Membrane Fouling Resistance Research Articles

A comprehensive study on the effects of electrocoagulation integrated in a membrane bioreactor treating sunflower oil refinery wastewater on treatment performance, biological properties, and fouling behavior.

This study evaluated the effects of electrocoagulation integrated in a laboratory-scale membrane bioreactor (MBR), namely EC-MBR, on the treatment performance, activated sludge morphological characterization, and membrane fouling of MBR treating actual sunflower oil refinery wastewater. The EC-MBR system exhibited significantly higher chemical oxygen demand (COD) and oil and grease (O&G) removal efficiency compared to the MBR system. Additionally, both systems achieved excellent turbidity removal, with a percentage above 99%. The membrane fouling rate was higher in the EC-MBR system compared to the MBR system. Despite the decrease in the soluble microbial product (SMP) and extracellular polymeric substance (EPS) concentration in the EC-MBR system, especially their protein fraction, the significant increase in MLSS and carbohydrates/protein ratio, and the decrease in the mixed liquor and the cake layer particles size were the main membrane fouling factors. The membrane fouling resistance distribution showed that the EC-MBR system had a higher percentage of pore blocking resistance compared to the MBR. FTIR analysis identified a greater proportion of carbohydrate compounds in the cake layer of the EC-MBR system. SEM images revealed dense microbial clusters, mainly rod- and oval-shaped bacteria, in the EC-MBR system. Furthermore, EDX analysis detected elements such as Ca, K, O, Al, and P in both systems, with the EC-MBR system showing a higher Al content. The EC-MBR system showed low energy consumption (0.431kWhm-3) and total operating costs ($0.90m-3), showcasing its effectiveness and affordability for sustainable wastewater management.

Fabrication of cellulose nanocrystals-incorporated dense Janus membranes for enhanced desalination and oily saline wastewater treatment via membrane distillation

Conventional hydrophobic membranes used in membrane distillation (MD) face significant challenges, such as severe membrane fouling and wetting, when treating surfactant-containing oily wastewater. Current strategies to modify surfaces for anti-fouling and anti-wetting purposes are often complex and time consuming, potentially compromising the flux in MD. This study investigates the characteristics and performance of novel fabricated Janus membranes for the treatment of oily hypersaline wastewater in membrane distillation applications. Janus membranes, which have a dense polyamide layer containing cellulose nanocrystal nanoparticles, were synthesized using the reverse interfacial polymerization (R–IP) method on a polyvinylidene fluoride (PVDF) substrate. Characterization using scanning electron microscopy (SEM), atomic force microscopy (AFM), Fourier transform infrared spectrometry (FTIR), X-ray photoelectron spectroscopy (XPS), water contact angle (WCA) revealed that the modified Janus membranes exhibited an enhanced hydrophilicity and structural integrity due to the incorporation of cellulose nanocrystal nanoparticles. The fabricated membranes showed a dense surface layer without visible pores or cracks, with micron-scale patterned structures and widely distributed wrinkles, particularly at higher concentrations of cellulose nanocrystal nanoparticles. The desalination performance was evaluated in an air gap membrane distillation setup, where the modified Janus membranes demonstrated higher water vapor fluxes and stable salt rejection, even in the presence of surfactants. The wettability and fouling resistance of the Janus membranes were evaluated, with the PVDF-RIP0.5C membrane showing the highest hydrophilicity and underwater oleophobicity, thereby preventing oil adhesion and membrane fouling. These results underline the potential of Janus membranes with incorporated cellulose nanocrystal nanoparticles for efficient desalination and treatment of oily saline wastewater in the MD process.

