Mechanical Response Properties Research Articles

Stiffening of the Cytoplasm in Response to Intracellularly Applied Forces.

Cells constantly encounter mechanical forces that regulate various cellular functions, such as migration, division, and differentiation. Understanding how cells respond to forces at the intracellular level is essential for elucidating the mechanical adaptability of living cells. This study investigates how the cytoplasm alters its mechanical properties in response to forces applied inside a cell. The mechanical properties were measured through in situ characterization using magnetic tweezers to apply mechanical forces on magnetic beads internalized into cells. The findings reveal that the cytoplasm stiffens within seconds when force is applied to the cytoplasm. Macromolecular crowding and cytoskeletal structures, particularly F-actin, were found to significantly contribute to cytoplasm stiffening. The stiffening response was also observed across multiple length scales by using magnetic beads of varying diameters. These results highlight the rapid adaptation of the cytoplasm to mechanical forces applied to the inside of a cell.

Enhancement in the Mechanical Properties of Newly Developed Ceramic Reinforced Al-Based Syntactic Foams: Analysis of Microstructure, Mechanical Response, and Energy Absorption Properties

Enhancement in the Mechanical Properties of Newly Developed Ceramic Reinforced Al-Based Syntactic Foams: Analysis of Microstructure, Mechanical Response, and Energy Absorption Properties

Effect of impact position on the mechanical response and viscoelastic behavior of double‐blade composite stiffened structures

AbstractThis paper focuses on the mechanical response and viscoelastic properties of double‐blade composite stiffened structure (DCSS) under low‐velocity impact (LVI). Firstly, the impact resistance and viscoelastic behavior of the DCSS are revealed by LVI testing at four different locations using the same initial velocity. Next, the damage morphologies at the impact locations are observed with ultrasonic A‐ and C‐scan equipment and optical microscopy. At last, the DCSS containing impact damage is implemented for axial compression and the strain values of the DCSS surface are obtained using a strain testing system to reveal its residual properties and buckling behavior. The results show that there are significant differences in the impact damage modes at the four different locations. The maximum impact resistance is observed at location D, while location A has the opposite. The DCSS has a certain viscoelastic behavior at LVI and conforms to an exponential decay model. Moreover, position B presents interface debonding damage due to stiffness discontinuities at the flange and skin bonding and severely weakens the load carrying performance of the DCSS.Highlights The impact resistance of different positions is analyzed by LVI experimental results. Viscoelastic properties exist at different impact locations and obey the exponential decay model. Impact damage alters the buckling load and residual strength of the DCSS. The damage mechanism of the triangular zone is revealed by damage morphology.

Strain-Stiffening Mechanoresponse in Dynamic-Covalent Cellulose Hydrogels.

Mechanical stimuli such as strain, force, and pressure are pervasive within and beyond the human body. Mechanoresponsive hydrogels have been engineered to undergo changes in their physicochemical or mechanical properties in response to such stimuli. Relevant responses can include strain-stiffening, self-healing, strain-dependent stress relaxation, and shear rate-dependent viscosity. These features are a direct result of dynamic bonds or noncovalent/physical interactions within such hydrogels. The contributions of various types of bonds and intermolecular interactions to these behaviors are important to more fully understand the resulting materials and engineer their mechanoresponsive features. Here, strain-stiffening in carboxymethylcellulose hydrogels cross-linked with pendant dynamic-covalent boronate esters using tannic acid is studied and modulated as a function of polymer concentration, temperature, and effective cross-link density. Furthermore, these materials are found to exhibit self-healing and strain-memory, as well as strain-dependent stress relaxation and shear rate-dependent changes in gel viscosity. These features are attributed to the dynamic nature of the boronate ester cross-links, interchain hydrogen bonding and bundling, or a combination of these two intermolecular interactions. This work provides insight into the interplay of such interactions in the context of mechanoresponsive behaviors, particularly informing the design of hydrogels with tunable strain-stiffening. The multiresponsive and tunable nature of this hydrogel system therefore presents a promising platform for a variety of applications.

