Magnetic Susceptibility Measurements Research Articles

Europium spin dilution in the ferromagnetic solid solution Eu4–x Ca x PdMg

Abstract The intermetallic compounds Eu4PdMg and Ca4PdMg form a complete solid solution Eu4–x Ca x PdMg. Further phase analytical studies showed that Eu4PdMg does not allow substitution with strontium. The polycrystalline Eu4–x Ca x PdMg samples were characterized by powder X-ray diffraction. The structure of Eu2.233(6)Ca1.767PdMg was refined from single crystal X-ray diffractometer data: Gd4RhIn type, F 4 ‾ 3m, a = 1,475.42(10) pm, wR2 = 0.0476, 674 F 2 values, 23 variables. Temperature dependent magnetic susceptibility measurements show a drastic decrease of the Curie temperature with increasing calcium substitution. 151Eu Mössbauer spectra of Eu4PdMg and Eu2Ca2PdMg confirm the divalent ground state of europium.

Geophysical Methods Applied to the Mineralization Discovery of Rare-Earth Elements at the Fazenda Buriti Alkaline Complex, Goiás Alkaline Province, Brazil

In this case study, exploratory techniques were applied for the selection of potential targets for rare-earth elements (REEs) in the Fazenda Buriti Mafic–Ultramafic Complex, part of the Goiás Alkaline Province. The results of the processing and interpretation of aeromagnetic and radiometric data associated with the direct measurements of magnetic susceptibility and radiometry in rock samples collected in the study area allowed for the characterization and delimitation of the geological units. The application of Boolean logic in the radiometric data of uranium (U), thorium (Th), and the U/Th ratio allowed for the generation of a prospective map with the delimitation of two exploration targets. A 100 m deep exploratory drill hole was drilled at the main target, intercepting REE mineralization and validating the developed prospective technique. The results contributed to the detailing of a 1:25,000 scale geological map and the interpretation of shallow and deep magnetic structures. Petrophysical data allowed for the estimation of the magnetite content in the main units of the study area. The delimitation of targets with the applied method proved to be efficient after positive geochemical results for REE from the drilled rocks. The total sum of ∑REEs reached 19,629 ppm in the superficial part of the hole and 3,560 ppm in the fresh rock. Mineralogical results in two follow-up drill core samples indicated that monazite was the main REE mineral. Total REE ranged from 34,746 ppm in HG1 to 30,017 ppm in HG2, with LREEs in its majority. The bulk and clay XRD analyses indicated that monazite consisted of 5.7% (HG1) and 5.1% (HG2). The mineral abundance from the TIMA-X analysis indicated 4.2% (HG1) and 4.4% (HG2) in monazite content.

A Nanosized {NiII 18} Cluster with a 'Flying Saucer' Topology Exhibiting Slow Relaxation of Magnetisation Phenomena at Both 15 K and 1.3 K.

A high-nuclearity {Ni18} complex (1) with a unique 'flying saucer' motif has been prepared from the organic chelate, α-methyl-2-pyridine-methanol (mpmH), in conjunction with bridging azido (N3 -) and peroxido (O2 2-) ligands. Magnetic susceptibility measurements revealed the presence of both ferro- and antiferromagnetic exchange interactions between the metal centres in 1, and the stabilization of spin states with appreciable S values at two different temperature regimes. The end-on bridging azido and alkoxido groups are in all likelihood the ferromagnetic mediators, while the η3:η3:μ6-bridging peroxides most likely promote the antiparallel alignment of the metals' spin vectors, yielding an overall non-zero spin ground state for the centrosymmetric compound 1. Furthermore, the {Ni18} nanosized cluster behaves as a single-molecule magnet, exhibiting magnetic hysteresis at low temperatures and two relaxation processes at 15 K and 1.3 K, a very rare phenomenon in polynuclear magnetic 3d-metal clusters.

