Mercia Mudstone Research Articles

Physico-mechanical properties of halite and gypsum–mudstone crushed rock backfills of the Mercia Mudstone Group

Permanent disposal of radioactive waste in deep geological repositories (DGRs) relies on engineered barriers, such as crushed rock backfills, to ensure that wastes are isolated and contained. The performance of crushed rock backfill, during construction, operation and closure, relies on optimizing its mechanical properties. This paper explores how density and composition influence the strength of (i) crushed halite and (ii) crushed gypsum–mudstone mixtures of the Triassic Mercia Mudstone Group, which is a potential DGR host rock in the UK. Unconfined compressive strength (UCS) testing of compacted halite demonstrated that strength correlated with compaction density, with UCS increasing from 220 kPa at a density of 1.72 g cm −3 up to 6600 kPa at the maximum achieved density of 1.83 g cm −3 . Direct shear testing revealed an angle of internal friction for crushed halite samples of 39°–40° at a density of 1.5 g cm −3 . Direct shear testing of gypsum–mudstone composites from 100% gypsum to 100% mudstone revealed that higher gypsum percentages provide greater frictional shearing resistance, whilst higher mudstone percentages promote more cohesive strength. Data are also presented on bulk materials characterization by X-ray fluorescence (XRF), scanning electron microscopy with energy-dispersive spectrometry (SEM-EDS) and optical microscopy. This research provides insights into how the strength properties of compacted crushed halite and gypsiferous mudstone backfills can be engineered through control of density and composition.

CO2-induced micro-mechanical alterations of mudstone Caprock: Examples from the Mercia Mudstone Group, East Irish Sea Basin

Mechanical properties of caprock are important for subsurface energy sequestration as they determine the rock stability under the influence of external forces. Despite some advantages, there is a lack of knowledge regarding the interplay between rock texture and mechanical properties and their impact on the caprock stability within a short-term fluid-rock reaction period. Typical caprock samples from the Mercia Mudstone Group in the East Irish Sea Basin are studied in this work. X-ray diffraction (XRD), scanning electron microscopy (SEM) with energy-dispersive X-ray spectroscopy (EDX) were used to identify minerology and local heterogeneity characteristics. Nanoindentation tests were conducted before and after CO2-brine-rock reaction to investigate the changes of micro-mechanical properties. After CO2-brine treatment, significant dolomite dissolution was observed in all samples (although dolomite content was only minor in some samples). In contrast, the micro-texture of other minerals showed no significant changes indicating minimal to no dissolution at the current resolution. The changes of mechanical properties are lower than expected, which are probably related to the impaired cementation induced by the retained water in pore throats and relatively rough surface after reaction. For long-term carbon sequestration, the layered depositional characteristics of different phases may not only form a barrier to prevent fluids leaking upward, but also complement each other in mechanical properties to maintain stability. This study improves the understanding of the effect of microscale structural and micro-mechanical changes on caprock stability in carbon sequestration related applications.

Provenance constraints on the Late Triassic ejecta layer from Churchwood Quarry, SW England: An impactite suite from Manicouagan

AbstractIn situ LA‐ICP‐MS/MS U‐Pb and Rb‐Sr geochronology combined with geochemical analysis and electron microscopy have been performed on ejecta components sampled from the Mid‐to‐Late Triassic Mercia Mudstone Group at Churchwood Quarry, SW England. The layer comprises altered impact spherules, melt‐rich and fragment‐rich accreted grain clusters (AGCs), along with shocked mineral phases. Late Triassic ages are obtained: a U‐Pb age of 219 ± 72 Ma from variably shock‐metamorphosed apatite and a Rb‐Sr age of 213 ± 31 Ma from melt‐rich AGCs. A post‐depositional U‐Pb age of 200 ± 7.5 Ma obtained from the carbonate host matrix correlates with an early Jurassic dolomitization event associated with regional marine transgression. Several links to the Manicouagan impact structure, Canada, are identified that complement previous provenance studies: (1) rare earth element compositions of impact spherules and melt‐rich AGCs match those of the Manicouagan impact melt sheet; (2) the preservation of Archean and Paleo‐ to Neoproterozoic target rock U‐Pb ages in zircon and apatite match those recorded within Manicouagan basement lithologies; and (3) impact spherules and melt‐rich AGCs record initial 87Sr/86Sr compositions that overlap with those of the Manicouagan impact melt sheet and the target rocks involved in their generation.

