Bulk Mechanical Properties Research Articles

The role of annealing and grain boundary controls on the mechanical properties of limestones and marbles

Chemical and mechanical processes are coupled in many geological and geochemical environments. Reactive processes anneal defects and restructure grain boundaries, modifying their elastic properties, levels of internal friction, wave propagation rates and fracture behaviors. The nature of these changes is, however, contingent on the initial state of the rock. In this study, impulse excitation was used to measure changes in mechanical properties as a function of dry and steam heating time at 300 °C for three carbonate rocks: Carrara marble, Carthage marble (Burlington Limestone), and Texas Cream limestone (Edwards limestone), with initial porosities of about 1 %, 3 %, and 27 %, respectively. Frequency-dependent phenomena along with mineral recrystallization were observed. This was coupled with small-angle X-ray and neutron scattering analysis to determine the relationship between changes in bulk mechanical and microstructural properties. An observed decrease in both the Young's and shear moduli in the experimental limestones as a function of heating time reflects and quantifies a reduction in the stiffness of the rock due to annealing. The internal friction of the samples first increases then decreases with reaction time, reflecting defect annealing, but this was balanced against grain boundary dissolution apparently driven by condensation of steam in the confined grain-boundary environment. This suggests an increase in the boiling point under confinement leading to dissolution, increased porosity and widening of the grain boundaries. In addition, comparison of small-angle X-ray and neutron scattering results suggests that it is inappropriate to assume that pores are empty for quantitative analysis of typical small-angle scattering samples.

On the influence of structural and chemical properties on the elastic modulus of woven bone under healing.

Woven bone, a heterogeneous and temporary tissue in bone regeneration, is remodeled by osteoblastic and osteoclastic activity and shaped by mechanical stress to restore healthy tissue properties. Characterizing this tissue at different length scales is crucial for developing micromechanical models that optimize mechanical parameters, thereby controlling regeneration and preventing non-unions. This study examines the temporal evolution of the mechanical properties of bone distraction callus using nanoindentation, ash analysis, micro-CT for trabecular microarchitecture, and Raman spectroscopy for mineral quality. It also establishes single- and two-parameter power laws based on experimental data to predict tissue-level and bulk mechanical properties. At the macro-scale, the tissue exhibited a considerable increase in bone fraction, controlled by the widening of trabeculae. The Raman mineral-to-matrix ratios increased to cortical levels during regeneration, but the local elastic modulus remained lower. During healing, the tissue underwent changes in ash fraction and in the percentages of Calcium and Phosphorus. Six statistically significant power laws were identified based on the ash fraction, bone fraction, and chemical and Raman parameters. The microarchitecture of woven bone plays a more significant role than its chemical composition in determining the apparent elastic modulus of the tissue. Raman parameters were demonstrated to provide more significant power laws correlations with the micro-scale elastic modulus than mineral content from ash analysis.

The effect of aging on the mechanical properties of bulk molding compound with different fiber lengths

The effect of aging on the mechanical properties of bulk molding compound with different fiber lengths

Densification mechanism and corrosion properties of h-BN/MgAl2O4 ceramics prepared by hot-pressed sintering

The dense h-BN/MgAl2O4 composites without additives were fabricated by hot-pressed sintering. The effect of sintering temperature and MgAl2O4 on the bulk density, mechanical properties and corrosion resistance were systematically investigated. The results showed that the collaboration of sintering temperature and MgAl2O4 dominated the densification behavior due to the enhanced pore filling effects and solid diffusion. The improved densification and induced microstructure development contributed to enhanced mechanical properties. Additionally, the residual MgAl2O4 is more conducive to forming plate-like complex oxide with molten steel after BN oxidation and B2O3 volatilization. Consequently, the plate-like complex oxide can effectively hinder direct contact between molten steel and the composite, which determines the corrosion resistance of the h-BN/MgAl2O4 composite. This study highlights the enormous potential of h-BN/MgAl2O4 composites for future use as side-sealing materials.

