It has been predicted that high equatorial temperatures on Mercury could promote thermal annealing by Ostwald ripening, where nanophase metal particles (a product of space weathering) coalesce and grow into larger, microphase particles, resulting in lower albedo. Here, we test this prediction by studying the correlation between albedo and temperature in 1° spatial bins using newly recalibrated 1064 nm reflectance data acquired by the Mercury Laser Altimeter (MLA), low incidence angle data from the Mercury Dual Imaging System (MDIS), and newly modeled maximum surface temperatures (MSTs). Accounting for local geology and latitude, we compare the reflectance values of surfaces with MSTs >675 K (where Ostwald ripening is predicted to be most effective) to surfaces with MSTs <473 K (where ripening is predicted not to be effective). Smooth plain surfaces >675 K are 10% and 12% darker than surfaces <473 K in MLA and MDIS data, respectively, and nonsmooth plain surfaces >675 K are 8% and 7% darker than surfaces <473 K. However, open questions remain regarding the causation of this darkening; statistical tests cannot distinguish whether the reflectance differences are systematic or the result of compositional variations that happen to correlate with MST. Along Mercury’s thermal longitudes, we find that reflectance is typically lower along hot poles than along the 90°E cold pole in the low-to-midlatitudes, especially in the smooth plains, consistent with previous work identifying a decrease in optical maturity along the 90°E cold pole. Longitudinal reflectance variations correlate with temperature variations, rather than variations in micrometeoroid or solar wind fluxes.
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