Dynamic Mechanical Response and Fracture Properties of Rock-Like Materials with Parallel and Intersecting Flaws

Dynamic Mechanical Response and Fracture Properties of Rock-Like Materials with Parallel and Intersecting Flaws

Research of flexible sensor based on nanomaterial

Research of flexible sensor based on nanomaterial

Temperature Dependent Dynamic Response of Open-Cell Polyurethane Foams

BackgroundPolyurethane foams have many uses ranging from comfort fitting seats and shoes to protective inserts in helmets and sports equipment. Current military helmet designs employ foam pads of varying densities and bulk material properties to help absorb energy from impacts ranging from quasi-static to ballistic level strain-rates.ObjectiveThis study aims to analyze the thermomechanical uniaxial compression behavior of a high density liner foam pad and a low density liner foam pad used in the Advanced Combat Helmet. These experiments were conducted under strain-rates of 102\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$10^2$$\\end{document} s-1\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$^{-1}$$\\end{document} and under temperature conditions ranging from -20 to 40 °C. This temperature range was chosen to simulate desert and arctic conditions, with a strain-rate regime chosen to represent loads that would occur often throughout the life of the helmet, such as drops, bumps from riding in a vehicle, or heavy collisions from falling.MethodMultiple experimental apparatuses were used in this study, including a Shimadzu TCE-N300 thermostatic chamber (used to create the varying temperature environments) and a custom-built drop-test system (used to induce intermediate strain-rates). Every experiment was paired with two accelerometers and a high speed camera used for Digital Image Correlation (DIC) to analyze sample deformation and resultant acceleration. The foam’s mechanical response and energy absorption properties were investigated from the measured stress-strain curves. Additionally, each foam composition was analyzed with X-ray computed micro-tomography (XCT) to investigate microstructure properties pre and post-mortem.ResultsResults show that temperature decreased the energy absorption of the low density composition by 48% ± 5% as temperature changed from -20 °C to 40 °C, while energy absorption increased by 53% ± 16% for the high density composition over the same temperature.ConclusionA comparison between the loading response and the material’s density characteristics revealed that the foam’s mechanical properties are heavily dependent on strain-rate applications, as well as environmental factors including temperature. Several important characteristics surrounding each foam composition’s deformation mechanics and damage tolerance as a result of temperature are discussed.

Mechanically Adaptive Polymers Constructed from Dynamic Coordination Equilibria.

Designing materials capable of adapting their mechanical properties in response to external stimuli is the key to preventing failure and extending their service life. However, existing mechanically adaptive polymers are hindered by limitations such as inadequate load-bearing capacity, difficulty in achieving reversible changes, high cost, and a lack of multiple responsiveness. Herein, we address these challenges using dynamic coordination bonds. A new type of mechanically adaptive material with both rate- and temperature-responsiveness was developed. Owing to the stimuli-responsiveness of the coordination equilibria, the prepared polymers, PBMBD-Fe and PBMBD-Co, exhibit mechanically adaptive properties, including temperature-sensitive strength modulation and rate-dependent impact hardening. Benefitting from the dynamic nature of the coordination bonds, the polymers exhibited impressive energy dissipation, damping capacity (loss factors of 1.15 and 2.09 at 1.0 Hz), self-healing, and 3D printing abilities, offering durable and customizable impact resistance and protective performance. The development of impact-resistant materials with comprehensive properties has potential applications in the sustainable and intelligent protection fields.

