Metamafic Rocks Research Articles

Petrogenesis and tectonic setting of mafic magmatism within the Laguna Amarga Metamorphic Complex, Andes of Catamarca, Argentina: Insights into the opening of the Cuyania/Precordillera terrane from the Ouachita rift

Neoproterozoic crystalline basement rocks are exposed as fault-bounded blocks over the high Andes of Catamarca. The crystalline basement is stratigraphically grouped into the unique Laguna Amarga Metamorphic Complex and represents the northern extension of the Cuyania/Precordillera terrane. Tabular bodies of meta-mafic rocks are widespread in the basement interspersed within a thick sequence of meta-sedimentary rocks derived from siliciclastic, calc-silicate, and limestone protoliths. Overall, the geochemical characteristics of meta-mafic rocks are in the compositional range of Normal-Mid Ocean Ridge Basalt (Normal-MORB), reflecting a common depleted-mantle source with varying degrees of partial melting. While preserving the typical bulk chemistry of MORB magmatism, some mafic magma underwent differentiation at emplacement, leading to the development of high-Ti mafic rocks. New U-Pb zircon geochronology reveals three distinct age peaks, with two coinciding with ages identified in the metasedimentary host rocks. The dominant Mesoproterozoic age cluster is linked to inherited zircon crystals assimilated within a single meta-mafic rock. In contrast, zircon ages from the late Ordovician to early Devonian are attributed to metamorphic overgrowths. Notably, the third age cluster, delineates a Late Neoproterozoic magmatic event, indicating the temporal span of mafic magmatism. The finding agrees with the best available age (576 ± 17 Ma) for mafic magmatism on the Precordillera Mafic-Ultramafic Belt. Stratigraphic relationships and geochemical fingerprints enable correlation among the meta-mafic rocks from Laguna Amarga, tracing a belt of mafic magmatism with an oceanic affinity that extends southward. Building upon previous works, this study reaffirms that the rift-drift transition of the Cuyania/Precordillera terrane, linked to the Ouachita rift opening from southeastern Grenville, evolved during the latest Neoproterozoic.

Ca–Zn isotope fractionation during fluid–rock interaction in subduction zones and its implication for deep carbon cycle

Subducting slabs transport Earth's surface carbon into the deep mantle, with a portion of this carbon potentially recycled through volcanic eruptions at mid-ocean ridges or ocean islands. Non-traditional stable isotopes such as calcium (Ca) and zinc (Zn) are increasingly used to trace this deep carbon cycle. However, the potential for Ca and Zn isotope fractionation in the subduction zone, critical for the successful application of these tracers, remains insufficiently explored. In this study, we investigate high-pressure carbonated metamafic rocks and enclosed vein systems from a Paleo-oceanic subduction complex (SW Tianshan) to explore the possible fractionation of Ca and Zn isotope during subduction-related metamorphism and fluid–rock interaction. The δ44/40Ca (0.77 ‰–0.90 ‰) and δ66Zn isotope compositions (0.20 ‰–0.39 ‰) of greenschist-, blueschist- and eclogite-facies metabasites are consistent with their protoliths (OIBs and MORBs). We observe no systematic fractionation of either Ca and Zn isotopes across prograde metamorphism and associated dehydration. However, the precipitation of carbonate in surrounding rock along fluid pathways leads to an increase in the δ44/40Ca of residual fluids (>0.90 ‰). More significantly, we find detectable Zn isotope fractionation (ΔA-H = ẟ66Znaltered - ẟ66Znhost of 0.06–0.10 ‰) during fluid-mediated metasomatism of some blueschists/eclogites. Light Zn isotopes are preferentially released into the infiltrating fluid, resulting in an elevated δ66Zn isotope composition in the immediate carbonated eclogites along the vein. The modified slab fluids during migration are likely charactered by heavy δ44/40Ca and light δ66Zn compositions, which may play a crucial role in determining the low δ66Zn values found in some arc lavas. However, the MORB-like δ44/40Ca compositions observed in global arc magmatic rocks suggest that the slab-released Ca (possibly along with some carbon) is probably sequestered and stored along the migration path of the fluid, thereby hindering the slab–arc carbon recycling. Our study emphasizes that intraslab fluid–rock interaction results in similar δ44/40Ca and δ66Zn signature in carbonate-bearing eclogites compared to sedimentary carbonates. Consequently, deeply subducted carbonate-bearing eclogites –not necessarily sedimentary carbonates– might carry light δ44/40Ca and heavy δ66Zn signatures into the deep mantle, potentially influencing the corresponding Ca-Zn isotope compositions of some mantle-derived basalts.

