Metal Concentrations In Samples Research Articles

Evaluation of Heavy Metal Presence in Agricultural Samples of Lactuca sativa and Trifolium alexandrinum Using Picosecond Laser-Induced Breakdown Spectroscopy and Flame Atomic Absorption Spectroscopy in Banha and Giza Governorates, Egypt

This pioneering study utilizes Flame Atomic Absorption Spectroscopy (FAAS) and Picosecond Laser-Induced Breakdown Spectroscopy (Ps-LIBS) to quantify heavy metal contents in samples of Lactuca sativa L. and Trifolium alexandrinum L. collected from Banha and Giza, Egypt for the first time. In order to enhance the performance of Ps-LIBS, laser parameters were carefully optimized. Expressly, laser energy was set to 100 ± 5% J/cm², pulse duration was calibrated to 170 picoseconds, and 1064 nm Nd: YAG pulses were employed. This optimization facilitated the creation of linear LIBS calibration curves, a crucial element in ensuring precise elemental quantification and bolstering the overall analytical reliability. The assessment of pollution indices revealed concerningly high levels of copper, nickel, and cadmium consistently across all study sites. Lactuca sativa L. and Trifolium alexandrinum L. also demonstrated multiple metals’ bioaccumulation factors (>1), further underscoring the potential health risks associated with copper, nickel, and cadmium contents. Given these findings, it is imperative to recommend constructing a dedicated wastewater treatment facility to address Al Mansouria village’s environmental challenges in the Giza governorate.

Determination of metal contents in some green leafy vegetables in Marmara region of Turkey

This study focused on the analysis of mineral and heavy metal contents of spinach, lettuce and parsley samples in different regions to investigate the risks of chronic exposure to heavy metal contamination. After the microwave digestion process, the metal contents of the samples (Na, Mg, Al, P, K, Ca, Fe, Cu, Zn, As, Se, Cd, Sn, Hg, Pb) were determined with the ICP-MS. Two parallel analysis samples were prepared from each sample, analyzed three times, and the mean values of the analyzes performed were reported. From the analysis, the order of finding heavy metals in the samples is Cu > Pb > Cd > As > Sn > Hg. The results were evaluated statistically and Cu, Pb, Cd, As and Sn values were found high in spinach samples (p < 0.05). According to the results of the analysis; the samples with the highest content of Cu, Pb and Cd in spinach samples are samples taken from Tekirdağ (5.1 ± 0.3 mg/kg), Edirne (0.106 ± 0.007 mg/kg) and Tekirdağ (0.080 ± 0.004 mg/kg), respectively. One of the important reasons for this is the increase in industrial areas in those regions. The results were compared with the certified reference materials, the quantities of analytes were determined to be compatible with the certificate values and the results of the analysis were proved to be correct.

Pressure leaching behaviors of copper-cobalt sulfide concentrate from Congo

Pressure leaching is a promising technology to process the copper-cobalt sulfide. In this work, the behaviors of copper-cobalt sulfide flotation concentrates received from Congo during pressure leaching were investigated for varying temperatures, acidity, leaching time, solid to liquid ratio, and oxygen partial pressure. A one factor at a time method was implemented to obtain the optimal operating condition, XRD, EDS, ICP-OES methods were used to examine the chemical composition, state as well as metal content of samples. It is found that the recovery percentage for copper and cobalt can reach 99 % and 98 % under temperature 190 °C, oxygen partial pressure 6 atm, leaching time 2 h, liquid to solid ratio 5:1, initial acidity 0 g/L. The kinetics study shows that the chemical reaction is the control step during pressure leaching of copper and cobalt. The coating of hematite on the mineral surface is the main reason for the incomplete leaching of copper and cobalt.