Mechanically Adaptive Polymers Constructed from Dynamic Coordination Equilibria

AbstractDesigning materials capable of adapting their mechanical properties in response to external stimuli is the key to preventing failure and extending their service life. However, existing mechanically adaptive polymers are hindered by limitations such as inadequate load‐bearing capacity, difficulty in achieving reversible changes, high cost, and a lack of multiple responsiveness. Herein, we address these challenges using dynamic coordination bonds. A new type of mechanically adaptive material with both rate‐ and temperature‐responsiveness was developed. Owing to the stimuli‐responsiveness of the coordination equilibria, the prepared polymers, PBMBD‐Fe and PBMBD‐Co, exhibit mechanically adaptive properties, including temperature‐sensitive strength modulation and rate‐dependent impact hardening. Benefitting from the dynamic nature of the coordination bonds, the polymers exhibited impressive energy dissipation, damping capacity (loss factors of 1.15 and 2.09 at 1.0 Hz), self‐healing, and 3D printing abilities, offering durable and customizable impact resistance and protective performance. The development of impact‐resistant materials with comprehensive properties has potential applications in the sustainable and intelligent protection fields.

Thermo-Hydro-Mechanic-Chemical coupling model for hydrate-bearing sediment within a unified granular thermodynamic theory

The extraction process of methane hydrate involves interactions of multiple fields, phases, and loading stages. By extrapolating deductions from the thermodynamic equation in granular thermodynamic framework and amalgamating with coupled flow theory and linear non-equilibrium theory, a comprehensive Thermo-Hydro-Mechanic-Chemical (THMC) coupling model for hydrate-bearing sediment is established in this study. The mechanical field is established by energy dissipation conservation, the hydraulic field considers the increase in gas and liquid permeability due to temperature gradients, while the thermal field incorporates the rates of seepage, hydrate dissociation, and volumetric strain. Meanwhile, Darcy's law is explained as general deductions from the thermodynamic equation without the need for assumption. The proposed model is applied from the perspective of unit scale and coupling field, and verified with the test data. The modelling results show that the deduced model can capture the strain-softening, dilatancy, and stress paths behavior under various drainage conditions, and the volumetric strain, methane gas production and variations in heat exchange caused by the hydrate dissociation can also be predicted. Furthermore, the mechanical response and dissociation properties of sediment samples with various parameter values are discussed.

Harnessing multifunctional collagen mimetic peptides to create bioinspired stimuli responsive hydrogels for controlled cell culture.

The demand for synthetic soft materials with bioinspired structures continues to grow. Material applications range from in vitro and in vivo tissue mimics to therapeutic delivery systems, where well-defined synthetic building blocks offer precise and reproducible property control. This work examines a synthetic assembling peptide, specifically a multifunctional collagen mimetic peptide (mfCMP) either alone or with reactive macromers, for the creation of responsive hydrogels that capture aspects of soft collagen-rich tissues. We first explored how buffer choice impacts mfCMP hierarchical assembly, in particular, peptide melting temperature, fibril morphology, and ability to form physical hydrogels. Assembly in physiologically relevant buffer resulted in collagen-like fibrillar structures and physically assembled hydrogels with shear-thinning (as indicated through strain-yielding) and self-healing properties. Further, we aimed to create fully synthetic, composite peptide-polymer hydrogels with dynamic responses to various stimuli, inspired by the extracellular matrix (ECM). Specifically, we established mfCMP-poly(ethylene glycol) (PEG) hydrogel compositions that demonstrate increasing non-linear viscoelasticity in response to applied strain as the amount of assembled mfCMP content increases. Furthermore, the thermal responsiveness of mfCMP physical crosslinks was harnessed to manipulate the composite hydrogel mechanical properties in response to changes in temperature. Finally, cells relevant in wound healing, human lung fibroblasts, were encapsulated within these peptide-polymer hydrogels to explore the impact of increased mfCMP, and the resulting changes in viscoelasticity, on cell response. This work establishes mfCMP building blocks as versatile tools for creating hybrid and adaptable systems with applications ranging from injectable shear-thinning materials to responsive interfaces and synthetic ECMs for tissue engineering.