Plasma/Ozone Induced PolyNaSS Graft-Polymerization onto PEEK Biomaterial for Bio-integrated Orthopedic Implants

Owing to its superior bulk mechanical properties, poly (ether ether ketone) (PEEK) has gained popularity over the past 15 years as a metal substitute in biomedical implants. Low surface energy is a fundamental issue with PEEK implants. This low surface energy caused by a moderately hydrophobic surface may be able to inhibit cellular adherence and result in the development of an inflammatory response, which may result in cell necrosis and apoptosis. In this work, plasma and ozone treatments have been utilized to surface activate PEEK and graft ionic bioactive polymer polyNaSS (poly (sodium styrene sulfonate)) successfully on the surface to promote cellular attachment and biomineralization. The main goal of our research has been to find a stable green process for surface modification of PEEK by plasma/ozone approaches to increase PolyNaSS grafting efficiency and biomineralization. To further the field of bioactive orthopedic and dental implant technology, this research attempts to address a significant constraint of PEEK implants while preserving their favorable mechanical properties.

A study of fatigue property enhancement of 1045 steel processed by surface mechanical rolling treatment with an emphasis on residual stress influence

Several factors contribute to the observed bulk mechanical properties enhanced by surface mechanical rolling treatment (SMRT), and it is important to distinguish the influences of each major factor. A commonly used engineering carbon steel, 1045 steel, was chosen for the current study because the material does not have stress-induced phase transformation. A fully reversed strain-controlled gradual decreasing amplitude loading spectrum (ENV) was employed to release the residual stresses induced by SMRT. Fatigue experiments were conducted on the 1045 steel specimens with and without ENV to assess the influences of grain refinement and the residual stress on fatigue. It was found that SMRT refined and recombined the microstructures in the surface layer through deformation and fragmentation of brittle cementite, and extrusion of ductile ferrite between adjacent cementite layers. In the high cycle fatigue regime, both the SMRT induced residual stresses and the refined/recombined microstructures contributed to the enhancement of fatigue strength and fatigue ductility but the gradient microstructure contributed significantly more than do the residual stresses. Unlike stainless steels processed by SMRT, the carbon steel does not display a kink point in the strain-life fatigue curve, and all the crack initiations were found to occur on the specimen surface.

Uncovering Reduction Mechanisms of Fluoroethylene Carbonate

Energy storage plays an integral role in climate change mitigation, given that many promising alternatives to fossil fuel-based technologies rely on intermittent energy sources like the sun or wind. Particularly, lithium metal batteries (LMBs) are a promising technology due to lithium’s high theoretical specific capacity and low reduction potential, which can result in batteries with energy densities surpassing current state of the art lithium-ion batteries.1 Electrolyte design is a key strategy to improve the cycling stability and Coulombic efficiency of LMBs, where the highly reductive lithium metal anode reacts with the electrolyte during cycling, resulting in capacity loss. These reactions form a solid electrolyte interphase (SEI), and many successful electrolyte engineering strategies have involved tuning the SEI to be mechanically and chemically stable to prevent further reactions.In this research, we focus on fluoroethylene carbonate (FEC), a highly effective electrolyte solvent in LMBs.2 Although prior research has illuminated key reduction products of FEC2,3, including lithium fluoride (LiF), there remains a gap in understanding regarding the mechanism by which FEC and other similar fluorinated solvents are reduced to form an SEI. Furthermore, recent research has demonstrated that a preformed SEI comprised solely of LiF breaks down during cycling, illustrating that bulk chemical and mechanical properties of SEI components may not translate to their function within the SEI.4 In this work, we employ electron paramagnetic resonance (EPR) spectroscopy to study intermediate generation during FEC reduction. We pursued both a chemical reduction using lithium naphthalenide and an electrochemical approach to reduce FEC. The use of EPR with spin traps enables insight into the radical species formed during FEC reduction, which we hypothesize are precursors to cross-linked polymer networks that are key to a high performing SEI. Here, we employed conventional post-mortem SEI analysis like X-ray Photoelectron Spectroscopy (XPS) in addition to EPR to clarify reduction mechanisms of FEC and form a framework for studying electrolyte reduction intermediates. Ultimately, this approach affords insight into electrolyte breakdown mechanisms to form an effective SEI which can both accommodate volume expansion and inhibit parasitic electrolyte consumption. This will guide electrolyte design for high Coulombic efficiency LMBs in the future.References K. G. Gallagher et al., Energy Environ. Sci., 7, 1555–1563 (2014).X.-Q. Zhang, X.-B. Cheng, X. Chen, C. Yan, and Q. Zhang, Advanced Functional Materials, 27, 1605989 (2017).Y. Jin et al., J. Am. Chem. Soc., 139, 14992–15004 (2017).M. He, R. Guo, G. M. Hobold, H. Gao, and B. M. Gallant, Proceedings of the National Academy of Sciences, 117, 73–79 (2020).