Initial results of coring at Prees, Cheshire Basin, UK (ICDP JET project): towards an integrated stratigraphy, timescale, and Earth system understanding for the Early Jurassic

Abstract. Drilling for the International Continental Scientific Drilling Program (ICDP) Early Jurassic Earth System and Timescale project (JET) was undertaken between October 2020 and January 2021. The drill site is situated in a small-scale synformal basin of the latest Triassic to Early Jurassic age that formed above the major Permian–Triassic half-graben system of the Cheshire Basin. The borehole is located to recover an expanded and complete succession to complement the legacy core from the Llanbedr (Mochras Farm) borehole drilled through 1967–1969 on the edge of the Cardigan Bay Basin, North Wales. The overall aim of the project is to construct an astronomically calibrated integrated timescale for the Early Jurassic and to provide insights into the operation of the Early Jurassic Earth system. Core of Quaternary age cover and Early Jurassic mudstone was obtained from two shallow partially cored geotechnical holes (Prees 2A to 32.2 m below surface (m b.s.) and Prees 2B to 37.0 m b.s.) together with Early Jurassic and Late Triassic mudstone from the principal hole, Prees 2C, which was cored from 32.92 to 651.32 m (corrected core depth scale). Core recovery was 99.7 % for Prees 2C. The ages of the recovered stratigraphy range from the Late Triassic (probably Rhaetian) to the Early Jurassic, Early Pliensbachian (Ibex Ammonoid Chronozone). All ammonoid chronozones have been identified for the drilled Early Jurassic strata. The full lithological succession comprises the Branscombe Mudstone and Blue Anchor formations of the Mercia Mudstone Group, the Westbury and Lilstock formations of the Penarth Group, and the Redcar Mudstone Formation of the Lias Group. A distinct interval of siltstone is recognized within the Late Sinemurian of the Redcar Mudstone Formation, and the name “Prees Siltstone Member” is proposed. Depositional environments range from playa lake in the Late Triassic to distal offshore marine in the Early Jurassic. Initial datasets compiled from the core include radiography, natural gamma ray, density, magnetic susceptibility, and X-ray fluorescence (XRF). A full suite of downhole logs was also run. Intervals of organic carbon enrichment occur in the Rhaetian (Late Triassic) Westbury Formation and in the earliest Hettangian and earliest Pliensbachian strata of the Redcar Mudstone Formation, where up to 4 % total organic carbon (TOC) is recorded. Other parts of the succession are generally organic-lean, containing less than 1 % TOC. Carbon-isotope values from bulk organic matter have also been determined, initially at a resolution of ∼ 1 m, and these provide the basis for detailed correlation between the Prees 2 succession and adjacent boreholes and Global Stratotype Section and Point (GSSP) outcrops. Multiple complementary studies are currently underway and preliminary results promise an astronomically calibrated biostratigraphy, magnetostratigraphy, and chemostratigraphy for the combined Prees and Mochras successions as well as insights into the dynamics of background processes and major palaeo-environmental changes.

Potenential for thermal energy from Tunnels beneath Manchester and Crewe: a case study

potenential for thermal energy from Tunnels beneath Manchester and Crewe: a case study

Magnetostratigraphy of the Mercia Mudstone Group (Devon, UK): implications for regional relationships and chronostratigraphy in the Middle to Late Triassic of Western Europe

