Meguma Terrane Research Articles

New constraints on the timing and nature of metamorphism in the eastern Meguma terrane, Nova Scotia, Canada

The Meguma terrane in Nova Scotia consists mainly of Cambrian to Ordovician metasedimentary rocks intruded by abundant peraluminous granite, granodiorite and minor diorite-tonalite-plutons between ca. 380 Ma and 360 Ma. The metasedimentary rocks were variably metamorphosed to greenschist- to amphibolite- facies during the early Devonian. In the eastern Meguma terrane, the regional M1 chlorite- and biotite- zone assemblages are overprinted by two types of high-temperature low-pressure M2 metamorphism. In contact aureoles around plutons the regional M1 assemblages are overprinted by cordierite- and andalusite-bearing M2 contact metamorphic assemblages, and away from plutons chlorite-bearing, (or biotite-bearing) regional M1 assemblages are overprinted by staurolite-, garnet-, and/or cordierite-bearing M2 regional assemblages that represent metamorphism driven by a regional elevated thermal gradient. The interpreted metamorphic conditions in the eastern Meguma terrane range from ca. 480 – 550 °C and pressures below 2.5 kbar up to 550 – 650 °C with pressures between 4 and 5 kbar. Based on a new garnet Lu-Hf age, regional metamorphism was ongoing at ca. 372 Ma, hence broadly coeval with pluton emplacement. Metamorphism and pluton emplacement took place in a largely transpressional tectonic setting during the collision of the Meguma terrane with Avalonia. After pluton emplacement, peak metamorphic assemblages were variably overprinted with retrograde chlorite and sericite M3 assemblages while deformation continued. Regional structures were transposed into a composite transposition foliation as a result of continued motion along the terrane-bounding Minas Fault Zone and associated ductile shear zones.

Devonian plutons in the eastern Meguma terrane, Nova Scotia, Canada: zircon U–Pb, Lu–Hf, and O isotopic compositions, age, and petrogenetic implications

Abundant granitic plutons intruded the eastern Meguma terrane of Nova Scotia in the middle- to late Devonian. Less voluminous diorite–tonalite and gabbro intrusions are associated with the granitic plutons along the northern margin of the terrane adjacent to the Cobequid–Chedabucto fault zone. All plutons contain metasedimentary xenoliths, and the mafic plutons show magma mingling textures with their adjacent granitic plutons. New U–Pb zircon data from autocrystic zircon in 13 samples indicate coeval emplacement of mafic and granitic plutons between ca. 382 and 368 Ma. However, the zircon grains contain numerous inherited domains that range in age from Palaeoproterozoic to Devonian. These inherited ages correspond to detrital zircon U–Pb dates from the Cambrian to Ordovician metasedimentary host rocks. Zircon oxygen isotopic data (δ18O) are between +7.4 ± 0.2‰ and +9.3 ± 0.3‰ indicating significant involvement of the crust as the magma source or contaminant. If the high δ18Ozrn values are a result of contamination, the contaminant was likely the metasedimentary rocks of the Meguma terrane. Hafnium isotopic data from autocrystic zircon have εHf( t) between −6.0 ± 1.5 and +2.1 ± 2.5. The new zircon U–Pb, O, and Hf isotopic data from plutons in the eastern Meguma terrane are indistinguishable from published data from the South Mountain Batholith. The data suggest that Devonian magmatism in the Meguma terrane post-dated the main orogenic event that caused folding and regional metamorphism and involved the same magma source and/or contaminants throughout the terrane.

Conjugate shear model for emplacement of mid-crustal plutons during dextral transpression, southern Nova Scotia, Canada: tectonic and petrological consequences

The South Mountain Batholith (SMB) is a syn-tectonic composite batholith emplaced in the upper crust within the Meguma terrane between 380 and 370 Ma during the later stages of the Neoacadian orogeny. Coeval plutons in southern Nova Scotia are surrounded by mid-crustal (∼4 kbar) andalusite–staurolite aureoles and are discordant to northeast-trending, regional Neoacadian folds. Detailed field studies, combined with published results, indicate emplacement within a dextral transpressional regime during the transition from distributed (D1) to focused heterogeneous strain (D2), which provided vertical conduits that facilitated magma ascent. The Port Mouton Pluton intruded along P-orientated crustal-scale fractures as a series of subvertical granitic sheets, which were progressively rotated and folded with ongoing dextral shearing. By contrast, the Barrington Passage Pluton intruded between crustal-scale, antithetic (sinistral) P-shear fractures and spread laterally between them as pulsed increments to form a layered, subhorizontal, and sill-like complex resembling the laccolithic structure of the SMB. The SMB was emplaced below the Meguma Supergroup, with magma derived from underthrust Avalon terrane and Silurian Rockville Notch Group. The lack of mantle components in the SMB suggests transpressional orogenesis facilitated conductive crustal heating without significant mantle addition, consistent with low p-wave velocities of Meguma lower crust. 400–355 Ma zircons, recorded either as inherited grains in granites or in felsic granulite xenoliths, imply the Neoacadian thermal anomaly extended for 45 Ma, but magmatism represented only ∼40% of that perturbation.