Influence of Remote Laser Cutting on Magnetic Loss and Mechanical Properties in 0.2 mm Silicon Steel

Energy loss due to eddy current generation is a significant factor in reduced efficiency of electrical machines, therefore motor cores with thinner sheets are required due to their effect in reducing eddy currents. However, reducing the thickness of laminations is challenging due to the high tooling costs in blanking due to the small tolerances required, whilst other methods such as conventional laser cutting are too slow to be commercially viable. In this paper the influence of remote laser cutting on thin electrical steel sheets (Cogent/Tata Steel NO20 3.2% Si) has been investigated on the tensile strain to fracture, fatigue life, edge hardness, and energy loss in an AC magnetisation cycle for two laser power levels. The laser power has found to have no statistically significant influence on the bulk mechanical properties of the material, but significantly affects the measured specific loss. The latter was associated with the increased edge hardness at higher laser powers. Based on the parameters selected it is highly questionable whether RLC offers a viable method for lamination cutting, significant refinement of the laser parameters and/or the use an alternative laser such as an ultra-fast pulsed laser is required to be competitive with existing methods. Additionally, it is shown that energy loss increases linearly with respect to length of the cut edge - to the minimum cut spacing tested of 6 mm. These results can be used to optimise laser parameters to reduce the degradation of magnetic properties by decreasing laser power where possible.

Insights into molecular and bulk mechanical properties of glassy carbon through molecular dynamics simulations and mechanical tensile testing

With increasing interest in the use of glassy carbon (GC) for a broad range of application areas, the need for developing a fundamental understanding of its mechanical properties has come to the forefront. Furthermore, recent theoretical and modeling works that highlight the synthesis of GC via the pyrolysis of polymer precursors has explored the possibilities of a revisit to the investigation of their mechanical properties at a fundamental level. Although there are isolated reports on the experimental determination of its elastic modulus, insights into the stress-strain behavior of a GC material under tension and compression obtained through simulations, either at the molecular level or for the bulk materials, are missing. This study fills the gap at the molecular level and investigates the mechanical properties of GC using molecular dynamics (MD) simulations, which model the atomistic-level formation and breaking of bonds using bond-order-based reactive force field formulations. The molecular model considered in this simulation has a characteristic 3D cage-like structure of five-, six-, and seven-membered carbon rings and graphitic domains of a flat graphene-like structure. The GC molecular model was subjected to loading under varying strain rates (0.4, 0.6, 1.25, and 2.5 ns−1) and temperatures (300 K–800 K) in each of the three axes: x, y, and z. The simulations show that the GC nanostructure has distinct stress-strain curves under tension and compression. In tension, MD modeling predicted a mean elastic modulus of 5.71GPa for a single GC nanostructure with some dependency on the strain rate and temperature, whereas, in compression, the elastic modulus was also found to depend on the strain rate and temperature and was predicted to have a mean value of 35 GPa. To validate the simulation results and develop experimental insights into the bulk behavior, mechanical tests were conducted on dog-bone-shaped testing coupons that were subjected to uniaxial tension and loaded until failure. The GC test coupons demonstrated a bulk modulus of 17 ±2.69 GPa in tension, which compares well with those reported in the literature. However, comparing MD simulation outcomes to those of uniaxial mechanical testing reveals that the bulk modulus of GC in tension found experimentally is higher than the modulus of single GC nanostructures predicted by MD modeling, which inherently underestimates the bulk modulus. With regard to failure modes, the MD simulations predicted failure in tension accompanied by the breaking of carbon rings within the molecular structure. In contrast, the mechanical testing demonstrated that failure modes are dominated by brittle failure planes largely due to the amorphous structure of GC.