Global synchronization of environmental change in terrestrial successions in deep time is challenging owing to the paucity of dating methods, a case also applicable to the Middle to Upper Triassic Mercia Mudstone Group in Britain. Using coastal cliff sections, magnetostratigraphy was evaluated at 263 horizons, defining 53 magnetozones. Magnetozones from the lower 140 m of the group demonstrate correspondence to those from the mid-Ladinian to early Carnian polarity timescale, dating that is compatible with magnetostratigraphy from the underlying Sherwood Sandstone Group. Magnetostratigraphy of the Dunscombe Mudstone Formation, and associated palynological data, suggest a late Carnian to earliest Norian age, and a dramatically lower accumulation rate than for adjacent formations. The polarity record demonstrates coeval flooding events, evaporite deposits and intervals of sand supply between the Wessex Basin and the Central European Basin in the Carnian. This is the result of linked climatic and eustatic changes between these separate basins, related to aeolian dust supply and the shrinkage of hyper-arid source regions for the fine material. Magnetostratigraphy from the Branscombe Mudstone and Blue Anchor formations demonstrates their Norian and early Rhaetian age. These and other data suggest an alternative synchronization of marine and non-marine polarity records for the Norian polarity timescale. Supplementary material : Section details and detailed logs of the sampled sections and inferred sequence boundaries, magnetic mineralogy data, demagnetization behaviour and mean directions, summary of virtual geomagnetic pole data and a comparison with other European poles, construction of other composite reference sections and revised polarity scales, an Excel sheet of magnetic data, statistically evaluated correlation models and age models are available at https://doi.org/10.6084/m9.figshare.c.6613788

‘A hard rain's a‐gonna fall’: torrential rain, flash floods and desert lakes in the Late Triassic Arden Sandstone of Central England

The Arden Sandstone Formation of central and western England is a thin but conspicuous arenaceous unit within the Late Triassic Mercia Mudstone Group. Sedimentological and palaeontological data point to lacustrine depositional conditions, in contrast to the red desert mudstones above and below which were deposited as continental dryland desert floodplains. The Arden Sandstone records deposits of the lake margins and may be the high stand lateral equivalent of the halite and gypsum deposits which formed in the lake centre. The Carnian age of the Arden Sandstone potentially links it to the Carnian Pluvial Episode, marking the coalescence, spread and freshening of the formerly saline desert lakes, and deposition of sandy, fluvial and lacustrine deposits, during the wetter climate that prevailed for at least a million years.

Rare preservation of Triassic pedorelicts with biogenic traces from a hot semi-arid upland palaeoenvironment at Portishead, SW England

Pedorelicts occur sporadically in coastal exposures of Middle to Late Triassic continental sediments, at Portishead, SW England. The clasts include aeolian and bedrock constituents, calcrete textures, vesicles and other pedogenic features reflecting a hot semi-arid palaeoenvironment. Interpreted as being derived from an upland soil, they are classified in palaeosol terms as Calcic Protosol. In the most significant exposure, cryptic tubular trace fossils in branching networks occur within these pedorelict clasts in a localised fluvial deposit. This extremely rare palaeoecological archive offers a glimpse into continental upland life in a Pangaean desert landscape. It is documented for its own merit, to support continuing studies of its palaeobiology and to prompt investigation for comparable deposits.The pedorelicts occur within the Mercia Mudstone Marginal Facies (MMMF), close to its basal unconformity with underlying Paleozoic strata, at the margin of the Somerset Basin. The soil from which they are derived is interpreted to have developed in an upland regolith over Tournaisian bedrock of interbedded limestone and siltstone. These weathered and, with aeolian dust containing calcite and iron minerals and siliciclastic sand, formed a structured soil. This was aided by intermittent light and moderate rainfall that promoted mainly vadose pedogenic calcretization with displacive calcite crystallisation and siliciclastic grain breakage. In places, the soil was vesicular, as an ‘Av’ horizon, and in others, it was bioturbated with the development of calcite-lined tubules and unlined tunnels. At intervals of perhaps 104 to 105 years, catastrophic deluges eroded the regolith and transported clasts downslope towards the basin to form onlapping coarse clastic beds typical of the MMMF. The soil structure disintegrated but fragments that became pedorelicts were segregated in a fault-controlled palaeo-valley, possibly partly as a debris-flow, to be deposited as localised conglomeratic lenses with fluvial sand. After burial by further sedimentation, this deposit underwent diagenetic calcite cementation and baryte mineralisation before its present exposure by coastal erosion.