Synthesis of magnetically solid base catalyst of NaOH/Chitosan-Fe3O4 for biodiesel production from waste cooking oil: Optimization, kinetics and thermodynamic studies

In this research, biodiesel was produced from waste cooking oil (WCO) via a magnetically and biodegradable heterogeneous base catalyst of NaOH/Chitosan-Fe3O4. The catalyst was characterized using X-ray powder diffraction (XRD), Field Emission Scanning Electron Microscopy (FESEM), Energy Dispersive X-Ray (EDX), EDX-mapping, Vibrating-Sample Magnetometer (VSM), Brunauer-Emmett-Teller (BET), Transmission Electron Microscopy (TEM), and Fourier-transform infrared spectroscopy (FTIR) analyses. The catalyst performance was also studied in the transesterification reaction of WCO conversion to biodiesel. The process was optimized via the central composite design (CCD) through the response surface methodology (RSM) method. The influences of major factors, including methanol to oil molar ratio (6:1–12:1), catalyst weight (0.25–1 wt%), and time (4–8 h), were examined on the reaction behavior. The maximum FAME yield was 92% under the following optimal conditions: 0.5 wt% NaOH/Chitosan-Fe3O4 catalyst, methanol to oil ratio of 6:1, reaction time of 4.5 h, and temperature of 25 °C. The Gas Chromatography–Mass Spectrometry (GC–MS) and Inductively Coupled Plasma- Optical Emission Spectroscopy (ICP-OES) were used to determine the fatty acid profile and metal contents of samples, respectively. Based on the physicochemical properties, it was concluded that the produced biodiesel had the same properties as conventional petro-diesel. Further, a kinetic study revealed that the electrolysis method was a situ-transesterification reaction with a pseudo-first-order kinetics and activation energy of 21 kJ/mol. From the thermodynamic calculations, the values of ΔS, ΔΗ, and ΔG were found to be −0.23 kJ/mol K, 18.20 kJ/mol, and 95.13 kJ/mol, respectively.

Analysis of adsorption of heavy metals from water solutions by wood of selected domestic species using X-Ray Fluorescence (XRF)

Analysis of adsorption of heavy metals from water solutions by wood of selected domestic species using X-Ray Fluorescence (XRF).The aim of this study was to analyze the absorption of three specific heavy metals from model water solution by wood species from domestic Polish forests. This paper focuses on XRF method to determine metal content in samples. European aspen (Populus tremula L.) and Black locust (Robinia pseudoacacia L.) have been chosen. Firstly, shavings were prepared and soaked with standard solutions of lead (II) nitrate, cadmium nitrate and mercury (II) chloride for 7 days. Then, the material was dried and reduced to ashes using muffle furnace. Finally, content of absorbed metal was marked (XRF) and analyzed with a view to initial contents of metal ions in standard solutions. It was established, that the higher the concentration of mercury in standard solution is, the higher impulse counts is obtained for European aspen. This reversal of the dependence is noticeable for second analyzed species.

Impact Assessment of Farm Tractor Engine Fuel Injector Damage on Engine Oil Properties

Abstract It is justified that the problems related to changes in physico-chemical properties, concentration of trace elements in lubricat-ing oil and the impact of these changes and their dynamics on vehicle structural elements should be considered in detail. It is important that empirical data, theoretical relationships and test results should be taken into account. The paper presents re-search results of the selected physico-chemical parameters and the content of metals in samples of the used engine oil. The samples were collected both after the fuel system failure and during the operation of the farm tractor according to the date of changing engine oil assumed by the producer. An instrumental chemical analysis method HDXRF was used to determine chang-es of the content of trace elements Fe, Sn, Cu, Pb, P, Zn, Ca in engine oil. Additionally, changes in physico-chemical properties were determined with the use of FT-IR spectrometry. Courses of these changes were analysed on account of their impact on the utility properties of the engine oil.

DIFFERENCES IN FYTOCHEMICALS CONTENT IN COLOURED CULTIVARS OF COMMON BEAN (PHASEOLUS VULGARIS L.)

