Megacity In South China Research Articles

Ambient Ozone and Fine Particular Matter Pollution in a Megacity in South China: Trends, Concurrent Pollution, and Health Risk Assessment

Over the past several years, Shenzhen’s air quality has significantly improved despite increased ground-level ozone (O3) and the challenges in reducing fine particulate matter (PM2.5). We investigated concentration trends, concurrent pollution features, and long-term exposure health risks to enhance our understanding of the characteristics of O3 and PM2.5 pollution. From 2016 to 2022, there was a decrease in PM2.5 levels, but an increase in O3. Additionally, the premature mortality attributed to long-term air pollution exposure decreased by 20.1%. High-O3-and-PM2.5 days were defined as those when the MDA8 O3 ≥ 160 μg m–3 and PM2.5 ≥ 35 μg m–3. Significantly higher levels of O3, PM2.5, nitrogen dioxide (NO2), OX (OX = O3 + NO2), and sulfur dioxide (SO2) were observed on high-O3-and-PM2.5 days. Vehicle emissions were identified as the primary anthropogenic sources of volatile organic compounds (VOCs), contributing the most to VOCs (58.4 ± 1.3%), O3 formation (45.3 ± 0.6%), and PM2.5 formation (46.6 ± 0.4%). Cities in Guangdong Province around Shenzhen were identified as major potential source regions of O3 and PM2.5 during high-O3-and-PM2.5 days. These findings will be valuable in developing simultaneous pollution control strategies for PM2.5 and O3 in Shenzhen.

Nighttime ozone in the lower boundary layer: insights from 3-year tower-based measurements in South China and regional air quality modeling

Abstract. Nighttime ozone in the lower boundary layer regulates atmospheric chemistry and surface ozone air quality, but our understanding of its vertical structure and impact is largely limited by the extreme sparsity of direct measurements. Here we present 3-year (2017–2019) measurements of ozone in the lower boundary layer (up to 500 m) from the Canton Tower in Guangzhou, the core megacity in South China, and interpret the measurements with a 1-month high-resolution chemical simulation from the Community Multiscale Air Quality (CMAQ) model. Measurements are available at 10, 118, 168, and 488 m, with the highest (488 m) measurement platform higher than the typical height of the nighttime stable boundary layer that allows direct measurements of ozone in the nighttime residual layer (RL). We find that ozone increases with altitude in the lower boundary layer throughout the day, with a vertical ozone gradient between the 10 and 488 m heights (ΔO3/ΔH10–488 m) of 3.6–6.4 ppbv hm−1 in nighttime and 4.4–5.8 ppbv hm−1 in daytime. We identify a high ozone residual ratio, defined as the ratio of ozone concentration averaged over nighttime to that in the afternoon (14:00–17:00 LT), of 69 %–90 % in January, April, and October, remarkably higher than that in the other three layers (29 %–51 %). Ozone in the afternoon convective mixing layer provides the source of ozone in the RL, and strong temperature inversion facilitates the ability of RL to store ozone from the daytime convective mixing layer. The tower-based measurement also indicates that the nighttime surface Ox (Ox= O3+NO2) level can be an effective indicator of RL ozone if direct measurement is not available. We further find significant influences of nocturnal RL ozone on both the nighttime and the following day's daytime surface ozone air quality. During the surface nighttime ozone enhancement (NOE) event, we observe a significant decrease in ozone and an increase in NO2 and CO at the 488 m height, in contrast to their changes at the surface, a typical feature of enhanced vertical mixing. The enhanced vertical mixing leads to an NOE event by introducing ozone-rich and NOx-poor air into the RL to enter the nighttime stable boundary layer. The CMAQ model simulations also demonstrate an enhanced positive contribution of vertical diffusion (ΔVDIF) to ozone at the 10 and 118 m heights and a negative contribution at the 168 and 488 m heights during the NOE event. We also observe a strong correlation between nighttime RL ozone and the following day's surface maximum daily 8 h average (MDA8) ozone. This is tied to enhanced vertical mixing with the collapse of nighttime RL and the development of a convective mixing layer, which is supported by the CMAQ diagnosis of the ozone budget, suggesting that the mixing of ozone-rich air from nighttime RL downward to the surface via the entrainment is an important mechanism for aggravating ozone pollution the following day. We find that the bias in CMAQ-simulated surface MDA8 ozone the following day shows a strong correlation coefficient (r= 0.74) with the bias in nighttime ozone in the RL, highlighting the necessity to correct air quality model bias in the nighttime RL ozone for accurate prediction of daytime ozone. Our study thus highlights the value of long-term tower-based measurements for understanding the coupling between nighttime ozone in the RL, surface ozone air quality, and boundary layer dynamics.