A new exposure of the North Curry Sandstone Member (Dunscombe Mudstone Formation, Mercia Mudstone Group: Carnian, Triassic), near Taunton, Somerset (UK): The location of Charles Moore's vertebrate specimens resolved

There is renewed interest in a series of Carnian-aged sandstone units across the UK because they represent a unique event in the Late Triassic, the Carnian Pluvial Episode (CPE), from 233 to 232 Ma. The North Curry Sandstone Member of the Mercia Mudstone Group in Somerset is of particular importance because it yielded a rich fauna of shark, bony fish and amphibian remains in coarse-grained sandstones to Charles Moore in the 1860s. However, the exact location and age of his important collection had not been identified. Here, we demonstrate that the Moore collection comes from the North Curry Sandstone Member in a location in the village of Ruishton, just east of Taunton, where a new road cutting reveals both the bone-rich units and a complete succession through the CPE, a time of major climatic and biotic upheaval. The 16 m section comprises several sandstones interbedded with red-green mudstones, representing a terrestrial environment with lacustrine, evaporitic mud flat and fluvial deposits.

The short-term and creep mechanical behaviour of clayey soil-geocomposite drainage layer interfaces subjected to environmental loadings

In this paper, to investigate the impact of environmental loadings on the short-term and creep mechanical characteristics of different types of clayey soil-Geocomposite Drainage Layers (GDL) interfaces, a series of rapid loading and creep shear tests were conducted on Mercia Mudstone Clay-GDL interfaces and Kaolin Clay-GDL interfaces subjected to drying-wetting cycles, thermal cycles and elevated temperature, etc, using a bespoke temperature and stress-controlled large direct shear apparatus. The experimental results indicate that, compared with the original specimens, the interfaces subjected to drying-wetting cycles, thermal cycles and elevated temperature, have lower peak shear strength and creep shear resistance. For example, under 25 kPa normal stress, the peak shear strength of original Mercia Mudstone Clay-GDL interfaces and Kaolin Clay-GDL interfaces falls by 11.91% and 10.11%, respectively, when subjected to 1 drying-wetting cycle. This can be ascribed to the weakening of interlocking effects and skin friction between soil and GDL caused by the softening of drainage core and geotextile fibres of GDL. The peak shear strength of clayey soil-GDL interfaces subjected to one drying-wetting cycle is lower than that subjected to one thermal cycle because of the reduction in the peak shear strength of clayey soil above GDL during drying-wetting cycles. The impact of drying alone on the decrease in the peak shear strength of clayey soil-GDL interfaces during drying cycles with heating is small, and the main influence factor is the elevated temperature.

On the records of the brachiopod ‘ Lingula ’ and associated fossils in Mid-Triassic deposits in England

Brachiopods were reported, as ‘ Lingula ’, from Anisian (early Mid-Triassic) deposits of the Tarporley Siltstone Formation (Mercia Mudstone Group) in Nottinghamshire in 1955, and from the Helsby Sandstone Formation (Sherwood Sandstone Group) in a borehole in Oxfordshire in 1975. Burrows ( Lingulichnus ) attributed to this organism were reported from the Tarporley Siltstone in Cheshire in 1981. These records are evidence of marine influence in the depositional environments of those formations.

Permo-Triassic aeolian red clay of southwestern England and its palaeoenvironmental implications

Late Permian and Triassic red mudstones are widely distributed and exposed in southwestern England. This homogenous, massive mudstone succession has been extensively studied for its palaeoenvironmental potential. However, its origin and palaeoenvironment remain under debate. The Triassic Mercia mudstone was early proposed to be aeolian loessic clay based on collapse nature when wetted or loaded and its similarities with aeolian clay in Quaternary Australia, but lacks experimental confirmation and is not generally accepted. In comparison with aeolian red clay in China, here we confirmed that the Triassic Mercia mudstone, together with the Upper Permian Aylesbeare mudstone, was dominated by aeolian clay. This was based on lines of evidence regarding sedimentary structure, particle grain size, geochemistry, micromorphology, and pedogenic features. The results showed that the Mercia mudstone and the Aylesbeare mudstone had sedimentary structures and grain size distributions that were similar to the aeolian red clay in the Chinese Loess Plateau. The major chemical elements correlated well with the aeolian red clay, with the exception of minor discrepancies in CaO and K2O. The similarity in the rare earth element (REE) distribution of the Mercia mudstone and the Aylesbeare mustone with aeolian red clay inferred their similar origin. Widespread pedogenic features indicated the universal development of palaeovertisols forming in alternating wet/dry climates. It was hypothesised that Permo-Triassic southwestern England was dominated by aeolian dust accumulation in a seasonal wet/dry climate, whereas perennial lakes or longstanding rivers across the study area might not exist.

