Isotopic and elemental proxies are useful for discerning the original compositions of ancient rocks subject to later diagenetic/thermal alteration, low-rank metamorphism, outcrop weathering, etc. Recent work in the Cariaco Basin [Chem. Geol. 195 (2003) 131] has shown a high correlation between total organic carbon (TOC) content and Mo normalized to Al in these modern euxinic sediments: microlaminated, dark olive gray, silty clay (0–11.6 kyr BP), %TOC=1486∗(Mo/Al)+2.8, n=13, r 2=0.52, mean rate of deposition=36 cm/kyr; distinctly microlaminated, dark olive gray, clayey mud (11.6–14.5 kyr BP), %TOC=1622∗(Mo/Al)+0.22, n=15, r 2=0.89, mean rate of deposition=79 cm/kyr. Here, we use these relationships to estimate the original TOC contents of ancient black shales with overall characteristics similar to those of the modern Cariaco sediments. These “Group IV” black shales as defined by Quinby-Hunt and Wilde [Econ. Geol. 91 (1996) 4] are characterized by relatively high concentrations of V, Mo and Co but low Mn contents. The Cariaco regressions and those from the Carboniferous of Iowa and the Devonian of New York were used to estimate the ‘original’ TOC contents for Lower Ordovician black shales of the Baltica and Avalonia plates, where C org values were not taken. For individual samples, the Carboniferous regression produced TOC values approximately double that derived from the regression equation of the Cariaco Basin lower anoxic zone. Such variations among the results from the four regressions suggest that there is no universal proxy for TOC using Mo/Al. These calculated TOC values, however, are consistent with the higher levels of primary production predicted from the paleogeographic settings of these intervals. In general, the Mo proxy for original TOC content, while approximate, works for oxygen-deficient sites of deposition where other proxies for C loss, such as C org/S py ratios in normal (oxic) marine shales, do not apply. Estimates of original TOC from Mo content in samples spanning the geologic record, combined with paleogeography and paleoecology, should be useful in estimating pathways of C synthesis and remineralization in ancient oceans and initial hydrocarbon potential of petroleum source rocks.