Thick Metal Research Articles

Control of coherent phonon dynamics in CoFeB/heavy metal heterojunction structures for future hybrid phononic and spintronic devices

Abstract The heterojunction structure of CoFeB/heavy metal has shown significant potential for spintronics, where both electrons and magnons potentially can serve as information carriers. However, another promising information carrier, coherent phonons, has not been fully explored for hybrid phononic and spintronic devices. In this study, we used time-resolved pump-probe spectroscopy to investigate the dynamic behavior of coherent phonons. We observed variations in reflectivity spectra, corresponding to changes in phonon frequency and relaxation times, with different thicknesses of the heavy metal and CoFeB layers. The experimental results demonstrated a decrease in coherent phonon oscillation frequency as the thickness of the CoFeB and heavy metal layers increased. These findings were further supported by first-principles calculations, which showed that the frequency of the optical modes is suppressed due to interface relaxation between the magnetic and heavy metal layers.

Designing TiB2/Cr multilayer coatings on Ti6Al4V substrate for optimized wear resistance

The difference in mechanical properties between the TiB2 coating and the Ti6Al4V substrate can deteriorate the wear resistance of the TiB2 coating. To enhance the TiB2-based coating’s ability to deform in coordination with the ductile Ti6Al4V substrate and improve its tribological performance, the TiB2/Cr multilayer coatings were designed and deposited on Ti6Al4V substrates by magnetron sputtering. Results reveal that the FEM stress distribution of the TiB2/Cr multilayer coatings was optimized by varying the ceramic–metal thickness ratio (Q). As Q decreased from 1.0 to 0.5, the fracture toughness and adhesion strength of the coatings improved. The multilayer coating with Q = 0.5 exhibited the best toughness, crack propagation resistance (CPRs), and the smallest equivalent stress area, leading to a threefold enhancement in wear resistance compared to the TiB2 monolayer coating. However, further reduction of Q to 0.3 diminished wear resistance due to low hardness and significant stress concentration. Thus, there is an optimal balance between hardness, toughness, and stress distribution for achieving improved wear resistance in the multilayer design. Moreover, a notable correlation was observed between CPRs and the wear resistance of TiB2/Cr multilayer coatings.

Re-manufacturing of Pre-deformed Automotive Sheet Metal Stamping Scrap Without Melting

Abstract The recycling of aluminium sheet metal typically involves shredding and re-melting, processes which are both energy-intensive and challenged by the presence of metallic contaminants. To mitigate these issues, this study explores an alternative approach: the re-manufacturing of deep-drawn parts directly from scrap aluminium sheets, thus bypassing the melting step. We used 2 mm thick Al-Mg sheet metal in H111 temper to produce simulated stamping scrap (miniaturized bonnets). Blanks were cut from these bonnets and secondary parts in a cross-cup geometry were deep-drawn using two different forming processes: warm-forming at 200 °C and O-temper forming at room temperature. The resulting maximum draw depths were 20-22 mm for warm-forming and 25-30 mm for O-temper forming. While warm-forming resulted in lower draw depths, O-temper forming led to coarse recrystallized grain formation in some regions. Our approach could significantly reduce the energy consumption associated with aluminium recycling.

Enhanced Photocatalytic Paracetamol Degradation by NiCu-Modified TiO2 Nanotubes: Mechanistic Insights and Performance Evaluation.

Anodic TiO2 nanotube arrays decorated with Ni, Cu, and NiCu alloy thin films were investigated for the first time for the photocatalytic degradation of paracetamol in water solution under UV irradiation. Metallic co-catalysts were deposited on TiO2 nanotubes using magnetron sputtering. The influence of the metal layer composition and thickness on the photocatalytic activity was systematically studied. Photocatalytic experiments showed that only Cu-rich co-catalysts provide enhanced paracetamol degradation rates, whereas Ni-modified photocatalysts exhibit no improvement compared with unmodified TiO2. The best-performing material was obtained by sputtering a 20 nm thick film of 1:1 atomic ratio NiCu alloy: this material exhibits a reaction rate more than doubled compared with pristine TiO2, enabling the complete degradation of 10 mg L-1 of paracetamol in 8 h. The superior performance of NiCu-modified systems over pure Cu-based ones is ascribed to a Ni and Cu synergistic effect. Kinetic tests using selective holes and radical scavengers unveiled, unlike prior findings in the literature, that paracetamol undergoes direct oxidation at the photocatalyst surface via valence band holes. Finally, Chemical Oxygen Demand (COD) tests and High-Resolution Mass Spectrometry (HR-MS) analysis were conducted to assess the degree of mineralization and identify intermediates. In contrast with the existing literature, we demonstrated that the mechanistic pathway involves direct oxidation by valence band holes.