Geological interpretation of wide-angle seismic reflection/refraction profiles along the Scotian margin and across Nova Scotia, Canada

Two wide-angle seismic reflection/refraction profiles were acquired to determine the velocity characteristics of the Meguma terrane and adjacent Avalonia northeast of the Cobequid-Chedabucto Fault Zone (CCFZ) in eastern Canada. Line 99–1 is located along the Scotian margin whereas line 99–2 crosses the Scotian margin and onshore Nova Scotia and extends into the Gulf of St. Lawrence. Velocity models were derived by forward modelling of travel times. P-wave velocities of 5.5–6.0 km/s and 6.0–6.4 km/s are interpreted to be metasedimentary rocks of the Goldenville and Halifax groups and granitic rocks, respectively. This inference is based on comparison with laboratory velocities of a suite of rock samples, offshore sampling, links to onshore geology with multibeam bathymetry, and gravity modelling. On both lines a low velocity zone (LVZ) >350 km wide and up to 15 km thick is present at mid-crustal levels. The LVZ is not observed beneath onshore Nova Scotia or northeast of Orpheus Graben, the offshore extension of the CCFZ. The crustal thickness of the Meguma terrane varies between 31 and 38 km; in contrast, the Moho is at a depth of 41 km beneath Avalonia. The velocity of the lower crust on line 99–2 is 6.8–7.1 km/s beneath the LVZ and Avalonia, and 6.6 km/s beneath onshore Meguma terrane. Poisson's ratios calculated from P- and S-wave velocities are 0.19–0.23 in the Meguma terrane crust; in contrast, Poisson's ratios of 0.24–0.25 are indicated for Avalonian crust.

Late Devonian syntaxis in the Northern Appalachian orogen

Abstract The pre-accretionary shapes of cratonic margins form successions of promontories and re-entrants inherited from the rifting of supercontinents. In accretionary orogens, the extent of deformation related to a collision with a continent characterized by an irregular margin is obfuscated through the partitioning of deformation along pre-existing structures. In the Northern Appalachians, the extent of the deformation related to the oblique collision of the Meguma terrane with the composite Laurentian margin is disputed. Herein, we use a framework based on modern collisional settings to investigate the Late Devonian to Mississippian deformation inboard of the Avalonia–Meguma boundary and evaluate the regional tectonic setting. We combine published shear zone kinematic interpretations, deformation ages and regional 40 Ar/ 39 Ar cooling ages with structural interpretation of aeromagnetic and gravimetric depth slices covering the Northern Appalachians. We find that the deformation related to the collision of the Meguma terrane, attributed to the Neoacadian orogeny, has a larger structural footprint than previously documented. While this deformation is partitioned in multiple structures in the Canadian Appalachians, northern New England is characterized by rapid crustal deformation, high palaeoelevation and fast erosional exhumation, similar to modern syntaxis structures.

Late Devonian shear-zone reactivation in the Canadian Appalachian orogen

Abstract Oblique accretion zones often display transpressive, strike-slip and transtensive structures of different orientations with respect to the convergence axis. The Late Devonian oblique collision of Meguma within the Canadian Appalachian orogen is often characterized as transpressive. However, the simultaneous opening of the Maritimes Basin indicates that the orogenesis also partitioned into an extensional component. In this context, few of the shear zones reactivated during this time period have been characterized while accounting for the possibility of strain partitioning. To do so, we characterize the kinematics and timing of deformation of the Eastern Highlands Shear Zone (EHSZ) and the Coinneach Brook Shear Zone (CBSZ) on Cape Breton Island, Nova Scotia, using a combination of U–Pb geochronology (zircon, monazite, xenotime and apatite) and 40 Ar/ 39 Ar geochronology in situ and step-heating experiments (amphibole, muscovite and biotite). Results show that the Silurian EHSZ was reactivated at c. 385–367 Ma and the CBSZ was formed at c. 395–369 Ma, both yielding oblique kinematics. Together, these structures accommodated the rapid exhumation of the Cape Breton Highlands during the docking of the Meguma terrane. This study thus highlights the heterogeneous distribution of transtensive and transpressive deformation during the Neoacadian Orogeny.

