Metals In Sediment Cores Research Articles

Heavy metals in core sediments from the western Bay of Bengal: implications on historical pollution, eco-environmental risks, and potential sources

The western Bay of Bengal is particularly susceptible to the harmful impacts of increasing coastal pollution, as coastal population and urban development are occurring at unprecedented rates. The rapid urbanization and industrialization along the east coast of India coupled with the transfer of contaminants into the Bay of Bengal through riverine systems, causing a direct impact on marine ecosystems. In the present study, an attempt has been made to understand the heavy metal distribution on shelf sediments in the western part of the Bay of Bengal to infer their source, processes, and historical changes in marine pollution. Three short sediment core samples were collected and analysed for sediment texture, organic matter, and heavy metals. Cores 1 and 2 contain a high amount of sand content, representing shallow marine with moderate to high-energy conditions, and were deposited at a recent time. Core 3 was dominated by muddy sand to sandy mud, which denotes calm sedimentation without any turbulence, and these sediments were deposited under relatively low-energy conditions. The higher concentration of organic matter in the top layers of the core indicates both marine and terrestrial input. The heavy metal contents show quite heterogeneous and variable distributions from one element to another and from one core to another. The calculated pollution indices such as Contamination Factor (CF), and Geoaccumulation Index (Igeo) and Pollution Load Index (PLI) values indicate that all the core sub-samples are severely enriched and highly polluted by Cd and moderately polluted by Pb. The increased heavy metal concentration in the upper portion of the sediment cores and moderate to considerable ecological risks indicate that these metals have been deposited in the study area for the past few decades.

Distribution of heavy metals in core sediments of Southern Iraq Waterways

The object of the study is heavy metals in the Shatt Al-Arab River. Shatt Al-Arab River is considered one of the most important internal rivers in Iraq due to its multiple economic and social importance. In addition, this river has an important strategic location. Despite its importance mentioned above, the Shatt Al-Arab River suffers from various wastes from many and varied sources, which have directly affected the quality of its water and consequently the quality of the community of living organisms that live in it. Levels and distribution of certain heavy metals, Cd, Cu, Fe, Mn, Ni, and Pb, were determined in core sediments from Southern Iraq Waterways. Six sites were investigated, two in the lower reaches of Al-Hammar Marsh, 1) El-Barka, 2) El-Garmah, and four sites along Shatt Al-Arab River, 3) Al-Ashar, 4) Abu Al-Khaseeb, 5) Abu Floos Port, and 6) Al-Faw. The results indicate that Al-Faw station was distinguished by the fact that the highest values of heavy elements were obtained at this station and all depths, except Cd at Al-Ashar station at a depth of 25 cm (26.1375 μ/gm), Cu at a core depth of 50 cm (4.9635 μ/gm), Ni at a core depth of 25 cm (5.2483 μ/gm), and surface water (2.9021 μ/gm) and Pb in surface water at Abu Floos Port station (3.5001 μ/gm). The lowest concentrations of heavy elements for Cu, Mn, and Ni are in all depths of core sediments. Other elements, Cd, Pb, and Fe, were higher; on the other hand, higher levels of concentrations for all studied heavy metals were recorded at a depth of 100 cm. Iron was the highest in all depths of core sediments.

Controlling factors and sources-specific ecological risks associated with toxic metals in core sediments from cascade reservoirs in Southwest China