Influence of surface finishing by grinding on the cavitation erosion resistance of 316L and NiAl-bronze

Improving the mechanical properties of bulk and near-surface materials and alternating the dynamics of cavitating bubbles are two main methods to reduce cavitation erosion damage. Grinding and polishing, as two common surface finishing stages, can alter the cavitation erosion damage on metallic materials by affecting both the bubble dynamics and the mechanical properties of the surface. In this paper, the ultrasonic cavitation erosion resistance of 316L and NiAl-bronze alloys, each with two initial surface conditions of grinding and polishing is investigated, focussing on the material reaction. The mechanisms of material removal are discussed based on surface and subsurface observations to explain the effect of surface finishing on the cavitation erosion damage. After 8.5 h cavitation erosion testing time, a lower erosion mass loss was obtained for both alloys in the ground state as compared to the polished state suggesting that grinding can improve the cavitation erosion resistance of alloys. On the other hand, the polishing process improved the erosion resistance of NiAl-bronze at the early stages of cavitation. This is discussed in light of the two distinct surface characteristics of roughness and hardness, which, in turn, tend to increase and decrease cavitation erosion damage. Planar crystallographic boundaries and intermetallic-matrix interfaces were found to be the most susceptible sites to early erosion damage on the polished 316L and bronze, respectively.

Comparison of Mechanical Properties of Bulk NiAl-Re-Al2O3 Intermetallic Material Manufactured by Laser Powder Bed Fusion and Hot Pressing

AbstractThe low fracture toughness of NiAl at room temperature is one of the critical issues limiting its application in aircraft engines. It has been previously shown that a small addition of rhenium and alumina significantly improves the fracture toughness of hot-pressed NiAl. In this work, NiAl with an admixture of rhenium and alumina was produced by laser powder bed fusion additive technology (LPBF). The purpose was to compare the fracture toughness, bending strength, and microhardness of the NiAl-Re-Al2O3 material produced by LPBF and hot pressing (HP). Our results show that the LPBF material has lower fracture toughness and bending strength compared to its hot-pressed equivalent. Microcracks generated by thermal stresses during the LPBF process were the primary cause of this behavior. To improve the LPBF material, a post-processing by HP was applied. However, the fracture toughness of the (LPBF + HP) material remained at 50% of the KIC of the HP material. This study supports hot pressing as a suitable processing method for NiAl with rhenium and alumina additions. However, a hybrid approach combining LPBF and HP proved to be highly effective on the raw NiAl powder, resulting in superior fracture toughness of the final material compared to that consolidated by singular HP.

Mechanophysical and Anti-Adhesive Properties of a Nanoclay-Containing PMMA Denture Resin.

Poly(methyl methacrylate) (PMMA) is commonly used for dental dentures, but it has the drawback of promoting oral health risks due to oral bacterial adhesion. Recently, various nanoparticles have been incorporated into PMMA to tackle these issues. This study aims to investigate the mechanophysical and antimicrobial adhesive properties of a denture resin by incorporating of nanoclay into PMMA. Specimens were prepared by adding 0, 1, 2, and 4 wt % surface-modified nanoclay (Sigma) to self-polymerizing PMMA denture resin. These specimens were then evaluated using FTIR, TGA/DTG, and FE-SEM with EDS. Various mechanical and surface physical properties, including nanoindentation, were measured and compared with those of pure PMMA. Antiadhesion experiments were conducted by applying a Candida albicans (ATCC 11006) suspension to the surface of the specimens. The antiadhesion activity of C. albicans was confirmed through a yeast-wall component (mannan) and mRNA-seq analysis. The bulk mechanical properties of nanoclay-PMMA composites were decreased compared to those of pure PMMA, while the flexural strength and modulus met the ISO 20795-1 requirement. However, there were no significant differences in the nanoindentation hardness and elastic modulus. The surface energy revealed a significant decrease at 4 wt % nanoclay-PMMA. The antiadhesion effect of Candida albicans was evident along with nanoclay content in the nanocomposites and confirmed by the reduced attachment of mannan on nanoclay-PMMA composites. mRNA-seq analysis supported overall transcriptome changes in altering attachment and metabolism behaviors on the surface. The nanoclay-PMMA materials showed a lower surface energy as the content increased, leading to an antiadhesion effect against Candida albicans. These findings indicate that incorporating nanoclay into PMMA surfaces could be a valuable strategy for preventing the fungal biofilm formation of denture base materials.