Late Jurassic High-Pressure Metamorphism of Variscan I-Type Granitoids in the Northern Part of the Pelagonian Unit (Republic of North Macedonia)

Abstract The high P/T metamorphic Pelagonian Unit in the Republic of North Macedonia comprises (1) a Variscan basement consisting of gneisses, schists and minor meta-mafic rocks, which are all intruded by I-type granitoids and rare related dikes; (2) a metamorphosed sedimentary sequence of Permian to Lower Triassic age, and (3) a sequence of calcite and dolomite marbles resulting from Late Triassic to Middle Jurassic carbonate sediments. All these rocks underwent a common high-P/T metamorphism of Late Jurassic age. This paper deals with the metamorphism of the Variscan I-type granitoids which contained the igneous mineral assemblage plagioclase I + alkali feldspar I + quartz I + biotite I + titanite I + allanite I + zircon I + apatite I ± magnetite I. During Late Jurassic high-P/T metamorphism, these undeformed granitoids were thoroughly metamorphosed under isotropic pressure conditions as documented by undeformed granitic textures that are overgrown by metamorphic minerals such as garnet II, epidote II, and phengite II. Various, eventually metasomatic mineral reactions took place in different textural positions: (1) Former igneous plagioclase grains became completely transformed to Na-rich plagioclase IIa (An09–14) containing numerous small grains of epidote IIa and phengite IIa. Either this transformation was an allochemical one and was accompanied by the syn-metamorphic introduction of an aqueous fluid phase containing Fe, Mg and K or, alternatively, the more Ca-rich parts of plagioclase I became considerably sericitized before high-P/T metamorphism, and the resulting mixture of more Na-rich relic plagioclase with its sericite-rich domains became later metamorphosed under high-P/T conditions. In the first case, an aqueous phase is needed during metamorphism, while in the second case high-P/T metamorphism might have proceeded under H2O-undersaturated conditions; (2) igneous alkali feldspar I was changed to albite-poor orthoclase II or microcline II; (3) igneous Ti-rich biotite I reacted with plagioclase to metamorphic garnet II + Ti-poorer biotite II + titanite II + phengite II + quartz II ± epidote II ± rutile II, which is rimmed by Ttn II. At textural positions, where igneous plagioclase I was not available, igneous biotite I was transformed to Ti-poorer biotite II + titanite II ± ilmenite-hematite II; (4) during uplift, high-P/T metamorphic rutile II became marginally overgrown by titanite II ± ilmenite II; (5) igneous allanite I grains stayed unaltered, but when located near to former plagiocase I, they became partially rimmed by metamorphic epidote II. Equilibrium phase diagram calculations showed that the observed metamorphic paragenesis (plagioclase II + K-rich feldspar II + biotite II + garnet II + epidote II + phengite II + garnet II + quartz II + rutile II + titanite II) is only stable under H2O-unsaturated conditions. The I-type granitoids and their metamorphic country rocks were metamorphosed under high-P/T conditions of 1.3 to 1.5 GPa and 560 to 590 °C.

Successful subduction of oceanic plate after failed attempts in the Late Archean: Petrological and geochemical constraints

When and how plate tectonics started and evolved to the style as we know it today is a fundamental yet highly controversial question. Numerical geodynamic modelling predicts that the transition into plate tectonics in the Archean was episodic with possible alternation between success and failure of subduction. However, direct geological evidence for failed subduction is scarce. While this possibility has been suggested by numerical modelling, it is still lack of geological evidence. Here we present a combined study of zircon U-Pb ages and Hf-O isotopes, as well as whole-rock major and trace elements, for meta-igneous rocks from the Alxa Block in the westmost North China Craton (NCC). Two periods of Late Archean magmatism ca. 2.75 Ga and 2.5 Ga are identified to occur surrounding a pre-3.0 Ga continental nucleus. Geochemical analyses of the ca. 2.75 Ga meta-mafic and meta-felsic igneous rocks show two different modes of tectonic regime. The felsic rocks resemble typical Archean TTG (tonalite-trondhjemite-granodiorite) in composition, with variable εHf(t) values from -2.8 to 11.0 and δ18O values from 4.3 ‰ to 7.9 ‰. Petrogenetic modelling suggests that their magmatic source was the ca. 3.1–2.75 Ga oceanic crust that was hydrothermally altered at different temperatures and then mixed with the older continental crust and partially melted in lower crust in the garnet stability field. This requires tectonic accretion of the oceanic crust to the continental nucleus, signifying an attempted or failed subduction. On the contrary, the meta-mafic rocks exhibit arc-like trace element patterns and calc-alkaline evolution trend, indicating a metasomatic mantle source due to successful subduction of the oceanic slab to subarc depths. Taken together, the present results provide robust constraints on the behavior of oceanic slab at the Archean convergent margin, where successful oceanic subduction would be achieved after several failed attempts. Such failure-success processes of oceanic subduction may be applicable to the whole NCC and other cratons elsewhere in the world, reflecting the gradual maturation of plate tectonics in the Archean, consistent with predictions of numerical modelling.

