The structure of model alloys of the aluminum-zirconium system and industrial 1973-type alloy with an increased content of zirconium after rapid cooling to temperatures of the liquid-solid region and isothermal holding at these temperatures has been studied. It is shown that during primary crystallization of intermetallic precipitates with low crystallization rate, it is advisable to use the model of decomposition of supersaturated solid solutions. It was determined that formation of Al3Zr particles leads to zirconium decrease in the solid solution in center and grain boundary. Under certain crystallization conditions, there is an incubation period for the zirconium intermetallic compounds precipitation. It is shown that the incubation period for aluminum with 0.25 % zirconium is more than 2 minutes, and for 0.5 % zirconium — less than 0.5 minutes. The value of the dendritic parameter of the 1973-type alloy with an increased zirconium content during two-stage crystallization corresponds to the known regularity of the change in the dendritic parameter depending on the cooling rate. Casting of alloy ingots of 1960-type alloy with 0.27 % Zr by the two-stage cooling with the use of a water-cooling tray has been tested. This made possible to produce ingots with 84 mm diameter without the formation of primary intermetallic compounds. The mechanical properties of forgings from such ingots showed an increase in ductility by 20 % while maintaining the strength characteristics.
Read full abstract