Nowadays, legume production is increasing as the world population but its consumption is declining due to dietary habit changes. Industry is finding new uses of legumes and creating new foods with a positive effect on health and well-being of humans. Key components in legume (like protein, soluble and insoluble fibre, resistant starch, and bioactive polyphenols) make beans suitable for a wide range of food product applications. The main phenolic compounds present in legume flours are flavonoids. The study is focused on determination of bioactive compounds content in seeds of four varieties of common bean. The samples of plant material were collected from the area of Piesťany (Slovakia). The samples of common bean seeds were homogenized and a methanolic extract was prepared. These extracts were used for analyses. The total content of polyphenols was determined spectrophotometrically and the content of individual phenolic by using the RP-HPLC/DAD method. The content of risky metals in samples was determined using the AAS method. TPC in studied varieties of common bean were determined in the range from 2156.87 mg.kg-1 (NEGRA) to 1362.70 mg. kg-1 (ZENIT). Highest concentration of phenolic acids was determined in ellagic acid, where the average value was 0.21845 mg.kg-1 DM (dry matter) and the lowest in trans- caffeic acid, with the average value 0.02380 mg.kg-1 DM. Highest concentration of flavonoids was determined in vitexin, where the average value was 0.02480 mg.kg-1 DM and the lowest in kaempferol, with the average value 0.00545 mg.kg-1 DM. Highest macro elements amount was determined in white beans. For potassium it was 12277 mg.kg-1 (ZENIT) and the lowest was in manganese, and it was 10.70 mg.kg-1 (RUBIN) in red beans. From the analyzed varieties we have found that they are important source of polyphenol substances with a demonstrable bioactive effect.

Basement faults deduction at a dumpsite using advanced analysis of gravity and magnetic anomalies

ABSTRACTA study of the fracture systems in the basement of the Matatlan urban waste dump of Guadalajara City, near the western edge of the Rio Grande de Santiago canyon (southwestern Mexico), is reported. The Matatlan dumpsite was developed on top of andesitic and rhyolitic rocks. Measurements at outcrops indicated that N–S (0°–15° and 165°–180°), N45–90E and N105–135E fracture systems affect the basement. Statistical analysis (micromagnetic method) of magnetic lineament azimuths indicated the presence of two lineament groups. The major one (N60–120E) has a maximum at N90–105E, and a secondary group (N120–165E). The gravity anomalies are featured by a major group (N60–120E, with maximums at N60–75E, and N105–120E) and a secondary group (N120–180E). Thus, a good to fair correlation exists between the measured fracture orientations and the lineaments featuring the gravity and magnetic anomalies. Horizontal derivative and tilt angle depicted horizontal limits of anomaly‐causative bodies. Results of the micromagnetic method are consistent with fracture orientations and with the limits established through edge‐detection techniques. Lineaments established by means of the gravity and magnetic Euler deconvolution are also consistent. Gravity and magnetic Euler deconvolution helped to estimate the depth extent of the limits of gravity and magnetic common sources. Euler deconvolution indicated the fault or contact nature of these lineaments. Furthermore, Euler deconvolution indicated slopes of the limits of gravity and magnetic sources. The fault or fracture nature of the major lineaments was finally confirmed by forward modelling (forward 2D cooperative modelling of gravity and magnetic profiles). For example, lineaments delimiting the northern depression could be characterized as normal faults. In general, this study indicates that it is possible, based on gravity and magnetic data, to characterize fractures affecting the basement of a dumpsite, a key parameter in hydrogeophysical studies. In particular, through this study, the inferred structures could be associated with regional tectonic faulting, which might provide migration paths to unhealthy lixiviate outside the dumpsite, giving rise to the contamination of the neighbouring environment. In particular, the study explains the presence of an unhealthy leachate waterfall to the northeast of the dumping site. Heavy metal contents in samples from this waterfall support that lixiviates originate at the dumpsite.