Petrogenesis of newly identified mantle-plume-related ca. 3.3 Ga tholeiitic-komatiitic rocks in the Anshan area, North China Craton

The geodynamic regime that governed the crustal evolution of Earth during the early Archean remains intensely debated. The North China Craton (NCC) preserves a geological history spanning 3.8–2.5 Ga, particularly in the Anshan area, making it an ideal natural laboratory for probing the formation and evolution of the NCC and its associated geodynamic regime. Here, we document new geochronology, geochemistry, and zircon Hf-O isotope data from newly discovered Paleoarchean meta-mafic rocks in the Anshan area. Based on their whole-rock geochemistry, these unit can be divided into tholeiitic and komatiitic series. Of which, the komatiitic rocks are characteristic by high MgO contents (up to 20.6 wt%). Zircon U-Pb dating shows that all meta-mafic rocks formed contemporaneously, with crystallization ages of ca. 3.3 Ga. Most of the studied meta-mafic rocks display radiogenic zircon Hf isotopes, with TDM1 ages ranging from 3592 to 3346 Ma and εHf(t) values from −1.94 to + 3.49. They also exhibit mantle-like zircon δ18O values (+4.92 ‰ to + 5.98 ‰). These zircon Hf-O isotope data indicate that the protoliths of the ca. 3.3 Ga meta-mafic rocks originated from the partial melting of a depleted mantle without significant crustal contamination. Furthermore, the parental magmas of the komatiitic rocks and some of tholeiitic rocks were generated from 20 % and 5–10 % partial melting of spinel-lherzolite, respectively, whereas other tholeiitic rocks were the result of a low degree (1–5 %) of partial melting of spinel-garnet lherzolite. The ca. 3.3 Ga tholeiitic-komatiitic rocks were most likely formed in an intraplate rifting setting, associated with a mantle plume.

Multistage mineralizing episodes of the Proterozoic world-class Volta Grande gold deposit, Amazonian Craton, northern Brazil: Implications for the Bacajá Domain metallogenesis

The easternmost region of the Amazonian Craton in northern Brazil has been the focus of several mining exploration surveys, which led to the identification of the world-class Volta Grande gold deposit (∼6.0 Moz@1.02 g/t). The deposit is inserted in the Bacajá Domain (2.24–2.0 Ga), and part of the mineralization occurs in Proterozoic mylonite, gneiss, and associated metamafic rocks that underwent greenschist to amphibolite-facies metamorphism. Electrum (Au–Ag) occurs as grains in cm-sized quartz high-grade veins and veinlets (up to 34.1 g/t in some rock intervals) that follow the mylonitic foliation and are associated with pervasive carbonate alteration, synchronous with the dynamic metamorphism. Disseminated electrum grains, pyrite, chalcopyrite, arsenopyrite, tellurides, and galena occur associated with potassic, argillic, propylitic, and silicic alteration types mainly in fracture-controlled or pervasive styles. These geological features as a whole suggest an orogenic high-tonnage orogenic gold system. Isotropic core samples along a stratigraphic profile reveal late andesite, dacite, rhyodacite, and rhyolite lava flows and dikes and plutonic rocks such as quartz monzonite, granodiorite, monzodiorite, and subordinate microgranite crosscutting the older metamorphic rocks. These rocks reveal potassic, propylitic, argillic, silicic, and sericitic alteration types. Electrum grains, possibly related to boiling deposition, occur along cm-sized quartz, calcite, and adularia high-grade veins (up to 29.5 g/t in some rock intervals) with chalcopyrite, pyrite, arsenopyrite, tetradymite, and tellurobismuthite. Such mineralogy is compatible with a low-sulfidation epithermal system. Data integration points to at least two distinct mineralizing events leading to the Volta Grande gold deposit – orogenic gold and low-sulfidation epithermal – which explains such large-tonnage and high-grade ore accumulation. It configures a new exploration guide for the Bacajá Domain of the Amazonian Craton, attested by other worldwide regions with similar metamorphic, magmatic, and hydrothermal alteration characteristics.

The passive margin of the southern São Francisco paleocontinent, metamorphic record and implications for the assembly of West Gondwana: Evidence from the Lima Duarte Nappe, Ribeira Orogen (SE Brazil)

In this contribution, we report new P-T (pressure–temperature) and U-Pb zircon geochronological data from the Lima Duarte Nappe and basement rocks from the Mantiqueira Complex, Central Ribeira Orogen, southeastern Brazil, highlighting their relevance to the understanding of the West Gondwana assembly. The lower metasedimentary sequence of the Lima Duarte Nappe records a passive margin environment, with a majority of Paleoproterozoic detrital zircon grains, with probable main source rocks located in the São Francisco paleocontinent. The upper foreland sequence of the Lima Duarte Nappe has a prevalence of Tonian-Cryogenian detrital zircon grains, absent in the lower passive margin sequence and source rocks were most likely in a magmatic arc developed during the convergence between the São Francisco and the Paranapanema paleoplates. Zircon rims from the Lima Duarte passive margin and foreland sequences, and zircon grains from an amphibolite of the Lima Duarte Nappe record granulite facies metamorphism at ca. 560–590 Ma (Th/U ratio < 0.1). Similar ages are recorded by CL-dark zircon rims and overgrowths in orthogneisses of the Mantiqueira Complex and are interpreted to reflect basement reworking. Metapelitic metatexites from the foreland sequence record granulite facies peak metamorphism at ∼ 780–800 °C and 8–9.5 kbar in the sillimanite-rutile stability field, constrained by phase equilibrium modeling. Rutile inclusions in garnet record minimum peak temperatures of ∼ 750 °C. The retrograde mineral assemblage in the matrix is marked by the disappearance of rutile and the presence of ilmenite and mineral compositions re-equilibrated at upper amphibolite facies. Late Tonian (ca. 850–750 Ma) metamafic rocks within the Mantiqueira and Juiz de Fora complexes might record an extensional intraplate mafic magmatism episode that culminated with the establishment of the passive margin at the south of the São Francisco paleocontinent. The Lima Duarte metasedimentary sequence along with the Canastra and Carrancas groups (western and southern portions of the Brasília Orogen, respectively) represent a Tonian proximal passive margin environment, developed at the margin of the São Francisco paleocontinent. The Lima Duarte Nappe metasedimentary units and the orthogneisses of the Mantiqueira Complex record Ediacaran syn-collisional metamorphism related to the Araçuaí-Ribeira Orogenic System.

