With the rapid development of mobile communication technology and wearable electronic devices, the electromagnetic radiation generated by high-frequency information exchange inevitably threatens human health, so high-performance wearable electromagnetic interference (EMI) shielding materials are urgently needed. The 2D nanomaterial MXene exhibits superior EMI shielding performance owing to its high conductivity, however, its mechanical properties are limited due to the high porosity between MXene nanosheets. In recent years, it has been reported that by introducing natural nanocellulose as an organic framework, the EMI shielding and mechanical properties of MXene/nanocellulose composites can be synergically improved, which are expected to be widely used in wearable multifunctional shielding devices. In this review, the electromagnetic wave (EMW) attenuation mechanism of EMI shielding materials is briefly introduced, and the latest progress of MXene/nanocellulose composites in wearable multifunctional EMI shielding applications is comprehensively reviewed, wherein the advantages and disadvantages of different preparation methods and various types of composites are summarized. Finally, the challenges and perspectives are discussed, regarding the performance improvement, the performance control mechanism, and the large-scale production of MXene/nanocellulose composites. This review can provide guidance on the design of flexible MXene/nanocellulose composites for multifunctional electromagnetic protection applications in the future intelligent wearable field.
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