Melting Method Research Articles

Improvement of the Technology of Melting of Low Alloy Steel Alloy in an Electric Arc Furnace

This article presents the optimal method of melting the 35XGCL (analog is JIS G 5111) low alloy steel alloy in DSP-2.0 2000 kg electric arc furnace. All the main stages of melting in an electric arc furnace are considered. In addition, analytical data on the study of the slag mode during the fluidization of the alloy are presented. The results of the evaluation of oxygen activity in metal depending on the chemical composition of slag oxidation and reduction cycles in the furnace are presented. Graphs of oxygen activity in the alloy depending on the total amount of iron, silicon, and manganese oxides in the slag are presented. Moreover, the effect of constant and additional deoxidizing aluminum content in the alloy on the impact strength of low alloy steel alloy is presented. The impact strength is improved when the constant aluminum content is in the range of 0.05-0.07%.

Effect of Nb and Zr Alloying Additives on Structure and Properties of Ti-Ta-Nb-Zr Alloys for Medical Applications

This work investigated two titanium-based alloys with a constant tantalum content and variable contents of alloy additives – niobium and zirconium. The Ti-30Ta-10Zr-20Nb (wt.%) and Ti-30Ta-20Zr-10Nb (wt.%) alloys were obtained using a combination of powder metallurgy and arc melting methods. The influence of alloying additives on the structure and properties of the Ti-Ta-Nb-Zr system was studied using, among others: X-ray diffraction and scanning electron microscopy. The X-ray diffraction confirmed the single-β-phase structure of both alloys. In addition, the microscopic analysis revealed that a higher amount of zirconium favoured the formation of larger grains. However, the microhardness analysis indicated that the alloy with the higher niobium content had the higher microhardness. Importantly, the in vitro corrosion study revealed that the addition of niobium promoted the better corrosion resistance of the investigated alloy.

Effect of Cu Additive on the Microstructure and Magnetic Properties of Fe-6.5wt%Si High Silicon Steel by Induction Melting Method

Fe-6.5wt%Si high silicon steel alloy was prepared using the vacuum induction melting method. Ordered phase formation in Fe-6.5wt%Si alloy was inhibited by adding trace Cu and induction cycle heating purification treatment. The microstructure and magnetic properties of high silicon steel were investigated. The results show that with the increase of Cu content, the alloy microstructure first changed from coarse grain to fine isoaxial crystal, followed by strip dendrite, with ordered cracking. The saturated polarization strength of the alloy decreased from 25.1 emu of the sample without adding Cu and heating once to 21.5 emu for seven cycles, the residual magnetic polarization increased from 0.0255 emu to 0.048 emu, the slope of the magnetization curve slowed down, and the coercive force increased from 2.4 Oe to 4.0 Oe. With the increase of cyclic heating times, the microstructure of the alloy without added Cu refined and transitioned from columnar to equiaxial crystals, from isoaxial dendrite to strip with the addition of 0.03 wt%Cu, and from strip to isoaxial structure with the addition of 0.05 wt%Cu. With the increase of cycle heating times, the saturation magnetization strength of the alloy without Cu and with 0.03 wt%Cu alloy increased, while the recalcitrant force reduced. Conversely, the saturation polarization strength decreased for the alloy with 0.05 wt% Cu, and the coercive force was also reduced.

Nano-Sized Graphene Cages Realize Highly Loaded “Solid-Solid” Process in Cathode Materials of Lithium Sulfur Batteries

Abstract The effects of polysulfide shuttle and volume expansion in lithium sulfur batteries limit their practical applications. In this work, a two-dimensional fabric with graphene cage interweaving was designed by the chemical vapor deposition method to resolve these issues. It has a large number of micropores, mesopores, and macropores. Sulfur was deposited in these pores by melting method to form sulfur/graphene complex. Polysulfides were confined within these pores, making them less likely to diffuse and shuttle. Graphene walls have strong flexibility and can alleviate the volume expansion effect during charge and discharge process. Sulfur/graphene complex as active materials were directly coated on aluminum foil by graphene oxide to build lithium-sulfur battery, where graphene oxide served not only as an adhesive but also as a conductive agent to improve the electrochemical performances of batteries. The lithium-sulfur battery had an initial capacity of 1400 mAh g-1 and high capacity retention (500 mAh g-1 after 200 cycles at 0.2 C rate). These results suggest that the reasonable design of material morphology for sulfur loading will effectively improve the performance of lithium sulfur batteries.