Reservoir quality and diagenesis of Triassic sandstones and siltstones from arid fluvial and playa margin environments: A study of one of the UK's earliest producing oilfields

The Triassic stratigraphy of the UK contains many important reservoir rock units, present in all major offshore and onshore basins, that are rich in oil, gas and water resources. The Ormskirk Sandstone Formation (Sherwood Sandstone Group) and Tarporley Siltstone Formation (Mercia Mudstone Group) represent the main reservoirs found in one of the UK's earliest producing oilfields, at an unusually shallow depth of 30–90 m. In this study, environments of deposition, maximum burial depth, and reservoir quality have been evaluated from well Formby-7, drilled in 2012, using modern analytical techniques. Wireline data and core analysis data were made available by Aurora Energy Resources for the purposes of this study. Formby-7 was continuously cored so that the whole section was logged for sedimentary structures and grain size. Optical analysis of thin sections was conducted, along with SEM-EDS, using thin sections from core plugs. The Ormskirk Sandstone Formation was deposited in a proximal setting by a braided, dryland river with aeolian influence; the Tarporley Siltstone Formation was deposited in a more distal setting on the margins of a playa environment. The study found that the reservoir quality is excellent in the deeper Ormskirk sediments, but relatively poor in the overlying Tarporley sediments. Good reservoir quality present in the Ormskirk Sandstone Formation is linked to early depositional textures, grain size (medium sand) and general lack of pore-filling cements. In the Tarporley, reservoir quality is poor due to the grain size (very fine sand) and the variable presence of pore-filling gypsum associated with playa deposits. Minor feldspar diagenesis (both dissolution and precipitation) occurred in both the Sherwood and Mercia sediments. The small degree of mechanical compaction and lack of any signs of mesodiagenesis suggest that the clastic sediments in the Formby-7 well have not been buried deeper than about 1000 m. The findings reported here can be used to help the understanding of UK Triassic sedimentology and reservoir quality for oil and gas, geothermal energy, CCS (carbon capture storage) and water supply.

A missing link in the mid‐late Permian record of north‐eastern Pangea: A sedimentological evaluation of the Permian Belfast Harbour Evaporite Formation of County Antrim, Northern Ireland

AbstractAncient salt deposits preserve a record of highly specific environmental, climatic and biological conditions, including past surface water chemistry and water depths, local air temperatures, atmospheric composition and halophilic microorganisms. This paper presents the first sedimentological study of the mid‐Late Permian Belfast Harbour Evaporite Formation of Northern Ireland. This formation is dominated by bedded halite, contains some siliciclastic mudstone and bedded anhydrite, and is cross‐cut by intrusive igneous rocks. The bedded halite lithology contains bottom‐growth chevron and cornet crystals, efflorescent crusts and dissolution pipes, which are evidence of a saline surface brine that underwent periods of evapoconcentration, desiccation and flooding. The mudstone lithology contains dewatering structures, intraclasts and mudcracks, which indicate flooding and desiccation in dry mudflats. Bedded anhydrite was deposited as beds of gypsum cumulate crystals in saline surface waters. The Belfast Harbour Evaporite Formation was formed by saline lakes with associated mudflats, based on sedimentary characteristics and supported by mineralogical, geochemical and stratigraphic context. Diagenetic features reflect dissolution and cementation at the surface and shallow subsurface in the depositional environment and limited late‐stage alterations. Syndepositional dissolution pipes in bedded halite were formed by flooding events. Early halite cement is present in dissolution pipes and mudstones. Gypsum/anhydrite repeatedly dehydrated and rehydrated to form an interlocking crystal mosaic. Later features include fluid migration and the intrusion of mafic rocks. The Belfast Harbour Evaporite Formation was deposited by an ephemeral saline lake and dry mudflat system in an arid climate. This study, when compared to age‐equivalent continental deposits elsewhere, suggests that arid settings with saline lakes existed across much of Pangea during the Permo‐Triassic. The Belfast Harbour Evaporite Formation stratigraphically underlies the extremely low pH saline lakes of the Mercia Mudstone Group, implying that it aids in understanding the formation of Pangean acid brine lakes.