Daily mobilities with smartphone apps and their failures: A study in urban Guangzhou

The key purpose of this article is to provide a nuanced understanding of the platform-city-people nexus shaped by digitally mediated mobilities. This article focuses on urban practices of walking, driving and ride-hailing with mobile technologies and their failures on an everyday basis in urban Guangzhou (a megacity in south China), based on an analysis of both quantitative and qualitative data collected from the fieldwork in 2021. It finds that digitally mediated mobilities can be seen as everyday digital practices which are simultaneously produced and reproduced through everyday encounters with platforms and their breakdowns, places, and people's knowledge, skills, and imaginations in both digital and physical spaces. Moreover, digital platforms, as well as their failures, affect daily mobilities in contradictory ways. On the one hand, digital platforms mediate and reshape the time-space of people's daily mobilities and make people adjust and adapt their practices to the logic of platforms. While on the other hand, they allow people to creatively produce valuable data for themselves and enhance their skills of re-organising their mobilities with smartphone apps efficiently. These findings can advance digital geographies' understanding of the complex, contingent and messy relations between digital platforms, urban spaces and everyday practices.

Polybrominated diphenyl ethers in water, suspended particulate matter, and sediment of reservoirs and their tributaries in Shenzhen, a mega city in South China.

Urban reservoirs serve many purposes including recreation and drinking water, and larger bodies of water can alter the surrounding air temperatures, making urban areas cooler in summer and warmer in winter. However, reservoirs may also be sinks for contaminants. One such group of contaminants, the polybrominated diphenyl ethers (PBDEs), are persistent organic pollutants known to accumulate in sediments and suspended particulate matter (SPM). Few studies have been conducted on PBDEs in water, SPM, and sediment from reservoirs of Shenzhen which is a mega city in South China. To this end, 12 PBDEs were measured in water, SPM, and sediment samples during the dry season (DS) and wet season (WS), to explain the spatiotemporal distribution, congener profiles, sources, and risks of pollutants in four reservoirs (A-D) and their tributaries in the study region. The concentration of ∑12PBDEs during the DS was found to be significantly higher than that during the WS. Source apportionment suggested that commercial penta-, octa-, and deca-BDEs are the major components of PBDEs, resulting mainly from atmospheric deposition, wastewater discharge, and external water-diversion projects. Further, attention should be paid to electronic equipment manufacturing factories in the study area. Risk assessment indicated risk of PBDEs (especially BDE-209) in sediment and SPM to be of concern. This study provides important data support for the control of PBDEs in natural drinking water sources.

Toward the Origins of Quadruple Sulfur Isotope Anomalies in Modern Sulfate: A Multitracer Approach and Implications for Paleo- and Planetary Atmospheres

Sulfur isotope mass-independent fractionation signatures (S-MIF) have been widely found in modern sulfate aerosols. Their mechanistic origins and potential implications for atmospheric sulfate formation chemistry are however poorly understood. Of particular importance is that the mystery of modern sulfate S-MIF hinders precise interpretations of S-MIF in geological sediment and meteorite samples. Here, we examine several proposed origins of modern sulfate S-MIF using a multiple-tracer approach. Quadruple sulfur isotopes of sulfate aerosols collected from Guangzhou, a megacity in South China, were measured along with various chemical and isotopic tracers for high-altitude air masses, biomass burning, and mineral dusts in the same samples. Similar to previous studies, we found that negative Δ36S values in modern sulfate aerosols are linked to combustions, and to a larger extent, to high-temperature processes that may involve symmetry-dependent recombination reactions of sulfur. The origins of Δ33S anomalies widely observed in modern sulfate aerosols remain elusive and require further investigation before we can unambiguously use this proxy to quantify sulfur emission and transformation pathways in the modern atmosphere. From a comparative planetology perspective, we highlight that a complete understanding of S-MIF in modern aerosols is crucial for tracking paleo- and planetary atmospheres by multiple sulfur isotope measurements in Phanerozoic sediments and Martian meteorites because their S-MIF magnitudes are similar.