Study on the effects of electrode volume fraction and electrode particle radius on dynamic electrochemical-thermal-aging coupling characteristics of lithium cell based on cylindrical cell design method

Electrode volume fraction and electrode particle radius are important electrode parameters for the lithium cell design and deeply influence the electrochemical-physical processes inside lithium cell, which is still insufficiently clear. In order to obtain the effects of electrode parameters on lithium cell, a combine method of the dynamic electrochemical-thermal-aging coupling model and cylindrical cell design was proposed. Simulation was conducted at charge rate 1C. Cell temperature, current density and Solid-Electrolyte-Interface at ambient temperature 25 °C, and total strain energy density and lithium plating at ambient temperature −5 °C were analyzed. As electrode volume fraction or electrode particle radius increases, maximum temperature and maximum temperature difference of lithium cell increase. When electrode volume fraction increases from 0.3 to 0.7, maximum temperature of cell increases by 2.6 °C at least. Current density peak increases with the increase of the positive electrode volume fraction or electrode particle radius. When electrode volume fraction increases from 0.3 to 0.7, current density peak increases by 44 %∼74 %. As electrode volume fraction increases, total strain energy density Ws decreases in the early stage of charge, while increases in the late stage of charge. As the negative (or positive) electrode particle radius increases, Ws of the negative (or positive) electrode increase, while Ws of the positive (or negative) electrode decreases. Solid-Electrolyte-Interface thickness increases with the increase of the electrode volume fraction or electrode particle radius. The effect range of negative electrode volume on lithium plating is 0.5 ∼ 0.7. The lithium metal thickness increase with the increase of the positive electrode volume fraction. As the negative or positive electrode particle radius increases, the lithium metal thickness increase or decrease, respectively.

Brownfield Topsoil Vertical Heterogeneity: Implications for Germination and Soil Microbial Functioning.

Soil vertical heterogeneity refers to the variation in soil properties and composition with depth. In uncontaminated soils, properties including the organic matter content and nutrient concentrations typically change gradually with depth due to natural processes such as weathering, leaching, and organic matter decomposition. In contaminated soils, heavy metals and organic contaminants can migrate vertically through leaching or root uptake and translocation by plants and macrobiota, if present, leading to vertical heterogeneity in contaminant concentrations at different depths. Contaminants can alter soil properties, and we investigated the implications of soil vertical heterogeneity for germination and microbial functioning. We collected soil from an urban brownfield and created two conditions: structured soil samples collected with the soil core intact and mixed (unstructured) samples. When planted, the germination rate was significantly lower in the structured conditions (3.1 ± 1.7%) compared to mixed soils (17 ± 4.6%), suggesting that the vertical heterogeneity of contaminated soil influenced plant germination. To map the vertical distribution of contaminants and nutrient cycling rates in the structured soil samples, we collected 10 cm-deep soil cores from the barren site and a neighboring vegetated reference site and measured heavy metal concentrations, soil enzyme activities, and organic matter content in five 2 cm vertical layers. In the barren soil cores, metals were found concentrated in the top 2 cm layer, while in the vegetated soil cores, metals were uniformly distributed. No significant differences were observed for the organic matter content or moisture along depth. Published studies on vertical distribution of enzyme activities and metal concentrations have treated the top 10-20 cm as a single layer and thus would have not revealed the thin (<2 cm thick) metal cap on the surface of the barren soil core. Despite the metal cap, enzyme activities in the top layer were similar to those in the lower layers of the barren soil core, suggesting that high metal concentrations do not limit soil enzyme activity under all circumstances. Investigating vertical heterogeneity in postindustrial soils can inform efforts to convert industrial barrens to vegetated environments.