A comparison study on membrane fouling in A/O-MBR and A/A-MBR at different mixed liquor-suspended solids concentrations

ABSTRACT Membrane fouling leads to decreased membrane flux, increases the frequency of membrane tissue replacement and membrane cleaning, and increases the operating cost of membrane bioreactor. In this study, the pollutant removal effects, membrane fouling differences and microbial characteristics of anaerobic/aerobic MBR (A/O-MBR) and anaerobic/anoxic MBR (A/A-MBR) were investigated at different mixed liquor suspended solids (MLSS) concentrations. The results showed that the chemical cleaning cycle of membrane contamination was 12, 28, 44 h and 24, 40, 104 h, respectively, and the cycle was prolonged with the increase of MLSS concentration (from 6000 to 9000 mg L−1). A/O-MBR was 1.4–2.4 times the rate of membrane fouling of A/A-MBR. In irreversible resistance, extracellular polymer substances (EPS) were the most significant contributors to membrane fouling. EPS concentration in A/A-MBR (118.33, 73.75, 54.26 mg/gMLSS) was lower than that in A/O-MBR (171.68, 91.92, 62.33 mg/gMLSS). Therefore, increasing MLSS concentration could mitigate membrane fouling. 16S rRNA high-throughput sequencing demonstrated that filamentous bacteria was the primary reason for the membrane fouling difference. Filamentous bacteria were more likely to be attached to the surface of the membrane, causing membrane fouling. The abundance percentage of filamentous bacteria in A/A-MBR was smaller than that in A/O-MBR. In summary, The excellent performance of A/A-MBR in membrane fouling behaviour, resistance analysis, EPS and microorganisms proved that A/A-MBR is more promising than A/O-MBR in wastewater nitrogen and phosphorus removal. This study can provide a theoretical basis for the application of MBR in the field of sewage treatment.

Tourmaline triggered biofilm transformation: Boosting ultrafiltration efficiency and fouling resistance

Ultralow pressure filtration system, which integrates the dual functionalities of biofilm degradation and membrane filtration, has gained significant attention in water treatment due to its superior contaminant removal efficiency. However, it is a challenge to mitigate membrane biofouling while maintaining the high activity of biofilm. This study presents a novel ceramic-based ultrafiltration membrane functionalized with tourmaline nanoparticles to address this challenge. The incorporation of tourmaline nanoparticles enables the release of nutrient elements and the generation of an electric field, which enhances the biofilm activity on the membrane surface and simultaneously alleviates intrapore biofouling. The tourmaline-modified ceramic membrane (TCM) demonstrated a significant antifouling effect, with a substantial increase in water flux by 60 %. Additionally, the TCM achieved high removal efficiencies for contaminants (48.78 % in TOC, 22.28 % in UV254, and 24.42 % in TN) after 30 days of continuous operation. The fouling resistance by various constituents in natural water was individually analyzed using model compounds. The TCM with improved electronegativity and hydrophilicity exhibited superior resistance to irreversible fouling through increased electrostatic repulsion and reduced adhesion to foulants. Comprehensive characterizations and analyses, including interfacial interaction energies, redox reaction processes, and biofilm evolutions, demonstrated that the TCM can release nutrient elements to facilitate the development of functional microbial community within the biofilm, and generate reactive oxygen species (ROS) on the membrane surface to the degrade contaminants and mitigate membrane biofouling. The electric field generated by tourmaline nanoparticles can promote electron transfer in the Fe(III)/Fe(II) cycle, ensuring a stable and sustainable generation of ROS and bactericidal negative ions. These synergistic functions enhance contaminant removal and reduce irreversible fouling of the TCM. This study provides fundamental insights into the role of tourmaline-modified surfaces in enhancing membrane filtration performance and fouling resistance, inspiring the development of high-performance, anti-fouling membranes.