Depositional environment and provenance of Early Carboniferous clastic sedimentary rocks at McIsaacs Point, Nova Scotia: implications for syntectonic basin development during the formation of Pangaea

Abstract Following the collision of Gondwana and Laurussia to form Pangaea, a large system of regional-scale strike-slip faults developed which resulted in the formation of transtensional syncollisional basins. One such basin, the Antigonish Basin, contains late Devonian fluvial, marine and lacustrine sedimentary rocks, including sandstone, conglomerate and shale. LA-ICP-MS U–Pb detrital zircon data from three samples from the lower and middle of the McIsaacs Point section have a strong Silurian–Devonian ( c. 440–380 Ma) population whereas the top of the section lacks these age populations and is instead dominated by Neoproterozoic ( c. 630–550 Ma) grains. Detritus was derived from a mix of local Avalonian and more distal Meguma terrane sources. Detrital zircon and field data show that sediments were deposited in a braided to meandering fluvial system transitional to a proximal braided stream environment followed by evolution to a more distal braided stream environment. As the basin evolved, the source of detritus shifted from a dominantly Meguma terrane source to a more local Avalonian source. This temporal evolution in provenance and depositional environment attests to the complex depositional processes associated with syntectonic basin evolution during the formation of Pangaea.

Revised stratigraphy in the eastern Meguma terrane, Nova Scotia, Canada, and variations in whole-rock chemical and Sm–Nd isotopic compositions of the Goldenville and Halifax groups

As a result of new geological mapping, the Goldenville and Halifax groups in the eastern Meguma terrane have been divided into formations. They have a total stratigraphic thickness of about 7750 m and correspond to only the upper half of the Goldenville Group and lower half of the Halifax Group in the northwestern and southeastern areas of the terrane. The revised stratigraphy combined with compiled and new whole-rock major and trace element and Sm–Nd isotopic analyses enable more detailed documentation of the chemical changes with stratigraphy that were demonstrated in previous studies. Based on chemical compositions, the protolith compositions of the analysed samples range from lithic arenite to wacke to shale. Major and trace element characteristics are consistent with deposition in an active continental margin, basins associated with island arcs, or most likely at a passive continental margin with volcanic rocks in the source area. Chemical compositions show a scattered but overall increasing abundance of lithophile elements such as La and Th with stratigraphic position. Epsilon Nd(t) values become increasingly negative up-section, and depleted mantle model ages become increasingly older. The data are consistent with increased mixing between sediments derived from Mesoproterozoic upper crustal sources and sediments derived from a magmatic arc. These data are consistent with published detrital zircon patterns which show increasing amounts of ca. 2 Ga zircon with decreasing age, and with a source area comprising a Pan-African (800–540 Ma) volcanic arc and/or active margin magmatism and mainly Eburnean crust, most likely in the West African craton.

Garnet crystallization mechanisms and localized polymetamorphism in the southwestern Meguma Terrane, Nova Scotia, Canada

AbstractWe present data on the pressure and temperature (P–T) conditions experienced by metamorphic rocks of the Meguma Terrane, Nova Scotia, Canada, also utilizing three‐dimensional microstructural data on one sample to better constrain the mechanisms that controlled garnet crystallization. Inverse and forward thermodynamic modelling place peak P–T conditions in the southwestern Meguma Terrane at ~650°C and 4.5 kbar. Interpretation of these results with petrographic observations and previous P–T constraints across the terrane suggests that amphibolite facies metamorphism occurred during the Devonian Neoacadian orogeny (406–388 Ma). Integration of quantitative 3D textural data with an estimated metamorphic heating rate of <5°C/Myr is consistent with amphibolite facies metamorphism resulting from tectonic loading during the Neoacadian orogeny, though the exact nature of the orogeny is still not well understood. Further, the intrusion of granitic plutons into the Meguma metasediments at 373 Ma likely locally drove metamorphic recrystallization (polymetamorphism). The 3D size, shape, and location of garnet crystals in one sample reveal that the rate‐limiting step for garnet crystallization was likely the diffusion of aluminium through the intergranular matrix at length scales less than the mean nearest neighbour distance between garnet crystals. Nucleation was aided by epitaxial overgrowth onto a muscovite substrate, though it appears there may have been a decoupling between minerals providing a substrate and those providing nutrients during garnet growth.