Enrichment of Organic Acids in Fine Particles Over a Megacity in South China

AbstractOrganic acids are abundant aerosol components that impact the hygroscopicity and multiphase processes of particulate matter, yet their changing compositions and sources are poorly understood. In this study, filter‐based PM2.5 samples were collected concurrently at three sites (urban, rural, and coastal) during the summer and winter of 2018 in the megacity Guangzhou, south China, to determine organic acids including C9–C32 fatty acids, C4–C10 dicarboxylic acids, and aromatic acids. On average, the total concentrations of the speciated organic acids were higher in winter than in summer, and were the highest at the urban site. Compared to observations at the same sites in winter 2009, average concentrations of organic acids in winter 2018 increased by 35.0%, 66.0%, and −3.2% at the urban, rural and coastal sites, while their fractions in organic matter (OM) increased by approximately 261.5%, 266.7%, and 61.1%, and their fractions in PM2.5 increased by approximately 318.2%, 308.7%, and 221.1%, respectively. Source apportionment of organic acids revealed that cooking emission and vehicle exhaust were the major sources at the urban site, plant wax and vehicle exhaust were the two largest sources at the rural site with substantial contributions from biomass burning in winter, while vehicle exhaust and ship emission were the two major sources at the coastal site. Less contributions from secondary production were retrieved in winter 2018 than in winter 2009, and the enrichment of organic acids in PM2.5 or OM was attributed to their elevated primary emissions from vehicles and ships, cooking, and plant wax.

Characterizing formation mechanisms of secondary aerosols on black carbon in a megacity in South China

Refractory black carbon (rBC) aerosols emitted from incomplete combustion are important climate forcers. Understanding the chemical characteristics and evolution of rBC-related components is particularly crucial to assess rBC environmental impacts. Here, we explored the chemical components of rBC in Shenzhen, China, using a soot-particle aerosol mass spectrometer (SP-AMS). The observations showed that the rBC coating was mainly composed of secondary aerosols with an average mass contribution of 84.7 %. Among them, secondary organic coating occupied ∼57.7 % of the total coating mass. Exploration of the relationship between secondary organic aerosol (SOA) coating and Ox (=NO2 + O3, an indicator of the extent of photochemical processing) showed that SOA coating was generated mainly through photochemical oxidation during the day. Similarly, sulfate coating, with a small mass fraction of 0.9 %, was also dominated by photochemical oxidation. In contrast, nitrate coating responded positively to ambient relative humidity, especially at night, indicating that it was driven by heterogeneous reactions. In addition, the increased ratio of nitrate on rBC to bulk nitrate at night suggested that black carbon surface could facilitate nocturnal nitrate formation.

Aquatic environmental fates and risks of benzotriazoles, benzothiazoles, and p-phenylenediamines in a catchment providing water to a megacity of China