Novel membrane bioreactor with iron-tannin-framework based membrane for effluent quality improvement and fouling control

A 10 L membrane bioreactor (MBR) was constructed with novel iron-tannin-framework ultrafiltration membrane (ITUM) for membrane fouling mitigation and effluent quality improvement. Compared to commercial ultrafiltration membrane (CUM) in the same MBR, ITUM exhibited hydrophilicity with a contact angle of 64.18° (71.36° for CUM), resulting the permeance of ITUM (50.2 L m-2h−2 bar−1) 1.8 times higher than CUM. During 70-day operation, ITUM was consistently run at lower transmembrane pressure. After operation, the polyethersulfone (PES) peak intensity of ITUM reduced less than 1 % (85 % for CUM), which indicated a thinner sludge layer on ITUM. Meanwhile, the average effluent chemical oxygen demand concentration for ITUM and CUM achieved 16.69 and 17.60 mg L-1 in stable phase, respectively. For NH4+-N, it could reach 0 and 0.04 mg L-1. 16 s RNA results showed that Saccharibacteria accounted for 1.48 % and 1.20 % on ITUM and CUM, respectively. According to first-principles density functional theory simulations, simulated adsorption energies was −1.330 eV for gram-positive bacteria (such as Saccharibacteria). It was −0.867 eV for Fe(Ⅲ) to gram-negative bacteria. It suggests that ITUM could easily attract microorganisms with the ability of polysaccharide degradation, while reducing this type of pollutants deposition on membrane. Therefore, the ITUM received a more superior effluent quality and membrane fouling resistance.

Synthesis of Responsive Membranes for Water Recovery through Desalination of Saline Industrial Effluents

Polysulfone (PSF) and smart polymers (SRPs)—including polyacrylic acid (AAc), poly N-isopropylacrylamide (NIPA), and sulfonated poly(1,4-phenylene ether-ether-sulfone) (SPEES)—were used in the synthesis of responsive membranes (PSF-SRP) for application in sustainable desalination processes involving food industry effluents for water recovery and recycling. With the inclusion of SRPs, PSF-SRP membranes showed different characteristics when compared to the PSF membrane. AAc caused fibers to occur in the surface structure, increasing the MWCO of the PSF membrane, whereas NIPA and SPEES diminished the MWCO, resulting in ultrafiltration and nanofiltration membranes. Furthermore, NIPA and SPEES provided high mechanical and thermal resistance when incorporated into the PSF membrane. The performance of the membranes also showed important changes. In comparison with only PSF, PSF-SPEES and PSF-NIPA increased the water flux and salt rejection percentage by 20–30%. In addition, the highest membrane fouling resistance was observed with PSF-NIPA, while PSF-AAc and PSF-NIPA-AAc presented the lowest resistances. Therefore, PSF-NIPA and PSF-SPEES resulted in membrane improvement, including stimuli-responsive properties, allowing for effective saline effluent treatment.

Study on efficiency and mechanism of ultrasonic controlling membrane fouling in ceramic membrane bioreactors.

In recent years, ceramic membranes have been increasingly used in membrane bioreactors (MBRs). However, membrane fouling was still the core issue restricting the large-scale engineering application of ceramic MBRs. As a novel and alternative technology, ultrasonic could be used to control membrane fouling. This research focused on the efficiency and mechanism of ultrasonic controlling membrane fouling in ceramic MBRs. The results showed that ultrasonic reduced the sludge concentration in MBR, and the average particle size of sludge was always in a high range. The sludge activity of the system was stable at 6-9 (mg O2·(g MLSS·h)-1), indicating that ultrasonic did not destroy the activity of microorganisms in the system. The extracellular polymer substance (EPS) of the ultrasonic group was slightly higher than that of the control group, while the soluble microbial product (SMP) content was relatively stable. The ceramic membrane of the ultrasonic group has a partial retention effect on the organic components. The application of ultrasonic slowed down the decrease of the hydrophilicity of the ceramic membrane. The main pollutants on the membrane surface exist in the form of aromatic and heteroaromatic rings, alkynes, and so forth. Ultrasonic removes the amide substances from the membrane surface. Membrane fouling resistance is mainly due to membrane pore blockage, accounting for 75.53%. PRACTITIONER POINTS: Enrich the research on the mechanism of ultrasonic technology in membrane fouling control. The MBR can still operate normally with ultrasonic applied. The time for the ceramic membrane to reach the fouling end point is 2.4 times that without ultrasonic. The main cause of membrane fouling was pore blocking, accounting for 75.53%.