Mechanical Janus lattice with plug-switch orientation

In recent years, materials with asymmetric mechanical response properties (mechanical Janus materials) have been found possess numerous potential applications, i.e. shock absorption and vibration isolation. In this study, we propose a novel mechanical Janus lattice whose asymmetric mechanical response can be switched in orientation by a plug. Through finite element analysis and experimental verification, this lattice exhibits asymmetric displacement responses to symmetric forces. Furthermore, with such a plug structure inside, individual lattices can switch the orientation of asymmetry and thus achieve reprogrammable design of a mechanical structure with chained lattices. The reprogrammable asymmetry of this material will offer multiple functions in design of mechanical metamaterials

Constructing a viscoelastic film for enhanced oil recovery via self-adsorption of amphiphilic nanosheets at oil-water interface

Immiscible liquid-liquid interfaces have widespread applications in drug delivery, oil-water separation, oil recovery, emulsion and foam stability, etc. Here, a dense viscoelastic interface film is constructed via the self-adsorption of amphiphilic molybdenum disulfide nanosheets at the oil-water interface, which has significant implications for enhanced oil recovery. The microscopic dispersion characteristics of amphiphilic nanosheets in water phase are characterized using Cryo-EM, and the adsorption regularities of amphiphilic nanosheets in horizontal and vertical directions of oil-water interface are also revealed. Besides the mechanical response and rheological properties of interface adsorption film are systematically studied. Experimental results demonstrate that the amphiphilic nanosheet can self-curl to form a single amphiphilic nanosheet with a size of 30 nm in the water phase as the amphiphilic nanosheets concentration is lower than 50 mg/L. When the amphiphilic nanosheets concentration reaches 100 mg/L, obvious water-phase aggregation behaviors happen. The amphiphilic nanosheets can reduce the oil-water interfacial tension from 18.47 mN/m to 0.27 mN/m by forming multilayer adsorption at the oil-water interface. The adsorption ratio of amphiphilic nanosheets from bulk phase to oil-water interface can reach 97.50 %. In addition, the oil-water interface adsorption film exhibits excellent elastic properties and higher strength because the amphiphilic nanosheets can form a planar network structure at the oil-water interface which can be also directly observed in microfluidic pores. The storage modulus and interface shear viscosity of interface adsorption film are 1.65 Pa and 1.38 mN·s/m, respectively. In theory, the required desorption energy of a single amphiphilic nanosheet from oil-water interface to bulk phase is deduced to be 587 KBT. This work is expected to provide amphiphilic molybdenum disulfide nanosheet as an effective candidate for enhanced oil recovery.

Shape and Stiffness Switchable Hydroplastic Wood with Programmability and Reproducibility.

Stiffness switchable materials (e.g., supramolecular polymers, metals) that alter their shape and mechanical properties in response to specific stimuli are potentially utilized in the structural engineering field but still limited due to the use of petroleum-based synthetic monomers and large energy consumption. Herein, a sustainable and facile solvent casting strategy is proposed to fabricate the "hydroplastic wood" with shape and stiffness switchable properties via cell wall wetting, cell wall softening and subsequent moisture evaporation. Therein, a wetting agent with low surface tension and low viscosity is utilized for covering the rough surface of solid wood to form a liquid lubricating layer, thereby increasing the interfacial wettability and achieving uniform softening of the cell walls. This interface wetting treatment can easily break through the hydro-plasticization process for thick wood (Balsa wood, Ochroma lagopus Swartz, density: 0.25 g/cm3; Pinewood, Pinus armandii, density: 0.38 g/cm3). Additionally, the capillary force arising from moisture evaporation induces the self-densification of oriented cellulose nanofibrils and achieves moisture-mediated shape design capabilities through periodic saturation-dehydration. This work makes hydroplastic wood a promising candidate for engineering materials because of its combined advantages of strong durability, formability, and load-carrying capacity.