Wearing of vehicle parts could release many chemical additives into the environment, such as benzotriazoles (BTRs), benzothiazoles (BTHs), and p-phenylenediamines (PPDs), which are potentially toxic to wildlife and humans. This study investigated the occurrence, source, and risks of BTRs, BTHs, and PPDs in a source catchment providing water to Guangzhou, a megacity in South China, covering groundwater, surface water, and stormwater. The results showed that BTRs and BTHs were predominant in surface water and groundwater. Unexpectedly, the BTR and BTH concentrations were lower in surface water than groundwater in a third of the paired samples. For the first time, 6PPD-quinone, a toxic ozonation product of N-(1,3-dimethylbutyl)-N′-phenyl-1,4-phenylenediamine (6PPD), was extensively detected in source waters. Stormwater decreased the BTR concentrations but increased the 6PPD-quinone concentrations in surface water owing to their affiliation to suspended particles. From natural to urban segments of Liuxi river, a downstream increasing trend in BTR and BTH concentrations was observed, confirming that they are indicative of urban anthropogenic activities. Strong correlations between industrial activities and BTR or BTH concentrations in surface water indicated that industrial activities were their main sources. Six compounds were prioritized as potentially persistent, mobile, and toxic (PMT) chemicals, combing our monitoring results and REACH criterion. This study improves our understanding of the environmental fates and risks of water-soluble tire-wear chemicals, which provides important information for chemical management, and indicates attention should be paid to the risk posed by 6PPD-quinone in the source water.

Greenway service supply and public demand in Guangzhou city, China

Small-size green spaces contain convenient service capabilities for urban residents and satisfy the daily needs of citizens for high-quality ecological products. A greenway is a kind of linear green space, which can create a beautiful and livable environment in a high-density urban area. This study explored whether the services provided by the greenway can meet the daily needs of urban residents for green space in Guangzhou, a mega city in south China. Based on the Analytic Hierarchy Process (AHP) method and the entropy weight (EW) method, both the coupling coordination degree model and spatial autocorrelation analysis were adopted to quantify and determine the coordination degree of greenway service supply and public demand in Guangzhou. The results showed that the comprehensive score of the greenway service supply (GSS) subsystem and the public demand (PD) subsystem in Guangzhou was 0.3865 ± 0.08 and 0.3778 ± 0.03 (mean±s.e., n = 11), respectively. The GSS subsystem score was slightly higher than that of PD subsystem (P > 0.05), indicating that the two subsystems had no significant differences. The supply and demand subsystem of ten districts (excluding Conghua) in Guangzhou achieved different levels of coordination, and the average coupling coordination degree was 0.5885, suggesting that the districts were barely balanced at the city level. The Moran's I value was 0.580, indicating that the coupling coordination degree had significant positive global spatial autocorrelation and showed a spatial agglomeration effect. Furthermore, the local Moran’s I spatial autocorrelation showed that three districts (i.e., Yuexiu, Haizhu and Liwan) formed a high supply-high demand cluster and a spatial difference was detected when coupling the GSS and PD in Guangzhou. Therefore, we proposed the differentiated optimization strategies based on the results of the coupling coordination degree and the development status of each district and the entire city. This knowledge can better guide the subsequent construction and development of greenway in Guangzhou and may be useful for adjacent cities in Asia-Pacific region.

Young population consume twice as much artificial sweetener than the general population – A wastewater-based assessment in China

Understanding artificial sweetener consumption patterns and levels in different demographics is important for formulating public health policies on controlling sugar consumption. There is a considerable knowledge gap with respect to the pattern of artificial sweetener consumption in China. To narrow this gap, wastewater analysis was used to assess the temporal patterns of consumption of seven artificial sweeteners in an urban population and a university town in a megacity in South China over a one-year period. Daily influent wastewater samples were collected from an urban catchment and weekly samples collected from a university sub-catchment. Population normalized per capita consumption of the four detected artificial sweeteners (cyclamate, acesulfame, sucralose and saccharin) in the university catchment (1.0–5.9 mg d−1 p−1) was much higher than those in urban catchment (0.5–1.3 mg d−1 p−1), indicating younger population consume more artificial sweeteners than the general population. The daily consumption of artificial sweeteners was found to be stable throughout the week in the urban catchment. Time-series analysis showed that an average increase in temperature of 1 °C was associated with an increase consumption of 33 μg d−1 p−1 for acesulfame, 15 μg d−1 p−1 for sucralose and 14 μg d−1 p−1 for saccharin. This was the first study that objectively quantified the greater consumption of artificial sweeteners (proxy for consumption of artificially sweetened food and beverages) in a younger age group when compared to the general population, which could potentially pose a risk of health related diseases.