Magmatic and Inherited Zircon Ages from a Diorite Xenolith of the Popes Harbour Dyke, Nova Scotia: Implications for Late Ediacaran Arc Magmatism in the Avalon Terrane of the Northern Appalachians

The Meguma terrane is a unique unit of the Northern Appalachians as it is only identified in Nova Scotia. It was thrust over the Avalon terrane during the Early Devonian Acadian Orogeny. The Avalon and Meguma terranes are exotic to North America and likely originated along the margin of Gondwana. The precise relationship between the terranes is uncertain and very little is known about the basement rocks of each terrane. Hosted within the Late Devonian lamprophyric Popes Harbour dyke of the Meguma terrane are xenoliths of meta-sedimentary and meta-igneous rocks that are from the basement of the Avalon terrane. The xenoliths offer a glimpse into the nature of the lower crust of the Northern Appalachians. In this study, we present in situ zircon U-Pb age dates from a rare dioritic xenolith in order to assess its origin. The results show that the majority of zircons ages are between ~580 Ma and ~616 Ma with smaller groups at 750–630 Ma, ~2100 Ma, and <570 Ma. The zircon 206Pb/238U weighted-mean age of the rock is 603 ± 5.3 Ma and contemporaneous, with granitic intrusions of the Avalon terrane located within the Antigonish and Cobequid highlands of Nova Scotia. The diorite is compositionally similar to granitoids from an active continental margin. The discovery of Early Paleoproterozoic (~2100 Ma) zircons and the absence of Late Paleoproterozoic (1900–1700 Ma) and Mesoproterozoic (1600–1000 Ma) zircons suggests that the parental magma either encounters only Early Paleoproterozoic and Late Neoproterozoic rocks during emplacement or is derived by the melting of Paleoproterozoic rocks and/or the melting and mixing of Paleoproterozoic and Late Neoproterozoic rocks. Therefore, it is possible that Paleoproterozoic rocks may exist within the basement of the Avalon terrane.

The age and origin of the South Mountain Batholith (Nova Scotia, Canada) as constrained by zircon U–Pb geochronology, geochemistry, and O–Hf isotopes

The South Mountain Batholith (SMB; Nova Scotia, Canada) is the largest composite batholith exposed in the Appalachians and lies entirely within the most outboard Meguma terrane. In situ and CA–TIMS U–Pb dating and in situ isotopes (Lu–Hf, O) and geochemistry for zircon from all phases of the SMB constrain its source as well as its evolution. CA–ID–TIMS for zircon yields emplacement (autocryst) ages, indicating a transition from granodiorite (378.7 ± 1.2 to 375.4 ± 0.8 Ma) to leucogranite (375.4 to 371.8 ± 0.8 Ma) over several million years. Furthermore, in situ SHRIMP, LA–MC–ICP–MS, and SIMS analyses of distinct zircon domains reveal: (1) abundant ancient xenocrysts (∼420 Ma to 2.2 Ga); (2) antecryst ages ca. 3–15 million years older than SMB emplacement; (3) autocryst δ18O values between +7.3‰ and +9.1‰ (V-SMOW); (4) similar isotopes, REE signatures, and derived fO2 values among antecrysts and autocrysts; and (5) εHf values from the 371.8 ± 0.8 Ma Davis Lake Pluton (DLP) autocrysts that are higher (+1.74 to +4.38) than the rest of the SMB (−2.99 to +1.68). Collectively, these data suggest a protracted magmatic evolution for the SMB with melt generation and assembly from ∼390 to 370 Ma via melting of a metasomatized mantle source followed by contamination, first from the structurally underlying Avalonian terrane and later by metasedimentary wall rocks of the Meguma terrane. The most southwesterly part of the SMB (i.e., DLP) represents a petrogenetically distinct magmatic phase that underwent less overall contamination than the rest of the SMB.