Ta-Fe in-situ coating PES membrane and its application in oily wastewater treatment: Insight into modification and anti-fouling mechanisms

Membrane fouling is a serious problem that limits the widespread application of membrane technology. Herein, we propose an effective modification method by in-situ modifying polyethersulfone (PES) ultrafiltration membrane with tannic acid (TA) and Fe3+ chelates to improve its pollution resistance. The TA-Fe3+ complexes could deposit on the PES membrane surface and form a hydration layer by Van Der Waals force, hydrogen bonding force, and hydrophobic association. The modified membrane (PES\\TA\\Fe3+) had enhanced fouling resistance and membrane flux due to its dual advantages of abundant OH groups and favorable spatial structure. After modification, the roughness of membrane surface increased from 219 nm to 257 nm, and its water contact angle decreased from 58.9° to 26.5°, endowing the PES\\TA\\Fe3+ membrane with a strong resistance to oil droplets through electrostatic repulsion, steric hindrance effect, and hydrogen bonding force. Polyaluminum chloride-polydimethyldiallylammonium chloride (PAC-PDMDAAC) could alleviate 85 % membrane fouling resistance. PAC-PDMDAAC mainly mitigated irreversible membrane fouling by removing oil droplets and forming large and loose flocs. While the use of PES\\TA\\Fe3+ membrane mainly reduced the adsorption resistance and the resistance of membrane itself. The anti-fouling performance of PES\\TA\\Fe3+ membrane changed with pH owing to the changes in the properties of TA-Fe3+ complexes. The hydrophilic layer would be decomposed under alkaline conditions due to the deprotonation of TA and excessive hydrolysis of Fe3+. This study provides an efficient anti-fouling strategy and reveals the modification and anti-fouling mechanisms of the hydrophilic membrane, providing theoretical guidance for the further development of membrane technology.

Effects of coagulant bath temperature toward separation performance and antifouling properties of PVDF/CA membranes for filtration of dyes

Phase inversion is used to prepare poly(vinylidene fluoride) (PVDF) microfiltration membranes by combining it with the hydrophilic polymer additive cellulose acetate (CA). For the filtration of methylene blue (MB) and acid yellow 17 (AY17), the effects of coagulant bath temperature (CBT) on the separation performance and antifouling properties are thoroughly investigated. SEM analysis shows that the membrane at higher CBT has a larger pore diameter than at lower CBT, resulting in differences in membrane surface hydrophilicity. It is found that the increase in surface hydrophilicity causes the permeability of PVDF/CA membranes to be higher at higher CBT than at lower CBT. Rejection values above 90% indicate that the membranes are more effective for MB separation at both lower and higher CBT. Otherwise, lower CBT provides better AC rejection than higher CBT. The Flux Recovery Ratio, which is higher at higher CBT, remains in the 75–95% range at lower CBT. As a result, lower CBT is better for membrane fouling resistance than higher CBT. In addition, the fouling observed at lower CBT is similar to the fouling observed at higher CBT, but lower CBT has a higher percentage of reversible fouling than higher CBT. The membranes with more reversible fouling are therefore easier to clean using the backwashing process. As a result, PVDF/CA membranes manufactured at lower CBT have better separation performance and antifouling characteristics than those manufactured at higher CBT.

Selective ion permeation enables reduced combined gypsum-organic fouling of loose nanofiltration membranes