Influence of atomic substitution on the structural stability and half-metallicity of Fe2-xCrxCoSi (x = 0 to 1) alloys

Bulk Fe2-xCrxCoSi (x = 0, 0.25, 0.5, 0.75, and 1) Heusler alloys have been prepared by arc melting method. Alloys with 0.0 ≤ x ≤ 0.75 show a highly ordered phase pure XA structure. However, 17 % of an impurity (A15 phase) was detected in the alloy with x = 1. The saturation magnetization (Ms) and Curie temperature (TC) decreased linearly with an increase in Cr content for alloys with x ≤ 0.75. Ms measured at 5 K followed the Slater–Pauling rule for half-metals. Ab initio calculations with the GGA + U approach revealed that spin polarization (P) increased with an increase in Cr and eventually reached 100 % for the alloys with x = 0.5. Though Fe-Co disorder affects P, it is still high (>98 %) for alloys with x ≥ 0.5. Despite the smaller bandgap (0.61 eV) of Fe1.5Cr0.5CoSi than FeCrCoSi (0.91 eV), it has higher Ms, elevated TC, and 100 % P. These factors, coupled with the challenges associated with obtaining phase pure FeCrCoSi alloy, make Fe1.5Cr0.5CoSi a preferred candidate for spintronic device applications.

High cyan-emissive CsPbCl1.5Br1.5 quantum dots borosilicate glass modified by SrO

Currently, it has been found that white light emitting diode (WLED) lack cyan light, which not only hinders high-color-quality lighting applications but also results in an excess of blue light in WLED. In this work, cyan-emissive CsPbCl1.5Br1.5 quantum dots (QDs) were synthesized in a borosilicate glass matrix using a high-temperature melting method. The findings suggest that the increasing SrO leads to a looser glass network, which in turn intensifies phase separation, promotes the crystallization of QDs and enhances the intensity of cyan PL. Significantly, after a heating-cooling cycle, the cyan-emissive glass sample still retained 97% of its initial PL, suggesting that the synthesized sample exhibited good thermal stability. Finally, the prepared cyan-emissive QDs glass was incorporated into a WLED, effectively fills the lack of cyan light in 470-500 nm, showed a color rendering index (CRI) of 78 at a correlated color temperature (CCT) of 8300 K. This study provides an effective and convenient approach to enhancing the cyan luminescence performance of QDs, highlighting the significant application potential of cyan-emissive QDs glass in optoelectronic devices.

Microstructure Evolution and Mechanical Behavior of TiB-Reinforced Ti-6.5Al-2Zr-1Mo-1V Matrix Composites Obtained by Vacuum Arc Melting and Spark Plasma Sintering

Ti-6.5Al-2Zr-1Mo-1V/TiB metal matrix composites with 3 wt.% of TiB2 were obtained using vacuum arc melting and spark plasma sintering methods and compared with an unreinforced Ti-6.5Al-2Zr-1Mo-1V alloy. The microstructures of the unreinforced Ti6.5Al-2Zr-1Mo-1V alloy in the as-cast and as-sintered conditions were quite typical and consisted of colonies of α-lamellae embedded in the β matrix. The microstructure of the as-cast Ti-6.5Al-2Zr-1Mo-1V/TiB composite composed of TiB fibers randomly distributed within the two-phase α/β matrix, while the as-sintered composite had a network-like microstructure, in which areas of the two-phase α/β matrix were delineated by walls of TiB fibers. At room temperature, the yield strength of the as-cast and as-sintered Ti-6.5Al-2Zr-1Mo-1V alloy were 800 and 915 MPa, respectively, with a plasticity of 18% in both conditions. The addition of TiB fibers contributed to a ~40 and 50% strength increment, with values of 1100 and 1370 MPa for the as-cast and as-sintered composites, respectively. In the as-sintered composite, the strengthening effect reduced at 400 °C and almost disappeared at elevated temperatures of 800–950 °C. The as-cast composite showed much higher strength during warm and hot deformation—at 800–950 °C, the yield strength of the as-cast composite was 50% higher compared to the Ti-6.5Al-2Zr-1Mo-1V unreinforced alloy. A higher rate and degree of globularization were established for the as-cast composite compared to the unreinforced alloy. For the as-sintered composite, a noticeably lower rate and degree of globularization was shown. During hot compression of the as-cast composite, TiB fibers reoriented towards the metal flow direction, while the network microstructure formed in the as-sintered composite transformed into clusters of borides unevenly distributed within the matrix. Based on the obtained results, the apparent activation energy of plastic deformation was calculated, and the operating deformation mechanisms were discussed both for the as-cast and as-sintered composites. The Arrhenius flow stress model and the dynamic material model were used to evaluate the deformation behavior of composites beyond the experimentally studied temperatures and strain rates.