Non-stoichimometric square sheets in RSe2−x (x ∼ 1/6) (R = Gd and Tb)

The application of optimal electron count has proven effective in predicting the existence of complex structural topologies containing electron-rich polyanionic networks, including linear and zig-zag chains, square planar structures, and simple cubic lattices of main group elements. In this study, we report the successful synthesis of a new family of magnetic compounds, RSe2−x (x ∼ 1/6) (R = Gd and Tb), using KCl flux. The resulting crystal structure of RSe2−x is tetragonal, exhibiting PbFCl-type symmetry with space group P4/nmm. Chemical composition analysis consistently reveals x ∼ 1/6, indicating chalcogen-deficient square sheets. This observation suggests that RSe2−x adheres to the 14-electron rule, as the total valence electrons per RSe2−x (x ∼ 1/6) is 14 e−. In GdSe2−x (x ∼ 1/6), the magnetic susceptibility measurement displays a lambda-shaped peak around 8 K, indicating an antiferromagnetic-type transition. However, the positive Curie–Weiss temperature (θCW) suggests the presence of an additional ferromagnetic interaction, which may result from the large magnetic moment of the Gd atoms. In contrast, TbSe2−x (x ∼ 1/6) exhibits antiferromagnetic ordering. Chemical bonding analysis also indicates that the strong Se–Se antibonding in the square net may be related to Se deficiency. Our work shed light on ellucidating the interplay between chemical rule, defects, and magnetism.

Frustrated Radical Pairs: From Fleeting Intermediates to Isolable Species.

We present the design and comprehensive investigation of stable para-substituted triarylamine-2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) radical ion pairs (RIPs) generated via single-electron transfer (SET). We quantified the degree of SET in both solution and solid phases, utilising a suite of spectroscopic techniques including IR, EPR, NMR, and single-crystal X-ray diffraction (SC-XRD). Our findings reveal that the extent of SET is significantly influenced by the nature of the substituents (MeO > tBu > Br) and the polarity of the solvent (MeCN > DCM > toluene). The radical ion pair [(pMeOPh)3N]•+[DDQ]•- was unambiguously identified using EPR and UV-vis spectroscopy, and its structure was confirmed by SC-XRD. Detailed analysis indicates an open-shell singlet ground state with a thermally accessible triplet state, as corroborated by EPR, magnetic susceptibility measurements, and DFT calculations. This study offers crucial insights into the mechanistic pathways of RIP formation and tuning both in solution and solid states, laying the groundwork for future exploration of their reactivity and potential applications.

Superconducting properties and electronic structure of CuAl2-type transition-metal zirconide Fe1-xNixZr2

CuAl2-type transition-metal (Tr) zirconides are a superconductor family, and the Tr-site element substitution largely modifies its transition temperature (Tc). Here, we synthesized polycrystalline samples of Fe1-xNixZr2 by arc melting. The crystal structure and the superconducting properties were studied through synchrotron X-ray diffraction, magnetic susceptibility, electrical resistivity, and specific heat measurements. Bulk superconductivity was observed for 0.4 ≤ x ≤ 0.8, and the highest Tc of 2.8 K was observed for x = 0.6. The obtained superconductivity phase diagram exhibits a dome-shaped trend, which is similar to unconventional superconductors, where magnetic fluctuations are essential for superconductivity. In addition, from the c/a lattice constant ratio analysis, we show the possible relationship between the suppression of bulk superconductivity in the Ni-rich compositions and a collapsed tetragonal transition.

Structural Effect of N-7 Alkylation in 6-Chloropurine on Cu (II) Binding: Effect of Anions and Magnetic Studies.

This study investigates the anion-directed assembly of discrete copper (II) complexes. The ligands of choice are two N7-alkyl-purine-based neutral ligands. These ligands facilitate the exclusive coordination through the N3 and N9 positions, preventing polymeric chain formation. Perchlorate ions promoted the formation of discrete paddlewheel-like complexes with the general formula [Cu2(μ-Pur)4(CH3CN)2]4+, while chloride ions yielded chloride-bridged dimers of the form [Cu2(Pur)2(μ-Cl)2Cl2]. Copper-copper bond distances within these complexes ranged from 2.92 to 2.98 Å. Magnetic susceptibility measurement of chloride-bridged complexes exhibited antiferromagnetic coupling, whereas paddlewheel complexes displayed more complex alternating ferromagnetic and antiferromagnetic interactions. Chloride-bridged compounds exhibited strong near-infrared absorption.