The inhibited response of accessory minerals during high‐temperature reworking

AbstractU–Pb zircon and monazite geochronology are considered to be among the most efficient and reliable methods for constraining the timing of high‐temperature (HT) metamorphic events. However, the reliability of these chronometers is coupled to their ability to participate in reactions. A case study examining the responsiveness of zircon and monazite has been conducted using granulite facies metapelitic and metamafic lithologies in the Warumpi Province, central Australia. In some instances, metapelitic granulites from this locality are polymetamorphic, with an early M1 assemblage containing orthopyroxene, cordierite, biotite, quartz, ilmenite and magnetite, and an M2 assemblage represented by garnet, sillimanite, orthopyroxene, cordierite, biotite, sapphirine, ilmenite and magnetite. M2 metamorphism is linked to HT peak conditions of 8–10 kbar and 850–915°C. Detrital and metamorphic zircon and monazite from these rocks dominantly record U–Pb dates of 1670–1610 Ma and have trace element compositions suggesting they grew prior to peak M2 garnet in the rock. Lu–Hf geochronology from M2 garnet gives ages of c. 1150 Ma. Zircon and monazite are therefore suggested to have remained largely inert during HT metamorphism. We attribute the relatively minor response of zircon and monazite during high‐temperature Mesoproterozoic metamorphism to the localized development of refractory bulk compositions at c. 1630 Ma during M1 metamorphism. This created refractory Mg–Al‐rich bulk compositions that were unable to undergo significant partial melting, despite experiencing subsequent temperatures of ~900°C at c. 1150 Ma. In contrast, metapelitic and metamafic rocks in the area that did not develop refractory bulk compositions during M1 metamorphism were able to partially melt and record c. 1150 Ma accessory mineral U–Pb ages. These results contribute to a small, but growing number of case studies investigating the systematics of the U–Pb system in zircon and monazite in polymetamorphic HT terranes and their apparent resistance to isotopic resetting. Where disequilibrium is apparent, garnet Lu–Hf geochronology can form an important tool to interrogate the significance of accessory U–Pb ages. In the Warumpi Province in central Australia, c. 1640 Ma zircon U–Pb ages had previously been interpreted to reflect the formation of HT garnet‐bearing granulites during a collisional event. Instead, the garnet‐bearing assemblages formed at c. 1150 Ma during the Mesoproterozoic, calling into question the existence of a late Palaeoproterozoic collisional system in central Australia.

Tonian rifting coeval with the last stages of amalgamation of Rodinia: Evidence from southern Borborema province, northeastern Brazil

During the last stages of assembly of the Rodinia supercontinent at 1000-900 Ma, rifting processes were occurring in places that would be part of Gondwana in the late Neoproterozoic. In the Borborema Province, northeastern Brazil, this event is known as Cariris Velhos. It is represented in the Alto-Pajeú Domain from the Central subprovince by a 700 km-long, 70 km-wide NE-SW belt comprising bimodal metavolcanic rocks and granitic orthogneisses. Orthogneisses with similar ages were found in previous works in the western Pernambuco-Alagoas Domain from the Southern subprovince immediately to the south of the ESE-trending dextral West Pernambuco shear zone. The Airi Complex comprises several elongate bodies that extend for at least 80 km. It consists of a bimodal sequence of metafelsic (granitic orthogneisses) associated with layers and enclaves of metamafic (amphibolites) rocks. Seven orthogneiss samples dated by LA-ICPMS yielded zircon U–Pb crystallization ages of 950–1011 Ma. Zircon Hf analyses from two samples yielded εHf(t) values ranging from −1.4 to 2.1 and TDM model ages of 1.7–1.9 Ga. Geochemical analyses allow to distinct different source rocks for the protoliths of the orthogneisses. Orthogneisses derived from metasedimentary sources have modal muscovite ± garnet, are ferroan, alkali-calcic and predominantly peraluminous, exhibiting strong negative Eu anomalies in chondrite-normalized rare earth elements diagrams. Orthogneisses derived from high-K mafic rocks are calc-alkalic, slightly peraluminous, with small or absent negative Eu anomalies. Orthogneisses from tonalitic sources are magnesian, calc-alkalic to alkali-calcic, and slightly peraluminous, without Eu anomalies. There is no correlation between crystallization ages and source rock types. The results indicate that the Airi Complex originated through partial melting of ancient heterogenous crustal sources. Therefore, its geochemistry reflects the nature of these sources, not the tectonic setting of intrusion. Emplacement of the complex was broadly coeval with well-documented extensional processes in the São Francisco/Congo Craton and represents a failed attempt to break-up a larger paleocontinent encompassing this craton and the basement of the Borborema Province.