During the long-term operation of NF membranes, the occurrence of combined gypsum-organic fouling is a significant challenge. While numerous studies have focused on enhancing the fouling resistance of NF through various methods (e.g., antiscalants, pretreatment), there has been limited exploration into the correlation between its structural looseness and fouling resistance. Herein, we conducted an experimental study to evaluate the correlation by employing three NF membranes with different looseness degrees: a custom-developed loosely structured NF membrane (CLNF), the moderately loose NF270, and the tightly structured NF90. Our findings indicated that NF membranes with loose polyamide structure exhibited superior fouling resistance to gypsum scaling and combined gypsum-organic fouling, induced by model organic matters like bovine serum albumin (BSA), humic acid (HA), and sodium alginate (SA). After applying SA-coating to calibrate the surface properties of the membranes to exclude the influence of surface roughness, hydrophilicity, and functional groups, our study attributed the difference in fouling resistance to variations in ionic selectivity stemming from membrane looseness. Specifically, the primary advantage of looser polyamide NF membranes lies in enhanced Ca2+ permeation, which not only reduces the “egg-box” effect and surface foulant accumulation but also diminishes cake-enhanced concentration polarization, effectively mitigating gypsum-organic fouling. In real water testing scenarios, the enhanced fouling resistance of loose NF membranes was further affirmed. This research underscored the unexpected benefit of loose NF membranes in terms of fouling resistance, providing a novel insight for future application.

Novel dual-layer ZIF-71/PH-PSF electrospun nanofiber for robust membrane distillation

Membrane distillation (MD) is a promising technology for the treatment of hypersaline dyeing wastewater. However, commercial membranes still have limitations such as low permeate flux, membrane fouling, and membrane wetting issue in MD process. Herein, a dual-layer MD membrane was fabricated with a polysulfone (PSF) bottom layer and a poly(vinylidene fluoride-co-hexafluoropropylene) (PH) hydrophobic surface layer incorporated with ZIF-71 nanoparticles. The addition of ZIF-71 was optimized based on the results of surface morphology, contact angle, and MD performance. The incorporation of ZIF-71 nanoparticles into PH nanofiber membranes, along with their dual-layer structure, has led to notable improvements in both permeate flux and rejection performance. The fouling resistance of membrane was further evaluated with model dyeing wastewater as feed solution, which contained four types of dyes and heavy metal antimony. The MD performance of the optimized membranes was also measured with real dyeing wastewater as feed solution. The dual-layer membrane decorated with ZIF-71 nanoparticles significantly outperformed the pristine membrane in treating real dyeing wastewater, exhibiting potential for practical applications. Finally, the underlying mechanism on the improved permeate flux and rejection was elucidated systematically.

Photocatalytic Zinc Oxide Nanoparticles in Antibacterial Ultrafiltration Membranes for Biofouling Control.

Global water scarcity is a threat that can be alleviated through membrane filtration technologies. However, the widespread adoption of membranes faces significant challenges, primarily due to membrane biofouling. This is the reason why membrane modifications have been under increasing investigation to address the fouling issues. Antibacterial membranes, designed to combat biofouling by eliminating microorganisms, offer a promising solution. Within this study, flat sheet ultrafiltration (UF) membranes with integrated photocatalytic zinc oxide (ZnO) nanoparticles were developed, characterized, and assessed through filtration and fouling tests. The antibacterial properties of the membranes were conducted in static tests using Gram-negative bacteria-Escherichia coli-and natural tap water biofilm. The results demonstrated a notable enhancement in membrane surface wettability and fouling resistance. Furthermore, the incorporation of ZnO resulted in substantial photocatalytic antibacterial activity, inactivating over 99.9% of cultivable E. coli. The antibacterial activity persisted even in the absence of light. At the same time, the persistence of natural tap water organisms in biofilms of modified membranes necessitates further in-depth research on complex biofilm interactions with such membranes.

Surface modification of GO/PVDF composite membrane by MXene/protonated g‐C₃N₄ nanosheets hybrids with improved dye separation and antifouling properties