Simulation of quantum states in solid-state ferromagnetic nanostructures

Purpose of the article. Identification and analysis of mathematical expressions for the energy spectrum of charge carriers in nano-sized magnetic films of nickel and Ni-Cu (substrate), as well as NiO-Ni-Cu (substrate) structures.Methods. In this work, based on basic quantum mechanical concepts and taking into account the boundary conditions for coupled quantum wells, expressions for the energy spectrum of electrons are obtained. The ferrimagnetic properties of nickel are taken into account through the effective mass value. The solution of nonlinear equations that determine discrete energy levels was achieved by numerical methods using the Mathcad mathematical package.Results. Transcendental expressions for the energies of free charge carriers in quantum wells of ferromagnetic nickel films are obtained, and the influence of the position of nickel on the copper substrate is shown. It has been shown that the use of a copper substrate leads to an increase in the density of energy levels in the nickel nanofilm. The influence of the oxide layer on single-electron states in nanofilms of nickel and its oxide is considered within the framework of the Anderson model. Based on the numerical solution of the transcendental equations obtained in the work, the influence of the ratio of the thicknesses of a ferromagnetic metal and its oxide on the energy levels of electrons localized in the oxide layer is shown.Conclusions. The formulas presented in the work for the energy spectrum take into account the energy relief of a complex quantum well, the dimensions of the film, surface oxide, and the significant effective mass in the region of the ferromagnetic film. It has been shown that an increase in the effective mass in magnetic heterostructures leads to an increase in the electron density of states. It was found that the density of electronic states in the region of surface nickel oxide is practically independent of the thickness of the nickel film. The results and conclusions of the work can be used for theoretical prediction of the physical properties of magnetic nanostructures, in particular spintronic elements.

Dispersion-free characterization of terahertz slab–waveguide modal confinement based on a metal Bragg grating structure

Photonic waveguide structures that use periodic metal grooves and periodically perforated metal slits (PPMSs) can laterally confine Sommerfeld and Zenneck surface waves of metals with the electric field accumulation among metal interspaces in the terahertz (THz) region, instead of the total internal reflection principle of dielectric slab media. For the efficiency enhancements of THz-wave coupling and slab–waveguide confinement, specific integrators with high refractive indices or specified for input angles of transverse magnetic polarized waves, such as prisms, metal blades, and waveguides, are requested to excite spoof surface plasmons in the THz region. However, the integrator-assembled slab–waveguides encounter challenges of THz pulse-wave communication in compact and low-distortion systems. A resonant waveguide grating structure based on PPMSs is experimentally demonstrated to confine THz lateral waves from the plane-wave radiation in free space. The open frame and periodic metal cavities of PPMSs can work as a slab–waveguide to transmit structural confined waveguide modes with forwarding evanescent waves of Fabry–Pérot resonance. For 0.1–1 THz waves, the short wavelengths that are both less than half the metal slit width and 3.75 times the metal thickness can lead to zero dispersion and the highest confinement factor in a slab–waveguide for PPMS-confined THz waves. This behavior is opposite to the high structural dispersion in confined THz waves of surface plasmonic devices.

New Method to Recover Activation Energy: Application to Copper Oxidation

The calculation of the activation energy helps to understand and to identify the underlying phenomenon of oxidation. We propose a new method without any a priori hypothesis on the oxidation law, to retrieve the activation energy of partially and totally oxidized samples subject to successive annealing. The method handles the uncertainties on the measurement of metal and oxide thicknesses, at the beginning and at the end of the annealing process. The possible change in oxidation law during annealing is included in the model. By using an adapted Particle Swarm Optimization method to solve the inverse problem, we also calculate the time of final oxidation during the last annealing. We apply the method to successive annealings of three samples with initial nanometric layers of copper, at ambient pressure, in the open air. One, two and three successive laws are recovered from experimental data. We found activation energy values about 105–108 kJ mol−1 at the beginning of the oxidation, 76–87 kJ mol−1 at the second step, and finally 47–59 kJ mol−1 in a third step. We also show that the time evolution of copper and oxide thicknesses can also be retrieved with their uncertainties.

Enhanced adhesion and corrosion resistance through the modulation of a metallic Ti underlayer thickness

In this investigation, TiCN/TiN thin solid film was selected as a protective coating and deposited onto AZ31 alloy through reactive magnetron sputtering. To mitigate the potential failure resulting from the significant physical disparity between the ceramic film and the metal substrate, a Ti thin film was employed as a base layer. Following the deposition process, an analysis was conducted on the structural features, residual stress, fracture morphology, adhesion strength, and corrosion characteristics of the film/substrate system utilizing X-ray diffraction, scanning electron microscopy, scratch testing, and electrochemical workstation. The findings indicate that the incorporation of a Ti metallic underlayer significantly improves the adhesion and corrosion resistance of the TiCN film. However, when the thickness of the Ti layer surpasses 0.37 μm (deposition of 15 min), it leads to the formation of a distinct columnar crystal microstructure, increased residual stress, and diminished adhesion and corrosion resistance. Additionally, this study delves into the corrosion failure mechanisms in a chloride environment and explains the principles of residual stress measurement through XRD.