Impact Behaviour Modelling of Magnetorheological Elastomer Using a Non-Parametric Polynomial Model Optimized with Gravitational Search Algorithm

This paper presents an approach to model the impact behaviour of a dual-acting magnetorheological elastomer (MRE) damper using 4th-order polynomial functions optimized with a gravitational search algorithm. MRE is a type of smart material that can change its mechanical properties in response to an injected current, making it well-suited for a wide range of applications such as vibration absorption, noise cancellation, and shock mitigation. The proposed model uses a combination of polynomial functions designed to predict the nonlinearity of MRE during compression and extension stages. The model is tuned and validated using experimental data from impact tests conducted on the MRE damper under various currents. The results indicate that the developed model can accurately track the impact behaviour of MRE with minimum error. Additionally, an interpolation model is proposed to estimate the appropriate forces for median currents. The interpolation model predicts the force between the upper and lower currents, demonstrating the model's ability to predict MRE behaviour accurately. The main contribution of this study is proposing a non-parametric model of MRE that is able to identify the hysteretic behaviour of the MRE based on specific current applied. In addition, an interpolation model is introduced in this study to cover not only the input current starting from 0 A to 2 A but also the intermediate current such as 0.3 A, 0.7 A, 1.3 A and 1.7 A.

3D printing of stimuli-responsive hydrogel materials: Literature review and emerging applications

Additive manufacturing (AM) aka three-dimensional (3D) printing has been a well-established and unparalleled technology, which is expanding the boundaries of materials science and is exhibiting an enormous potential to fabricate intricate geometries for healthcare, electronics, and construction sectors. In the contemporary era, the combination of AM technology and stimuli-responsive hydrogels (SRHs) helps to create dynamic and functional structures with extreme accuracy, which are capable of changing their shape, functional, or mechanical properties in response to environmental cues such as humidity, heat, light, pH, magnetic field, electric field, etc. 3D printing of SRHs permits the creation of on-demand dynamically controllable shapes with excellent control over various properties such as self-repair, self-assembly, multi-functionality, etc. These properties accelerate researchers to think of unthinkable applications. Additively manufactured objects have shown excellent potential in applications like tissue engineering, drug delivery, soft robots, sensors, and other biomedical devices. The current review provides recent progress in the 3D printing of SRHs, with more focus on their 3D printing techniques, stimuli mechanisms, shape-morphing behaviors, and their functional applications. Finally, current trends and future roadmap of additively manufactured smart structures for different applications have also been presented, which will be helpful for future research. This review holds great promise for providing fundamental knowledge about SRHs to fabricate structures for diverse applications.

Investigation on the crystal plasticity of α phase Ti-6Al-4V based on nano-indentation simulation and experiment

Ti-6Al-4V parts are usually hypothesized as isotropic mechanical properties during micro-machining operation. However, the crystal anisotropic mechanical property is an influential factor in the machining of crystals with different sizes and orientations. The hypothesis causes distinct variation in predicting machining force, and consequently the surface integrity cannot be exactly predicted in the micro-machining. Actually, Ti-6Al-4V parts are pseudo isotropy composed of grains with different orientations, elastic modulus, and hardness. Simultaneously, the initiation mode of plastic slip system varies with the grain orientation when the crystal is subjected to an applied load. It is challengeable to evaluate the effect of crystal orientation on its macroscopic properties, either by traditional experimental methods or macroscopic finite element analysis. Nano-indentation provides one novel method to investigate the plastic deformation of selected grains with specific orientations to characterize their mechanical response properties. This research aims to investigate the plastic behavior of α phase Ti-6Al-4V with different orientation grains by means of nano-indentation experiment and crystal plastic finite element method. In the study, single crystals of α phase are classified into “hard grains” (θ < 30°), “soft grains” (θ > 60°) and “normal grains” (30° < θ < 60°) by defining the crystal inclination angle (θ). The elastic modulus and hardness of hard grains are 9% and 28% larger than those of soft grains, respectively. This difference in mechanical properties depends on the slip system that dominates the plastic deformation behavior. The plastic deformation of soft grains is dominated by prismatic slip (48%), while hard grains are accommodated to plastic deformation by basal slip (51%). The average total cumulative shear strain of the soft grains is double that of the hard grains at a maximum load of 10 mN. Meanwhile, the sensitivity analysis is performed to evaluate the effects of the three sets of < a > slip systems and the two sets of < c + a > slip systems on plastic deformation with different grain orientations. The research contributes to the understanding of the plastic deformation mechanism in micro-machining and the exactly predicting the surface integrity generated from micro-machining.