AbstractGraphene oxide‐polyvinylidene composite membranes were fabricated via the phase inversion technique. Then, GO‐PVDF membrane with highest water flux was achieved via surface modification with 2‐D MXene and 2‐D MXene /protonated 2‐D g‐C₃N₄ nanosheets hybrid via vacuum filtration of an aqueous dispersion of MXene and MXene‐protonated g‐C₃N₄ nanosheets hybrid, respectively, on GO‐PVDF membrane support to improve filtration efficiency and antifouling properties. The membranes were designated as MXene/GO‐PVDF (M2) and MXene‐protonated g‐C₃N₄/GO‐PVDF(M3). XRD, SEM, and FTIR analysis were used for characterization. The results showed that the performance of both MXene /GO‐PVDF and MXene‐ Pg‐C₃N₄/GO‐PVDF membranes was improved significantly in removing cationic dyes, unlike anionic pigments. Also, the resistance of these membranes against fouling has improved. The MXene‐ Pg‐C₃N₄/GO‐PVDF shows a significant enhancement in the removal of crystal violet (CV) cationic dye (100%) compared to the pristine membrane (84%) after 4 h of the filtration process. Tests also were performed to remove another two cationic dyes Methylene blue (MB), Rhodamine B (RB), and an anionic dye Methyl‐orange. The anionic dye separation rate from the stream did not show significant improvement while cationic dyes show significant enhancement in separation efficiencies. Modified membranes exhibit an enhancement of fouling resistance properties compared to pristine membranes.Highlights The water contact angle decreased from 71 to 45, which means hydrophilicity improved successfully. Membrane fouling resistance was improved around 15%–20%. PVDF membrane was prepared and graphene oxide was added to the matrix to modify the bulk properties. MXene and C3N4 were synthesized successfully. Surface modification of the PVDF membrane was successful by MXene and C3N4.

Coupling pretreatment of ultraviolet/ferrate (UV/Fe(vi)) for improving the ultrafiltration of natural surface water.

Ultrafiltration (UF) is a high-potential technology for purifying natural surface water; however, the problem of membrane fouling has limited its widespread application. Herein, ultraviolet (UV)-activated ferrate (Fe(vi)) was used to purify natural surface water and improve the performance of the UF membrane. The combination of UV and Fe(vi) could generate active species (Fe(v), Fe(iv), ˙OH and O2˙-) to degrade pollutants, while the in situ produced Fe(iii) had the effect of coagulation. With the above action, pollutants were removed, and the pollution load of natural surface water was reduced. After treatment with the UV/Fe(vi) system, dissolved organic carbon was reduced by 49.38%, while UV254 was reduced by 45.00%. The removal rate was further increased to 54.88% and 51.67% after UF treatment. In addition, the fluorescent organics were reduced by 44.22%, and the molecular weight of the organics became smaller. In the stage of UF, the terminal J/J0 was increased from 0.61 to 0.92, and the membrane fouling resistance was decreased by 85.94%. The analysis of the membrane fouling mechanism indicates that the role of cake filtration was weakened among all the mechanisms. Fourier transform infrared spectroscopy showed that less pollutants were accumulated on the membrane surface, and scanning electron microscopy revealed that the membrane pore blockage was relieved. In summary, the UV/Fe(vi) co-treatment process proposed in this study can significantly improve the purification efficiency of the UF systems in natural surface water treatment.

Insights into dynamic evolution of combined scaling-biofouling in reverse osmosis

Although extensive research has focused on individual membrane fouling, there is still a lack of studies regarding combined scaling-biofouling, which is more commonly encountered in practical membrane desalination processes due to the coexistence of inorganic scalants and microorganisms. To our best knowledge, it is the first study that elaborated the dynamic evolution of combined scaling-biofouling in the reverse osmosis (RO) cross-flow filtration process, compared with gypsum scaling and biofouling alone. The results indicated that scaling ions (35 mM CaCl2 + 20 mM Na2SO4) stimulated protein secretion but inhibited that of polysaccharide and total organic carbon (TOC). The gradually formed scaling layer evidently enhanced the hydrophilicity of the fouled membrane, and consequently improved the repulsion of membranes against microbes and the secreted extracellular polymeric substances (EPS), proved by the augmented energy barrier for microbial adhesion through XDLVO interfacial energy analysis, and resulted in the slower flux decline at the later stage of combined scaling-biofouling. In the other perspective, microorganisms and EPS diminished the (020), (021) and (041) facets of gypsum crystals, decreased the crystallinity and size of gypsum crystals, and thus prolonged the formation of inorganic scaling. It was suggested that scaling ions should be effectively controlled through pretreatment as they contributed to more rapid flux decline, as the cleaning efficiency of Ca2+ ions decreased from 84.8 % to 57 % after they combined with EPS, and thus chiefly contributed to reversible membrane fouling resistance. This study fills in the knowledge gap on interactions between gypsum scaling and biofouling during the formation of combined scaling-biofouling in RO filtration, which had significant environmental effects under the strict industrial wastewater discharge standards and zero liquid discharge (ZLD) requirements.

