Melting Mechanism Research Articles

Porphyry copper formation driven by water-fluxed crustal melting during flat-slab subduction

AbstractThe prevailing view of the formation of porphyry copper deposits along convergent plate boundaries involves deep crustal differentiation of metal-bearing juvenile magmas derived from the mantle wedge above a subduction zone. However, many major porphyry districts formed during periods of flat-slab subduction when the mantle wedge would have been reduced or absent, leaving the source of the ore-forming magmas unclear. Here we use geochronology and thermobarometry to investigate deep crustal processes during the genesis of the Late Cretaceous–Palaeocene Laramide Porphyry Province in Arizona, which formed during flat-slab subduction of the Farallon Plate beneath North America. We show that the isotopic signatures of Laramide granitic rocks are consistent with a Proterozoic crustal source that was potentially pre-enriched in copper. This source underwent water-fluxed melting between 73 and 60 Ma, coincident with the peak of granitic magmatism (78–50 Ma), porphyry genesis (73–56 Ma) and flat-slab subduction (70–40 Ma). To explain the formation of the Laramide Porphyry Province, we propose that volatiles derived from the leading edge of the Farallon flat slab promoted melting of both mafic and felsic pre-enriched lower crust, without requiring extensive magmatic or metallogenic input from the mantle wedge. Other convergent plate boundaries with flat-slab regimes may undergo a similar mechanism of volatile-mediated lower-crustal melting.

Understanding photo-thermal and melting mechanisms in optical charging of nano and micro particles laden organic PCMs

Engineering efficient optical charging process necessitates efficient photo-thermal energy conversion, transfer, as well as storage of the incident solar radiant energy. The present work is a determining step in deciphering, quantifying, and understanding the aforementioned steps involved in the optical charging of PCMs. Herein, the effect of particle size, concentration and thermochromism have been critically investigated. In particular, detailed optical characterization and photo-thermal experimentation pertinent to non-thermochromic nanoparticles laden PCM (referred to as NP-PCM) and thermochromic micro capsules laden PCM (referred to as TMCP-PCM) has been undertaken. Detailed optical analysis points out that opposed to NP-PCM, TMCP-PCM significantly scatter the incident radiations – the diffuse transmittance (at room temperature) in the two cases being approximately 2 % and 39 % respectively. Furthermore, whereas, optical properties of non-thermochromic nanoparticles are nearly invariant to temperature changes; in the case of thermochromic microcapsules, the magnitude of scattering further increases and diffuse transmittance reaches as high as 51 % at elevated temperatures. Although, thermochromism helps in enhancing the penetration depth at elevated temperatures, but, due to significant fraction of scattering, the photo-thermal energy conversion is not that effective. In terms of temperature field, spatial-temporal temperature distribution curves reveal that temperature spread (in the liquid phase) in case of optical charging of non-thermochromic particles (carbon soot nanoparticles) laden PCMs is significantly high (as high as approximately 24 °C) relative to that observed in case of thermochromic particles (microcapsules) laden PCMs (approximately, 4 °C). The magnitude of the temperature spread (being representative of the deviation from thermostatic optical charging) clearly points out that opposed to non-thermochromic laden PCMs, nearly thermostatic optical charging can be achieved in case of thermochromic particles laden PCMs.Furthermore, in case of optical charging without thermochromic assistance, the temperature spread, peak temperatures and the melting rates increase with increase in particles concentration. Whereas, in the latter case, although the temperature spread and peak temperatures are nearly independent; the melting rates do depend on the particles’ concentration. Overall, the present work is a significant step towards accelerated-thermostatic thermal energy storage.

A Novel Multiple Shape Memory Effect in PVDF‐Based Ferroelectric Copolymers and Terpolymers