Minimizing CoxMn1-xO content in a Co2C catalyst for low CO2 selectivity in Fischer-Tropsch synthesis to olefins

The Co2C-based catalyst is a promising candidate for the Fischer-Tropsch to olefins reaction. However, it consistently exhibits high CO2 selectivity (∼40 %), and the origin of the high activity in the water–gas-shift reaction is not well-understood. In this study, Co2C catalysts constructed with the same elemental compositions but using the melting and co-precipitation methods resulted in drastic differences in CO2 selectivity − one at 3.8 % and the other at 35.3 %. A detailed structural study revealed that the presence of CoxMn1-xO instead of Co2C is responsible for the elevated CO2 selectivity. Interestingly, CoxMn1-xO alone demonstrates limited CO2 selectivity, but when promoted with Na, its WGSR activity is greatly enhanced. Conversely, the catalysts maintained consistently low CO2 selectivity even with improved Na content, as long as a high fraction of Co2C is present. This finding is important for designing Co2C-based catalysts that can achieve high olefin selectivity while minimizing undesirable CO2 emissions.

Sulphated zirconia on cyclodextrin nanosponge: A carbohydrate-based catalyst for conversion of mono-saccharides to 5-hydroxymethylfurfural

To expand the utility of cyclodextrin nanosponges for catalytic purpose, β-cyclodextrin nanosponge was prepared via melting method and then utilized as a catalyst support for the stabilization of sulphated zirconia. The resulting catalyst, denoted as CDNS-SO42−/ZrO2, was then applied as a heterogeneous acidic catalyst for conversion of fructose to 5-hydroxymethylfurfural. The results, underpinned that the catalytic activity of CDNS-SO42−/ZrO2, was superior to that of ZrO2 and SO42−/ZrO2, confirming the role of sulfonation of ZrO2 and immobilization of SO42−/ZrO2 on CDNS in catalysis. To optimize the reaction parameters and achieve maximum yield of the desired product, Response Surface Method that is an accurate procedure for appraising the impacts of the reaction variables was employed and it was found that using 35 wt% CDNS-SO42−/ZrO2 at 80 °C, HMF in 93 % yield was achieved in 45 min. Kinetic study also showed that the activation energy was 13.28 kJ/mol. Furthermore, thermodynamic parameters, i.e. enthalpy, entropy and Gibbs free energy were estimated as 10.46 kJ/mol, −150.40 J/mol and 63.58 kJ/mol respectively. Noteworthy, the catalysis was true heterogeneous, as confirmed by Hot filtration test and the catalyst could be recycled several times with low leaching of SO42−/ZrO2.

Phase evolution and mechanical properties of AlxCrTaTi refractory medium entropy alloys

In multi-principal refractory alloys (high-entropy alloys, medium-entropy alloys), the presence of the second phase has an important influence on the mechanical properties of the alloys. In this paper, AlxCrTaTi (x = 0, 0.25, 0.5, 1.0) refractory medium-entropy alloys were prepared by vacuum arc melting method, and the microstructure, density, and mechanical properties were investigated. The CrTaTi alloy consists of BCC dendritic and C15 Laves phases, whereas the AlxCrTaTi alloys consist of a two-phase eutectic organization (BCC phase and C14 Laves phase). With the increase of Al content, the content of the second phase increases from 15.97 % to 42.19 %, resulting in an increase in the yield strength of the alloy from 1491 MPa to 2354 MPa at 25 °C, and from 253 MPa to 426 MPa at 1000 °C. The addition of Al element changes the enthalpy, elemental distribution, and solidification process of the alloy, resulting in the formation of Cr-rich and Ti-rich two-phase eutectic organizations in the alloy. With the increase of Al, the second phase strengthening is the main reason for the enhancement of alloy properties.