Surface plasmon polariton excitation and propagation in metal tripod systems

Through the activation of a planar gaseous medium consisting of four-level tripod atoms, our approach provides a mechanism to generate the Surface Plasmon Polariton (SPP). We investigate a three-layer structure in which the bottom layer is composed of atoms arranged in a tripod configuration, a metal film is layered in the middle, and a transparent layer of either air or vacuum resides on top. The bottom layer facilitates SPP excitation via amplification in the atom arrangement, caused by three laser beams: control, weak probe, and signal. The electromagnetically induced transparency effect, which can be seen in atoms, compensates for the momentum difference between light and SPP. We can coherently change SPP propagation length by altering control field strength, resonance, and off-resonant detuning. SPP optical gain power, propagation length, penetration depth, and metal thickness effects are also examined. Our method to generate SPPs may find use in lithography, sensors, polarizers, along with photodetectors.

Room temperature self-healing and high gas barrier properties of elastomer composites incorporated with liquid metal

Flexible electronic devices require stretchable packaging materials that provide a hermetic seal. However, conventional soft materials often exhibit strong gas permeability, making it difficult to achieve stable operation, which requires films with high deformability, self-healing capability, and gas barrier functionality. In this study, a layer by layer (LBL) method was employed to uniformly coat a controllable thickness of liquid metal (LM) onto a designed and synthesized self-healing thermoplastic polyurethane (TPU) film, successfully developing a stretchable gas barrier film (TPU/LM) with high gas barrier properties. The designed polyurethane film significantly enhanced the adhesion of the liquid metal, effectively preventing leakage. The experimental results show that the water vapor transmission rate (WVTR) of the TPU/LM composite film with a thickness of 40 μm is 4.04g/(m2·day). Compared to the film without LM, the gas barrier performance has been improved by approximately 16 times. Additionally, there is a significant enhancement in nitrogen (N2) barrier, with a permeation rate reaching 4.0*10−17 cm3 cm/(cm2·s·Pa), effectively blocking the N2 permeation. This demonstrates the universality of the TPU/LM in gas barrier applications. Furthermore, the TPU/LM film also demonstrated excellent electromagnetic shielding effectiveness. The self-healing capability of the stretchable gas barrier film allows it to recover its initial gas barrier performance after mechanical damage. Humidity-sensitive resistors encapsulated with TPU/LM exhibited stable operation in both air and 90 % humidity environments, confirming the superior barrier properties of the TPU/LM. Generally, the developed TPU/LM is suitable for packaging applications in the next generation of flexible electronic devices.

3D oscillation-assisted laser beam cutting with time-synchronized process monitoring

A current subject of research is to optimize the laser cutting process in terms of process efficiency and cut edge quality, especially in thick sheet metal cutting. One approach is to influence the energy distribution in the cut kerf using various beam shaping options, including dynamic beam oscillation. The challenge lies in the fact that the oscillation parameters of beam shaping, which are added to the conventional laser cutting process, create an infinite number of new parameter combinations. For the first time, a complete system has been set up at the IWS in cooperation with the CMA with the aid of the process monitoring options. This system is intended to help provide deeper insights into the processes taking place in the cutting zone and thus contribute to an expanded understanding of the process. First experiments were carried out to investigate the influence of the 3D beam oscillations on the cut quality and cutting speed.