Application of hyperbolic differential quadrature method for vibration responses of the electrorheological disk

The Electrorheological (ER) disk is a widely used smart material in various engineering applications due to its ability to change its mechanical properties in response to electric fields. The vibration analysis of such a disk is essential for understanding its dynamic behavior and designing efficient control strategies. In this paper, the hyperbolic differential quadrature method (HDQM) is applied to investigate the vibration responses of the ER disk. Both first and higher-order shear deformation theories are incorporated for modeling displacement fields in sandwich disks. In the interface of the layers’ compatibility conditions are applied. The HDQM is a numerical technique based on the differential quadrature method that can handle problems with hyperbolic partial differential equations. The validity and accuracy of the proposed method are confirmed by comparing the results with those obtained by previous studies. Finally, the effects of disk geometry, and boundary conditions on the natural frequencies and mode shapes of the ER disk are investigated. The results demonstrate the effectiveness of the HDQM in solving the vibration problems of the ER disk and provide valuable insights for designing ER-based devices.

Hysteresis Behavior Modeling of Magnetorheological Elastomers under Impact Loading Using a Multilayer Exponential-Based Preisach Model Enhanced with Particle Swarm Optimization.

Magnetorheological elastomers (MREs) are a type of smart material that can change their mechanical properties in response to external magnetic fields. These unique properties make them ideal for various applications, including vibration control, noise reduction, and shock absorption. This paper presents an approach for modeling the impact behavior of MREs. The proposed model uses a combination of exponential functions arranged in a multi-layer Preisach model to capture the nonlinear behavior of MREs under impact loads. The model is trained using particle swarm optimization (PSO) and validated using experimental data from drop impact tests conducted on MRE samples under various magnetic field strengths. The results demonstrate that the proposed model can accurately predict the impact behavior of MREs, making it a useful tool for designing MRE-based devices that require precise control of their impact response. The model's response closely matches the experimental data with a maximum prediction error of 10% or less. Furthermore, the interpolated model's response is in agreement with the experimental data with a maximum percentage error of less than 8.5%.

Possible Mechanisms of Stiffness Changes Induced by Stiffeners and Softeners in Catch Connective Tissue of Echinoderms

The catch connective, or mutable collagenous, tissue of echinoderms changes its mechanical properties in response to stimulation. The body wall dermis of sea cucumbers is a typical catch connective tissue. The dermis assumes three mechanical states: soft, standard, and stiff. Proteins that change the mechanical properties have been purified from the dermis. Tensilin and the novel stiffening factor are involved in the soft to standard and standard to stiff transitions, respectively. Softenin softens the dermis in the standard state. Tensilin and softenin work directly on the extracellular matrix (ECM). This review summarizes the current knowledge regarding such stiffeners and softeners. Attention is also given to the genes of tensilin and its related proteins in echinoderms. In addition, we provide information on the morphological changes of the ECM associated with the stiffness change of the dermis. Ultrastructural study suggests that tensilin induces an increase in the cohesive forces with the lateral fusion of collagen subfibrils in the soft to standard transition, that crossbridge formation between fibrils occurs in both the soft to standard and standard to stiff transitions, and that the bond which accompanies water exudation produces the stiff dermis from the standard state.