Transformation of metals migration and biogeochemical cycling under the influence of copper mining production (the Southern Urals)

This study aims to estimate the migration and accumulation of metals (Cu, Zn, Fe, Mn, Ni, Pb, Cd, Co, Cr, Zr, Ba, and Sc) in terrestrial and aquatic landscapes. The research is based on the results of a long-term study (1998–2018) in one of the copper mining centers in Russia in the vicinity of Sibay City in the Southern Urals. The metal contents in samples of water, bottom sediments, soils, plant shoots (total aboveground phytomass samples, agrobotanical group samples, and shoots of indicator terrestrial and aquatic species), and fish muscles are measured. It is found that within natural geochemical anomalies, the migration ability of chemical elements in the soil–plant system and general biogeochemical cycle is low because of the high soil buffer capacity (determined by the high humus content, high percentage of fine fractions in granulometric composition, and neutral pH) and the adaptation of local plants to ore mineralization. The ecosystems affected by low pollution maintain natural homeostasis, stabilize the flow of chemical elements, and preserve the natural features of geographic components. Metal pollution and the replacement of natural steppe vegetation with secondary herbaceous-ruderal communities in critical areas near copper–zinc mining objects can stimulate the mobilization and inclusion of chemical elements in biogeochemical cycling, as well as the disruption of bonds among landscape components. The water systems in catenae function as stabilizers through a system of geochemical barriers and low uptake of metals by hydrophytes, such as the common reed (Phragmites australis).

Sadržaj bakra i pratećih elemenata u višeslojnom blatnjavom zemljištu iz Bučimskog jezera ispod jalovišta rudnika "Bučim", Republika Severna Makedonija

The intense mineral extraction in mining areas during the last several decades has produced a large amount of waste material and tailings, which release toxic elements to the environment. The aim of the study was to determine in two vertical profiles/sections (1 and 2) the heavy metal contents of samples derived from six samples, three from each section located in the porphyry copper mine Buchim area, Republic North Macedonia. The results have been compared to new Dutchlist (DL) and Kabata-Pendias (KP) standards and the following was concluded: As values ranged 14.985÷60.131 mg kg-1 with 4 samples above the target value of the DL (29 mg kg-1 As) and 6 above standard values given in KP value (5 mg kg-1 As), in that context Co values ranged 11 ÷57 mg kg-1 with 6 values above the target value of the DL (9 mg kg-1 Co) and 5 above standard values given in KP value (12 mg kg-1 Co), Cr with range 29.32÷75.76 mg kg-1 with 6 over KP value (10 mg kg-1 Cr) and none above the target value of the DL (100 mg kg-1 Cr), Cu with range 2694÷6749 mg kg-1 with 6 samples above the target value of the DL (36 mg kg-1 Cu) and 6 above standard values given in KP value (20 mg kg-1 Cu), Ni with range 59.57÷105.98 mg kg-1 with 6 samples above the target value of the DL (35 mg kg-1 Ni) and 6 above standard values given in KP value (20 mg kg-1 Ni), Pb with range 27.06 ÷96.08 mg kg-1 with 1 sample above the target value of the DL (85 mg kg-1Pb) and 6 above standard values given in KP value (25 mg kg-1Pb), Zn with range 147÷273 mg kg-1 with 6 over target value of the DL (140 mg kg-1 Zn) and 6 above standard KP value (64 mg kg-1 Zn), V with range 34.44÷92.57 mg kg-1 with 5 over target value of the DL (42 mg kg-1 V) and one above KP value (90 mg kg-1 V).In order to compare the level of contamination, the contamination factor (𝐶𝑓 𝑖 ), degree of contamination (Cd), and pollution load index (PLI) were computed. Serious numbers were found for Cu, as, Zn, Co and Ni, which exceeded standard values at almost all samples from both vertical sections. Compared from section 1 and section 2, pollution load index increased by 13.43%, which in almost all samples was classified as heavily polluted to extremely polluted. The fact that mining activities at the Buchim Mine last for almost 40 years, the presence of heavy metals in soils at a serious level is understandable. The high level of contamination is a result of heavy metal persistence and non-biodegradability.

Heavy Metal Pollution Monitoring in Vulnerable Ecosystems: A Case Study of the Lagos Lagoon, Nigeria.