Mapping the anxiety of digitally mediated mobilities in the mundane

This article focuses on the ‘small moments’ of digitally mediated mobilities in the mundane. Drawing on a qualitative GIS analysis of people’s walking, driving and ride-hailing in urban Guangzhou (a megacity in south China), this article maps the complex and dynamic anxieties from a social practice perspective. It argues that anxieties of daily mobilities are entangled with digital practices of reducing, removing or producing future uncertainties, as well as those of generating instant confusion of the digital/data during the management and organisation of familiar routines. The key findings of this study suggest that anxieties of digitally mediated mobilities are situated knowledges generated by the temporalities, spatialities and socialities of daily movements. These complex, contingent and dynamic anxieties are coped with improvisationally. These findings can bring new insights into mobilities studies by constructing an understanding of the co-constitution of embodied and emotional movements and mobile technologies in the digital mundane.

PM2.5-bound phthalates and phthalate substitutes in a megacity of southern China: spatioseasonal variations, source apportionment, and risk assessment.

Plasticizers are ubiquitous pollutants in the environment, whereas few efforts have been made to elucidate their emission sources in the atmosphere. In this research, the spatioseasonal variations and sources of particle-bound (PM2.5) phthalates (PAEs) and their substitutes (APs) at residential sites in seven districts and at four potential point-source sites across a megacity in South China were revealed. The total concentrations of PAEs ranging from 10.7 to 528ng/m3 were substantially higher than those of APs (1.45.58.5ng/m3). Significant spatial variations in the concentrations of the pollutants were observed, which were generally higher at the sites with intensive industrial activities and the point-source sites. Most atmospheric plasticizer levels peaked in summer, probably due to the temperature-promoted volatilization. Seven sources of plasticizers were identified by the positive matrix factorization (PMF) model. The sources in less industrialized districts are mainly associated with domestic and commercial emissions and with industry in the industrialized districts. Specifically, plastics and personal care products together contributed 60% of the plasticizers in the atmosphere of this city, followed by solvents and polyester industry sources. The incremental lifetime cancer risk of inhalation exposure to bis(2-ethylhexyl) phthalate in the study city is below the acceptable level. Relatively higher risks were found for residents living around sites with intensive industrial activities and around wastewater treatment plant.

Characterizing Formation Mechanisms of Secondary Aerosols on Black Carbon in a Megacity in South China

Characterizing Formation Mechanisms of Secondary Aerosols on Black Carbon in a Megacity in South China

Characteristics of Aerosol Pollution Under Different Visibility Conditions in Winter in a Coastal Mega-City in China

To investigate chemical profiles and formation mechanisms of aerosol particles in winter haze events, comprehensive measurements including hourly concentrations of PM2.5 and water-soluble inorganic ions and related gas-phase precursors were conducted via an online monitoring system from January to March of 2016 in Shenzhen, a coastal mega-city in south China. In this study, high concentrations of PM2.5, NO2 and lower levels of O3 were observed during haze periods in comparison with clear days (Visibility > 15km). The major secondary ionic species were \begin{document}${\rm NH_4^ +} $\end{document} 、 \begin{document}${\rm NO_3^ -} $\end{document} and \begin{document}${\rm SO_4^{2 - }}$\end{document} -, which varied significantly on haze and clear days. The ratio of \begin{document}${\rm NO_3^ -}$\end{document} / \begin{document}${\rm SO_4^{2 - }}$\end{document} in haze days was greater than that on clear days and tended to be larger when air pollution became more serious. At the same time, compared with previous studies, it has been found that the ratio has been increasing gradually in Shenzhen, indicating that the motor vehicle exhaust emissions have a more and more important impact on air quality in Shenzhen. Sulfur oxidation rate(SOR) and nitrogen oxidation rate(NOR) was higher during the haze period than that in clean days, indicating efficient gas to particle conversion. Further analysis shows that high concentrations of sulfate might be explained by aqueous oxidation, but gas-phase reactions might dominate nitrate formation. This study also highlights that wintertime nitrate formation can be an important contributor to aerosol particles, especially during haze periods.