Toxic metals (TMs) in reservoir sediments pose significant risks to ecosystem security and human safety, yet their presence in the cascade reservoirs of the Lancang River remains understudied. This research examined TMs in core sediments from the Manwan (MW) and Dachaoshan (DCS) cascade reservoirs, aiming to elucidate contamination characteristics, controlling factors, and source-specific ecological risks. The study revealed that the concentrations of As, Cd, Cr, Cu, Hg, Ni, and Zn in the MW Reservoir (37.3, 0.54, 95.1, 44.0, 0.09, 44.8, and 135.7 mg/kg) were notably higher compared to the DCS Reservoir (14.6, 0.30, 82.6, 31.0, 0.08, 36.6, and 108.7 mg/kg). While both reservoirs demonstrated elevated contamination levels of Cd and Hg, the MW Reservoir also exhibited high levels of As, whereas the DCS Reservoir showed relatively high levels of Pb. Mining activities in upstream metal deposits significantly correlated Cd, Hg, and Zn in the MW Reservoir with sulfur. In both reservoir sediments, Cr and Ni displayed a greater affinity for iron oxides, while As, Cd, Cu, Hg, and Zn showed more affinity with manganese oxides. Ecological risk index (RI) values in half of the sediments from the MW Reservoir ranged from 300 to 600, denoting a significant ecological risk. Conversely, in the DCS Reservoir, 93.3 % of the sediments exhibited RI values between 150 and 300, signifying a moderate ecological risk. Source-oriented ecological risks highlighted the need for particular attention to Cd from anthropogenic sources in the MW Reservoir. These findings underscore the importance of implementing measures for TM contamination prevention and control, contributing to strategic planning for sustainable water resource management in the Lancang-Mekong River.

Temporal variation and pollution status of heavy metals in core sediments from Jiangsu intertidal area, China

Eight heavy metal concentrations were analyzed from a 60.35-m-long sediment core in the Jiangsu intertidal area, China. Based on the lithofacies characteristics, mean grain size, downcore distributions of elements, and accelerator mass spectrometry (AMS) 14C and optically stimulated luminescence (OSL) data, the sediments in the core were divided into three units that formed during marine isotope stages 4 (MIS 4), MIS 3, and MIS 1. Except for Cd, all the other heavy metals had the lowest average concentrations in U3, which formed during MIS 4 with the coarsest sediment, representing a fluvial deposit. Most of the heavy metals were positively correlated with Al, Fe, and the total organic carbon (TOC), indicating these metals had the same sources. Pearson's correlation coefficient, enrichment factor, geoaccumulation index, and principal component analysis suggested that there was no element enrichment or contamination in the core sediments and that all heavy metals were naturally sourced.

Metals and microorganisms in a Maar lake sediment core indicating the anthropogenic impact over last 800 years

A closed Maar lake, receiving mostly atmospheric deposition, offers a unique setting for investigating the impact of human activities on the environment. In this study, we aimed to investigate the historical record of metals in core sediments of Maar Lake in Huguangyan (HGY), Southeast China, and elucidate the possible microbial responses to anthropogenic metal stress. Five stages were divided according to the historical record of metals and corresponding distribution of microbial community, among which Pb and Sn showed a peak value around 1760 CE, indicating the ancient mining and smelting activities. Since the 1980s, a substantial enrichment of metals such as Zn, As, Mo, Cd, Sn, Sb, and Pb was observed, due to the rapid industrial growth in China. In terms of microorganisms, Chloroflexi phylum, particularly dominated by Anaerolineales, showed significant correlations with Pb and Sn, and could potentially serve as indicator species for mining and smelting-related contamination. Desulfarculales and Desulfobacterales were found to be more prevalent in recent period and exhibited positive correlations with anthropogenic metals. Moreover, according to the multivariate regression modeling and variance decomposition analysis, Pb and Sn could regulate Anaerolineales and further pose impact on the carbon cycle; while sulfate-reducing bacteria (SRB) could response to anthropogenic metals and influence sulfur cycle. These findings provide new insights into the interaction between metals and microbial communities over human history.

Comparison of spatiotemporal burial and contamination of heavy metals in core sediments of two plateau lakes with contrasting environments: implication for anthropogenic-driven processes.