Impact of sintering time on structure and electrical properties of Pb-free BNT-BKT-SZ ceramics

The work focuses on preparing and characterising BNT-based ceramics via a solidstate method. To investigate the phase, microstructure, and physical and electrical properties of BNT-based ceramics.Lead-free piezoelectric bismuth sodium titanate – bismuth potassium titanate – stronsium zirconate (BNT-BKT-SZ) ceramics were fabricated by the solid-state reaction method. The effect of sintering temperature with soaking times of 2, 4, and 6 h at 1150C on structural, microstructure, density, porosity, and electrical properties was examined. The phase formation of the ceramics was examined using X-ray diffraction (XRD). Scanning electron microscopy (SEM) (JEOL JSM5910LV) was employed to investigate ceramic microstructure. The bulk density and mechanical properties of the sample were measured using Archimedes’ method, respectively. The electrical properties of ceramics, such as dielectrics, ferroelectrics, and piezoelectrics, were investigated.XRD showed all samples had a single perovskite structure and no secondary phase. All sintered samples at different temperatures have a coexisting phase boundary between the rhombohedral phase and the tetragonal phase. The sintered ceramic at 1150C with a soaking time of 4 h shows a maximum density of 5.89 g/cm3. In addition, the temperature at which the sintering process is carried out substantially impacts the electrical characteristics. Dielectric and electric field-induced strain (Smax) properties that sintered at 1150C with a soaking time of 4 h exhibited the highest values of 4.489 and 0.39% (d33* of 650 pm/V), respectively.The impact of the coercive field on the electrical breakdown characteristics of ceramics should be investigated further in the course of research that has to be carried out.The characterisation confirmed the effects of sintering temperature on the physical, phase, microstructure, and electrical properties of BNT-based ceramics.Such research demonstrates a suitable sintering temperature for producing BNT-BKT-SZ. The mechanical and electrical properties of a material are dependent on its sintering parameters. The ceramic system is suitable for piezoelectric and/or energy storage applications.

Assessing the feasibility of laser ablation coating removal (LACR) on legacy bridge steel: Coating removal and adhesion, and effects on mechanical properties

The application of protective organic coatings is one of the most effective and commonly used corrosion mitigation strategies. To maintain the protective nature of coatings on long-term-exposed surfaces such as steel bridge components, coatings must be periodically removed and reapplied. A relatively new method called laser ablation coating removal (LACR), which incorporates a high energy nanosecond pulsed laser beam in combination with a high efficiency filtration system, allows for safe and effective removal of coatings and contamination from metal surfaces. In this study, LACR cleaning is tested on legacy bridge steel components to investigate the effect on substrate cleanliness and steel mechanical properties. These bridge sections were never blasted and contain a 20–100 μm thick mill-scale layer (iron oxide) below several coating layers (including lead-rich coatings). The top micron of the oxide layer is melted by LACR and also thermally insulates the underlying steel and prevents any melting within the metallic substrate. The resulting surfaces are analyzed using microscopy, hardness testing, tensile, and fatigue testing, and it is shown that LACR does not cause any measurable detrimental effects to the bulk mechanical properties of the bridge steel, as well as effectively removes all paint coatings. Furthermore, adhesion testing on LACR-cleaned substrates shows excellent adhesion, qualifying above adhesion requirements for coated steel.