Origin and age of the Shenshan tectonic mélange in the Jiangshan-Shaoxing-Pingxiang Fault and late Early Paleozoic juxtaposition of the Yangtze Block and the West Cathaysia terrane, South China

AbstractWhen and how the Yangtze Block (Yangtze) and the West Cathaysia terrane (West Cathaysia) in South China were amalgamated are critical to a better understanding of the Neoproterozoic to early Paleozoic tectonic evolution of South China and remain highly debatable. A key to this debate is the tectonic significance of the Jiangshan-Shaoxing-Pingxiang (JSP) Fault, the boundary between Yangtze and West Cathaysia. The Shenshan mélange along the JSP Fault has the typical block-in-matrix structure and is composed of numerous shear zone-bounded slivers/lenses of rocks of different types and ages that formed in different tectonic environments, including middle to late Tonian volcanic and volcanogenic sedimentary rocks (turbidite) of arc/back-arc affinity, a series of middle Tonian ultramafic to mafic plutonic rocks of oceanic island basalt affinity, a carbonaceous shale that was deposited in a deep marine environment, and a red mudstone. U-Pb zircon ages and acritarch assemblages (Leiosphaeridia-Brocholaminaria association) found in the turbidite confirm its Tonian age, and fossils from the carbonaceous shale (Asteridium-Comasphaeridium and Skiagia-Celtiberium-Leiofusa) constrains its age to the Early to Middle Cambrian. Field relationships and available age data leave no doubt that the ultramafic-mafic rocks are exotic blocks (rather than intrusions) in the younger metasedimentary rocks. We conclude that the Shenshan mélange is not an ophiolitic mélange, but rather a tectonic mélange that formed as a result of movement along the JSP Fault in the early Paleozoic. We suggest that Yangtze and West Cathaysia were two separate microcontinents, were accreted to two different parts of the northern margin of Gondwana in the early Early Paleozoic, and juxtaposed in the late Early Paleozoic through strike-slip movement along the JSP Fault. We further suggest that the ca. 820 Ma collision in the Jiangnan Orogen took place between Yangtze and a (micro)continent that is now partly preserved as the Huaiyu terrane and was not related to West Cathaysia. We compare our model for South China with the accretion of terranes in the North American Cordillera and propose a similar model for the relationship between the Avalon and Meguma terranes in the Canadian Appalachians, i.e., the two terranes were accreted to two different parts of the Laurentian margin and were later juxtaposed through margin-parallel strike slip faulting.

Paleolatitude and tectonic rotations of the Early Carboniferous Fountain Lake Group, Cobequid Highlands, Nova Scotia, Canada

The ca. 355 Ma Fountain Lake Group in the Cobequid Highlands of Nova Scotia, is part of the transtensional basin fill that formed during dextral strike-slip motion between Avalonia and the Meguma terranes following the Acadian Orogeny. Paleomagnetic analysis of the Fountain Lake Group offers a paleolatitude estimate for the Laurentian accretionary margin in the Early Carboniferous as well as locality-specific paleomagnetic directions, which indicate clockwise-sense block rotations during dextral strike-slip motion along the Cobequid Fault zone. Stepwise demagnetization of 142 specimens from 20 sites in three Fountain Lake Group localities across the Cobequid Highlands (Squally Point, West Moose River, and Wentworth exposures) reveals remanence consisting of an easily removed component of probable recent origin, and more persistent components carried by magnetite and hematite, which in petrographic and electron beam analysis appear to be of primary igneous and volcanic oxidation origins, respectively. Sites from all three localities carry stable characteristic remanent magnetization (ChRM) directions that assume similar moderate downward inclinations when tilt-corrected. A Block Rotation Fisher analysis inclination-only fold test demonstrated best agreement at 90% unfolding, showing that remanence acquisition pre-dates Alleghenian deformation in the Late Carboniferous and is most likely of primary 355 Ma age. Paleomagnetic results for the Squally Point, West Moose River, and Wentworth localities show relative rotations between the blocks that are variously clockwise-rotated compared with a Laurentia cratonic reference frame. Inclinations at all three localities imply a subtropics paleolatitude for the margin (at Squally Point, 27.2° ± 9.4°; N = 7 sites), directly supporting the depicted location of Laurentia and its Appalachian accretionary margin in most Devonian to Early Carboniferous reconstructions.