A comparison of micro-flocculation and ozonation as pretreatments for ultrafiltration: organic removal and membrane fouling.

Micro-flocculation and ozone were applied as pretreatments of ultrafiltration to treat sodium alginate (SA) and humic acid (HA) simulated water, respectively, to investigate the effects of different pretreatments of ultrafiltration (UF) on filtration flux and removal of organic matters. Regarding the SA simulated water, micro-flocculation helped to improve the dissolved organic carbon (DOC) removal efficiency highly, maximum DOC removal efficiency reached to 79.77%, due to the rejection of gel layer introduced by the alginate-aluminum complexes, but the gel layer had a negative impact on membrane flux. Compared with micro-flocculation, ozone as pretreatments had better ability to enhance the membrane specific flux, the maximum final specific flux remained as 0.786, larger than that of MF-UF process (0.574). Ozonation oxidizing SA into small organic molecules significantly reduced membrane fouling and filtration resistance, but also produced some dissolved organic matters hindering DOC removal of effluent. As for HA simulated water, both the micro-flocculation and ozone could effectively improve the specific flux, the final specific flux of MF-UF and ozone-UF were about 0.930, but MF-UF exhibited better DOC removal than ozone-UF, which avoided the introduction of additional dissolved organic matters.

Tailoring the microstructure of silver nanoparticle-intercalated graphene oxide membranes for desalination by pervaporation: Water permeation, membrane fouling, and antibacterial property

Low water flux has limited pervaporation (PV) from being applied in industrial-scale desalination. In this work, membranes embedded with silver nanoparticles (Ag NPs)-intercalated graphene oxide (GO) are proposed and prepared through two methods (self-assembly and blend) to improve membrane water permeation and fouling resistance. The Cs/Ag NP/GO@BM exhibited superior water permeation among the prepared membranes for the following reasons: 1) Water adsorption was improved by both the surface and interlamellar space of the blended matrix; 2) The intercalation effect of Ag NPs and looser stacking structure created more favorable diffusion pathways for water transportation. In the brine fouling test, the water flux of the membrane declined, while the fouling was reversible by NaOH cleaning with a high flux recovery rate (>97 %). Additionally, the Cs/Ag NP/GO@BM exhibited a remarkable antibacterial rate of 99.6 % against E. coli, benefiting from the synergistic inhibiting effect of GO and Ag NPs.

Enhanced membrane fouling by microplastics during nanofiltration of secondary effluent considering secretion, interaction and deposition of extracellular polymeric substances

Microplastic (MP) has been found to influence membrane fouling during microfiltration/ultrafiltration processes in direct and indirect ways by acting as fouling components and changing microbial activities, respectively. However, there is no relevant research about the contribution of MPs to nanofiltration membrane fouling. In this study, for the first time, the impacts of MPs on membrane fouling during the nanofiltration of secondary effluent (SE) were systematically investigated from the perspective of bacterial extracellular polymeric substances (EPS) secretion, their interaction with coexisting pollutants and also deposition. Membrane flux behaviors indicate that MPs simultaneously aggravated the short-term and long-term membrane fouling resistance of nanofiltration by 46 % and 27 %, respectively. ATR-FTIR, XPS and spectrophotometry spectra demonstrate that the deteriorated membrane fouling by MPs directly resulted from the increased accumulation of protein-like, polysaccharides-like and humic-like substances on membranes. EEM spectra further confirmed that MPs preferred to induce serious cake layers, which dominated membrane flux decline but hindered pore fouling. According to CLSM and SEM-EDS mappings, MPs in SE could stimulate microbial activities and then aggravate EPS secretion, after which their interaction with Ca2+ was also enhanced in bulk solution. The cross-linker nets could promote the deposition of other unlinked pollutants on membranes. Besides, MPs could weaken the rejection of certain dissolved organic matters (from 57 % to 52 % on the 50th day of filtration) by aggravating cake-enhanced concentration polarization (CECP), but improved the average removal of inorganic salts from 58 % to 63 % by improving their back diffusion through cake layers. Based on these analyses, the mechanisms of MP-enhanced membrane fouling during the nanofiltration of SE can be thoroughly revealed.