Superconductivity and nematic order in a new titanium-based kagome metal CsTi3Bi5 without charge density wave order

The cascade of correlated topological quantum states in the newly discovered vanadium-based kagome superconductors, AV3Sb5 (A = K, Rb, and Cs), with a Z2 topological band structure has sparked immense interest. Here, we report the discovery of superconductivity and electronic nematic order in high-quality single-crystals of a new titanium-based kagome metal, CsTi3Bi5, that preserves the translation symmetry, in stark contrast to the charge density wave superconductor AV3Sb5. Transport and magnetic susceptibility measurements show superconductivity with an onset superconducting transition temperature Tc of approximately 4.8 K. Using the scanning tunneling microscopy/spectroscopy and Josephson scanning tunneling spectroscopy, we demonstrate that the single crystals of CsTi3Bi5 exhibit two distinct superconducting gaps. Furthermore, the superconducting gaps break the six-fold crystal rotational symmetry down to two-fold. At low energies, we find that the quasiparticle interference patterns exhibit rotational-symmetry-breaking C2 patterns, revealing a nematic ordered normal state with the same nematic direction as in the superconducting state. Our findings uncover a novel superconducting state in CsTi3Bi5 and provide new insights for the intrinsic electron liquid crystal phases in kagome superconductors.

Novel Imine Complexes Incorporating ZrO(II), VO(II), and Pd(II) Cations: Synthesis, DFT Calculation, Molecular Docking, Antimicrobial, and Antitumor Activity

ABSTRACTNovel imine complexes of ZrO(II), VO(II), and Pd(II) have been synthesized and described using IR, TGA, UV/Vis, and 1HNMR methods, along with powder X‐ray diffraction (XRD), elemental (CHN) analysis, mass spectrometry, molar conductance, and magnetic susceptibility measurements. Conductivity measurements indicate that none of the complexes function as electrolytes. Magnetic susceptibility data confirm the paramagnetism of the VO(II) complex, while ZrO(II) and Pd(II) complexes exhibit diamagnetic properties. Various analyses suggest that divalent cations favor a 1:1 metal‐to‐ligand ratio. Biological studies demonstrated that all complexes possess significant antimicrobial activity against a range of bacterial and fungal strains. We also observed that the antimicrobial potency of the metal complexes follows the order: ZrO(II) > Pd(II) > VO(II) > H2A, with the ZrO(II) complex showing the highest inhibition zone (28 mm) against Gram‐negative bacteria. The antifungal activity against Aspergillus flavus increases in the order VO(II) > ZrO(II) > Pd(II) > H2A. Additionally, the complexes exhibit high cytotoxicity against carcinoma cell lines, including the HepG‐2, when compared with the clinically proven vinblastine. Density functional theory (DFT) calculations were performed to elucidate the equilibrium geometry of the imine ligand and its complexes at the B3LYP level of theory, using the Gaussian 09 program with 6‐311G++(dp) basis set for C, H, O, N, and Cl atoms, and lanl2dz for Pd, V, and Zr atoms. Finally, docking studies revealed potential binding modes at the active sites of bacterial and fungal receptors.

Heavy metal contamination in soils of industrial estates of Tamil Nadu, India and source identification by magnetic susceptibility.

An increase in erratic industrial activity has been a major contributing factor to the significant contamination in environmental matrices. This study aimed to ascertain the level of heavy metal contamination in soils in major industrial estates of Tamil Nadu as well as the threats to human health and the environment that concomitant with it. This led to the use of the total reflection X-ray fluorescence (TXRF) spectroscopy technique to analyse 31 soil samples. Thus, the mean heavy metal concentrations were found to be in the ascending order: As < Ni < Pb < V < Cu < Zn < Cl < Mn < Sr < Cr < Al < Fe. Pb, Cr, Cu, As, and Zn have been identified as predominantcontaminants in the study area using the conventional pollution indices such as geo-accumulation index (Igeo), contamination factor (CF), and enrichment factor (EF). The magnetic susceptibility measurements indicates that the percentage of frequency dependence of magnetic susceptibility of the studied soil samples varied from 0.88 to 11.15 and that represents the presence of admixture ofsuperparamagnetic (SP) particles in the soil samples. From the results of multivariate statistical analyses, the sources ofidentified heavy metals were classified as anthropogenic sources(Cr, Cu, Pb, As, and Zn),natural sources(V, Mn, Fe, Ni, and Sr ),and intermediate sources (Al and Cl).

Dynamic Magnetic Susceptibility Method in Studies of Coordination Compounds

The measurement of the dynamic magnetic susceptibility is a universal method, which is used for the evaluation of magnetic properties of single molecule magnets by scientists all over the world. An information in the Russian scientific literature that can be useful for practical mastering of this method is presently insufficient. To fill this gap, in this work we present a detailed procedure of a magnetochemical experiment for observing slow magnetic relaxation in coordination compounds of 3d- and 4f-element ions and the complete characterization of the dynamics of the magnetic behavior. Special attention is given to usually omitted but important details related to all stages of studying the magnetic relaxation dynamics. The main variants of sample preparation are described, the logics of the construction of a measuring sequence and the procedure of experimental data processing are discussed, and advantages and drawbacks of some programs of the calculation of magnetic relaxation dynamics data are considered. The main concepts and equations used in experimental data analysis are presented, and the primary conclusions that can be made from the obtained results are proposed.