Application of bulk fluid volatile chemistry to exploration for metasedimentary rock-hosted orogenic gold deposits: An example from the Meguma terrane, Nova Scotia, Canada

Disseminated gold (Au) deposits hosted in metasedimentary rocks present unique exploration challenges because the Au is generally very fine-grained or refractory, and not vein-hosted. Exploration programs in such settings rely on extensive lithogeochemical surveys, lesser structural analysis, and little emphasis on ore-fluid geochemistry. The Moose River anticline (MRA) in the Lower Paleozoic Meguma terrane (Nova Scotia, Canada) hosts several high-tonnage (~10–20 Mt), low-grade (≤1–4 g/t Au) Au deposits comprised of disseminated ± quartz vein-hosted mineralization in metamudstones. Here, the Touquoy deposit hosted in the MRA is used to evaluate a new approach to geochemical exploration by examining if the volatile chemistry of host rocks preserves a signature related to Au mineralization, using a gas chromatographic (GC) technique that analyzes bulk volatiles released from crushed rock. Since GC is a bulk analytical technique, (i.e., multiple generations of fluid inclusion volatiles yielding a mixed analytical volume), the volatile composition of fluid inclusions were also investigated in-situ using laser Raman microspectroscopy to reconcile bulk analyses with the composition and abundance of different inclusion types. Inclusions in quartz pressure shadows associated with porphyroblasts host N2 ± CH4-dominant vapor phases and represent wall rock-equilibrated fluids. In comparison, fluid inclusion vapor phases in quartz veinlets crosscutting the metamudstones are more complex in composition and show a continuum between CO2-dominant and N2 ± CH4-dominant compositions; the former is interpreted as the fluid responsible for Au mineralization in the Meguma terrane (e.g., H2O-CO2 ± CH4 ± N2 fluids). GC shows statistically significant differences in the compostion of the bulk volatiles released from crushed metamudstones from the Touquoy deposit (n = 21) and barren (n = 24) settings. Whereas the former commonly contain detectable CO2 (50% of samples; LoQ(CO2) ~ 10−10 mol/g), only ~4% of metamudstones from barren settings along the MRA contain CO2, yielding a t-test p-value of 0.0103 between the two sample populations. Whereas the more frequent detection of CO2 in mineralized samples is related to increasing carbonate alteration proximal to Au mineralization, no correlation is observed between bulk CO2 abundance and Au grade. Additionally, anomalous differences in abundances of released C3 (t-test p-value = 0.043) and C4 (t-test p-value = 0.03) hydrocarbons (HC) are recognized between the two populations (LoQ(HC) ca. 10−13 to 10−12 mol/g), with Touquoy metamudstones having higher Σ(C3)/CH4 and Σ(C4)/CH4 ratios compared to barren equivalents. The compositional differences suggest that more aqueous-carbonic fluids infiltrated metamudstone units where locally favorable physical and/or chemical conditions were present, resulting in increased Au endowment. The relative increase in fluid flux, and thus Au grade, resulted in more trapped CO2 (i.e., resulting from more trapped inclusions and/or greater CO2 fluid component) and modification to hydrocarbon signatures through homologation and/or degradation reactions. Rigorous sample preparation ensures these compositional differences are related to paleofluids and not contamination.Tentatively, the results suggest that the bulk analysis of volatiles released from fluid inclusions in metamudstones may be a useful vectoring tool for disseminated Au mineralization in Meguma-type gold systems and similar environments (e.g., Carlin-type). This technique may be appropriately scaled to complement exploration drilling programs and may be more sensitive in determining ore proximity than often ambiguous pathfinder elements.

Whole-rock and Sm–Nd isotopic geochemistry of Triassic SW Iberia sandstones: implications for provenance

Whole-rock and Sm–Nd isotopic geochemistry data were used to characterise the probable sources of the Triassic Alentejo and Algarve sandstones. These rocks were deposited in a rift setting, plot within the recycled field in the QFL and discrimination function diagrams for sandstones, thus supporting derivation from a recycled orogenic terrane. They all show negative Eu anomalies, enrichment of LREE, and nearly flat HREE patterns, typical of upper-continental crustal sources. Their Nd TDM model ages and detrital zircon populations are significantly coincident with those of the Late Devonian-Early Carboniferous Phyllite-Quartzite and Tercenas formations and Early Carboniferous Mira turbidites of the South Portuguese Zone (SPZ), indicating that these may have been their dominant sources, with a minor contribution from the Visean Mertola turbidites. In particular, the Mira turbidites may also be regarded as the dominant source of the eastern Algarve Triassic sandstones. Furthermore, the Nd TDM model ages and the detrital zircon populations of the central Algarve Triassic sandstones as compared with those of the SPZ Late Carboniferous Brejeira and Late Devonian Ronquillo formations suggest a strong source to sink relationship. Finally, some of the western Algarve Triassic sandstones show older Nd TDM model ages which have not been recognized in the SPZ basement rocks, and, hence, suggest that these sediments may derive directly from primary remote sources. We advance the suggestion that beyond remote potential sources from the Meguma Terrane, others from the Moroccan Variscan Belt have been reproduced in the Devonian-Carboniferous SPZ basement as the result of sediment recycling. These SPZ would represent intermediate sediment repositories and would be later on reworked and incorporated into the Triassic Algarve Basin, thus indicating multi-cycle sedimentation.