Zircon U–Pb chronological and geochemical characteristics of Paleoproterozoic meta-mafic rocks in Tonghua area, Southern Jilin Province: implication for the tectonic evolution of the Jiao-Liao-Ji Belt, North China Craton

Zircon U–Pb chronological and geochemical characteristics of Paleoproterozoic meta-mafic rocks in Tonghua area, Southern Jilin Province: implication for the tectonic evolution of the Jiao-Liao-Ji Belt, North China Craton

Ti-Bearing Minerals: from the Ocean Floor to Subduction and Back

Abstract Rutile, titanite, and ilmenite are the most common Ti-bearing minerals in metamorphic rocks. Experimental constraints have shown that titanite is stable at low-grade metamorphic conditions, rutile at high pressure (HP), and ilmenite at high temperature, low pressure (HT-LP) conditions. Yet, petrological evidence suggests that titanite can also be stable at low temperature, HP (LT-HP). This implies that both titanite and rutile can be used to develop proxies to track HP metamorphism, which can have interesting applications. In this study, we have investigated the natural occurrence and chemistry of Ti-bearing minerals in gabbroic rocks and basalts that record different degrees of metamorphism, including LP amphibole-bearing gabbros from the ocean floor (Mid-Atlantic and Indian ridge IODP LEGs) and from an obducted ophiolite (Chenaillet) and HP Alpine metagabbros and metabasalts, including blueschist and eclogite facies rocks from the Western Alps and Corsica. We have performed detailed petrography, Raman spectroscopy and analyzed major and trace elements mineral chemistry using EPMA and LA-ICPMS. We found that rutile is stable at low pressure (&amp;lt; 2 kbar) in ocean-floor amphibole-bearing gabbros, lower than experimental constraints had previously suggested. Rutile is also found in eclogitic metagabbros from the Western Alps and can be chemically distinguished from LP rutile. Blueschist metagabbros from the Western Alps and eclogitic metabasalts from Corsica have titanite stable instead of rutile. While the titanite to rutile transition is pressure- and temperature-dependent, we demonstrate how small variations in bulk-rock Ti/Ca and Ca/Al values within the NCKFMASHTO chemical system may shift their stabilities. High-pressure titanite from these metamafic rocks exhibits La depletion and low La/SmN values in comparison to titanite from amphibolite-facies mafic rocks. La/SmN or Nb together with Yb and V can be used to distinguish HP titanite from titanite formed under other P–T settings. These new systematics can be useful in studies using detrital Ti-bearing minerals to probe the HP metamorphic record through time.

Boron and Molybdenum Isotope Evidence for Source‐Controlled Compositional Diversity of Cenozoic Granites in the Eastern Tethyan Himalaya

AbstractThe origins of Cenozoic granites in the Himalaya are key to understanding the evolution of the Himalayan orogen. However, it is unclear whether these granites represent primary melts, and the nature of their magma source is controversial. Here, we present a systematic element and Sr–Nd–B–Mo isotope study of Cenozoic granites from the Yardoi area in the eastern Tethyan Himalaya, China. These granites can be divided into two groups: mid‐Eocene porphyritic two‐mica granites with low SiO2 contents (65.9−69.6 wt.%) and adakitic geochemical signatures, and mid‐Eocene to Miocene equigranular granites with high SiO2 contents (71.6−75.5 wt.%). The high‐SiO2 granites (HSG) have similar Sr−Nd isotope compositions to the low‐SiO2 granites (LSG), but they have distinct δ11B values of −19.4‰ to −11.4‰ and −10.6‰ to −6.89‰. This indicates that the two groups have different sources, with the LSG derived by partial melting dominantly of metamafic rocks at thickened lower crustal conditions, and the HSG generated by partial melting of the mid‐crust metasedimentary rocks with less enriched Nd isotope compositions. The δ98/95Mo of the LSG and HSG are highly variable with values of −0.68‰ to 0.12‰ and −1.13‰ to 0.46‰, respectively. δ11B values of the HSG correlate positively with δ98/95Mo and Sr/Y values and correlate negatively with K2O, Rb, Zr, and Rb/Sr, reflecting the addition of external metamorphic fluids during anatexis of the metapelites. The B–Mo isotope data robustly suggest source‐controlled compositional diversity of the Himalayan granites, which could provide clues to the physical and geochemical responses during the evolution of a large orogen.