Investigating the impacts of climatic factors and human activities on sedimentary records of heavy metal (HM) contamination in lakes is essential for decision-making in global environmental monitoring and assessment. Spatiotemporal distributions of grain size (GS) and HM (Al, Cr, Mn, Ni, Cu, Zn, As, and Pb) concentrations have been conducted in core sediments that are collected from two adjacent plateau fault-bound lakes in southwest China with contrasting environments, i.e., deep oligotrophic Lake Fuxian (FX) and shallow hypertrophic Lake Xingyun (XY). Results showed that the average value of d50 in FX (4.61 μm) was lower than that in XY (8.35 μm), but the average concentrations of HMs (except Cr and Mn) in XY were higher than those in FX. Heavy metal burial rates (HMBR) were mainly controlled by sediment accumulation rates (SARs) rather than HM concentrations. The correlation coefficients between GS and HM concentrations became strong as the increasing water depths were associated with a stable sedimentary environment. Time-integrated enrichment factors (EF) and source identification of HMs between FX and XY represented that Cr, Ni, and Cu originated from natural sources but Mn, Zn, As, and Pb from anthropogenic sources, respectively. Regardless of FX and XY, the transition times of HMs from natural to anthropogenic sources occurred in the mid-1960s. Comparison of qualification impacts of climatic factors and human-induced factors on increased anthropogenic HMBR by the partial least squares path modeling (PLS-PM) implied that socio-economic activities, such as population density (PD) and gross domestic product (GDP), provided higher contributors to increased anthropogenic HMBR in XY (0.23/0.71) than FX (0.11/0.18). The comparative results of this study provided new insights into environmental monitoring and management of HM contamination for adjacent lakes with contrasting environments.

Heavy metals and Pb isotopes in sediment cores from the Bering and Chukchi seas: Implications for environmental changes and human activities over the past century

The Bering Sea and the Chukchi Sea are important regions for marine ecosystems and climate change. However, the historical deposition and sources of metals in these regions are poorly understood. In this study, we utilized Pb isotopes and multi-element concentrations (Ni, Cu, Fe, Mn, Zn, Cd, Pb) coupled with Pb-210 dating to investigate the historical deposition and source identification of metals in sediment cores collected from the Bering Sea and the Chukchi Sea. Our findings reveal that the transport of organic matter was mainly transported by marine and terrestrial sources in the Bering and Chukchi Sea, respectively. Historical variations of metals were similar in both seas, showing an increasing trend of metals (excluding Mn) from the 1960s to the 1990s, followed by a gradual decrease after the 1990s, which can be attributed to the development of industrial and gasoline emission. The results of the geo-accumulation index indicated that sediment in both seas was relatively unpolluted with metals. Additionally, Pb isotopic ratios suggested that natural weathering was the primary source of Pb in the area, but the use and phase-out of gasoline were also well-reconstructed. This study provides valuable information for assessing environmental changes and human activities over the past century in the Arctic and subarctic Ocean.

Historical trends and pollution assessment of heavy metals in core sediments from the Jiangsu offshore area, China

To assess the historical changes and pollution status of heavy metals, core sediments from the Jiangsu offshore area of China were systematically sampled and analyzed to determine the concentrations of Cu, Pb, Zn, Cr, Cd, As, Hg, Li, Ni, and Co. The stratigraphic framework of the SYS-1501 core was identified based on sedimentary structures, sedimentary facies, grain size, and comparison with seismic reflections and other well-studied cores from adjacent areas. The Pearson’s correlation coefficient, enrichment factor (EF), geoaccumulation index (Igeo), and principal component analysis (PCA) were used to distinguish the sources and assess the pollution risk of heavy metals. The results showed no elemental enrichment or contamination in the core sediments, and the high EF and Igeo values of Pb, As, Hg, and Li may be related to the selected background values of these metals. Except for Mn, all other metals and TOC exhibited similar vertical distribution patterns that were closely related to the mean grain size (Mz). Almost all the heavy metals were positively correlated with Al, Fe, and Mz, and all had high loadings on PC1, indicating that they are naturally sourced. Manganese (Mn) had a high loading on PC2, mainly representing the effect of marine authigenic elements on the sediments. Historical changes in the heavy metals in the core sediments were predominantly related to the sedimentary environment, sediment sources, and Mz.

