Closed-loop supply chains (CLSCs) play a crucial role in promoting sustainable resource management, yet their implementation faces challenges in balancing economic viability with environmental goals. While existing research has explored various aspects of CLSC operations, the interplay between government subsidies and risk-averse behavior of supply chain members remains understudied, particularly in systems involving third-party recyclers. This gap hinders the development of effective policies and management strategies for sustainable CLSCs. Herein, we employ a Stackelberg game-theoretic model to investigate decision-making processes in CLSCs under four distinct subsidy scenarios, incorporating risk aversion through mean-variance utility functions. Our results reveal that subsidy effectiveness significantly depends on remanufacturing costs and risk attitudes of supply chain participants. When remanufacturing costs are high, subsidizing third-party recyclers yields superior environmental and economic outcomes, whereas manufacturer subsidies prove more effective when these costs are low. Moreover, we identify critical thresholds in subsidy levels and risk aversion that alter decision-making patterns. These findings provide a framework for designing targeted subsidy policies and risk management strategies in CLSCs, advancing the field of sustainable supply chain management by offering nuanced insights into the complex dynamics between government interventions, risk preferences, and CLSC performance.