Geochemical data, Nd and Hf isotopes and U–Pb geochronology of meta-mafic rocks from western Gondwana suture zone

The West Gondwana orogen, represented in NE Brazil by Santa Quitéria continental magmatic arc and ultrahigh-pressure metamafic rocks of a suture zone, have amphibolite and coesite-bearing retro-eclogite in both margins of the magmatic arc. This research reports and discuss the geochemical and geochronological data (U–Pb and Lu–Hf in zircon and Sm–Nd whole-rock) of amphibolite and retro-eclogite from the eastern margin of a continental magmatic arc. The Santa Quitéria Complex and metasedimentary Ceará Complex hosted these rocks. The Santa Quitéria amphibolites shows evident fractionation of REE. Nb–Ta–Ce anomalies evidence magma generated in a subduction zone with contribution and recycling of crustal sedimentary material, corroborate for slightly negative εNd (−1.56) and Paleoproterozoic NdTDM value (1.80 Ga). Isotopic Lu–Hf in zircon data indicates positive εHf (+5.00 to +7.78) and Neoproterozoic model ages (HfTDM from 0.97 to 0.86 Ga) (t = 637 ± 34 Ma - sample TJF5-258) indicate their extraction from the mantle. For the amphibolite samples from the Ceará Complex, the elemental distribution suggest that these rocks place them among oceanic basalts of enriched segments of mid-ocean ridges (E-MORB) and oceanic island basalts (OIB) – intra-oceanic arc basalts (IOAB). U–Pb zircon data of Ceará Complex amphibolite points to crystallization at ca. 670 Ma (674 ± 9 Ma, sample TJJV-07) and two metamorphic events around 640 Ma (644 ± 9 Ma) and 600 Ma (591 ± 5 Ma) related to the continental collision. Positive εNd values (+1.66 to +4.16) and model ages (NdTDM from 1.26 to 1.00 Ga) suggest a protolith crystallized from juvenile material of mantle source. Our data support that the eastern edge of the Santa Quitéria magmatic arc constitutes an active margin with subduction of the Cryogenian oceanic crust.

Neoproterozoic ophiolite exotic blocks in the Outer Western Carpathians, southern Poland: a record of the fast ocean-floor cooling and alterations

Ophiolitic blocks, represented by metagabbro and serpentinite containing relict pyroxene, olivine, baddeleyite, zirconolite, Ni-pyrite and pyrrhotite, were found as exotic blocks in an olistostrome in the Magura Nappe, Outer Western Carpathians. The geochemical and isotopic features of the blocks suggest they represent mantle-derived rocks, with within-plate geochemistry signatures, modified by subduction, with lithospheric mantle input. A U-Pb apatite cooling age (614 ±3 Ma) is within age uncertainty of a published U-Pb zircon magmatic crystallization age (~614 Ma) implying rapid post-crystallization cooling. Pervasive alteration with replacement of primary minerals by low-temperature assemblages is observed in all rock fragments and is interpreted as contemporaneous with shearing. The secondary mineral assemblages and temperature modelling allow the interpretation that the pervasive ocean-floor metamorphism is the alteration in these meta-mafic rocks. These ophiolitic fragments can be linked to the Neoproterozoic break up of Rodinia/Pannotia.

Discovery of Early Tonian Calc‐alkaline and Shoshonitic Metamafic Rocks from the North Purulia Shear Zone, Chhotanagpur Gneissic Complex, Eastern India: Implications of Proterozoic Sub‐continental Lithospheric Mantle

AbstractReports of shoshonitic rocks in Precambrian terrains are relatively rare. Pl‐Grt amphibolites and Hbl‐Bt mafic granulites occurring in the migmatitic gneisses of the Chhotanagpur Gneissic Complex (CGC) show calc‐alkaline and shoshonitic characteristics. Relict porphyritic, sub‐ophitic and poikilitic textures are noted in these rocks. Their parent magma was emplaced during the waning phase of the regional metamorphism. Geochemically, these metamafics are similar to the Group III potassic and ultrapotassic rocks of Foley et al. (1987). The magma was derived from the metasomatized subcontinental lithospheric mantle (SCLM). Subduction‐related sediment melts metasomatized the SCLM. Compositionally, the SCLM is a metasomatized phlogopite‐amphibole‐spinel‐bearing harzburgite. 1%–5% batch melting of the SCLM could produce the parental magma of the mafic granulites. Pressures and temperatures of metamorphic equilibration were carried out by pseudosection modeling. Peak metamorphic assemblage (M1: Grt‐Cpx‐Pl‐Qz) in garnetiferous amphibolite equilibrated at 740°C and 8.7 kbar. The Cpx‐Pl corona appeared around the garnet during decompression (M2: 655°C, 6 kbar). The Hbl‐Pl symplectites around garnet formed during isobaric cooling (M3: 580°C and 5.9 kbar). The emplacement of shoshonitic magma and subsequent decompression happened at the slab break‐off stage of continental collision (∼990 Ma).