AbstractShape memory polymers (SMPs) have been extensively investigated because of their wide range of biomedical and robot applications. In most of SMPs, only one temporary shape can be formed and recovered through the mechanism of melting or glass transition. Herein, a multiple shape memory effect (mSME), i.e., formation of at least two temporary shapes, can be realized in polyvinylidene fluoride (PVDF)‐based ferroelectric polymers by exploiting their expanded ferroelectric–paraelectric (F‐P) phase transition temperature range. Although P(VDF‐TrFE) (TrFE: trifluoroethylene) (55/45) copolymer is thought to be a normal ferroelectric, its ferroelectric phase transforms into a paraelectric phase through an intermediate relaxor ferroelectric‐like state and mSME is observed in this extended phase transition temperature range. By incorporating CTFE (chlorotrifluoroethylene) into P(VDF‐TrFE), P(VDF‐TrFE‐CTFE) becomes a relaxor ferroelectric with a further extended phase transition temperature range. The terpolymer exhibits improved mSME and at least three temporary shapes can be formed and recovered. A comparison of SME and structures of several PVDF‐based copolymer and terpolymers suggests that the amount of polar phase is a critical factor affecting the SME. This study not only demonstrates mSME in ferroelectric polymers, which expands their application potential, but also provides an in‐depth understanding of the shape memory mechanism of the polymers.

How bacteria initiate DNA replication comes into focus.

The ability to initiate DNA replication is a critical step in the proliferation of all organisms. In bacteria, this process is mediated by an ATP-dependent replication initiator protein, DnaA, which recognizes and melts replication origin (oriC) elements. Despite decades of biochemical and structural work, a mechanistic understanding of how DnaA recognizes and unwinds oriC has remained enigmatic. A recent study by Pelliciari etal. provides important new structural insights into how DnaA from Bacillus subtilis recognizes and processes its cognate oriC, showing how DnaA uses sequence features encoded in the origin to engage melted DNA. Comparison of the DnaA-oriC structure with archaeal/eukaryl replication origin complexes based on Orc-family proteins reveals a high degree of similarity in origin engagement by initiators from di domains of life, despite fundamental differences in origin melting mechanisms. These findings provide valuable insights into bacterial replication initiation and highlight the intriguing evolutionary history of this fundamental biological process.

A hybrid mesoscale-continuum approach to understand and predict melting kinetics of Al powders during laser processing

Abstract Laser interaction with metallic powders during additive manufacturing (AM) leads to fast heating and cooling rates that can affect the quality of the final products due to the formation of defects. One of the first steps towards predicting microstructures generated during AM, therefore, requires an accurate understanding of the laser energy deposition mechanisms that determine the melting kinetics at the level of individual powders. The critical challenge, however, is the availability of computational methods that can model the laser energy absorption, heat transfer, and the related microstructure evolution in individual metal powders at the length and time scales of AM. This manuscript demonstrates the capability of a novel scale-bridging methodology that combines the mesoscale quasi-coarse-grained dynamics (QCGD) simulations with a continuum two-temperature model (TTM) to account for the atomistic mechanisms of laser energy deposition and microstructure evolution and predict the kinetics of melting of individual powders at the experimental time and length scales. The scale-bridging capability of the hybrid QCGD-TTM simulations is demonstrated here by investigating the laser-induced microstructure evolution in aluminum powders with various sizes ranging from 200 nm to 20 µm. The analysis of the evolution of temperature, pressure, phase fraction, and melt fronts suggests the melting mechanism is heterogeneous due to the interaction with a laser, and the melting time is observed to decrease exponentially as the laser intensity increases. The solid-liquid interface velocity can be quantified to identify correlations with interface temperatures, and the predicted values satisfy the theoretically reported limits of crystal stability of metals against homogeneous melting. In addition, the pre-melting is found at the grain boundaries of 20 µm polycrystalline aluminum powder, while a minute contribution to melting is observed. This manuscript demonstrates the capability of the QCGD-TTM method to capture laser-powder interaction and allow the investigation of the kinetics of laser melting.

Morphodynamics of melting ice over turbulent warm water streams

We investigate the morphodynamics of an ice layer over a turbulent stream of warm water using numerical simulations. At low water speeds, characteristic streamwise undulations appear, which can be explained by the Reynolds analogy between heat and momentum transfer. As the water speed increases, these undulations combine with spanwise ripples of a much greater length scale. These ripples are generated by a melting mechanism controlled by the instability originating from the ice–water interactions, and, through a melting/freezing process, they evolve downstream with a migration velocity much slower than the turbulence characteristic velocity.