Unveiling trends in migration of iron-based nanoparticles in saturated porous media

Nanoscale zero-valent iron (nZVI) particles are routinely used for environmental remediation, but their transport dynamics in different settings remain unclear, hindering optimization. This study introduces a novel approach to predicting nZVI transport in saturated porous model environment. The method employs advanced long column devices for real-time monitoring via controlled magnetic susceptibility measurements. Numerical modeling with a modified version of the MNMs 2023 software was then used to predict nZVI and its derivatives mobility in field-like conditions, offering insights into the radius of influence (ROI) and shape factor (SF) of their distribution. A standard nZVI precursor was compared with its four major commercial derivatives: nitrided, polyacrylic acid-coated, oxide-passivated, and sulfidated nZVI. All these iron-based nanoparticles exhibited identical particle sizes, morphologies, surface areas, and phase compositions, isolating surface properties, dominated by charge, as the sole variable affecting their mobility. The study revealed optimal transport when the surface charge of nZVI and its derivatives was strongly negative, while rapid aggregation of nZVI derivatives due magnetic attraction reduced their mobility. Modeling predictions based on column scale-up, indicated that detectable concentrations of 20 g L⁻1 were found at distances ranging from 0.4 to 1.1 m from the injection well. Slightly sulfidated nZVI traveled farther than the nZVI precursor and ensured more homogenous particle distribution around the well. Organically modified nZVI migrated the longest distances but showed particle accumulation close to the injection point. The findings suggest that minimal sulfidation combined with organic modification of nZVI surfaces may effectively enhance radial and vertical nZVI distribution in aquifers. Such improvements increase the commercial viability of modified nZVI, reduce their adverse impacts, and boosts their practical applications in real-world scenarios.

Single-Step Synthesis of An Ideal Chain Antiferromagnet [H2(4,4'-bipyridyl)](H3O)2Fe2F10 with Spin S=5/2.

One-dimensional (1D) magnets are of great interest owing to their intriguing quantum phenomena and potential application in quantum computing. We successfully synthesized an ideal antiferromagnetic spin S=5/2 chain compound [H2(4,4'-bpy)](H3O)2Fe2F10 (4,4'-bpy=4,4'-bipyridyl) 1, using a single-step low-temperature hydrothermal method under conditions that favors the protonation of the bulky bidentate ligand 4,4'-bpy. Compound 1 consists of well-separated (Fe3+-F-)∞ chains with a large Fe-F-Fe angle of 174.8°. Both magnetic susceptibility and specific heat measurements show that 1 does not undergo a magnetic long-range ordering down to 0.5 K, despite the strong Fe-F-Fe intrachain spin exchange J with J/kB=-16.2(1) K. This indicates a negligibly weak interchain spin exchange J'. The J'/J value estimated for 1 is extremely small (<2.8×10-6), smaller than those reported for all other S=5/2 chain magnets. Our hydrothermal synthesis incorporates both [H2(4,4'-bpy)]2+ and (H3O)+ cations into the crystal lattice with numerous hydrogen bonds, hence effectively separating the (Fe3+-F-)∞ spin chains. This single-step hydrothermal synthesis under conditions favoring the protonation of bulky bidentate ligands offers an effective synthetic strategy to prepare well-separated 1D spin chain systems of magnetic ions with various spin values.