Petrological characterization of Fe–Ti oxides in metamafic rocks from the Nw borborema province, Ne Brazil

The coexistence of Fe–Ti oxide phases constitutes an important petrogenetic tool to understanding the evolution of metamafic rocks. In the NW part of the Borborema Province, NE Brazil, metamafic rocks occur in two distinct zones: the Cariré Granulite and the Forquilha Eclogite. The present work characterizes the sequence of crystallization involving Fe–Ti oxides of these lithotypes and constrains its redox conditions using the ilmenite-rutile oxybarometer. Multiphase association of Fe–Ti oxides of a mafic granulite from the Cariré Zone and a retrograded eclogite from the Forquilha Zone comprise ilmenite, magnetite, rutile, spinel, and hematite. Rutile occurs as inclusions, surrounded by vermicular, xenomorphic or coronitic titanite, within ilmenite crystals. The redox conditions set by the sequence of Fe–Ti oxides crystallization and the rutile-ilmenite oxybarometer are compared to the FMQ (fayalite-magnetite-quartz) buffer, indicating an increase in oxygen fugacity from peak to retrograde conditions. Our characterization stablishes (re)crystallization and oxyexsolution sequences for the Fe–Ti oxides and the rutile-ilmenite oxybarometer in the mafic granulite from the Cariré Zone suggests oxygen fugacity of FMQ – 3.6. The retrograded eclogite indicates a more reduced environment for the Forquilha Zone, in which the low Fe3+ content of ilmenite hampers the estimation of redox conditons. The constrained ΔFMQ is within the range of common redox compositions for subduction-related metamafic rocks, accordingly with the regional geochemical classification reported in the literature to the Cariré and Forquilha zones.

Ladik ve Esirağıl Alanı (Konya, Orta Anadolu) Yöresindeki Geç Silüriyen Erken Karbonifer Yaşlı Metakarbonatların Metamafik Dayklarla Kontak Metamorfizması

In NNW Konya, mafic rocks form as dyke swarm or isolated linear dykes, which are cut by a series of normal faults that developed possibly by emplacement of the dyke-forming magma. Some anhydrous oxidized calcic skarn zones have ever been found out in Silurian-Early Carboniferous metacarbonates next to the Triassic metamafic dykes faulted, and in roof pendants within the intrusion. The metamafic rocks are suggested to have a low temperature and a small amount (or even absence) of the heat of crystallization, which causes the development of a restricted skarn zone. Mineralogical studies show that the skarn contains garnet, magnetite/hematite, chlorite, and sericite. The magnetite/hematite minerals form mostly as large euhedral crystals, up to 0.5 cm in length, which may be resorbed by chlorite and felsic minerals or rimmed by goethite. The garnet typically forms as spectacular euhedral large crystals, up to ~1.5 mm in size. The existence of chlorite and sericite, and the lack of hornblende, biotite and wollastonite in the region indicate that contact metamorphism took place under low pressure, relatively low temperatures (albite-epidote hornfels) and/or high CO2 conditions in the area.

Inheritance versus subduction-related δ11B signatures of eclogites: Insights from the Voltri Massif (Ligurian Western Alps, Italy)

Trace element and isotopic compositions of exhumed high-pressure (P) mafic rocks are an important archive to investigate chemical processes in subduction zones. Here we report the B isotope (δ11B) composition of eclogitic mafic rocks enclosed in high-P serpentinite from the Voltri Massif, Ligurian Alps (Italy). Combined with bulk δ18O values, 87Sr/86Sr ratios and trace element data, the δ11B of eclogitic mafic rocks were investigated to test oceanic inheritance vs. subduction-related processes and to provide inferences on the timing of B uptake in eclogitic metagabbros.Petrographic observations along with major and trace element data indicate that the eclogite facies mafic rocks derived from primitive Mg-Al-bearing gabbros (Erro-Tobbio eclogites) and differentiated Fe-Ti-bearing oxide gabbros (Vara eclogites). Metarodingite from Vara shares similar REE pattern to that of the Erro-Tobbio eclogites, suggesting a plagioclase-rich gabbroic protolith. The studied rocks show variable enrichments in fluids-mobile elements (e.g., Cs, Ba, Li, Sr; high Li/Y, B/Nb). Boron concentrations range between 2.3 and 7.6 ppm, with no significant differences among the different samples. Oxygen isotope compositions (1σ ± 0.1‰) for the Vara and the Erro-Tobbio eclogites range from +5.4 to +6.4‰ and from +3.1 to +5.3‰, respectively, whereas the 87Sr/86Sr ratios range between 0.7036 and 0.7042 for the Vara eclogites and from 0.7030 to 0.7034 for Erro-Tobbio metagabbros. The B isotope compositions for the Vara eclogites range between −3.2 to +0.9‰, which are in striking contrast with the positive δ11B signatures of the Erro-Tobbio eclogitic metagabbros ranging from +4.3 to +8.9‰, the highest positive δ11B signatures observed in eclogitic metagabbros so far. Metarodingite from Vara has a δ18O of +3.7‰ and 87Sr/86Sr of 0.7046 and a δ11B value of +11.5‰.We argue that the δ18O signatures and the 87Sr/86Sr ratios of metamafic rocks from the Voltri Unit mainly reflect inherited signatures from the seafloor, whereas subduction-related processes are mainly traced through δ11B variations. Progressive B isotope fractionation due to dehydration processes during subduction is responsible for the dominantly negative δ11B signatures of eclogites from the Vara area and elsewhere, whereas the positive δ11B of the high-P metarodingite is compatible with an inherited oceanic signature, although interaction with fluids released by the surrounding serpentinites at peak conditions cannot be ruled out. We discuss three scenarios to explain the positive δ11B imprint reported for the Erro-Tobbio eclogites: (i) inheritance of oceanic signatures, (ii) records of B isotope fractionation from an extreme 11B-rich protolith, or (iii) interaction with 11B-rich slab fluids derived from serpentinite hydration at high-P. Based on these scenarios, two potential implications of global relevance are presented: (1) the transfer of largely unmodified oceanic signatures up to eclogite facies conditions, and (2) the formation of newly (subduction-related) 11B-rich reservoirs. We propose that the protolith composition of the mafic crust controls the development of hydrous phases at high-P thus enabling the preservation of high δ11B signatures. This mechanism of chemical transfer may generate a 11B-rich reservoir that, together with high-P serpentinites, may form positive δ11B domains in the mantle.