This comparative analysis was carried out to monitor heavy metal concentrations in the Lagos Lagoon over the last 2 decades. Surface water and sediment samples were collected from stations on the Lagos Lagoon based on their suitability for comparative analysis and future monitoring. Heavy metal content in samples was determined using Flame atomic absorption spectrophotometry (FAAS). The concentrations in the samples were compared to those obtained by Don-Pedro et al. (West African Journal of Applied Ecology 5:103-114, 2004) in previous studies from the same sampling zones. Results show that concentration of most heavy metals analysed has reduced significantly (p < 0.05) in the past 2 decades. However, the concentration of Cadmium (Cd) was found to have increased significantly (p < 0.05) over the same period. Increased concentration of Cadmium poses a threat to ecosystem health thus, it is imperative that safe limits for heavy metal discharge in waste streams should be revised and implemented.

Bioaccumulation of Heavy Metals in Hydromacrophytes from Five Coastal Lakes (North-Western Poland, Baltic Sea)

The study concerned Polish coastal lakes separated from the Baltic Sea by a sandbar. The study was designed to determine whether the aquatic plants in the coastal lakes in Poland accumulate Cu, Ni, Cd. The material consisted of water and aquatic plant samples collected in the years 2012 and 2013 in lakes Resko Przymorskie, Jamno, Bukowo, Kopań and Wicko. The metal with the lowest content (mg.kg−1) in the plants was Cd, and the concentrations can be arranged as follows: Cd &lt; Ni &lt; Cu (mean 0.46 &lt; 1.91 &lt; 5.56) in 2012 and (mean 1.04 &lt; 1.86 &lt; 4.68) in 2013. For water, the order of concentrations (mg.l−1) of metals was follows: Cd &lt; Ni &lt; Cu (mean 0.0010 &lt; 0.0033 &lt; 0.0035) in 2012 and Cd &lt; Cu &lt; Ni (mean 0.0036 &lt; 0.0107 &lt; 0.0115) in 2013. The metal bioaccumulation in hydro‑macrophytes expressed by means of a bioaccumulation factor (BCF) was as follows: Cd &lt; Ni &lt; Cu (mean 474 &lt; 1447 &lt; 1519) in 2012 and Ni &lt; Cd &lt; Cu (mean 201 &lt; 369 &lt; 542) in 2013. The metal concentrations in samples were found comparable with those in moderately polluted surface waters. Statistically significant regression was only found between Cd concentration in water and in plants (R = 0.3484). Conductivity does not affect metals content in samples. Statistically significant differences were noted between water reaction and the content of all metals in water, and Cd content in case of the plants.

Assessment of heavy metal pollution in abandoned Giap Lai pyrite mine (Phu Tho Province)

