosses the Orange River border between South Africa and Namibia. They occur in the central parts of the Kakamas Domain in the Namaqua Sector of the Namaqua-Natal Metamorphic Province where they intrude, and are deformed together with, slightly older (~1.21 Ga) orthogneisses and granulite-facies metapelitic gneisses. The Yas Gneiss occurs mainly on the outer perimeter and northern parts of the batholith and comprises equigranular leucogranite gneiss and biotite granite augen orthogneiss, whereas the Schuitdrift biotite-hornblende augen gneiss is located at the centre and southern parts of the batholith. The batholith is strongly deformed with penetrative Namaqua-aged gneissic fabrics defined by grain-flattening of quartz and feldspar in the equigranular leucogneisses and aligned K-feldspar megacrysts in the augen gneisses. The gneissic fabric is refolded during a large-scale folding event that results in the dome-shape of the batholith and controls the present outcrop pattern of its various components. Flexure along the margins of the batholith refoliated the gneisses into a zone of mylonitic rocks. The Yas and Schuitdrift Gneisses have similar geochemistry and classify as alkali granites and alkali leucogranites. They are felsic (mean SiO2: 74.5 wt%) and potassic (mean K2O: 5.8 wt%) but have low MgO, CaO and Na2O, reflecting their low mafic mineral and plagioclase contents. The Schuitdrift Gneiss yielded U-Pb zircon ages of 1 191 ± 7 and 1 187 ± 6 Ma.

A Multistage Genetic Model for the Metamorphosed Mesoproterozoic Swartberg Base Metal Deposit, Aggeneys-Gamsberg Ore District, South Africa

Abstract The polymetamorphosed Swartberg Cu-Pb-Zn-Ag deposit in the Namaqua Metamorphic Province of South Africa is a major metal producer in the region, yet its genesis remains poorly understood. The deposit comprises several stratiform to stratabound units, namely the Lower Orebody and Dark Quartzite, the overlying Barite Unit, and the Upper Orebody, all of which are folded by an F2 isoclinal syncline and refolded by an open F3 synform. A discordant Garnet Quartzite unit surrounds the Upper Orebody in the F2 hinge, where it overprints the Lower Orebody and Barite Unit. The Lower Orebody comprises sulfidic, pelitic lenses with fine-grained pyrite, sphalerite, galena, and lesser pyrrhotite, hosted by sulfide-poor but magnetite- and barite-bearing siliceous rock. The overlying Barite Unit is poorly mineralized and grades from massive magnetite-barite close to the F2 hinge to distal laminated baritic schist and quartzite. The Dark Quartzite is the stratigraphic equivalent of the Lower Orebody and Barite Unit but comprises siliceous quartzite and schist, with lenses of conglomerate and minor Fe-Mn-Zn phases. The Upper Orebody displays rapid zonations from massive magnetite-rich iron formation in the F2 hinge, rich in coarse galena, pyrrhotite, and chalcopyrite, to sulfide-poor, magnetite-bearing schist and quartzite. The Garnet Quartzite is dominated by quartz and almandine garnet and mineralized with pyrite and chalcopyrite. Geochemical discriminant plots show that the Lower Orebody has a significant detrital component, whereas the Upper Orebody and Barite Unit are strongly zoned, with the greatest chemogenic component close to the F2 hinge. This corresponds to a deposit-scale metal zonation from the Cu-rich F2 hinge to more Pb- and then Zn-dominated areas. Mineral assemblages and paleoredox proxies suggest generally oxic conditions, with a more reduced signature close to the hinge and in the sulfidic Lower Orebody lenses. The Lower Orebody is interpreted as a mixed chemogenic-pelitic unit, with sulfides deposited on or near the seafloor during stage 1 hydrothermal activity. The sulfidic lenses formed from fine mud and clay deposited in quiet seafloor depressions, in which warm, dense, reducing, Pb-Zn-Ba–rich stage 1 brines accumulated, while the siliceous portions formed from higher-energy clastic sediments on aerated seafloor highs. The Barite Unit forms a baritic cap to the Lower Orebody, while the Dark Quartzite is their shallower-water equivalent. Thereafter, clastic sediment with lesser hydrothermal input was deposited during stage 2a exhalations, forming the poorly mineralized portions of the Upper Orebody. During stage 2b hydrothermal activity, hot Cu-Fe–rich fluids invaded part of the Upper Orebody, creating the highly chemogenic protolith to the well-mineralized, magnetite-rich portion. Associated hydrothermal alteration in a discordant subseafloor feeder zone created the Garnet Quartzite protolith. The F2 hinge thus corresponds closely to the original vent zone. Swartberg therefore resembles a deformed and metamorphosed Selwyn-type sedimentary exhalative deposit, with both proximal- (Upper Orebody, Garnet Quartzite) and distal-style (Lower Orebody) mineralization. The close association of these styles suggests that differences in the mineralizing fluids and depositional environment, rather than proximity to a vent, determine the deposit style.