Chemical composition of precipitation in Shenzhen, a coastal mega-city in South China: Influence of urbanization and anthropogenic activities on acidity and ionic composition

Rainwater samples from Shenzhen in south China were collected over the period of a year, and the chemical compositions were measured with the main purpose of understanding the acidification of rainwater and the controlling factors. The pH value of precipitation ranged from 3.72 to 6.77, with a volume-weighted mean (VWM) value of 4.29, and the acid rain frequency was 97%. The VWM concentrations of anions and cations followed the order of SO42− > Cl− > NO3− and Na+ > Ca2+ > NH4+ > Mg2+ > K+, respectively. Air mass back-trajectory and positive matrix factorization analyses indicated that sources of ions in rainwater were mainly from sea salt, soil dust and anthropogenic activities. Compared with other areas in China, the rainwater of Shenzhen has the lowest values of the NP/AP, ∆pH and NF values of Ca2+ and NH4+, indicating that the lack of the capacity for neutralization could be the main reason for the severe acid rain problem. It is noteworthy that the rain acidification tendency is obvious, and the pH value has reduced by 1.0 units since the 1980s. Based on a comparison of the chemical compositions of the rainwater from different historical periods, the NO3− concentration was found to have increased consistently, whereas the NH4+ concentration maintained a decreasing trend since 1980. On the other hand, the nss-SO42− and nss-Ca2+ concentrations increased after 1980 and then decreased after 1994. Meanwhile, the decreasing pH was accompanied by a decreasing NP/AP ratio. These results suggest that the changes in human activities at different stages of urban development can lead to a synergistic change in the chemical characteristics of precipitation. Both an increase in the acidic species emissions (especially NOX) due to rapid economic development and a decrease in the alkaline ions concentration due to urbanization have resulted in the rain acidification tendency in Shenzhen.

Filter-based measurement of light absorption by brown carbon in PM2.5 in a megacity in South China

Carbonaceous aerosols represent an important nexus between air pollution and climate change. Here we collected filter-based PM2.5 samples during summer and autumn in 2015 at one urban and two rural sites in Guangzhou, a megacity in southern China, and got the light absorption by black carbon (BC) and brown carbon (BrC) resolved with a DRI Model 2015 multi-wavelength thermal/optical carbon analyzer apart from determining the organic carbon (OC) and elemental carbon (EC) contents. On average BrC contributed 12–15% of the measured absorption at 405nm (LA405) during summer and 15–19% during autumn with significant increase in the LA405 by BrC at the rural sites. Carbonaceous aerosols, identified as total carbon (TC), yielded average mass absorption efficiency at 405nm (MAE405) that were approximately 45% higher in autumn than in summer, an 83% increase was noted in the average MAE405 for OC, compared with an increase of only 14% in the average MAE405 for EC. The LA405 by BrC showed a good correlation (p<0.001) with the ratios of secondary OC to PM2.5 in summer. However, this correlation was poor (p>0.1) in autumn, implying greater secondary formation of BrC in summer. The correlations between levoglucosan (a marker of biomass burning) and the LA405 by BrC were significant during autumn but insignificant during summer, suggesting that the observed increase in the LA405 by BrC during autumn in rural areas was largely related to biomass burning. The measurements of light absorption at 550nm presented in this study indicated that the use of the IMPROVE algorithm with an MAE value of 10m2/g for EC to approximate light absorption may be appropriate in areas not strongly affected by fossil fuel combustion; however, this practice would underestimate the absorption of light by PM2.5 in areas heavily affected by vehicle exhausts and coal burning.