Novel insight into secondary effluent quality improvement and ultrafiltration fouling mitigation by UV/peracetic acid pretreatment

Ultrafiltration (UF) technology is widely used in the treatment for deep purification of municipal secondary effluent, however, the membrane fouling and low removal of N, P, and organic matter during actual operation have been the main bottlenecks limiting its wide-spread application. To address the above problems, this study employed peracetic acid (PAA) and UV/PAA to evaluate the effects of PAA-based pre-oxidation on ultrafiltration membrane fouling and secondary effluent water quality. The results demonstrated that the activated PAA pre-oxidation could prominently enhance the hydrophilicity of effluent organic matter, effectively destroy the high molecular weight organic matter and mineralize the low molecular weight organic matter. PAA and its metabolites, as well as the by-products of EfOM, increased the C/P ratio in water samples from 118 to 563 and the C/N ratio from 0.86 to 8.53. After UV/20 mg/L PAA pretreatment, the reversible and irreversible membrane fouling resistance significantly decreased by 55.97 % and 65.67 %, respectively. Moreover, the extended Derjaguin–Landau–Verwey–Overbeek (XDLVO) theory showed lower adhere potential of the foulants to the membrane surface. In general, UV/PAA as ultrafiltration pretreatment has a huge potential for secondary effluent treatment for membrane fouling mitigation and water quality improvement.

Role of Titanium Dioxide-Immobilized PES Beads in a Combined Water Treatment System of Tubular Alumina Microfiltration and PES Beads.

The membrane process has a limit to the decay of various pollutants in water. To improve the problem, the roles of backwashing media and titanium dioxide (TiO2) photocatalyst-immobilized-polyethersulfone (PES) beads' concentration were investigated in a combined system of tubular alumina MF and the PES beads for advanced drinking water treatment. The space between the outside of the MF membrane and the module inside was filled with the PES beads. UV at a wavelength of 352 nm was irradiated from outside of the acryl module. A quantity of humic acid and kaolin was dissolved in distilled water for synthetic water. Water or air intermittent backwashing was performed outside to inside. The membrane fouling resistance after 3 h process (Rf,180) was minimum at 30 g/L of the PES beads for water backwashing, and at 40 g/L for air backwashing when increasing the PES beads from 0 to 50 g/L. The irreversible membrane fouling resistance after physical cleaning (Rif) was at the bottom at 5 g/L of the PES beads for water backwashing, which was 3.43 times higher than minimal at 40 g/L of the PES beads for air backwashing. The treatment effectiveness of turbidity increased when increasing the PES beads' concentration from 0 to 50 g/L; however, it reached a maximum at 98.1% at 40 g/L and 99.2% at 50 g/L for water and air backwashing, respectively. The treatment effectiveness of UV254 absorbance, which was dissolved organic matter (DOM), increased dramatically when increasing the PES beads; however, it reached a peak of 83.0% at 40 g/L and 86.0% at 50 g/L for water and air backwashing, respectively. Finally, the best PES beads' concentration was 20~30 g/L to minimize the membrane fouling; however, it was 50 g/L to remove pollutants effectively. The water backwashing was better than the air at treating DOM; however, the air backwashing was more effective than the water at removing turbid matter and reducing membrane fouling.