Design and Development of Syringe Needle Destroyer Using Melting Method

Syringe needles are among the most commonly used medical tools in healthcare facilities across Indonesia, contributing significantly to medical waste. Improper disposal of syringe waste poses risks of disease transmission and potential misuse. Presently, small-scale beauty clinics resort to third-party waste management services due to the lack of incinerators. This research aims to develop a device capable of melting used syringe needles to ensure safe waste processing for both humans and the environment. Additionally, the objective is to create a low-budget needle destroyer, making it accessible to other healthcare services. The melting method is employed for needle destruction, utilizing a transformer to generate electrical current and heat. This approach offers ease of use and eliminates air, noise, and metal dust pollution. Through experimentation with various syringe sizes (1 cc, 3 cc, 5 cc, and 10 cc), it was found that melting times sequentially increase with needle size: 4 seconds for 1 cc, 5 seconds for 3 cc, 6 seconds for 5 cc, and 8 seconds for 10 cc syringes. This research contributes to sustainable healthcare waste management practices, ensuring safer and more affordable solutions for healthcare facilities

C3H7N6]3[B3O5(OH)2] and [C3H8N6]4[B12O19(OH)6]: Two Melamine Borates with Large Birefringence.

The π-conjugated [C3H6+xN6]x+ (x = 0-3) cations are good functional groups, which are widely employed in the preparations of nonlinear optical (NLO) and birefringent materials due to their high hyperpolarizability and optical anisotropy. In this paper, the first melamine hydroxyborate [C3H7N6]3[B3O5(OH)2] (MelBO-I) was synthesized by the boric acid melting method under the molar ratio of H3BO3:C3H6N6 = 1:1. MelBO-I (P21/c) exhibits a two-dimensional (2D) {[C3H7N6]3[B3O5(OH)2]}∞ layer composed of [C3H7N6]+ cations and [B3O5(OH)2]3- anions interconnected via hydrogen bonds. MelBO-I exhibits significant birefringence (Δn = 0.286@546 nm). Under the molar ratio of H3BO3/C3H6N6 = 3:1, [C3H8N6]4[B12O19(OH)6] (MelBO-II) was isolated. In MelBO-II (P21), highly polymerized [B12O19(OH)6]8- groups form a 3D network through hydrogen bonding, featuring 1D tunnels of 8-membered and 16-membered rings filled by [C3H8N6]2+ cations. MelBO-II is the first noncentrosymmetric (NCS) bifunctional melamine borate with a moderate SHG response (0.4 × KDP) and large birefringence (Δn = 0.285@546 nm). The results indicate that incorporating [C3H6+xN6]x+ (x = 0-3) cations into borate can effectively induce birefringence. A high concentration of boric acid promotes the formation of large boric acid cluster anions and facilitates the transformation from the CS to NCS structure.

Influence of ZnO content on liquid-liquid phase separation in photothermal refractive glass

At present, volume Bragg grating (VBG) is the core devices in the field of precision optical field modulation, and their performance is mainly influenced by the substrate photothermal refractive (PTR) glass. The liquid phase separation (LLPS) behavior occurring in the base glass can lead to unnecessary scattering losses and have adverse effects on the engineering applications of VBG. In recent years, many glass scientists have conducted research on the liquid-liquid phase separation (LLPS) of glass, believing that the structure of glass phase separation is related to the composition of the glass. This study used high-temperature melting method to prepare Na-Zn-Al-Si PTR glass doped with Ag, Ce, Sn and other elements through two-step heat treatment. In this experiment, the influence mechanism of ZnO on the LLPS of PTR glasses was investigated by controlling the doping amount of ZnO. Modern analysis techniques were used to investigate the mechanism of ZnO on the LLPS, the results confirm that no crystal phase is generated during the glass phase separation in this work, and doping 4 mol% ZnO is beneficial for suppressing the LLPS of PTR glasses. In addition, the introduction of Na2O by using NaNO3 can avoid the generation of Ag2O and Ag2CO3 impurities, which is conducive to the precipitation of NaF grains.

Monitoring of pyrethroid resistance in Aedes aegypti: first report of double and triple kdr mutations in Buenos Aires Province

