This research focuses on crafting highly flexible and efficient mechanical and magneto-mechano-electrical (MME) nanogenerators using electrospun poly (vinylidene fluoride)-nickel ferrite (PVDF-NiFe2O4) composite fibers, tailored for self-powered and wireless sensor networks. Nickel ferrite nanoparticles, averaging 40 nm in crystallite size, were synthesized through the autocombustion method and integrated as fillers within the PVDF matrix. Analysis via XRD and FTIR confirmed a greater presence of the ferroelectric β-phase in the PVDF electrospun fibers, accentuated by the incorporation of NiFe2O4. Notably, the mat containing 5 wt% of NiFe2O4 boasted an estimated 86 % β-phase. SEM micrographs depicted the formation of uniform bead-free fiber with a diameter of 900 nm. VSM analysis verified the ferrimagnetic properties of the composite fiber mats, registering a maximum saturation magnetization of 4.6 emu/cm3. Under mechanical tapping, the nanogenerator yielded an output voltage of 16.5 V and a power of 0.8 μW. The study also compared the performance of two MME nanogenerator geometries (rectangular and truncated) under an AC magnetic field of 10 Oe. Remarkably, the MME nanogenerator with a truncated geometry exhibited superior performance, generating 6.2 V, a 50 % increase over the rectangular counterpart.
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