Research on Process Characteristics and Properties in Deep-Penetration Variable-Polarity Tungsten Inert Gas Welding of AA7075 Aluminum Alloy

In this study, a new deep-penetration variable-polarity tungsten inert gas (DP-VPTIG) welding process, which is performed by a triple-frequency-modulated pulse, was employed in the welding fabrication of 8 mm AA7075 aluminum plates. The electric signal, arc shape, and weld pool morphology of the welding process were obtained by means of high-speed photography and an electric signal acquisition system under varying parameters of the intermediate frequency (IF) pulse current. The principle of the arc characteristics and the dynamic mechanism of the weld melting during the process are explained. In addition, the macroforming, microstructure, and microhardness of the welded joints were investigated. The results indicate that, with an intermediate frequency pulse of 750 Hz, the arc displayed a higher energy density and a more effective arc contraction, which improved weld appearance and penetration. Moreover, the impact and stirring action of the arc refined the microstructure grains of the weld center. Therefore, this new welding method is feasible for welding medium-thickness aluminum alloy plates without a groove.

Influence of Laser Power and Rotational Speed on the Surface Characteristics of Rotational Line Spot Nanosecond Laser Ablation of TC4 Titanium Alloy.

The TC4 titanium alloy is widely used in medical, aerospace, automotive, shipbuilding, and other fields due to its excellent comprehensive properties. As an advanced processing technology, laser processing can be used to improve the surface quality of TC4 titanium alloy. In the present research, a new type of rotational laser processing method was adopted, by using a beam shaper to modulate the Gaussian spot into a line spot, with uniform energy distribution. The effects of the laser power and rotational speed on the laser ablation surface of the TC4 titanium alloy were analyzed. The results reveal that the melting mechanism of the material surface gradually changes from surface over melt to surface shallow melt with the increase in the measurement radius and the surface roughness increases first, then decreases and, finally, tends to be stable. By changing the laser power, the surface roughness changes significantly with the variation in the measurement radius. Because low laser power cannot provide sufficient laser energy, the measurement radius corresponding to the surface roughness peak of the microcrack area is reduced. Under a laser power of 11 W, the surface roughness reaches its peak when the measurement radius is 600 μm, which is 200 μm lower than that of a laser power of 12 W, 13 W, and 14 W. By changing the rotational speed, the centrifugal force generated by the rotation of the specimen affects the distribution and re-condensation of the molten pool of the surface. As the rotational speed increases, the shallow pit around the pit is made shallower by the filling of the pit with molten material and the height of the bulge decreases, until it disappears. The surface oxygen content of the material increases first and then decreases with the increase in the measurement radius and gradually approaches the initial surface state. Compared with a traditional laser processing spot, the rotational line spot covers a larger processing area of 22.05 mm2. This work can be used as the research basis for rotational modulation laser polishing and has significance for guiding the innovative development of high-quality and high-efficiency laser processing technology.

Low temperature carbonization and synergistic flame retardancy of cotton fabric coated by phosphorus‑nitrogen flame retardants

To solve the problems of flammability and smoldering of cotton fabric, its flame-retardant finishing was executed with biomass wool keratin (WK) and cyclic phosphate ester (CPE) through the soaking and baking process. The synergistic mechanism of WK low-temperature melting and CPE catalytic dehydration prompted the formation of protective carbonization layer on cotton fabric surface, and this protective layer reduced its pyrolysis rate, inhibited the production of combustible materials and improved its flame retardancy. The results of synchronous thermal analysis indicate that the initial decomposition temperature of WK and CPE is lower than that of cotton fabric, and they precede the endothermic degradation before fabric main body. This effectively promotes the low-temperature carbonization of cotton fabric and inhibits its pyrolysis. The initial decomposition temperature of WK/CPE treated fabrics advances by 47.9 °C–97.8 °C, presenting significant low-temperature carbonization trend. Moreover, they form 3.0 %–20.0 % aromatic structural char before the pyrolysis of cotton cellulose due to the low-temperature dehydration and carbonization reactions. The damage length after vertical burning is only 4.0 cm for treated fabric with five layers, its after-flame and smoldering disappear, and its limiting oxygen index value increases to 28.7 %. This research provides an effective idea for the flammability and smoldering problems of cotton fabric.

Evolution of liquid phase during homogenous non-equilibrium melting of Ta at superheating temperature.

Homogenous melting at superheating temperature is commonly described by classical nucleation theory (CNT), but the atomic mechanism of the formation and development of critical liquid nuclei is still unclear. Molecular dynamics simulations were conducted to analyze the melting process of Ta. It is found that the process of subcritical liquid clusters evolving into critical liquid nucleus occupies most of the melting time, and merging between neighboring liquid clusters is the main path for subcritical liquid clusters to grow in size. Total melting time is strongly affected by the distribution of formation sites of subcritical liquid clusters, which has been considered random in homogenous melting. This work depicts a clear picture of the formation and development of liquid phase during the homogeneous melting process at superheating temperature and suggests an internal factor of melting mechanism.