BackgroundDengue is an emerging disease in Argentina due to the colonization of Aedes aegypti, the mosquito vector. Buenos Aires Province is the biggest and most populated district in Argentina, suffering dengue outbreaks of growing magnitude. During epidemic periods, pyrethroid insecticides are used in this country to control adult mosquitoes. Pyrethroid resistance in dengue vectors has been reported worldwide, making it necessary to implement resistance management strategies. The voltage-gated sodium channel is the target site of pyrethroids. Mutations in the gene encoding this protein, called kdr mutations, are usually the molecular cause of pyrethroid resistance in insects. In Ae. aegypti from the Americas, three kdr substitutions were described: V410L, V1016I, and F1534C. The diagnostic of kdr mutations is recommended for the early detection of pyrethroid resistance as well as the consequent planning of evidence-based control policies.MethodsWe distributed ovitraps across 16 localities in Buenos Aires Province, collecting 22,123 eggs. A total of 522 mosquitoes were genotyped in positions 1016 and 1534 of voltage-gated channel using multiplex high-resolution melting and/or TaqMan probe methods. A subset of 449 samples was also genotyped by a singleplex high-resolution melting method developed ad hoc and/or Sanger sequencing.ResultsWe have documented, for the first time to our knowledge in the central region of Argentina, the presence of the 1016Ikdr + 1534Ckdr allele. Additionally, our study reports the first identification of the V410L mutation in central Argentina. These results underscore a growing trend of pyrethroid resistance in Ae. aegypti, fueled by the widespread use of these insecticides.ConclusionsWe detected 1016Ikdr + 1534Ckdr and 410Lkdr mutations in central Argentina for the first time and improved the processivity and accuracy of kdr genotyping methods. The results are both a tool for resistance monitoring and a sign of alarm to direct efforts towards finding sustainable methods for vector control to complement or replace pyrethroids. Joint efforts between academia and authorities to develop and implement public policies for vector control are a productive way to transfer scientific results for their application in public health.Graphical

Effect of Solution Aging Heat Treatment on Tribological Properties of Selective Laser Melted WC/18Ni300 Composite

Different contents of WC particle‐reinforced 18Ni300 composites are prepared by selective laser melting method, and the tribological properties are comparatively studied before and after solution aging heat treatment. The results show that a part of WC particles are dissolved, and no obvious pore defects appear. With the increase of WC content, the microstructure gradually transforms from cellular and fine columnar α‐Fe martensite to γ‐Fe austenite. After solution aging heat treatment, the phase is transformed into acicular martensite. The grain size significantly decreases, and the Vickers hardness increases. The grain size decreases and the hardness increases with increasing WC contents. For the as‐built composite, the friction coefficient first decreases and then increases, and the wear rate first increases and then decreases with the increase of WC content. With WC content increasing, the wear rate first decreases and then increases. After heat treatment, the tribological properties are improved. The groove of the specimens before heat treatment is deep with large delaminated craters, and the wear mechanism is dominated by adhesive and abrasive wear. The grooves become shallower, and the adhesive trace becomes lighter after heat treatment. The wear mechanism is mainly adhesive wear and abrasive wear, accompanying with oxidative wear.

ISOLATING PURE SILICA FROM SYRIAN CLAY FOR BIOGLASS MANUFACTURING

One material that can be used in bone and soft tissue engineering is bioglass. By adhering to bone tissues and forming an apatite layer that further starts the biomineralization process, it can also encourage skin regeneration and wound healing in addition to playing a significant part in the healing processes of bone fractures.In this research, Syrian clay was used as a cheap silica source for preparation bioglass by melting method. Pure silica was isolated by mixing clay with sodium hydroxide in the following amounts (1:1), (2:1), (3:1), treated at different temperatures (700, 800, 900)˚C, treated with HCl solution, filtrated, dried, the yield reached to 96% with purity of 99% when clay was mixed with NaOH by (2:1) and treated at 800˚C. Bioglass was prepared using isolated silica according to thermal program, the formation of bioglass was confirmed by XRD, IR and biodegradability test, which confirmed formation of hydroxyapatite, on the surface which confirmed the biological effectiveness of the prepared bioglass.

Additively-manufactured lattice-grid sandwich cylinders and elastoplastic multi-failure analyses

Aluminum alloy lattice-grid sandwich cylinders, comprising a symmetric pyramidal truss core and open grid face-sheets, are additively manufactured using the selective laser melting method. The compression behaviors of these sandwich cylinders are investigated. Failure is controlled by three competing mechanisms: global buckling, core shear instability and grid buckling, with the active failure mode determined by the cylinder geometry and the material yield stress. Failure criteria are defined in terms of the effective elastoplastic properties of the grid-skins and core, which agree well with the measured and simulated failure responses, and are applied to generate multi-failure maps with cylinder geometrical parameters as axes. The maps help with failure load prediction and design optimization. For these cylinders, grid buckling is proposed as the dominant failure mode.