Additively manufactured β-Ti5553 with laser powder bed fusion: Microstructures and mechanical properties of bulk and lattice parts

Ti5553 (Ti-5Al-5Mo-5V-3Cr wt%) is a titanium alloy widely used for its high strength-to-weight ratio and good formability at elevated temperatures. Unlike Ti-6Al-4V, Ti5553 does not undergo martensitic transformation, preventing cracking of brittle martensite upon rapid cooling. This makes it a strong candidate for additive manufacturing (AM), particularly laser powder bed fusion (L-PBF). L-PBF offers the unique opportunity to make fine lattice structures to reduce component weight. Despite the growing field of AM, there have been limited studies on L-PBF Ti5553 lattices and how their properties differ from the bulk. The present work addresses this knowledge gap by investigating microstructures and properties of L-PBF bulk and lattice parts and the effect of post L-PBF heat treatments. Electron microscopy and mechanical testing show that the high dislocation density formed during L-PBF increases bulk part’s yield strength by approximately 100 MPa compared to the conventional alloy. Digital image correlation during compression testing of octet truss lattices reveals a layer-by-layer failure mode. Compared to the bulk, the lattice contains copious ω nanoprecipitation, weaker <001> texture, smaller average grain sizes, and larger content of high-angle grain boundaries. These features elicit differences in Taylor factor distributions for the lattice depending on load direction, underlining challenges in predicting lattice mechanical response based on bulk properties. By examining the processing-structure-property relationships in the bulk and lattice, the present results delineate their microstructural and mechanical differences and establish a benchmark for the future design applications of L-PBF Ti5553.

Analysis of water absorption on the efficiency of bonded composite repair of aluminum alloy panels

Abstract Carbon fiber-reinforced polymer (CFRP) exhibits aging effects over time that can degrade its mechanical properties. In this study, a systematic investigation was carried out to investigate the effect of distilled water aging on the mechanical properties of CFRP composite patch bonded on Al 2024-T3 plates. We built a finite element model to analyze the effect of water absorption by the composite and the adhesive on the effectiveness of the composite patch repair. Using the experimentally evaluated mechanical properties of CFRP and Araldite adhesive subjected to distilled water immersion, finite element simulations were validated. The experimental observations deduce that there was a negligible effect of moisture absorption on the bulk mechanical properties of CFRP and adhesive over time. However, a significant effect of moisture absorption was observed on the elasto-plastic behavior of both CFRP and adhesive. Consequently, the numerical simulations suggest that the moisture absorption reduces the bonded composite patch repair efficiency attributed to an increase in the plasticity around the crack front and accordingly increases the damage in the adhesive layer. This study attempts to provide guidelines on the severity of damage caused by water absorption on the performance of structures repaired with composite patches.

Open-cell cordierite-based foams from eco-friendly geopolymer precursors via replica route

Open-cell cordierite-based foams with high porosity were synthesized by a facile replica route, using geopolymers as precursors and polyurethane foams as polymer templates. The geopolymer precursors, incorporating MgO as an additional magnesium source, were prepared using metakaolin and fly ash under activation of NaOH solution and sodium silicate solution. Polyurethane foams with geopolymer were obtained by an impregnation method. The hybrid foams comprising polyurethane foam and geopolymer were cured/solidified at 75 °C for 24 h. Subsequently, the hybrid foams were subjected to ammonium ion-exchange followed by sintering at 1200 °C for 2 h to produce porous cordierite-based ceramics. The resulting foamed ceramics were characterized in terms of bulk density, porosity, structural evolution, and mechanical properties. Porous cordierite-based ceramic foams exhibiting a total porosity of approximately 88.64 vol% and a compressive strength of around 0.47 MPa were successfully fabricated by the replica route.

Directional Adhesion of Monodomain Liquid Crystalline Elastomers.

Pressure-sensitive adhesives (PSAs) are widely employed in consumer goods, health care, and commercial industry. Anisotropic adhesion of PSAs is often desirable to enable high force capacity coupled with facile release and has typically been realized through the introduction of complex surface and/or bulk microstructures while also maintaining high surface conformability. Although effective, microstructure fabrication can add cost and complexity to adhesive fabrication. Here, we explore aligned liquid crystalline elastomers (LCEs) as directional adhesives. Aligned LCEs exhibit direction-dependent stiffness, dissipation, and nonlinear deformation under load. By varying the cross-link content, we study how the bulk mechanical properties of LCEs correlate to their peel strength and peel anisotropy. We demonstrate up to a 9-fold difference in peel force measured when the LCE is peeled parallel vs perpendicular to the alignment axis. Opportunities to spatially localize adhesion are presented in a monolithic LCE patterned with different director orientations.