Age of the basement beneath the Mesozoic Lusitanian Basin revealed by granitic xenoliths from the Papôa volcanic breccia (West Iberia)

The dyke of the Papôa volcanic breccia cross-cutting the Lower Jurassic sequence of the Lusitanian Basin (West Iberia) contains granitic xenoliths. In this study, for the first time, U-Th-Pb zircon analysis of two xenoliths yielded 298±4Ma for biotite granite and of 292±2Ma for two-mica granite, indicating that the pre-Mesozoic basement of the Lusitanian Basin includes Permian intrusions. These ages are close within the margin of error of the age of the Late Carboniferous granites of the Berlengas isle that with the Late Devonian high-grade metamorphic rocks of the Farilhões isles, located northwest of the study area, which form the pre-Mesozoic basement of the Lusitanian Basin. These new geochronological findings enable it to be established that Permo-Carboniferous magmatism lasted at least 13Ma, in this region of the Appalachian-Variscan belt. Furthermore, a comparison with available data from Paleozoic tectonic units of the Appalachian-Variscan belt located both in the Iberian Massif and outside it enables the suggestion to be made that the Lusitanian Basin (Peniche) most probably rests on the South Portuguese Zone, which may also be correlated with the Rhenohercynian Zone present in southwest England, and the Meguma terrane of Nova Scotia.

Meguma terrane orocline: U–Pb age and paleomagnetism of the Silurian Mavillette gabbro, Nova Scotia, Canada

Paleomagnetic results and a U–Pb baddeleyite age from the Silurian Mavillette gabbroic sill in southwest Nova Scotia, Canada, provide new evidence about the Paleozoic tectonic evolution of the Meguma terrane. The Mavillette gabbro sill intruded ca. 440–430 Myr old bimodal rift-related metavolcanic and metasedimentary rocks of the White Rock Formation in the Silurian–Devonian Rockville Notch Group. The 426.4 ± 2.0 Ma Mavillette gabbro age is notably younger than the ca. 440 Ma magmatism, but is part of a geochemically defined suite of within-plate sills and volcanic rocks of the Rockville Notch Group with ages as young as Early Devonian. Paleomagnetic investigation of 13 sites distributed along the Neoacadian (ca. 390 Ma) synclinal limbs of the Mavillette sill reveal magnetization directions that fail a fold test and therefore postdate Silurian emplacement of the gabbro. The post-folding remanence has a mean direction of D = 153.4, I = 17.1°; α 95 = 6.5° (n = 12 sites), with corresponding paleopole 31.9 °S, 325.2 E; dp = 3.5°, dm = 6.7° that resembles a pervasive late Carboniferous Kiaman overprint magnetization in North America, but is rotated significantly 22.2° ± 8.1° counter-clockwise (CCW). Mavillette remanence acquisition likely occurred in concert with fluid mobilization related to Alleghanian deformation, recorded locally by ca. 320 Ma muscovite 40Ar–39Ar ages. Previously published paleomagnetic results from the Meguma terrane also have Carboniferous remanence directions with similar ∼24° CCW discordance. The regional CCW rotation of the southwest Meguma terrane post-dates this ca. 320 Ma tectonothermal remanence acquisition event, likely recording the development of an oroclinal bend of the Meguma terrane during the Alleghanian orogeny.