Late Mesoproterozoic to early Neoproterozoic evolution of the Meghalaya gneissic complex, NE India: significance in Rodinia assembly

ABSTRACT The Meghalaya Gneissic Complex (MGC) of northeast India is a little-studied high-grade metamorphic terrain, located close to the Late Palaeoproterozoic to early Neoproterozoic orogenic front. We include mapping, petrography, mineral chemistry, geochemistry, phase equilibria modelling, and U-Th-total Pb monazite geochronology to investigate the evolutionary history of deformed and metamorphosed ortho- and para-gneisses from the central MGC. The metapelite and metamafic rocks of the MGC are folded to E-W upright, antiforms-synforms; and intruded by charnockites during progressive deformations. Reconstructing the metamorphic history of pelite (garnet-cordierite granulite) and two pyroxene granulite, using a TiMnNCKFMASH and TiNCKFMASHO system, reveals a clockwise P–T path where the peak metamorphism was associated with mid crustal burial heating to granulite facies (~825°C and 5.5 to 6.5 kbar) and subsequent cooling with a minor decompression (~ 816°C and 5.3 kbar). Chemically zoned monazites were grown episodically during 1035 ± 13 Ma (n = 21), 976 ± 14 Ma (n = 16), and 494 ± 14 Ma (n = 26). The granulite metamorphism here initiated at 1035 ± 13 Ma and reached thermal peak at 976 ± 14 Ma. This contribution emphasizes the importance of late Mesoproterozoic to early Neoproterozoic metamorphic evolution of the MGC related to the collision of North and South Indian cratonic blocks. The studied P-T path differs from the previously reported Meso- to early Neoproterozoic paths of Central and Western India and close to Western Australia. This finding further explains the change in the early Neoproterozoic collisional pattern of the Central Indian Suture in extreme east (near MGC) and its significance in reconstructing the western Rodinia.

Late Paleozoic–Early Mesozoic granitic rocks in Eastern Peninsular Malaysia: New insights for the subduction and evolution of the Paleo-Tethys

• The granitoids in East Malaya were emplaced at 289–244 Ma. • The granitoids were formed in response to the Paleotethyan subduction . • The slab roll-back of the Eastern Paleotethyan initially occur at ∼ 270 Ma. • Subduction-related granitoids in East Malaya can extend to SW China and W Borneo. Well-preserved Late Paleozoic–Early Mesozoic igneous rocks in Peninsular Malaysia are important for investigating the Paleotethyan tectonic evolution. This study presents new zircon U-Pb dating, whole-rock geochemical, and Sr-Nd-Pb-Hf isotopic data for granitoids identified from the East Malaya. By utilizing all available data, the Permian–Middle Triassic granitoids in Eastern Peninsular Malaysia can be divided into three groups. Group A (289–270 Ma) I-type granites have higher ε Nd (t) values of − 6.6 to − 2.6 and zircon ε Hf (t) values of − 7.1 to + 4.9 than Group B S-type granites (285–272 Ma) with ε Nd (t) = − 10.1 and zircon ε Hf (t) = − 23.1 to + 1.5. Group C (254–244 Ma) with A-type characteristics, has ε Nd (t) and zircon ε Hf (t) values ranging from − 7.3 to − 3.8 and − 8.9 to + 2.2, respectively. The Pb isotopic values for three groups are similar with ( 206 Pb/ 204 Pb) i = 18.71–19.43, ( 207 Pb/ 204 Pb) i = 15.66–15.71 and ( 208 Pb/ 204 Pb) i = 38.27–39.43. Group A was derived from metaigneous rocks with a juvenile mafic component, while Group B was from metasedimentary rocks. Group C had a mixed source of “ancient” meta-mafic rocks with a juvenile mafic component. This study proposes that the Late Paleozoic–Early Mesozoic granitoids were formed in response to the subduction of the Paleotethyan Ocean, and that a tectonic transition from subduction to slab roll-back might occur at ∼ 270 Ma. Subduction-related granitoids in East Malaya can northernly extend to the Tachileik Batholith in eastern Myanmar and Jinghong in SW China, and southernly link with W Borneo.