In this paper, a refractive index sensor based on a metastructure (MS) is proposed, which achieves sensing through the sharp valleys formed in the reflection spectrum by the excitation of optical Tamm states (OTS) by gyroidal graphene. Differences in the refractive index of the filling medium in the pores of gyroidal graphene will cause shifts in the reflection valleys. The graphene layer is followed by a periodic structure consisting of alternating zirconium dioxide (ZrO2) and α-molybdenum trioxide (α-MoO3). The 4 × 4 transfer matrix method (TMM) is used for the calculation of the results, which allows the case of arbitrary polarization deflection angles ϕ to be considered in the discussion. Different values of ϕ can lead to a switch in the dominance of the sensor, specifically, the structure has a larger linear interval but lower sensitivity at ϕ = 0°, which is the opposite of the situation at ϕ = 90°. The sensor can be used in a variety of scenarios such as biochemical sensing, gas detection, etc, and brings the polarization deflection angle of the incident wave into the discussion.
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