Giap Lai pyrite mine had been exploited in the period 1975 - 1999, and abandoned after the mine became closed. This work is conducted with the aim to evaluate the impacts of the abandoned mine to the environment. 23 surface water, 15 ground water and 20 soil samples from the mining area were collected for experiments. Acid production potential and metal leaching of waste materials from tailings were tested. Results show that acid rock drainage (ARD) in the old mining area still occurs, with sulfide-rich tailings and waste rocks being sources of ARD, causing elevated metal concentrations in downstream water bodies. Surface water shows significant pollution of Fe, Mn, Ni and partially As. In the rainy season, the percentage of surface water samples having low pH values as well as metal contents in samples is higher than in the dry season. Metal concentrations in ground water are generally low, but many samples have low pH values, indicating the influence of the ARD. The geo-accumulation index reveals that soil from mining area is moderately contaminated with Ni, Cu, Hg and partially As. Most of the polluted samples are located near old mining pits, waste dumps and tailing ponds. The study also shows that negative effect of Giap Lai pyrite mine on the surrounding water and soil has been ongoing. However, no post-closure remediation measures have been applied at the mine, so there must be appropriate solutions for the acid mine drainage treatment before its being discharged to the environment. Given the facts revealed by this study, it is recommended that the Environmental Protection Law should be fully implemented at mining sites not only during the exploitation but also after their closures.References AMIRA, 2002. ARD Test Handbook. Project P387A Prediction &amp; Kinetic Control of Acid Mine Drainage. AMIRA international May 2002, 42p. Çevik, F., Göksu, M. Z. L., Derici, O. B., Fındık, Ö., 2009. An assessment of metal pollution in surface sediments of Seyhan dam by using enrichment factor, geoaccumulation index and statistical analyses. Environmental Monitoring and Assessment 152, 309-317. EPA, 2000. Abandoned mine site characterization and cleanup hand book, 129p, (https://yosemite.epa.gov/r10/amscch.pdf). Ghrefat, H.A., Abu-Rukah, Y., Rosen, M.A., 2011. Application of geoaccumulation index and enrichment factor for assessing metal contamination in the sediments of Kafrain Dam, Jordan. Environmental Monitoring and Assessment 178, 95-109. IAEA, 2000. Reference Sheet, reference material. Trace elements in soil. (https://nucleus.iaea.org/rpst/Documents/rs_iaea-soil-7.pdf). INAP, 2009. Global Acid Rock Drainage Guide. International Network for Acid Prevention. (http://www.gardguide.com/index.php/Main_Page). Loska, K., Wiechula, D., Korus, I. 2004. Metal contamination of farming soils affected by industry. Environment International, 30(2), 159-165. MCMPR/MCA, 2010. Strategic Framework for Managing Abandoned Mines in the Minerals Industry, http://www.industry.gov.au/resource/Mining/Documents/StrategicFrameworkforManagingAbandonedMines.pdf. Mhlongo, S.E. and Amponsah-Dacosta, F., 2015. A review of problems and solutions of abandoned mines in South Africa, International Journal of Mining, Reclamation and Environment, DOI: 10.1080/17480930.2015.1044046. Müller, G., 1969. Index of geoaccumulation in sediments of the Rhine River. Geojournal 2, 108-118. Newton, G., et al, 2000. California’s Abandoned Mines. A Report on the Magnitude and Scope of the Issue in the State, Vol.1, 60p. Http://www.conservation.ca.gov/omr/abandoned_mine_lands/AML_Report/Documents/volume1textonly.pdf Nordstrom, D.K., Alpers, C.N., 1999. Geochemistry of acid mine waste. In “Review in Economic Geology, the environmental geochemistry of ore deposits”/Eds. G.S.Plumlee, M.J. Logsdon. Part A: Processes, techniques, and health issues Vol.6A, 133-160. Nowrouzi, M. and Pourkhabbaz, A., 2014. Application of geoaccumulation index and enrichment factor for assessing metal contamination in the sediments of Hara Biosphere Reserve, Iran. Chemical Speciation and Bioavailability, 26(2),99-105. Pham Tich Xuan, Nguyen Van Pho, Hoang Tuyet Nga, Doan Thi Thu Tra, Cai Van Truong, Nguyen Van Thu, Vu Manh Long, 2010. Heavy metal pollution in some metal mines in the Northern Vietnam. Procceding of Conference in commemoration of the 35th day of Establish of VAST. Environment and Energy, Hanoi, 236-244 (in Vietnamese with English abstract). Sobek, A.A., Schuller, W.A., Freeman, J.R. and Smith, R.M., 1978. Field and laboratory methods applicable to overburden and minesoils. Report EPA 600/2-78-054, US Environmental Protection Agency, 204p. Tarras-Wahlberg N.H, Lan T. Nguyen, 2008. Environmental regulatory failure and metal contamination at the Giap Lai pyrite mine, Northern Vietnam. Journal of Environmental Management, 86(4), 712-720. Tran Xuan Toan, 1963. Some characteristics of pyrite mineralization in the Giap Lai deposit, Phu Thọ. Geology 10, 18-24, Hanoi (in Vietnamese). Wei, Z., Wang, D., Zhou, H., Qi, Z., 2011. Assessment of Soil Heavy Metal Pollution with Principal Component Analysis and Geoaccumulation Index. Procedia Environmental Sciences, 10, 1946 -1952. Zawadzki, J and P. Fabijan´czyk, P., 2013. Geostatistical evaluation of lead and zinc concentration in soils of an old mining area with complex land management. Int. J. Environ. Sci. Technol. 10, 729-742. Ziemkiewicz, P., J. Renton and T. Rymer, 1991. Prediction and Control of Acid Mine Drainage: Effect of Rock Type and Amendment. Proceedings Twelfth Annual West Virginia Surface Mine Drainage Task Force Symposium, April 3-4, Morgantown, West Virginia, Vol.1, 51-54.