Opto-mechanical Synthesis and Radiation protection of Environmentally friendly Nd2O3-doped Ba-Ga-Al-B Glasses

A new Ba-borate glass doped with Nd2O3 was synthesized based on the BaO-Ga2O3-Al2O3-B2O3 composition. Al2O3 is partially replaced by Nd2O3 with 0, 0.5, 1, and 2 (mol%) concentrations. Glass samples were manufactured via traditional melting methods and were characterized based on XRD reflections, Archimedes' density principle, UV-Vis spectrum, Makishima-Mackenzie’s principle, and the free Phy-X/PSD-soft programmed. The produced samples are visibly clear and transparent, with an amorphous nature. The measured density ranged from 3.31 to 3.49 g/cm3, while molar volume was decreased with Nd2O3/Al2O3 substitution. Additionally, the OPD values ranged from 65.366 to 65.789 g atom/l, and the V0 values ranged from 15.298 to 15.200 cc/mol, introducing an inverse relationship. The results indicated that adding neodymium instead of alumina results in a very slight decrease in all calculated elastic moduli and their related parameters. The optical band gap (Eg) value was decreased with the introduction of Nd2O3 while the index of refraction (n) and the width of localized state (EUr) values have been increased. This would be expected due to the Eg is inversely proportion to the n and EUr values. Furthermore, the refraction loss (RL) molar refraction (Rm), and molar polarizability have been estimated. The findings obtained provided useful information regarding the radiation-shielding properties of the glasses under investigation. Additionally, they provide strong support for contemporary ideas of glass's structure and properties, which help create novel glass materials and their uses in radiation shielding.

Effects of Isocyanate Structure on the Properties of Polyurethane: Synthesis, Performance, and Self-Healing Characteristics.

Polyurethane (PU) plays a critical role in elastomers, adhesives, and self-healing materials. We selected the most commonly used aromatic isocyanates, 4,4'-methylene diphenyl diisocyanate (MDI) and tolylene-2,4-diisocyanate (TDI), and the most commonly used aliphatic isocyanates, hexamethylene diisocyanate (HDI), isophorone diisocyanate (IPDI), and dicyclohexylmethane-4,4'-diisocyanate (HMDI), as raw materials, combined with polytetramethylene ether glycol (PTMG) and 1,4-butanediol (BDO) to successfully synthesize five PU materials. The effects of isocyanate structure on polymerization rate, hydrogen bonding, thermal properties, phase separation, wettability, self-healing performance, adhesion, and mechanical properties were systematically investigated. The results show that isocyanates with higher symmetry facilitate hydrogen bonding, but excessive flexibility and crystallinity may inhibit its formation. MDI-based PU exhibits the highest hydrogen bonding index (HBI) of 4.10, along with the most distinct phase separation and the highest tensile strength of 23.4 MPa. HMDI-based PU demonstrates the best adhesion properties, with the highest lap shear strength of 7.9 MPa, and also exhibits excellent scratch healing ability. IPDI-based PU shows good self-healing performance, recovering 88.7% of its original tensile strength and 90.6% of its original lap shear strength after heating at 80 °C for 24 h. Furthermore, all the samples can be reprocessed by melt or solution methods, showing excellent recyclability.

Transparent and Thermally Stable Rare-Earth-Doped Luminescent Gallate Glass toward Passive Daytime Radiative Cooling Applications.

Currently, the implementation of passive daytime radiative cooling based on zero-energy cooling methodologies primarily focuses on polymers and composite materials, whereas the available literature on all-inorganic materials is relatively few. Here, we present a novel microcrystalline glass material CaGa0.5Al1.5O4 (CGAO), doped with rare-earth elements and prepared by the high-temperature melting method. This material exhibits long-term stability at 200 °C, coupled with an effective infrared radiation cooling function, demonstrating a 4.9 °C temperature reduction at solar noon. The energy transfer and luminescence mechanisms of Tb3+ and Sm3+ doped CGAO glass have been thoroughly investigated, along with thorough assessments of its thermal stability and hardness. The glass exhibits ultrahigh light transmission in the ultraviolet to near-infrared range, with the transmittance reaching 98% in specific spectral bands. Furthermore, it demonstrates superior luminescent thermal stability, retaining 85.6% and 71.2% of its initial luminescence intensity at 423 and 523 K, respectively. The high-temperature resistance and stability and long-term cooling properties render CGAO glass as an optimal candidate for integration into future energy-efficient and sustainable building designs.