Testing the relationship between marine transgression and evolving island palaeogeography using 3D GIS: an example from the Late Triassic of SW England

The Rhaetian transgression marked a major change in landscape. The Permian and Triassic had been a time of terrestrial conditions across Europe, including much of mainland UK, as well as the North Sea and Irish Sea, represented by red bed clastic successions. Seas flooded across Europe at 205.7 Ma and the shift from terrestrial to marine environments is marked in the UK by the switch from the red beds of the Mercia Mudstone Group to the black mudstones and shelly limestones and sandstones of the Penarth Group. The area around Bristol was marked by a complex landscape in which an archipelago of islands of Carboniferous limestone was formed in the new shallow seas. The application of new methods in geographical information systems allows a detailed exploration of a number of conformable surfaces, the unconformity between the underlying Paleozoic rocks and the overlying Mesozoic strata, as well as levels within the latest Triassic sediments, marking the advance of the sea and interactions with the coeval tectonics, which caused some islands to rise and some basins to descend. The new geographical information system models show a sequence of palaeogeographical reconstructions of the archipelago and relate this to the island tetrapod faunas, which show strong evidence of the species–area effect. Supplementary material: Supplementary tables S1-S6 and 2D island map GIS files are available at https://doi.org/10.6084/m9.figshare.c.5273256

The age and formation mechanisms of Late Triassic fissure deposits, Gloucestershire, England: Comments on Mussini, G. et al. (2020). Anatomy of a Late Triassic Bristol fissure: Tytherington fissure 2

In the Late Triassic the landscape NE of present-day Bristol, SW England was dominated by Carboniferous Limestone ridges and cuestas that became progressively buried by continental Mercia Mudstones and finally inundated during the Rhaetian marine transgression. Mussini et al. (2020) adopt the assertions of earlier collaborators back to Whiteside and Marshall (2008) that terrestrial vertebrate assemblages from sediments contained within karstic fissure systems in the former limestone ridges at Cromhall, Tytherington and elsewhere are restricted to the Rhaetian. We review and reject the sedimentological, stratigraphic, geomorphological and topographic arguments for this and reassert a long pre-Rhaetian (Norian) history for the vertebrate-bearing fissure systems at both Tytherington and Cromhall. We also reject the contemporaneous Rhaetian freshwater-seawater mixing zone dissolution model for the fissure systems adopted by Mussini et al. (2020) and reaffirm that the Tytherington and Cromhall fissures developed as conduit caves with a long Triassic history. Applying a new regional study of the Rhaetian transgressive surface, we also show that whilst the fissures at Cromhall remained sealed after the Norian, those at nearby Tytherington were re-exposed in the Late Rhaetian. Already partially filled with Norian sediments, the Tytherington fissures were subject to reworking on the seabed. Internal collapses, probably triggered by well documented repeated regional seismicity, led to the chaotic state of the Tytherington fills when downward moving Rhaetian marine components came to lie amongst and mix with earlier Norian terrestrial sediments. The vertebrate associations in the Tytherington fissures therefore contain a substantial Rhaetian input whilst those at Cromhall do not.

The thermal properties of the Mercia Mudstone Group

The Mercia Mudstone Group (MMG) crops out extensively across England and Wales and its thermal properties are required for the design of infrastructure such as ground source heating and cooling schemes and electrical cable conduits. Data from the literature and new data from a borehole core have been compiled to generate an updated range of thermal conductivities related to rock type and the lithostratigraphy. These indicate a total range in saturated vertical thermal conductivity of 1.67–3.24 W m −1 K −1 , comprising 1.67–2.81 W m −1 K −1 for mudstones, 2.12–2.41 W m −1 K −1 for siltstones and 2.3–3.24 W m −1 K −1 for sandstones. These data are all from measurements on samples and there will be uncertainty when considering the thermal properties of the rock mass owing to micro- and macrostructural features. Geometric mean modelling of thermal conductivity based on mineralogy has overestimated the thermal conductivity. Correction factors for the modelled thermal conductivities have been calculated to allow a first estimate of MMG thermal conductivities when only mineralogical data are available. Measured thermal diffusivities from the borehole core were in the range of 0.63–3.07 × 10 −6 m 2 s −1 and are the first measured thermal diffusivities to be reported for the MMG.