Investigation of heavy metal contents in Cow milk samples from area of Dhaka, Bangladesh

Cow milk is considered as one of the responsible food sources contaminated with heavy metals. The objectives of the study were to assess the content of selected metals in cow milk and its associated human health risks in the food chain of Bangladesh. A total of 90 cow milk samples of Branded, Dairy and Domestically produced milk were collected randomly from different sources of Savar Upazila in Dhaka area. Cadmium (Cd), chromium (Cr), lead (Pb), manganese (Mn), copper (Cu) and iron (Fe) contents in collected milk samples were determined using Flame Atomic Absorption Spectrometry (FAAS). To ensure quality control, one of the best quality control parameters i.e. recovery test; from eight various sample digestion methods were used. The Hazard Quotient (HQ) and Carcinogenic Risk (CR) values were also calculated. From the results, it was found that, the orders of heavy metal content in brand, dairy and domestic cow milk were Cr > Fe > Cu > Mn > Cd > Pb, Cr > Fe > Mn > Cu > Cd > Pb and Fe > Cr > Mn > Cu > Cd > Pb, respectively. Among the six metals, only Cr showed to exceed the highest Estimated Daily Intake (EDI) rate (for brand cow milk: 0.413 mg/day, dairy farm cow milk: 0.243 mg/day, domestic cow milk: 0.352 mg/day),and the comparison percentages of calculated values per permeable values were as follows; 206.5 % for brand cow milk,121.5 % for dairy farm cow milk and 176.0 % for domestic cow milk. Hazard Quotients (HQ) values and Carcinogenic Risk (CR) values were found within the acceptable level. Although, the metal content in sampled cow milks were within the safe limit, the potential human health risks cannot be neglected for the regular/long time consumption of heavy metal contained cow milk.

Nuclear-physical methods of detection of non-ferrous metals content in samples on the basis of neutron and charged particle activation

Nuclear-physical methods of detection of non-ferrous metals content in samples on the basis of neutron and charged particle activation

Assessment of nutritional composition and heavy metal content in some edible mushroom varieties collected from different areas of Bangladesh

Four edible mushroom species (Pleurotus ostreatus, Agaricus bisporus, Volvariella volvacea, Ganoderma lucidum) from different locations of Bangladesh, were analysed for their protein and metal content profile (K, Na, Fe, Cu, Zn, Mn, Cr, Pb, As and Cd). Trace metals were determined by atomic absorption spectrophotometer, Na and K by flame emission spectrophotometer and protein by micro Kjeldhal method. All element concentrations were determined on a dry weight basis. The protein content of mushrooms varied from 13.8%–34.3% and the metal content of samples ranged from 0.54–2.25% for K and 12.6–81.6, 69.5–626.2, 39.2–163.4, 30.1–75.5, 52.9–104.5, 0.20–0.30, 0.13–0.59 ?g g-1 for Na, Fe, Cu, Zn, Mn, Cd, Pb, respectively. Arsenic and cadmium concentrations were below the detection limit of the method used. The detection limits of the method for As and Cd are 0.01 ?g g-1 for each element. In general, K and Fe content were higher than other metals in all mushroom species. The levels of Cu and Zn in some mushroom samples were found to be higher than legal limits.Asian J. Med. Biol. Res. December 2015, 1(3): 495-501

Effects of Mining Pollution on the Longjiang River in China

In order to investigate the effects of mining pollution to LongJiang River and to know the situation of LongJiang River, we collected water and sludge samples along the river and analyzed the heavy metal content of samples. Results showed that LiDeFen factory and JinHe mining released most of the heavy metals to LongJiang River two years ago, and the upstream of LongJiang River also released some metal to the river. These heavy metals were precipitated to the bottom of LongJiang River by using weak alkaline chemical precipitation technology, and water quality of LongJiang River can reach the second national environmental quality standards of surface water now. The precipitation effects were different in different remediation sites.

