Conductive hydrogels are regarded as an optimal flexible electronic material. Nevertheless, simultaneously achieving excellent mechanical and conductive properties in hydrogels necessitates attention. The high mechanical properties of hydrogels were achieved by employing a strategy that involves constructing a nano-structure network inspired by the highly ordered structure of dragonfly wings. The conductivity and anti-freezing of the hydrogel were enhanced through the construction of a conductive mechanism, achieved by combining ions with nano-particles. The hydrogel exhibits outstanding properties, including anti-freezing, ultra-stretchable (6000%), impressive conductivity (16.2Sm-1), a transparency level of up to 91.2%, and excellent sensitivity in strain sensors. Regulation of the hydrogel matrix's topology and the formation of bionic nano-structures synergistically establish the hydrogel's ultra-stretching and energy dissipation mechanism. The high conductivity of the hydrogel is achieved by constructing a synergistic conduction pathway, which incorporates nano-particles and ions. Under the stretching-induced effect of hydrogel, it facilitates a more efficient path for conduction, thereby enhancing its conductivity and sensing sensitivity under significant strains. Subsequently, this hydrogel was successfully applied to wearable sensor technology, demonstrating surprisingly remarkably prompt non-delayed sensing performance even at low-temperatures. It presents abundant opportunities for expanding the application of hydrogels in flexible electronics.
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