Heavy Metals in Sediments of Hulun Lake in Inner Mongolia: Spatial-Temporal Distributions, Contamination Assessment and Source Apportionment

The spatial and temporal distributions, contamination evaluation, and source apportionment of Cu, Zn, As, Pb, Cd, and Cr in the sediments of Hulun Lake were explored in this work. The pollution characteristics of six heavy metals were assessed by single factor pollution index (PI) and geo-accumulation index (Igeo). The sources of heavy metals in the surface sediments were analyzed by the positive definite matrix factorization (PMF) and Pearson correlation analysis. The sedimentary records of heavy metals in core sediments were reproduced by radioisotopes. The average concentrations of 6 heavy metals except Cd were lower than the corresponding background values. The spatial distributions of Cu, Zn, Cr, Cd and As were generally similar and showed higher abundances in the southwestern part of the lake. With the use and import of heavy metals, the concentration of heavy metals in core sediments increased with the fluctuation of years. The peak of heavy metal concentration was related to the high growth rate of gross domestic product in 2003-2008. The single factor pollution index and geo accumulation index results showed that the surface sediment was mainly polluted by Cd, followed by Zn and As. Natural parent material, agricultural activities and industrial activities were the main sources of heavy metal pollution in the sediments, accounting for 17.03%, 26.34%, and 56.63% of the total heavy metal accumulation, respectively. Pb was derived mainly from natural parent material. Cd and As were closely associated with agricultural activities. Cu and Zn were mainly attributed to industrial mining activities. Source apportionment of the ecological risks of heavy metals illustrated that industrial sources were the primary ecosystem risk sources (66.1%), followed by agricultural sources (23.75%) and natural sources (10.15%). The results will also provide reference data for future studies of heavy metals pollution in sediments from Hulun Lake and other lakes.

Vertical distribution, contamination status and ecological risk assessment of heavy metals in core sediments from a mangrove-dominated tropical river

Understanding the vertical distribution of heavy metals aids in tracing the contamination history, however, it is limited for mangrove-dominated river. Thus, this study aimed to assess the vertical distribution of nine heavy metals and their possible ecological risk in several layers of core sediments from a mangrove-dominated river inside the Sundarban mangrove forest (World heritage and Ramsar site), Bangladesh. 45 core samples from five stations were analyzed using Flame Atomic Absorption Spectrophotometer (FAAS). The findings showed that, with the exception of Fe, Ni, and Cu, which suggested increased metal release in recent times, higher metal levels were recorded in the surface layer (0–10 cm), followed by the middle layer (10–20 cm), and inner layer (20–30 cm) of sediment cores. When compared to non-industrial forest sediment, core sediment from industrial sites contained noticeably more metals (p < 0.05). Overall, the mean metal concentration (mg/kg) followed the increasing order of Cd < As < Pb < Cu < Cr < Zn < Ni < Mn < Fe. Among the studied metals, the levels of Cd and Ni exceeded the average shale value. Contamination indices such as enrichment factor (EF), contamination factor (CF), and geo-accumulation index (Igeo) showed that the studied sediments were only contaminated by Cd. Ecological risk assessed by ecological risk factor (Eri) and risk index (RI) suggested that the analyzed heavy metals, with the exception of Cd, posed no significant ecological threats. All of the heavy metals analyzed might have originated from similar anthropogenic sources, according to the correlation matrix, cluster analysis (CA), and principal component analysis (PCA).

Assessment of the vertical characteristics and contamination levels of toxic metals in sediment cores from typical Chinese intertidal zones

The heavy metal (As, Cd, Cr, Cu, Hg, Pb, and Zn) contents of 24 sediment cores were obtained and analyzed from 12 typical Chinese intertidal zones. The results revealed a gradual improvement in the environmental quality of the intertidal zone. Enrichment factor and geoaccumulation index analyses demonstrated a generally good environmental quality of intertidal sediment, with some areas of serious contamination, such as the Xiamen Jiulong Estuary, the Yangtze River Estuary, and the Pearl River Delta. Relative to the guidelines for sediment quality, the studied intertidal zones were moderately impacted, with a risk of biotoxic impacts. This research reveals the status of toxic metal pollution in the intertidal zone of China and provides a reference for coastal area development.