Determination of Heavy Metals Contents of Some Monofloral Honey Produced in Turkey

In the present work, some element contents (Cd, Se, Cr, Pb, Cu, Mn, Ni, Zn, Fe) of 23 different monofloral honey samples from different regions of Turkey were assessed. Origins of monofloral honey research materials are as follows; Pimpinella sp., Castanea sp., Astragalus sp., Onobrychis sp., Mentha sp., Coridothymus capitatus, Robinia pseudoacacia, Cedrus libani, Gossypium sp., Thymus sp., Euphorbia sp., Tilia sp., Eucalyptus sp., Ferula sp., Centaurea solstitialis, Petroselinum sp., Vitex agnus-castus, Helianthus annuus, Citrus sp., Pinus sp., Rhododendron sp., Arbutus sp., Ceratonia siliqua. Metal contents of samples were determined by wet combustion method in ASS machine. As a result of the study, heavy metal contents of honey samples were as follows; Cd

Assessment of trace metal concentrations in muscle tissue of certain commercially available fish species from Kayseri, Turkey

Regular consumption of fish has been widely recommended by health authorities. However, it is known that some species accumulate high levels of contaminants including heavy metals (e.g., Hg, Cd, Pb, and As). In this study, Cu, Pb, Co, Ni, Cr, Mn, Cd, and Fe were determined in the muscle tissue of 11 commercially available fish species (Sparus auratus, Dicentrarchus labrax, Mullus barbatus, Belone belone, Psetta maxima, Epinephelus aeneus, Salmothymus, Soleidae, Pomatomus saltatrix, Engraulis encrasicolus, and Sarda sarda) supplied from retailers in Kayseri, Turkey. Determinations were carried out by flame atomic absorption spectrometry after the wet digestion method. The average metal concentrations of the 11 species were determined in the range of 0.54-1.79, 0.82-1.40, 2.38-4.54, 1.23-3.67, 5.01-5.97, 0.77-3.59, 0.48-1.06, and 5.05-122.8μg/g wet weight for Cu, Pb, Co, Ni, Cr, Mn, Cd, and Fe, respectively. The permissible tolerable daily intake (PTDI) and calculated daily intake (CDI) values were compared, and the calculated daily intake values of the samples were found to be below the established values. Correlations between the metal contents in samples were investigated by performing correlation tests with SPSS 13.0 for windows.

Mineral nutrient imbalance, total antioxidants level and DNA damage in common bean (Phaseolus vulgaris L.) exposed to heavy metals.

The present study aimed to analyze the biological effects induced by bioaccumulation of metals in common bean (Phaseolus vulgaris L.). Effects of mineral nutrient imbalance, total antioxidants level and DNA damage induced by accumulation of heavy metals, were investigated in bean seedlings treated with two selected metal concentrations for 7days. Metal content is analyzed by inductively coupled plasma - atomic emission spectrometer (ICP-AES), for total antioxidants level assessment the Ferric-Reducing Antioxidant Power (FRAP) assay is used and Random Amplified Polymorphic DNA (RAPD) method was applied for investigation of DNA damages. The increasing metal concentration in the treatment medium changed synchronously metal content in samples, and decreased total antioxidant activity in all samples with exception only for samples treated with Ni and Cd. The obtained "DNA fingerprints" demonstrated that the increasing metal concentrations induced changes in RAPD profiles (disappearance and/or appearance of bands in comparison with untreated control samples). The highest number of missing bands was observed in samples treated with zinc (total 4 bands) and nickel (total 4 bands) at both concentrations. These results suggested that mineral nutrient imbalance is involved in changes of antioxidant levels and DNA damages of the seedlings, which may help to understand the mechanism of metal toxicity in plants.