Simulation of melting characteristics of thermal washing of the wax layer in the pipeline based on lattice Boltzmann method

ABSTRACT The escalation of transportation costs and the obstruction of pipelines due to wax deposition significantly impact the secure and efficient production of oil fields. The thermal washing method, characterized by its simplicity and cost-effectiveness, is widely employed for dewaxing crude oil gathering pipelines. The investigation of the melting mechanism of the wax layer during thermal washing is extremely important. In this paper, the two-zone composite model of multiphase flow-porous medium in the mushy zone is introduced into the solid-liquid phase change lattice Boltzmann model based on the enthalpy method, and the problem of circumferential inhomogeneity in the melting of the wax layer and the important influence of flow and heat transfer in the mushy zone on the thermal washing are systematically investigated. The demarcation point (γ tr) between the high and low liquid fraction zones is measured to be 0.81 by microscopic experiment. The impacts of varying γ tr and Ste numbers on wax melting at different circumferential locations are analyzed in detail. The results show that the melting efficiency of wax exhibits a nonlinear enhancement from − 90° to 90°. The melting efficiency of wax decreases with increasing γ tr for wax layers between 90° and − 45°. The melting efficiency of wax increases with higher Ste numbers at all angles. The Ste number increases from 0.42 to 5.0, and the melting efficiency of the wax layer at angles ranging from 90° to − 90° increases by factors of 2.16, 2.16, 2.20, 2.61, and 3.33 respectively. The growth of the Ste number improves the warming rate and shortens the generation time of convection at the center point of the wax layer. The research findings serve as a fundamental reference for formulating a rational and efficient thermal washing scheme.

The petrogenesis of Cenozoic basalts from Daihai, western North China Craton: Constraints from 40Ar-39Ar chronology, major and trace elements, and Sr-Nd-Pb-Hf isotopes

The Daihai Cenozoic intraplate basalts are distributed in the western North China Craton (NCC), which is a part of the Cenozoic volcanic province in eastern China, and they are all alkaline basalts. The fine-scale determination of their mantle source region properties, partial melting mechanisms, and petrogenesis can provide crucial information for exploring lithospheric destruction and thinning in the western NCC. 40Ar-39Ar dating of potassium feldspar grains from the Daihai alkaline basalts yielded plateau ages of 18.22 ± 1.84 Ma and 26.86 ± 0.72 Ma, indicating that the Daihai basalts underwent multiple eruptive cycles during the Late Oligocene-Middle Miocene. These basalts exhibit ocean island basalt (OIB)-like geochemical features and were subjected to negligible crustal contamination. Moreover, basaltic magmas underwent intense fractional crystallization of olivine and clinopyroxene. The geochemical differences in the Daihai basalts were controlled by partial melting. The Daihai basaltic magmas were composed of at least two types (type I-enriched mantle and prevalent mantle) of mantle end-members that partially melted and then mixed, and the lithology of the mantle source region was predominantly peridotite. Under enriched mantle conditions, the mixing of garnet lherzolite partial melts (<1%) and spinel lherzolite partial melts (2-5%) can reasonably explain the elemental variations characteristic of the Daihai basalts. Most importantly, the melting depth and lithospheric thickness of the Daihai basalts were < 70 km or even close to 50 km, implying that the western NCC underwent lithospheric destruction and thinning during the Cenozoic. However, these effects were spatially heterogeneous. The most plausible genetic mechanism for the generation of the Daihai basalts was the coupled effects of subduction of the Pacific slab and subduction–collision of the Indo–Eurasian Plate since the Oligocene. The mantle flows generated by these two events convected, blocked and triggered upwelling mantle flows at the eastern margin of the Ordos Block. The upwelling mantle flows resulted in frequent magmatism in the region.