Chronological deposition record of trace metals in sediment cores from Chaohu Lake, Anhui Province, China

Lakes located in the mid-low reaches of the Yangtze River watershed have been subjected to various degrees of human perturbation that would have resulted in toxic metal concentrations and would pose potential risk to the natural habitats. Therefore, in the present study, two sediment cores from Chaohu Lake were collected to determine any such concentration, expressed as the enrichment characteristics of major and trace metals (Al, Fe, Mn, Cu, Pb, Zn, Cr, Cd, As, Hg, and Ni) in response to natural and anthropogenic changes. An approximate 180-year (1840-2021) deposition record of trace metals in sediment cores was obtained on the basis of 137Cs and 210Pb dating. Enrichment factors (EFs) and the geo-accumulation index (Igeo) were adopted to evaluate the enrichment state and pollution status of trace metals. The results showed that Cu and Zn were persistently more enriched in sediment, whereas Mn, Pb, Cd, and Hg has shown remarkable increasing trends in the west lake since the 1970s. Evaluation of the Igeo confirmed that sediment was moderately polluted with Cu and Zn within the whole lake and with Cd in the west lake area, whereas it was uncontaminated with Cr and slightly contaminated with other metals. Furthermore, source identification based on multivariate statistical analysis including correlation analysis, principal component analysis, and cluster analysis suggested similar pollution sources for the studied metals. Combined with the natural and anthropogenic changes within the watershed, enhanced soil erosion due to population expansion and agricultural intensification was a major contributor to sedimentary metals before the 1970s while industrial wastewater, urban runoff, and domestic sewage were predominant inputs of trace metals after the 1970s.

Contamination Assessment of Heavy Metals in Sediment Cores from De Montigny Lake around Siscoe-Sullivan Former Mining Sites, Val-d’Or, Canada

Seven sediment cores were collected from De Montigny Lake in order to determine concentrations, and contamination assessment of heavy metals such as Cr, Zn, Ni, Pb, Cu, Co and Cd. The mean concentrations of heavy metals are as follows: 48.3 mg/kg for Cr, 36.4 mg/kg for Zn, 20.6 mg/kg for Ni, 14.7 mg/kg for Pb, 10.2 mg/kg for Cu, 6.7 mg/kg for Co and 0.1 mg/kg for Cd. Based on the sediment quality guidelines, the mean concentration metals such as Cr, Cu and Ni exceeded the US Environmental Protection Agency (USEPA) guideline. However, the concentration of Cr was more than the Canadian Water Quality Guidelines for Protection of Aquatic Life (CCME), and Threshold Effect Level (TEL) guidelines. The metal contamination in the sediments was also evaluated using Enrichment Factor (EF) and geoaccumulation index (Igeo) to assess natural and anthropogenic factors. The results of enrichment factor methods demonstrated that sediments from De Montigny Lake were moderately to high enriched, mainly controlled by through anthropogenic activities. According to Sediment Quality Guidelines (SQGs), the concentrations metals from the core sediment of De Montigny Lake are classified as having moderate impacts with potential adverse biotoxic effects.

Distribution of Heavy Metals in Sediment Cores Collected from the Nakdong River, South Korea

Understanding the distribution of heavy metals in sediment is necessary because labile heavy metals can partition into the water column and bioaccumulate in aquatic organisms. Here we investigated six heavy metals (Co, Cu, Mn, Ni, Pb, and Zn) in sediment cores using a five-step sequential leaching method to examine the occurrence of heavy metals in the sediment. The results showed that all elements, except Mn, are depleted in the exchangeable and carbonate fractions. However, heavy metal concentrations are much higher in the Fe-Mn oxide and organic matter fractions, especially for Cu, indicating enrichment in the organic matter fraction. Furthermore, contamination parameters (contamination factor and geoaccumulation index) indicate that Mn contamination is high, primarily derived from anthropogenic sources, presenting a potential risk to ecosystems in the Nakdong River.