Towards a low carbon transition of urban public transport in megacities: A case study of Shenzhen, China

The urgent need to develop low carbon urban transport systems particularly in Asian megacities is facing the significant challenge of growing motorization following population increase and economic development. Sustainable urban public transport (UPT) plays a crucial role to fulfil the ambitious targets on carbon emission reduction. In this study, life cycle assessment was employed to quantify the environmental impacts (measured by carbon emissions) of UPT systems (including bus and subway) in Shenzhen, a leading megacity in South China, and then to examine corresponding carbon intensity reduction potentials. Results showed that the total carbon emissions from UPT in Shenzhen have increased rapidly from 0.70 Mt in 2005 to 1.74 Mt in 2015 due to the fast growth of the volume of transport turnover. However, current low-carbon UPT mode has only reduced 0.21 Mt CO2 e (cumulative value, from 2005 to 2015), and thus could not contribute proportionally to the city’s overall emission reduction target. Three advanced scenarios (from conservative to optimistic) were further simulated to estimate carbon emissions and their intensity reduction potentials over the next 15 years (2016–2030). Compared to the business-as-usual scenario, all these three low-carbon transition scenarios could significantly mitigate the rapid growth of carbon emissions and consequently help achieve Shenzhen’s carbon intensity reduction goal by 2030 (60%, compared to 2005 level). These findings could not only inform evidence-based policy making to facilitate the low-carbon transition of the urban transport sector in Shenzhen, but also shed light on sustainable urban transition in other megacities.

Characterization of ambient-generated exposure to fine particles using sulfate as a tracer in the Chinese megacity of Guangzhou.

Total personal exposures can differ from the concentrations measured at stationary ambient monitoring sites. To provide further insight into factors affecting exposure to particles, chemical tracers were used to separate total personal exposure into its ambient and non-ambient components. Simultaneous measurements of ambient and personal exposure to fine particles (PM2.5) were conducted in eight districts of Guangzhou, a megacity in South China, during the winter of 2011. Considerable significant correlations (Spearman's Rho, rs) between personal exposures and ambient concentrations of sulfate (SO42-; rs>0.68) were found in contrast to elemental carbon (EC; rs>0.37). The average fraction of personal SO42- to ambient SO42- resulting in an adjusted ambient exposure factor of α=0.72 and a slope of 0.73 was determined from linear regression analysis when there were minimal indoor sources of SO42-. From all data pooled across the districts, the estimated average ambient-generated and non-ambient-generated exposure to PM2.5 were 55.3μg/m3 (SD=23.4μg/m3) and 18.1μg/m3 (SD=29.1μg/m3), respectively. A significant association was found between ambient-generated exposure and ambient PM2.5 concentrations (Pearson's r=0.51, p<0.001). As expected, the non-ambient generated exposure was not related to the ambient concentrations. This study highlights the importance of both ambient and non-ambient components of total personal exposure in the megacity of Guangzhou. Our results support the use of SO42- as a tracer of personal exposure to PM2.5 of ambient origin in environmental and epidemiological studies.

Homing pigeons as a biomonitor for atmospheric PAHs and PCBs in Guangzhou, a megacity in South China

The occurrence of polycyclic aromatic hydrocarbons (PAHs) and polychlorinated biphenyl (PCBs) in urban atmosphere in Guangzhou, China were assessed using homing pigeons as a biomonitor. Contaminant concentrations in lung were significantly higher than those in liver and fat, indicating chemical uptake was mainly through respiratory route. Tricyclic PAHs and low chlorinated PCBs dominated composition of PAHs and PCBs in homing pigeons, similar as their composition in local atmosphere. Different age-dependent bioaccumulation patterns were noted for PAHs and PCBs. For 1-year old homing pigeons, higher levels of PAHs and PCBs in lung and liver tissues were probably ascribed to more intense flying than 5- and 10-year groups. Fat concentrations of PCBs were greater in aged pigeons than 1-year old pigeons, but PAH concentrations in fat slightly decreased in aged pigeons because of relatively fast biotransformation. Overall, homing pigeons could serve as a suitable biomonitor for urban atmospheric contaminants in coastal cities. CapsuleHoming pigeons could serve as a good biomonitor for PAHs and PCBs in urban atmosphere, yet different biotransformation potential of the chemicals caused different bioaccumulation patterns in pigeon fat.

Assessing the carbon footprint of the transport sector in mega cities via streamlined life cycle assessment: a case study of Shenzhen, South China

Purpose As one of largest energy consumers, the transport sector (TS) has significant impacts on the environment. Shenzhen, a developed megacity in South China, plays a leadership role in promoting the development of energy efficient vehicles in China.