Comparison and optimization of electrochemical and thermal performances of SOFC with different configurations of a metal foam flow field

The effects of different configurations of a metal foam flow field on current density and temperature gradient of a single channel solid oxide fuel cell (SOFC) are investigated, and the overall performance of the optimum configuration is optimized. First, model A (conventional channel-rib flow field) is compared with three different configurations (i.e., model B with metal foam flow field only at anode, model C with that only at cathode, and model D at both). Although model C achieves the highest current density, its temperature is also fairly high. Although model B achieves the lowest temperature gradient, its current density is also fairly low. Model D performs well in both current density and temperature gradient. Then, the effect of electrode thickness and metal foam thickness on the performance of model D is investigated. The Ohmic polarization of model D remains almost constant with different electrode thicknesses, and its concentration polarization decreases as the electrode thickness decreases, which is totally different from the channel-rib flow field. Moreover, a thinner cathode causes lower activation overpotential, whereas a thinner anode causes higher activation overpotential. In general, a thick anode, a thin cathode, and thin metal foam can maximize the current density of model D, while a thick electrode and metal foam can always reduce the temperature gradient. Finally, the Taguchi method and gray relational analysis are used to optimize the current density and temperature gradient of model D. The current density of an optimized model is 3.27% higher than that of the original model with a temperature gradient of 9.05 K/cm.

Design of metal foam baffle to enhance the thermal-hydraulic performance of shell and tube heat exchanger

Solid baffles are widely used in shell and tube heat exchanger (STHX), while the highly increased flow resistance and dead zones remain serious drawbacks in the applications. To address this issue, metal foam baffle is proposed in this study to replace solid baffle. The numerical model with considering the thermal non-equilibrium between fluid and foam baffles was established. Laminar flow is assumed in the foam baffles region and the realizable k-ε turbulence model is assumed in the open region. Effects of porosity, pore density, thickness and number of foam baffle (N) on the performance were examined. Results show the foam baffles always lead to lower pressure drop of STHX compared to the solid baffles. Compared to five 2 mm thick solid baffles, five 6 mm thick metal baffles with the porosity of 0.80, 0.85 and 0.90 results higher outlet temperature at the pore density greater than 80, 120 and 160 PPI, respectively. The metal foam baffle leads to higher outlet water temperature compared with solid baffles at the baffle number N ≤ 7. The foam baffles with optimum pore parameters reduced the pressure drop by 12.9 % and increase the outlet and inlet temperature difference by 31.0 % compared to the solid baffles.

Exploring joining techniques for diamond chips on metallized substrates: Micro- and nano-scale mechanical testing approach

This paper aims to comprehensively evaluate the shear strength of various junctions between diamond chips and double copper bonded ceramic substrates. The study involves several stages, beginning with the deposition of Ti/Ni/Ag metallization system on diamond chips using a chemical vapor deposition (CVD) process. These metallization systems are selected to determine their suitability as ohmic contacts on diamond. In parallel, Ni/Au and Ni/Ag layers are electroplated onto the thick copper metallization of the ceramic substrate. Following these depositions, junctions are created for both Cu/Cu and C/Cu assemblies using different techniques: reflow process for AuGe solder joints, reflow-diffusion process for Ag-In joints, and a thermomechanical process for Ag nanoparticle joints. To assess the effectiveness of these techniques, the shear strength of the junctions is measured using a micro-shear test, which is analogous to a classical micro-scratching test. Additionally, the mechanical behaviors of the layers adjacent to the assemblies are analyzed through nano-indentation tests. Finally, the fracture surfaces are examined using scanning electron microscopy (SEM) and energy-dispersive X-ray (EDX) spectrometry to identify the microstructure and damage modes. The work described in the paper exhibits several innovative aspects. It introduces the novel combination of Ti/Ni/Ag metallization system on diamond chips, evaluated for its suitability as ohmic contacts, potentially leading to improved electrical and thermal performance in diamond substrate applications. The study employs diverse junction creation techniques, such as reflow for AuGe solder joints, reflow-diffusion for Ag-In joints, and a thermomechanical process for Ag nanoparticle joints, allowing for a thorough comparison and identification of the most effective method for different scenarios. We have also introduced an integrated testing methodology, which combines micro-shear tests and nano-indentation tests and provides a robust framework for assessing both the shear strength and mechanical properties of the junctions and adjacent layers, enhancing the reliability and depth of the evaluation. The specific focus on metallization system and junctions suitable for diamond, known for its exceptional thermal and electrical properties, positions this work as highly relevant for advanced electronic and thermal management applications.