The spatial-temporal evolution of heavy metal accumulation in the offshore sediments along the Shandong Peninsula over the last 100 years: Anthropogenic and natural impacts

The anthropogenic and natural impacts on the temporal and spatial variations of heavy metals in sediments under the Shandong Peninsula coastal current are still unclear. Here, the concentrations\\burial fluxes of Cr, Cu, Zn, As, and Pb in three sediment cores retrieved from the Bohai Sea and the Yellow Sea along the Shandong Peninsula were analyzed to study the spatial-temporal variability of heavy metal accumulation over the last century. The results showed that the buried heavy metal fluxes were relatively low at the end of the Shandong Peninsula coastal current. The enrichment factor (EF) and geoaccumulation index (Igeo) indicated that those metals did not severely pollute the sediments except As that reached a moderate enrichment. Principal component analysis (PCA) revealed that Cr, Cu, Zn, and Pb were mainly derived from natural weathering and As was determined by anthropogenic contamination. The strength of the Shandong Peninsula coastal current, the Yellow River estuary location, and sediment discharge load significantly influenced the concentrations of natural-origin heavy metals by affecting sediment grain size and the source-sink process. The emission of pollutants from agricultural and industrial activities in the Shandong Peninsula region resulted in As enrichment since the 1950s. Moreover, the EF values of heavy metals in sediment cores from China's coastal seas showed apparent spatial variations of heavy metal pollution but had coherent temporal variability with China's economic development process. Heavy metals pollution has weakened in most coastal seas since the 2000s, likely due to the extensive industrial upgrading and the implementation of pollution control. These results have a reference significance for studying the evolution and source-sink process of the heavy metals in offshore sediments and tracing anthropogenic impacts in different periods.

Vertical distribution of heavy metals in core sediments from Kelantan River off Tanah Merah, Kelantan, Malaysia

Core sediments from two sampling points namely TM 2 and TM3 which are located at the Kelantan Rive near to Tanah Merah district had been collected to determine the vertical profile of heavy metals contents. TM 2 and TM3 were located near to gold mining area and agriculture area, respectively. The heavy metals in Tanah Merah were analysed using Atomic Absorption Spectrophotometer (AAS) PinA Acle 900F model. The degree of pollution has been investigated using Geo-accumulation (Igeo) index. For the result, the average value of heavy metals in Tanah Merah are Cu (12.67 ± 5.38 mg/kg), Pb (44.57 ± 8.75 mg/kg), Cr (56.69. ± 10.38 mg/kg), Zn (157.89 ± 88.56 mg/kg), Fe (4.08 ± 0.82 %) and Al (7.84 ± 1.53 %). The vertical profile of Cu and Zn at the bottom layer showed the decreasing trend toward the bottom of sediment suggesting the additional anthropogenic input of both metals to the sediment. In addition, most of the concentration value of Zn at TM2 near to gold mining set were exceed the permissible limit set by WHO. Furthermore, the result from the Igeo index also supported sediments at TM 2 which is located near to mining area are extremely contaminated with Cu and Zn. As conclusion, the authorities should closely monitor the level of pollution at the Kelantan River especially near to mining area.

Vertical distribution and contamination assessment of heavy metals in sediment cores of ship breaking area of Bangladesh.