Laser-assisted surface alloying of titanium with silver to enhance antibacterial and bone-cell mineralization properties of orthopedic implants.

Orthopedic device-related infection (ODRI) poses a significant threat to patients with titanium-based implants. The challenge lies in developing antibacterial surfaces that preserve the bulk mechanical properties of titanium implants while exhibiting characteristics similar to bone tissue. In response, we present a two-step approach: silver nanoparticle (AgNP) coating followed by selective laser-assisted surface alloying on commonly used titanium alumina vanadium (TiAl6V4) implant surfaces. This process imparts antibacterial properties without compromising the bulk mechanical characteristics of the titanium alloy. Systematic optimization of laser beam power (8-40 W) resulted in an optimized surface (32 W) with uniform TiAg alloy formation. This surface displayed a distinctive hierarchical mesoporous textured surface, featuring cauliflower-like nanostructures measuring between 5-10 nm uniformly covering spatial line periods of 25 μm while demonstrating homogenous elemental distribution of silver throughout the laser processed surface. The optimized laser processed surface exhibited prolonged superhydrophilicity (40 days) and antibacterial efficacy (12 days) against Staphylococcus aureus and Escherichia coli. Additionally, there was a significant twofold increase in bone mineralization compared to the pristine Ti6Al4V surface (p < 0.05). Rockwell hardness tests confirmed minimal (<1%) change in bulk mechanical properties compared to the pristine surface. This innovative laser-assisted approach, with its precisely tailored surface morphology, holds promise for providing enduring antibacterial and osteointegration properties, rendering it an optimal choice for modifying load-bearing implant devices without altering material bulk characteristics.

Synthesis of cemented paste backfill by reutilizing multiple industrial waste residues and ultrafine tailings: Strength, microstructure, and GA-GPR prediction modeling

Industrial waste residues are increasingly reutilized in the preparation of cemented paste backfill for reducing the cost of mine filling. Therefore, to promote the utilization of the bulk industrial waste residues (IWRs), mechanical and microstructure properties of cemented ultrafine tailings backfill (CUFTB) manufactured by reutilizing 5–10 wt% steel slag (SS), 5–10 wt% fly ash (FA), 16–22 wt% carbide slag (CS), 0–3 wt% desulfuration gypsum (DG), and 40–74 wt% blast furnace slag (BFS) and ultrafine tailing (d50 = 10.84 μm) were investigated after curing of 1-, 3-, 7-, 14-, 28-, 56- days. Unconfined compressive strength (UCS) test was adopted to determine strength and the regression analysis was applied to establish UCS prediction model. XRD, SEM, and MIP were used to evaluate the evolution characteristics of CUFTB microstructure. The obtained results indicate that the cementitious material synthetized by IWRs can completely substitute Portland Cement (PC) for CUFTB. After curing of 28 days, CUFTB exhibit UCS values with increasing of 10.80% ∼ 44.89% than those made of PC. Logarithmic function UCS=α⋅lnt+β is constructed to characterize UCS development with curing time. By optimizing the hyperparameters of Gaussian process regression (GPR) using Genetic algorithm (GA), GA-GPR model is established with high accuracy for predicting UCS. Microscopic analysis reveals that under the alkaline environment, the hydration reaction of SS, FA, BFS occurred to generate calcite (CaCO3), ettringite (AFt) and hydrate calcium silicate gel with a low Ca/Si ratio. Microtopography formed with more refined pore distribution of 0.003- and 1- μm inside CUFTB. To substitute PC using the cementitious material synthesized by IWRs can reduce the mining cost and CO2 emission. The findings provide the guidance for the synthesis of sustainable filling material by reutilizing IWRs.