The effects of additions of those elements which are near neighbors in the periodic table on the mechanical properties of niobium have been studied. These effects vary widely and follow no simple general rule. Some of the most important observations are as follows: 1. (1) At low temperatures alloy additions increase strength due to normal solid-solution strengthening and by raising the range over which strength becomes strongly temperature-dependent. The fracture transition temperature range is raised, in part due to the strength increase and in part due to changes in fracture characteristics. When compared at equal atom percentages, the group tungsten-molybdenum exert the greatest increase in fracture transition temperature; titanium and hafnium have relatively little effect; and zirconium and vanadium are intermediate. 2. (2) When compared at room temperature, equal atom percentages of vanadium and chromium appear to give the largest increase in strength; titanium and hafnium the smallest; and the remaining elements are intermediate. With the purity, grain size and test procedures used here, additions of over 10 w/o molybdenum or tungsten resulted in very low room-temperature ductility. 3. (3) At 1095°C when compared at equal atom percentages, zirconium and vanadium show the largest increase in strength; titanium has very little effect; molybdenum, tungsten and hafnium are intermediate strengtheners. Limited data on chromium indicate it to be a potent strengthener. 4. (4) No single alloy addition confers the best combination of mechanical properties. Elements like molybdenum and tungsten, which confer reasonably good increases in low- and high-temperature strength, result in a significant increase in the low-temperature fracture transition. Titanium strengthens at low temperature with very little effect on fracture transition but has very little effect on high temperature strength. Zirconium and hafnium appear to be somewhat intermediate in their effects on low- and high-temperature strength and ductility. On the basis of workability, low-temperature ductility, and elevated temperature strength, vanadium additions appear to be very attractive. The only apparent disadvantage is the hot shortness condition observed in the 20 w/o V alloy. 5. (5) Interstitial elements appear to exert a very pronounced effect on the elevated temperature properties of certain niobium-base alloys.
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