Geochemical Evidence of Water-Fluxed Crustal Melting in the Northern Colombian Andes

Abstract The compositions of crustal magmas are powerful tools for understanding the formation and differentiation of continents. However, the geochemical fingerprints that distinguish the two dominant mechanisms of crustal melting, namely dehydration and water-fluxed melting, are still controversial. To provide new insights into this problem, we discuss the petrogenesis of the Paipa Volcanic Complex (PVC), an isolated Quaternary volcanic field in the Colombian Eastern Cordillera. The PVC is characterized by peraluminous trondhjemite-like rhyolites with exceptionally high Na2O contents (~6 wt %), super-chondritic Nb/Ta (~27), elevated Sr/Y ratios (~120), spoon-shaped REE patterns, and enriched isotopic compositions that overlap with those of the local basement. They also exhibit high pre-eruptive H2O contents (~up to 9.5 wt %) and abundant Paleozoic zircon inheritances. We demonstrate that these characteristics are inconsistent with a process of intra-crustal differentiation from a mafic or intermediate mantle-derived precursor. Instead, we propose that the origin of the PVC is best explained by melting the local (meta)sedimentary basement under H2O-saturated conditions, at middle-crustal pressures (~1.3 GPa) and relatively low temperatures (~690–740°C), following the complete breakdown of plagioclase and biotite, and the formation of reactive peritectic amphibole. This scenario differs from the high-temperature dehydration melting conditions that have been widely proposed for the Andes and globally, which result in the production of water undersaturated magmas in equilibrium with anhydrous lithologies rich in plagioclase and/or garnet. Accordingly, we speculate that an external H2O flux was ultimately sourced from a buoyant, cold, and hydrated mantle wedge that was extensively metasomatized by fluids derived from the Nazca and Caribbean flat-slab fronts. These conditions depressed the asthenospheric mantle potential temperature, likely inhibiting mantle melting. In turn, they facilitated the infiltration and ascent of mantle-derived H2O through pre-existing crustal faults and shear zones. Our results indicate that water-fluxed melting could be a plausible mechanism for generating crustal magmas in orogenic regions where the availability of free H2O has been difficult to confirm.

In situ high temperature transmission electron microscopy on melting mechanism of secondary copper smelting slag

A new technique for investigations in nano-scale is applied to secondary copper smelting slag with the aim to understand melting mechanism and phase development within the material: in situ transmission electron microscopy at high temperatures. Heating the material step by step with accompanying EDX analysis allows detailed tracking of phase transformations, including changes in chemical composition. The behavior of Cu nano-spheres as well as Fe and Zn in different phases is described in detail. Evaporation of Cu, Fe and Zn is compared to available thermodynamic data, showing relatively good agreement for Cu and Fe, but different results for Zn. The observation of liquid Fe formation is a new phenomenon, which needs further investigation. High temperature transmission electron microscopy is found to be a suitable method for certain research questions, when taking limiting factors like vacuum conditions and electron beam effects into account.

Corrosion behavior and mechanism of alkaline melt on aluminosilicate materials containing B4C powder

Alkali attack to refractory lining of the incinerator will severely decrease its service life. Utilizing high viscosity phase produced in refractory to suppress corrosion of molten salt is an important method. In this study, 1 wt%, 1.5 wt% and 2 wt% B4C powder were respectively introduced into aluminosilicate material, its effect on the microstructure and property of the material were analyzed and discussed. The static crucible method used K2CO3 as corrosion flux was employed to conduct corrosion experiments at 1000 °C. The results show that the B2O3 glass layer is formed in the surface of the specimens due to B4C oxidation. It inhibits O2 infiltration and causes different structure between the inner and outer layers. The high viscosity B2O3 can inhibit penetration of molten salts by adhesion effect. The penetration resistance will be improved with increase of B4C content, and 2 wt% B4C demonstrates excellent effect.

Drivers of the Extreme Early Spring Glacier Melt of 2022 on the Central Tibetan Plateau