Vertical heavy metal profiling reflects the history of the deposition of metals and helps to understand the characteristics of accumulation in various layers of the sediment. Nevertheless, no previous studies in Bangladesh had focused on the vertical distribution of heavy metals in core sediments. In this study, vertical distribution, contamination level and potential ecological risks of six heavy metals (Zn, Cu, Pb, Cr, Ni, Mn) from the core sediment of ship breaking were assessed and compared with the non-ship breaking area of Bangladesh. The concentration (µg/g) of heavy metals in the 0-10cm (surface), 10-20cm (middle) and 20-30cm (bottom) of sediment cores was as follows, respectively: Zn (35.54-100.68, 37.27-258.02, 42.78-66.45); Cu (16.38-75.25, 30.64-92.02, 34.99-52.98); Pb (4.84-132.08, BDL-204.48, BDL-23.51); Cr (14.57-42.13, 25.31-42.71, 15.26-36.34); Ni (4.02-42.23, 4.94-43.70, 4.40-43.13); Mn (198.74-764.16, 257.77-980.50, 255.62-856.44). The heavy metal content of core sediment from the shipbreaking region was substantially higher than that of non-shipbreaking area. Except for Ni, heavy metal content was highest in the middle layer, followed by the upper and lower layers of the sediment core. Contamination exponents such as enrichment factor, contamination factor and geo-accumulation index (Igeo) revealed contamination by Zn, Cu and Pb while potential ecological risk factor ([Formula: see text]) and risk index suggested low ecological risk by studied heavy metals except for Pb. Correlation matrix, cluster analysis and principal component analysis indicated that all studied heavy metals could have similar anthropogenic origins.

Distribution and Ecological Risk Assessment of Heavy Metals in Core Sediments of Burullus Lake, Egypt

Distribution and Ecological Risk Assessment of Heavy Metals in Core Sediments of Burullus Lake, Egypt

Thermokarst Disturbance Drives Concentration and Composition of Metals and Polycyclic Aromatic Compounds in Lakes of the Western Canadian Arctic

AbstractWhen assessing the environmental impact of petroleum hydrocarbon exploitation, it can be challenging to differentiate anthropogenic from natural hydrocarbon sources. For example, areas underlain by permafrost may be affected by erosion of hydrocarbon‐rich deposits from thermokarst activity, complicating environmental assessments of human impacts from petroleum extraction. Here we examined polycyclic aromatic compounds (PACs) and metals in sediment cores from lakes affected to varying degrees by thawing permafrost. We used a paired‐lake design on lakes with pronounced shoreline retrogressive thaw slumps and compared them to nearby lakes in undisturbed (no retrogressive thaw slump) systems in the Mackenzie Delta uplands (Northwest Territories, Canada). Total organic carbon (TOC)‐normalized concentrations of parent and alkylated PACs were higher in surface sediments of slump‐affected lakes. Slump‐affected lakes were also enriched in metals related to local shale‐based, Quaternary deposits (e.g., Ca, Sr, and Mn) when compared to reference lakes where surficial materials were not exposed by thermokarst activity. Diagnostic ratios of specific PACs suggested that slump‐affected lakes also had a greater influence from petroleum‐based compounds, likely sourced from the local geology. Higher PAC concentrations and petrogenic composition were best explained as a combination of low TOC availability and increased inputs of previously bound hydrocarbons from the catchment due to permafrost erosion.

Vertical profiles and contamination assessments of heavy metals in sediment cores from typical intertidal zones in northern China

The concentrations of 7 heavy metals (Cu, Pb, Zn, Cr, Cd, As and Hg) were analysed in 12 sediment cores collected from 6 typical intertidal zones in northern China. The data reveal that the environmental quality of the northern Chinese intertidal environment has gradually improved and that the concentrations of Cu, Pb, Zn, Cr, Cd, As and Hg averaged over all sediments were 29.2, 25.8, 78.5, 72.2, 0.168, 10.7 and 0.044 mg/kg, respectively. The results of the geoaccumulation index and enrichment factor methods demonstrate that most of the sediments in the intertidal zone in northern China have good environmental quality, although some areas are contaminanted, including the Yangtze River Estuary, which is seriously contaminanted. According to sediment quality guidelines, the heavy metal concentrations in the sediments in the 6 typical intertidal zones in this survey are categorized as having moderate impacts with potential adverse biotoxic effects.