Lift-Off Process for Patterning of a Sputter-Deposited Thick Metal Stack for High Temperature Applications on 4H-SiC

With the rising need for power devices suitable for harsh environment conditions like high temperature applications, contact materials and packaging of the devices have become critical factors in device fabrication [1, 2]. Therefore, a contact metal stack containing silver and titanium nitride which can be used at elevated temperatures under oxygen atmosphere was investigated. For patterning of the approx. 2 µm thick sputter-deposited metal stack on the wafer front side, a lift-off process using a negative photoresist was established. Characterization of the photoresist sidewall shape was performed by cross-sectional views prepared with SEM and top view images taken on a microscope. It was found that for a successful lift-off, a distinct undercut is needed so no metal is deposited at the downside of the undercut, ensuring a metal-free surface for the solvent to reach the photoresist. To obtain this, most influencing factors are exposure dose and development time, which were optimized considering the undercut shape as well as pattern fidelity. Lift-off with acetone proved to be good for the fabricated 4H-SiC MOSFET devices.

Analysis of current and heat transfer in locations with reduced critical current in coated conductor tape

Abstract Variation of the critical current along the conductor length is a feature commonly encountered in industrially produced REBCO tapes called coated conductors (CCs). A reduction of the critical current exceeding several percent in portions a few millimetres long can be observed in the data obtained by reel-to-reel characterization provided by manufacturers. Metallic layers in the CC architecture can take over some current in such a ‘weak spot’, and help to keep the local temperature stable, preventing its thermal runaway and conversion to a ‘hot spot’. Understanding this phenomenon is particularly crucial when space and weight limitations do not allow for the addition of a metallic layer with a thickness that would be sufficient to match the lost transport capability of superconductors. For this purpose, we studied a set of samples, representing both standard as well as infrequent profiles of weak spots identified in direct transport experiments. Analytical theory is then utilized as a basic tool for recovering the properties serving as input for numerical modelling. Temperature profiles and current redistribution at weak-spot locations were found, and the effect of cooling conditions and metallic layer thickness on the weak-spot resistance against thermal runaway was analyzed. Quantitative assessment of the possibility to improve the performance of CC tape by adding a Cu stabilizing layer or improving cooling settings could help to optimize the architecture of CCs intended for use in electrical transport.

Temperature Jump Methods for Measuring the Pme of RuO2

The potential of maximum entropy (PME) is used to understand the structure and charging of the electrochemical double layer. Closely related to the potential of zero charge (PZC), the PME occurs when disorder of the solvent molecules at the surface reaches a maximum. Using a laser induced temperature jump (LITJ) to measure the PME has been shown to be a convenient method for metal electrodes. We present experiments using LITJ to investigate a metal oxide thin film and film thickness. The PME of these thin films appears to change with thickness, correlating with surface strain where a thinner film shifts the PME closer to OER potentials in turn reducing the overpotentials required. Our experiments are shown to be reproducible and independent of sweep rate or the vertex potentials selected. Interestingly we observe a hysteresis with scan direction, of 100-250 mV which we nominally attribute to surface adsorbates. Our results highlight the link between excess surface charge and catalytic activity and how this may be tuned via surface strain. Figure 1

Kretschmann configuration as a method to enhance optical absorption in two-dimensional graphene-like semiconductors

Objectives. The optical properties of two-dimensional semiconductor materials, specifically monolayered transition metal dichalcogenides, present new horizons in the field of nano- and optoelectronics. However, their practical application is hindered by the issue of low light absorption. When working with such thin structures, it is essential to consider numerous complex factors, such as resonance and plasmonic effects which can influence absorption efficiency. The aim of this study is the optimization of light absorption in a two-dimensional semiconductor in the Kretschmann configuration for future use in optoelectronic devices, considering the aforementioned phenomena. Methods. A numerical modeling method was applied using the finite element method for solving Maxwell’s equations. A parametric analysis was conducted focusing on three parameters: angle of light incidence, metallic layer thickness, and semiconductor layer thickness.Results. Parameters were identified at which the maximum area of absorption peak was observed, including the metallic layer thickness and angle of light incidence. Based on the resulting graphs, optimal parameters were determined, in order to achieve the highest absorption percentages in the two-dimensional semiconductor film.Conclusions. Based on numerical studies, it can be asserted that the optimal parameters for maximum absorption in the monolayer film are: Ag thickness &lt;20 nm and angle of light incidence between 55° and 85°. The maximum absorption in the two-dimensional film was found only to account for a portion of the total absorption of the entire structure. Thus, a customized approach to parameter selection is necessary, in order to achieve maximum efficiency in certain optoelectronic applications.