AbstractExtreme glacier melt has important implications for climate change studies and glacier‐related hazards. Few attempts have been made to study the characteristics and mechanisms of extreme melt on the Tibetan Plateau (TP) and surroundings, one of the largest concentrations of glaciers beyond the polar regions. To address this gap, we investigated the magnitude and possible drivers of anomalous early spring glacier melt in 2022 on the central TP using multi‐source observations (October 2020–July 2022) of Kuoqionggangri and Sangqu glaciers and an energy and mass balance model. Our results show that anomalous melt of both glaciers occurred in early spring (18 March–10 April 2022), when glaciers are traditionally expected to be frozen. There were 89 cumulative hours with air temperatures above 0°C, with a positive cumulative air temperature of 121.80°C hour at 5,700 m on Kuoqionggangri Glacier. The glacier‐wide cumulative melts on Kuoqionggangri and Sangqu glaciers from 18 March to 10 April 2022 were 22 ± 14.2 and 48 ± 37.5 mm w.e., respectively. Such anomalous glacier melt was driven by high incoming shortwave radiation and sensible heat flux, which were influenced by low cloud fraction and precipitation, and high air temperature during early spring. The weakening and northward‐shift of the westerlies, coupled with descending air motions over the central TP, reduced cloud fraction and hindered the transport of cold, moist air to the central TP. These changes occurred both in the central TP and the Himalaya, indicating the influence of macroscale atmospheric circulation patterns on this extreme glacier melt.

Magnesium-containing pellet regulating blast furnace ferrous burden interaction: softening–melting behavior and mechanism

Magnesium-containing pellet regulating blast furnace ferrous burden interaction: softening–melting behavior and mechanism

Structural pathways for ultrafast melting of optically excited thin polycrystalline Palladium films

Due to its extremely short timescale, the non-equilibrium melting of metals is exceptionally difficult to probe experimentally. The knowledge of melting mechanisms is thus based mainly on the results of theoretical predictions. This work reports on the investigation of ultrafast melting of thin polycrystalline Pd films studied by optical laser pump – X-ray free-electron laser probe experiments and molecular-dynamics simulations. By acquiring X-ray diffraction snapshots with sub-picosecond resolution, we capture the sample's atomic structure during its transition from the crystalline to the liquid state. Bridging the timescales of experiments and simulations allows us to formulate a realistic microscopic picture of the crystal-liquid transition. According to the experimental data, the melting process gradually accelerates with the increasing density of deposited energy. The molecular dynamics simulations reveal that the transition mechanism progressively varies from heterogeneous, initiated inside the material at structurally disordered grain boundaries, to homogenous, proceeding catastrophically in the crystal volume on a picosecond timescale comparable to that of electron-phonon coupling. We demonstrate that the existing models of strongly non-equilibrium melting, developed for systems with relatively weak electron-phonon coupling, remain valid even for ultrafast heating rates achieved in femtosecond laser-excited Pd. Furthermore, we highlight the role of pre-existing and transiently generated crystal defects in the transition to the liquid state.

Copper isotopes track the Neoproterozoic oxidation of cratonic mantle roots

The oxygen fugacity (fO2) of the lower cratonic lithosphere influences diamond formation, melting mechanisms, and lithospheric evolution, but its redox evolution over time is unclear. We apply Cu isotopes (δ65Cu) of ~ 1.4 Ga lamproites and < 0.59 Ga silica-undersaturated alkaline rocks from the lithosphere-asthenosphere boundary (LAB) of the North Atlantic Craton to characterize fO2 and volatile speciation in their sources. The lamproites’ low δ65Cu (−0.19 to −0.12‰) show that the LAB was metal-saturated with CH4 + H2O as the dominant volatiles during the Mesoproterozoic. The mantle-like δ65Cu of the < 0.59 Ga alkaline rocks (0.03 to 0.15‰) indicate that the LAB was more oxidized, stabilizing CO2 + H2O and destabilizing metals. The Neoproterozoic oxidation resulted in an increase of at least 2.5 log units in fO2 at the LAB. Combined with previously reported high fO2 in peridotites from the Slave, Kaapvaal, and Siberia cratonic roots, this oxidation might occur in cratonic roots globally.

Fretting wear behavior and wear mechanism of selective laser melting IN738LC alloy with various loads and micro-structures

In this study, the ambient temperature fretting wear behavior and the wear mechanisms of the Selective Laser Melting prepared IN738LC alloy with various micro-structures were systematically investigated under varying load conditions (35 N, 100 N). The results indicate that the running states of fretting gradually transitions from the gross slip regime (GSR) to the mixed slip regime (MSR) as the load increases. The HT-2 samples (Unimodal precipitation, hardness 512 HV) present more fine homogeneous and dense secondary γ′ phase compared with HT-1 (Bimodal precipitation, hardness 487 HV) and As-built (No precipitation, hardness 392 HV) counterpart, which result in excellent wear resistance. The main fretting wear mechanisms for all samples were oxidation wear, abrasive wear, fatigue wear.