Single‐Step Synthesis of An Ideal Chain Antiferromagnet [H2(4,4′‐bipyridyl)](H3O)2Fe2F10 with Spin S=5/2

AbstractOne‐dimensional (1D) magnets are of great interest owing to their intriguing quantum phenomena and potential application in quantum computing. We successfully synthesized an ideal antiferromagnetic spin S=5/2 chain compound [H2(4,4′‐bpy)](H3O)2Fe2F10 (4,4′‐bpy=4,4′‐bipyridyl) 1, using a single‐step low‐temperature hydrothermal method under conditions that favors the protonation of the bulky bidentate ligand 4,4′‐bpy. Compound 1 consists of well‐separated (Fe3+−F−)∞ chains with a large Fe−F−Fe angle of 174.8°. Both magnetic susceptibility and specific heat measurements show that 1 does not undergo a magnetic long‐range ordering down to 0.5 K, despite the strong Fe−F−Fe intrachain spin exchange J with J/kB=−16.2(1) K. This indicates a negligibly weak interchain spin exchange J′. The J′/J value estimated for 1 is extremely small (&lt;2.8×10−6), smaller than those reported for all other S=5/2 chain magnets. Our hydrothermal synthesis incorporates both [H2(4,4′‐bpy)]2+ and (H3O)+ cations into the crystal lattice with numerous hydrogen bonds, hence effectively separating the (Fe3+−F−)∞ spin chains. This single‐step hydrothermal synthesis under conditions favoring the protonation of bulky bidentate ligands offers an effective synthetic strategy to prepare well‐separated 1D spin chain systems of magnetic ions with various spin values.

Baseline magnetic susceptibility measurements of rocks in the Precambrian basement terrain of southwestern Nigeria

Baseline magnetic susceptibility measurements of rocks in the Precambrian basement terrain of southwestern Nigeria

Selective Metal‐Coordinated Nanodrugs Based on Thiazine Moiety for Anticancer Therapeutics: Spectroscopic, Theoretical, and Molecular Docking Studies

ABSTRACTThe current study involved production, comprehensive structural analysis, and physicochemical characterizing of two distinctive complexes namely, Cu(TBH) and Zn(TBH); TBH donor ligand: N′‐(1‐(3,6‐dihydro‐4‐hydroxy‐2,6‐dioxo‐2H‐1,3‐thiazin‐5‐yl)ethylidene)‐2‐hydroxybenzohydrazide) using a wide range of analytical methods, including elemental analysis, UV–Vis, FT‐IR, and 1HNMR spectrometry, molar conductivity and magnetic susceptibility measurements, and thermal analysis. According to the findings, chelation can occur through O, N, and O donor atoms of monoanionic chelator for generating mono‐nuclear chelates with tetrahedral geometry for Cu (II) and octahedral geometry for Zn (II). The anticarcinogenic ability of TBH chelator and its coordinated compounds against human liver cancer (HepG‐2) was investigated. The Cu(TBH) complex was found to have selective and promising anticancer activity against a liver cancer cell line, with lower IC50 (liver carcinoma cell line) and higher IC50 (normal human cell line) values than other produced compounds and standard drugs. Utilizing DFT computations, the molecular structures of the TBH and its complexes were verified, offering a detailed understanding of their quantum chemical characteristics. A quantitative structure–activity relationship (QSAR) model, which illustrates the association between DFT‐computed descriptors and biological activities pIC50, was also created using multiple linear regression (MLR) on the synthesized compounds as anticancer medicines. Additionally, there are no issues with the produced compounds' oral bioavailability according to (ROF) Lipinski's rule of five. Furthermore, docking studies of the synthesized TBH chelator and its chelates with CDK2 kinase have been performed to validate the biological findings. According to our findings, the novel Cu(TBH) nanodrug exhibits considerable cytotoxic activity, prompting further study into its pharmacological profile and exploring its potential in drug development.

Synthesis and catalytic application to form cyclic carbonates of novel Pd(II) Cu(II), and Fe(II) benzoate-based Schiff base metal complexes

This work describes the synthesis and characterisation of six novel Schiff base complexes, Cu(II), Pd(II), and Fe(II), which, under the right circumstances, function as very efficient catalysts for the production of cyclic carbonates from CO2 and epoxides. FT-IR spectroscopy, elemental analysis, UV–Vis spectroscopy, molar conductivity, melting point, and magnetic susceptibility measurements are among the spectroscopic methods used to characterize newly synthesized complexes. The molar conductivity values, ranging from 2.58 to 4.03 µS/cm, suggest that the complexes exhibit no molar conductivity. Co-catalysts, such as 4-(dimethylamino)pyridine, pyridine, triethylamine, and triphenyl phosphine, were used in these processes, both with and without one. 4-(Dimethylamino)pyridine was used as the co-catalyst in the catalytic studies. Additionally, a number of variables that affect the cycloaddition process were examined, including the temperature, CO2 pressure, reaction time, and co-catalyst. All novel catalysts exhibited exceptional catalytic activity and selectivity in the catalytic assays. Regarding the coupling of CO2 and epichlorohydrin as epoxides, the L2-Cu catalyst outperformed other catalysts in terms of catalytic activity (90.7%) and selectivity (98.9%).