Detrital zircon provenance of Triassic sandstone of the Algarve Basin (SW Iberia): evidence of Gondwanan- and Laurussian-type sources of sediment

AbstractDetrital zircon populations from six samples of upper Triassic sandstone (Algarve Basin) were analysed, yielding mostly Precambrian ages. zircon age populations of the Triassic sandstone sampled from the western and central sectors of the basin are distinct, suggesting local recycling and/or lateral changes in their sources. Our findings and the available detrital zircon ages from the Palaeozoic terranes of SW Iberia, Nova Scotia and NW Morocco were jointly examined using the Kolmogorov–Smirnov test and multidimensional scaling diagrams. The obtained results enable direct discrimination of competing Laurussian-type and Gondwanan-type sediment sources, involving recycling and mixing relationships. The detrital zircon populations of the Algarve Triassic sandstone are very different from those of the lower–upper Carboniferous Mértola and Mira formations (South Portuguese Zone), upper Devonian – lower Carboniferous Horta da Torre, Represa and Santa Iria formations (Pulo do Lobo Zone), and the late Carboniferous Santa Susana and early Permian Viar basins, which are ruled out as potential sources. The detrital zircon populations of Triassic sandstone from the central sector and those from the Ossa–Morena Zone Ediacaran–Cambrian siliciclastic rocks, upper Devonian – Carboniferous Ronquillo, Tercenas, Phyllite-Quartzite and Brejeira formations (South Portuguese Zone), and Frasnian siliciclastic rocks of the Pulo do Lobo Zone are not statistically distinguishable. Thus, sedimentation in the central sector was influenced by Gondwanan- and Laurussian-type putative sources exposed in SW Iberia, in contrast to the western sector, where Meguma Terrane and Sehoul Block Cambrian siliciclastic rocks allegedly constituted the main (Laurussian-type) sources. These findings provide insights into the denudation of distinctive source terranes distributed along the late Palaeozoic suture zone that juxtaposed the Laurussian and Gondwanan margins.

Field relations and petrology of the Trafalgar Plutonic Suite and comparisons with other Devonian granitoid plutons in the Meguma terrane, Nova Scotia, Canada

The Trafalgar Plutonic Suite intruded metasedimentary rocks of the Goldenville and Halifax groups in the northeastern part of the Meguma terrane of southern Nova Scotia at about 374 Ma, based on previously published U–Pb and 40Ar/39Ar mineral ages. Using field and petrographic observations, the suite is divided into 20 different plutons on the combined basis of variations in grain size (fine, medium, or coarse), texture (equigranular or porphyritic) and modal mineralogy (quartz diorite/tonalite, granodiorite, monzogranite, and syenogranite). The granodiorite, monzogranite, and syenogranite plutons are relatively uniform in composition with little variation in mineralogy or chemistry within each pluton or between plutons of the same lithology. In contrast the quartz diorite/tonalite plutons show mineralogical and chemical variation, both within and between plutons. The granodiorite, monzogranite, and syenogranite plutons closely resemble other peraluminous granitoid plutons characteristic of the Meguma terrane. The quartz diorite/tonalite plutons are varied but chemically resemble minor Devonian mafic intrusions elsewhere in the Meguma terrane. Like other plutons of the Meguma terrane, the Trafalgar Plutonic Suite has chemical characteristics of volcanic-arc to syn-collisional granitoid rocks and likely has experienced extensive contamination by metasedimentary material as documented by previous studies of plutons in the Meguma terrane. The minor quartz diorite/tonalite plutons are additional examples of the mafic rocks that have been proposed in tectonic models of the Meguma terrane to have facilitated melting of the lower crust to generate granodioritic parent magmas, followed by crystal fractionation and extensive contamination by metasedimentary material.

Application of LA ICP-MS analysis of arsenopyrite to gold metallogeny of the Meguma Terrane, Nova Scotia, Canada

Investigation of gold metallogeny in the Paleozoic Meguma terrane (Canada) is conducted through LA-ICP-MS analysis of arsenopyrite collected from eight slate-belt style vein gold deposits using a novel approach integrating elemental distribution maps and their derived elemental paragenesis with multi-element binary plots. The data reveal two distinct gold events: 1) an early event characterized by a Co-Ni-Mo-Sb-Se elemental association related to initial growth of arsenopyrite that reflects the presence of invisible gold (>10 ppm); and 2) a second event, spatially associated with late fracture sets, that is characterized by an Al-Ti-V-Mn element association and reflects either remobilization or upgrading of primary invisible gold and is manifest as visible gold.The results of this study indicate a complex and protracted history of gold mineralization which has important ramifications for the Meguma gold deposits, as well as other orogenic gold districts globally. In the case of the Meguma Terrane, it involves an initial gold event that is followed by element mobilization and, in the case of precious metals (Au, Ag), an upgrading through a zone refining process. In addition, the variable coupling and decoupling of elements is only revealed using in-situ derived LA-ICP-MS data.