Data workflow for generating static geological model platform for petroleum prospect re-evaluation of Wytch Farm field, Wessex Basin, South Coast, United Kingdom

The analyses and interpretation of the old existing 3D seismic and well log data of Wytch Farm field, Wessex Basin, south coast of the United Kingdom provided relevant information employed to generate static geological model platform. The platform which is requisite for building and distributing petrophysical and production data across the field could be useful for simulating the field's performance, history matching as well as generate future prediction/forecast needful to establish the reasons for the early water breakthrough and sudden production decline from a peak value of 115,000 bbl/day in 1997 to the present production rate of less than 19,000 bbl/day. Six major faults which extend throughout the entire length of the field and five horizon surfaces which correspond to the top of Greensand, Combrash, Mercia mudstone and the top and base of Sherwood Formations aided the generation of the static geological model platform across the Wytch Farm field. The volume of delineated saturated reservoir rock lying above the Oil Water Contact (OWC) and enclosed within fault assisted anticlinal structures indicate a Gross Rock Volume (GRV) of 2,007,000,000 m3 and thus suggest that Wytch Farm field may likely still hold hydrocarbon potential beyond the present daily production rate. This potential could be unlocked through adequate reservoir management that requires detailed information such as could be generated from static geological model of the field.

Sediment Cyclicity and the Carnian Pluvial Episode: Evidence from Spectral Gamma-ray Logging of the Mercia Mudstone Group, SW England

The Late Triassic exposed on the Devon coast (SW England) is analysed through spectral gamma-ray logging and considered in terms of two theories of palaeoenvironmental change: sediment cyclicity and the Carnian Pluvial Episode (CPE). A decrease in total count gamma-ray output occurs at the CPE and reflects a geographically extensive change in depositional styles from siltstones and isolated playa-lake, evaporitic mudstones to more geographically-widespread evaporite-bearing mudstone cycles. Th/K and Th/U ought to increase (through humid weathering) in the CPE, but these ratios do not change until above the CPE-related Dunscombe Mudstone Formation. A delayed response in Th enrichment is considered likely, reacting to both the initiation of the 1.2my long CPE, but also longer-term and widespread Carnian rifting, marine inundation and volcanism in Pangaea.

The spatial distribution and geochemical variation of fault and fracture hosted calcite and gypsum cements in the eastern Bristol Channel Basin

Abstract The spatial distribution and geochemical variation of fault- and fracture-hosted cements can be used to reconstruct the evolution and migration of pore fluids in sedimentary basins. Geochemical data, from stable oxygen and carbon isotope and strontium isotope analyses, of calcite and gypsum cements provide valuable insights into the source of pore fluids and their evolution in the eastern Bristol Channel Basin. Overall, at both an outcrop-scale and a basin-scale there were no observable relationships between the dip angle and direction of fractures with the oxygen and carbon isotopic composition of calcite cements, indicating that the movement and distribution of fluids in fractures is not controlled by the orientation of fracture opening. Radiogenic strontium isotopic compositions of calcite and gypsum cements indicate at least two different mineralising fluid compositions that are strongly controlled by the lithologies (fossiliferous limestones and shales, and marls with gypsum nodules, respectively) in which they occur. These fluids originated as connate pore fluids that were altered during the diagenesis of their host lithologies. Mineralising fluids within the Lower Jurassic Lias Group are characterised by enriched oxygen and strontium isotopic compositions and relatively depleted carbon isotopic compositions, associated with the alteration of labile minerals and carbonaceous fossils. Mineralising fluids within the Triassic Mercia Mudstone Group have enriched strontium isotopic compositions as a result of the interaction of fluids with evaporitic intervals. The mineralising fluids were redistributed through migration along faults and their associated damage zones. This study highlights the importance of integrating a range of geochemical analyses when attempting to understand the source of fluids and their evolution through time. The findings from this study can also be applied to nearby petroleum producing basins, e.g. the Wessex Basin, where equivalent rocks are economically significant source rocks and caprocks and have experienced similar structural histories.