Chloride bibridged Cu(II) chains with n-Br-2-pyridone molecules

The compounds catena-[diaquadichloridocopper(II)] bis(4-bromo-2-pyridone) (1) and catena-[bis(5-bromo-2-pyridone)dichloridocopper(II)] (2) have been prepared and characterized crystallographically. Both show bichloride bridged chains of Cu(II) ions with coordinated water molecules in the axial sites for 1 and coordinated 5-bromo-2-pyridone molecules in the axial sites for 2. 1 incorporates two 4-bromo-2-pyridone molecules co-crystallized in the lattice. Variable temperature magnetic susceptibility measurements for 1 indicate the presence of weak antiferromagnetic interactions [J/kB = −7.06(5) K] similar to copper(II) chloride dihydrate, but without that compound’s significant inter-chain interactions and Néel transition.

Synthesis, structure, and solution chemistry of mixed-ligand oxidovanadium(IV) complexes incorporating ONO donor hydrazone ligands

Four mixed-ligand oxidovanadium(IV) complexes, [VIVO(L1-4)(phen)], 1-4, incorporating tridentate dibasic ONO donor hydrazone ligands (H2L1-4, general abbreviation H2L) derived from the condensation of 2-picolinyl hydrazide with 2-hydroxy acetophenone and its 5-substituted derivatives as primary ligands and 1,10-phenanthroline (phen) as auxiliary ligand have been synthesized in excellent yields. The complexes were characterized by elemental analyses, magnetic susceptibility measurements, and various spectral (e.g. IR, UV–Vis and EPR) studies. The molecular structure of one of the four complexes has been determined by single-crystal X-ray diffractometry. In 1, the hydrazone ligand is meridionally disposed of, coordinating through one enolic-O, one phenolic-O, and one imine-N. The other basal position is occupied by one pyridine-N of the phen moiety. The axial positions are occupied by one oxido-O atom and the other pyridine-N atom of the phen moiety. The complexes are paramagnetic with one unpaired electron (μeff ≈ 1.73 BM), suggesting no interaction with the neighboring molecules and are EPR active. The complexes display two d-d transitions, one near 725 and the other near 840 nm due to d xy → d xz , d yz and d xy → d x 2 − y 2 transitions, respectively. The other d-d transition associated with d xy → d z 2 transition was not observed as it falls in the UV region, which is masked by highly intense intra-ligand transitions. The complexes display one-electron oxidation peaks in the +0.75 to +0.89 V vs. Ag/AgCl region in the CH3CN solution that show a linear relationship with the Hammett parameter (σ) of the substituents in the aryloxy ring.

Investigation of slow magnetic relaxation in a series of 1D polymeric cyclobutane-1,1-dicarboxylates based on LnIIIVIV2 units (LnIII = Tb, Dy, Ho, Er, Tm, Yb): rare examples of VIV-4f single-molecule magnets.

The reactions of VOSO4·3H2O with Na2(cbdc) (cbdc2- - dianion of cyclobutane-1,1-dicarboxylic acid) and lanthanide(III) nitrates taken in a molar ratio of 1 : 2 : 1 were found to yield a series of isostructural heterometallic compounds [NaLn(VO)2(cbdc)4(H2O)10]n (1Ln, Ln = Tb, Dy, Ho, Er, Tm, Yb). These compounds are constructed from trinuclear anionic units [Ln(VO)2(cbdc)4(H2O)8]- ({LnV2}-) linked by Na+ ions into 1D polymeric chains. The crystal structures of 1Dy and 1Er were determined by single-crystal X-ray diffraction (XRD), and their isostructurality with 1Tb, 1Ho, 1Tm, and 1Yb was proved by powder X-ray diffraction (PXRD). According to alternating current (ac) magnetic susceptibility measurements, 1Dy, 1Er, and 1Yb exhibited field-induced slow relaxation of magnetization. Compound 1Er is the first representative of ErIII-VIV single-molecule magnets. Measuring the temperature dependences of the phase memory time (Tm) for 1Dy and 1Yb using pulsed EPR spectroscopy allowed us to observe the phenomenon of phase relaxation enhancement (PRE) at temperatures below 30 K. In future, this phenomenon may contribute to the evaluation of relaxation times of the lanthanide ions.